Research Article

Investigation of Chemical Modification and Enzymatic Degradation of Poly(vinyl alcohol)/Hemoprotein Particle Composites

Volume: 8 Number: 2 May 31, 2021
EN

Investigation of Chemical Modification and Enzymatic Degradation of Poly(vinyl alcohol)/Hemoprotein Particle Composites

Abstract

Polyvinyl alcohol (PVA) composite films with different hemp protein particles (HPP) as additives were successfully synthesized by a solution casting method. The properties of HPP-based PVA composites films were investigated. The characterizations of pure PVA and PVA composite films were performed regarding Fourier transform infrared spectroscopy (FTIR), ultra-violet (UV-Vis) to investigate the chemical properties. The formation of hydrogen bond in the PVA-HPP films, which could improve the compatibility of the two components was investigated by FTIR spectroscopy and UV-Vis analysis. The overall results showed that a higher loading of HPP into the PVA matrix improved the chemical interactions significantly. The swelling degree decreased while the water contact angle values increased as the HPP content increased.

Keywords

References

  1. 1. Silva EL da, Reis CA, Vieira HC, Santos JX dos, Nisgoski S, Saul CK, et al. Evaluation Of Poly(Vinyl Alcohol) Addition Effect On Nanofibrillated Cellulose Films Characteristics. CERNE. 2020 Mar;26(1):1–8. Doi: https://doi.org/10.1590/01047760202026012654.
  2. 2. Mendes JF, Paschoalin RT, Carmona VB, Sena Neto AR, Marques ACP, Marconcini JM, et al. Biodegradable polymer blends based on corn starch and thermoplastic chitosan processed by extrusion. Carbohydrate Polymers. 2016 Feb;137:452–8. Doi: https://doi.org/10.1016/j.carbpol.2015.10.093.
  3. 3. Haque ANMA, Remadevi R, Wang X, Naebe M. Biodegradable cotton gin trash/poly(vinyl alcohol) composite plastic: Effect of particle size on physicochemical properties. Powder Technology. 2020 Sep;375:1–10. Doi: https://doi.org/10.1016/j.powtec.2020.07.096.
  4. 4. Tan B, Ching Y, Poh S, Abdullah L, Gan S. A Review of Natural Fiber Reinforced Poly(Vinyl Alcohol) Based Composites: Application and Opportunity. Polymers. 2015 Nov 2;7(11):2205–22. Doi: https://doi.org/10.3390/polym7111509.
  5. 5. Guirguis OW, Moselhey MTH. Thermal and structural studies of poly (vinyl alcohol) and hydroxypropyl cellulose blends. NS. 2012;04(01):57–67. Doi: https://doi.org/10.4236/ns.2012.41009.
  6. 6. Eaysmine S, Haque P, Ferdous T, Gafur MA, Rahman MM. Potato starch-reinforced poly(vinyl alcohol) and poly(lactic acid) composites for biomedical applications. Journal of Thermoplastic Composite Materials. 2016 Nov;29(11):1536–53. Doi: https://doi.org/10.1177/0892705715569824.
  7. 7. Julinová M, Kupec J, Alexy P, Hoffmann J, Sedlařík V, Vojtek T, et al. Lignin and starch as potential inductors for biodegradation of films based on poly(vinyl alcohol) and protein hydrolysate. Polymer Degradation and Stability. 2010 Feb;95(2):225–33. Doi: https://doi.org/10.1016/j.polymdegradstab.2009.10.008.
  8. 8. Gadhave RV, S. K. V, Mahanwar PA, Gadekar PT. Effect of addition of boric acid on thermo-mechanical properties of microcrystalline cellulose/polyvinyl alcohol blend and applicability as wood adhesive. Journal of Adhesion Science and Technology. 2020 Oct 20;1–15. Doi: https://doi.org/10.1080/01694243.2020.1832775.

Details

Primary Language

English

Subjects

Polymer Science and Technologies

Journal Section

Research Article

Publication Date

May 31, 2021

Submission Date

February 11, 2021

Acceptance Date

May 7, 2021

Published in Issue

Year 2021 Volume: 8 Number: 2

APA
Awad, S. (2021). Investigation of Chemical Modification and Enzymatic Degradation of Poly(vinyl alcohol)/Hemoprotein Particle Composites. Journal of the Turkish Chemical Society Section A: Chemistry, 8(2), 651-658. https://doi.org/10.18596/jotcsa.878495
AMA
1.Awad S. Investigation of Chemical Modification and Enzymatic Degradation of Poly(vinyl alcohol)/Hemoprotein Particle Composites. JOTCSA. 2021;8(2):651-658. doi:10.18596/jotcsa.878495
Chicago
Awad, Sameer. 2021. “Investigation of Chemical Modification and Enzymatic Degradation of Poly(vinyl Alcohol) Hemoprotein Particle Composites”. Journal of the Turkish Chemical Society Section A: Chemistry 8 (2): 651-58. https://doi.org/10.18596/jotcsa.878495.
EndNote
Awad S (May 1, 2021) Investigation of Chemical Modification and Enzymatic Degradation of Poly(vinyl alcohol)/Hemoprotein Particle Composites. Journal of the Turkish Chemical Society Section A: Chemistry 8 2 651–658.
IEEE
[1]S. Awad, “Investigation of Chemical Modification and Enzymatic Degradation of Poly(vinyl alcohol)/Hemoprotein Particle Composites”, JOTCSA, vol. 8, no. 2, pp. 651–658, May 2021, doi: 10.18596/jotcsa.878495.
ISNAD
Awad, Sameer. “Investigation of Chemical Modification and Enzymatic Degradation of Poly(vinyl Alcohol) Hemoprotein Particle Composites”. Journal of the Turkish Chemical Society Section A: Chemistry 8/2 (May 1, 2021): 651-658. https://doi.org/10.18596/jotcsa.878495.
JAMA
1.Awad S. Investigation of Chemical Modification and Enzymatic Degradation of Poly(vinyl alcohol)/Hemoprotein Particle Composites. JOTCSA. 2021;8:651–658.
MLA
Awad, Sameer. “Investigation of Chemical Modification and Enzymatic Degradation of Poly(vinyl Alcohol) Hemoprotein Particle Composites”. Journal of the Turkish Chemical Society Section A: Chemistry, vol. 8, no. 2, May 2021, pp. 651-8, doi:10.18596/jotcsa.878495.
Vancouver
1.Sameer Awad. Investigation of Chemical Modification and Enzymatic Degradation of Poly(vinyl alcohol)/Hemoprotein Particle Composites. JOTCSA. 2021 May 1;8(2):651-8. doi:10.18596/jotcsa.878495

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