Research Article

Improved Photocatalytic Degradation of Methyl Orange Dye in UV Light Irradiation by K2Ti6O13 Nanorods

Volume: 8 Number: 3 August 31, 2021
EN

Improved Photocatalytic Degradation of Methyl Orange Dye in UV Light Irradiation by K2Ti6O13 Nanorods

Abstract

The K2Ti6O13 nanorods (KTNRs) were synthesized by Molten Salt Solution method (MSS) using TiO2 nanoparticles and potassium chloride as precursors. As synthesized KTNRs was characterized by powder X-ray diffraction to know the crystallinity, scanning electron microscopy confirms the rod type morphology with diameter 10 to 12 nm with length up to 80 nm, functional groups were studied with FT-IR spectroscopy, optical property of KTNRs showed the bandgap energy Eg= 3.41 eV by UV-Vis spectrophotometry. The synthesized KTNRs was used as photocatalyst for degradation of the methyl orange dye under UV light illumination. The degradation of methyl orange dye followed the pseudo first order rate law. The kinetics and mechanism of MO dye degradation dye was studied for different photocatalyst dosage 5, 10 and 15 mg of KTNRs, maximum for rate constant is found for 10 mg of photocatalyst.

Keywords

Supporting Institution

DST-Science and Engineering Research Board, Government of India

Project Number

SB/EMEQ-171/2014.

Thanks

Authors acknowledge the financial support from the DST-Science and Engineering Research Board, Government of India

References

  1. 1. Frank SN, Bard AJ. Heterogeneous photocatalytic oxidation of cyanide and sulfite in aqueous solutions at semiconductor powders. J Phys Chem. 1977;81(15):1484–8. DOI: https://doi.org/10.1021/j100530a011.
  2. 2. Ge M, Cao C, Huang J, Li S, Chen Z, Zhang K-Q, et al. A review of one-dimensional TiO 2 nanostructured materials for environmental and energy applications. J Mater Chem A. 2016;4(18):6772–801. DOI: https://doi.org/10.1039/C5TA09323F.
  3. 3. Lieber CM. One-dimensional nanostructures: Chemistry, physics & applications. Solid State Communications. 1998;107(11):607–16. DOI: https://doi.org/10.1016/S0038-1098(98)00209-9.
  4. 4. Xie JL, Guo CX, Li CM. Construction of one-dimensional nanostructures on graphene for efficient energy conversion and storage. Energy Environ Sci. 2014 30;7(8):2559. DOI: https://doi.org/10.1039/C4EE00531G.
  5. 5. Cho C-P, Perng T-P. One-Dimensional Organic and Organometallic Nanostructured Materials. j nanosci nanotechnol. 2008;8(1):69–87. DOI: https://doi.org/10.1166/jnn.2008.N14.
  6. 6. Nowak DJ, Hirabayashi S, Bodine A, Greenfield E. Tree and forest effects on air quality and human health in the United States. Environmental Pollution. 2014;193:119–29. DOI: https://doi.org/10.1016/j.envpol.2014.05.028.
  7. 7. Xu Y, Zhang B. Recent advances in porous Pt-based nanostructures: synthesis and electrochemical applications. Chem Soc Rev. 2014;43(8):2439. DOI: https://doi.org/10.1039/c3cs60351b.
  8. 8. Kilinc N, Cakmak O, Kosemen A, Ermek E, Ozturk S, Yerli Y, et al. Fabrication of 1D ZnO nanostructures on MEMS cantilever for VOC sensor application. Sensors and Actuators B: Chemical. 2014;202:357–64. DOI: https://doi.org/10.1016/j.snb.2014.05.078.

Details

Primary Language

English

Subjects

-

Journal Section

Research Article

Publication Date

August 31, 2021

Submission Date

July 9, 2020

Acceptance Date

June 14, 2021

Published in Issue

Year 2021 Volume: 8 Number: 3

APA
K S, K., & S V, L. (2021). Improved Photocatalytic Degradation of Methyl Orange Dye in UV Light Irradiation by K2Ti6O13 Nanorods. Journal of the Turkish Chemical Society Section A: Chemistry, 8(3), 723-730. https://doi.org/10.18596/jotcsa.766952
AMA
1.K S K, S V L. Improved Photocatalytic Degradation of Methyl Orange Dye in UV Light Irradiation by K2Ti6O13 Nanorods. JOTCSA. 2021;8(3):723-730. doi:10.18596/jotcsa.766952
Chicago
K S, Kiran, and Lokesh S V. 2021. “Improved Photocatalytic Degradation of Methyl Orange Dye in UV Light Irradiation by K2Ti6O13 Nanorods”. Journal of the Turkish Chemical Society Section A: Chemistry 8 (3): 723-30. https://doi.org/10.18596/jotcsa.766952.
EndNote
K S K, S V L (August 1, 2021) Improved Photocatalytic Degradation of Methyl Orange Dye in UV Light Irradiation by K2Ti6O13 Nanorods. Journal of the Turkish Chemical Society Section A: Chemistry 8 3 723–730.
IEEE
[1]K. K S and L. S V, “Improved Photocatalytic Degradation of Methyl Orange Dye in UV Light Irradiation by K2Ti6O13 Nanorods”, JOTCSA, vol. 8, no. 3, pp. 723–730, Aug. 2021, doi: 10.18596/jotcsa.766952.
ISNAD
K S, Kiran - S V, Lokesh. “Improved Photocatalytic Degradation of Methyl Orange Dye in UV Light Irradiation by K2Ti6O13 Nanorods”. Journal of the Turkish Chemical Society Section A: Chemistry 8/3 (August 1, 2021): 723-730. https://doi.org/10.18596/jotcsa.766952.
JAMA
1.K S K, S V L. Improved Photocatalytic Degradation of Methyl Orange Dye in UV Light Irradiation by K2Ti6O13 Nanorods. JOTCSA. 2021;8:723–730.
MLA
K S, Kiran, and Lokesh S V. “Improved Photocatalytic Degradation of Methyl Orange Dye in UV Light Irradiation by K2Ti6O13 Nanorods”. Journal of the Turkish Chemical Society Section A: Chemistry, vol. 8, no. 3, Aug. 2021, pp. 723-30, doi:10.18596/jotcsa.766952.
Vancouver
1.Kiran K S, Lokesh S V. Improved Photocatalytic Degradation of Methyl Orange Dye in UV Light Irradiation by K2Ti6O13 Nanorods. JOTCSA. 2021 Aug. 1;8(3):723-30. doi:10.18596/jotcsa.766952

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