Synthesis of 2,3-Dihydroxypropylsulfanyl Derivative Nonionic Surfactants and Their Inhibition Activities Against Metal Corrosion in Acidic Media

Yıl 2018, Cilt: 5 Sayı: 2, 333 - 346, 01.01.2018

Serkan Öztürk Sebghatullah Mudaber Ayhan Yıldırım

https://doi.org/10.18596/jotcsa.309423

Cited By: 1

Öz

Metallic corrosion is one of the most important
problem in various industrial fields. One of the most effective methods to deal
with metallic corrosion is to design and use appropriate organic corrosion
inhibitors. In the present study, various amide-based, sulfur-containing
nonionic surfactants were synthesized and characterized by spectroscopic
methods. The corrosion inhibition properties of these synthesized compounds
were investigated. For this purpose, mild steel coupons were immersed for 24
hours at room temperature in 1 M HCl containing different concentrations of
inhibitor according to the ASTM NACE / ASTMG31-12a standart method. As a
result of these corrosion tests, the synthesized compounds exhibited very good
inhibitory properties (76.58-93.74 IE%).
Surface characterization studies were also performed for the metal coupons to
support the obtained corrosion inhibition efficiency results.

Anahtar Kelimeler

Metal corrosion, non-ionic surfactant, acidic medium, SEM

Kaynakça

• 1. Görenler A. Al-Si Matrisli Kompozit Malzemelerin Korozyon Davranışlarının İncelenmesi. Yıldız Teknik Üniversitesi, Fen Bilimleri Entüsü, Yüksek Lisans Tezi, 2007 İstanbul.
• 2. Bereket G, Pinarbasi A. Inhibition effect of some heterocyclic compounds on pure aluminium in 0.1 M hydrochloric acid solution. Corrosion. 2008 16: 17-22.
• 3. Shaban S M, Abd-Elaal A A, Tawfik S M. Gravimetric and electrochemical evaluation of three nonionic dithiol surfactants as corrosion inhibitors for mild steel in 1 M HCl solution. J. Mol. Liq. 2010 Apr; 216:392–400.
• 4. Yıldırım A, Çetin M. Synthesis and evaluation of new long alkyl side chain acetamide, isoxazolidine and isoxazoline derivatives as corrosion inhibitors. Corros Sci. 2008 Jan; 50:155–65
• 5. Negm N A, Kandile N G, Badr E A, Mohammed M A. Gravimetric and electrochemical evaluation of environmentally friendly nonionic corrosion inhibitors for carbon steel in 1 M HCl. Corros. Sci. 2012 Dec; 65:94-103.
• 6. Hegazy M A, El-Tabei A S, Ahmed H M. Synthesis of nonionic surfactants and their inhibitive action on carbon steel in hydrochloric acid. Corros.Sci. 2012 Nov; 64:115-25
• 7. El-Tabei A S, Hegazy M A. A corrosion inhibition study of a novel synthesized gemini nonionic surfactant for carbon steel in 1 M HCl solution. J. Surfact. Deterg. 2013 Sep;16:757-66.
• 8. Sobhi M, El-Sayed R, Abdallah M. Synthesis, surface properties, and inhibiting action of novel nonionic surfactants on carbon steel corrosion in 1M hydrochloric acid solution. Chem. Eng. Commun. 2016; 203:758-68.
• 9. Fuchs-Godec R. Inhibitory effect of non-ionic surfactants of the Triton-X series on the corrosion of carbon steel in sulphuric acid. Electrochim. Acta 2007 Apr; 52:4974–81.
• 10. Hegazy M A, Zaky M F. Inhibition effect of novel nonionic surfactants on the corrosion of carbon steel in acidic medium. Corros. Sci. 2010 Apr; 52:1333–41.
• 11. Mobin M, Zehra S, Parveen M. L-Cysteine as corrosion inhibitor for mild steel in 1MHCl and synergistic effect of anionic, cationic and non-ionic surfactants, J. Mol. Liq. 2016 Apr; 216:598–607.
• 12. Van Esch J H, Hoffmann M M, Nolte R J M. Reduction of nicotinamides, flavins, and manganese porphyrins by formate, catalyzed by membrane-bound rhodium complexes. J. Org. Chem. 1995 Mar; 60:1599–1610.
• 13. Maksoud SAAE (2004) The effect of hexadecyl pyridinium bromide and hexadecyl trimethyl ammonium bromide on the behaviour of iron and copper in acidic solutions. J. Electroanal. Chem. 2004 Apr; 565:321–8.
• 14. Morris-Natschke S L, Gumus F, Marasco C J, Meyer K L, Marx M, Piantadosi C, Layne M D, Modest E J. Synthesis of phosphocholine and quaternary amine ether lipids and evaluation of in vitro antineoplastic activity. J. Med. Chem. 1993 Jul; 36:2018-25.
• 15. Alexander R L, Morris-Natschke S L, Ishaq K S, Fleming R A, Kucera G L. Synthesis and cytotoxic activity of two novel 1-dodecylthio-2-decyloxypropyl-3-phosphatidic acid conjugates with gemcitabine and cytosine arabinoside. J. Med. Chem. 2003 Sep; 46:4205-8.
• 16. Anonim. Cold rolled low carbon steel flat products for cold forming - Technical delivery conditions; German version EN 10130:2006, DIN Deutsches Institut für Normung e. V., 14s., 2007, Berlin, Germany.
• 17. Öztürk S, Yıldırım A, Çetin M, Tavaslı M. Synthesis of quaternary, long-chain N-alkyl amides and their corrosion inhibition in acidic media. J. Surfact. Deterg. 2014 May; 17: 471–81.
• 18. Yıldırım A, Öztürk S, Çetin M. Novel amide-based cationic surfactants as efficient corrosion inhibitors for carbon steel in HCl and H2SO4 media. J. Surf. Deterg. 2013 Jan; 16:13–23.
• 19. ASTM NACE / ASTMG31-12a, Standard Guide for Laboratory Immersion Corrosion Testing of Metals, ASTM International, West Conshohocken, PA, 2012 Oct; p.10.
• 20. Okoronkwo A E, Olusegun S J, Oluwasina O O. The inhibitive action of chitosan extracted from Archachatina marginata shells on the corrosion of plain carbon steel in acid media. Anti. Corros. Method M. 2015; 62:13-8.
• 21. Mohamed H A, Rehim, M H A. Surface active hyperbranched polyamide-ester as a corrosion inhibitor for carbon steel in both neutral and acidic media. Anti. Corros. Method M. 2015; 62:95-102.
• 22. Lashgari M, Arshadi M R, Biglar M. Comparative studies of some heterocyclic compounds as corrosion inhibitors of copper in phosphoric acid media. Chem. Eng. Commun. 2010; 197:1303-14.
• 23. Sobhi M, El-sayed R, Abdallah M. The effect of non ionic surfactants containing triazole, thiadiazole and oxadiazole as inhibitors of the corrosion of carbon steel in 1M hydrochloric acid. J. Surfact. Deterg. 2013 Nov; 16:937–46.
• 24. Shaban SM, Aiad I, El-Sukkary MM, Soliman EA, El-Awady MY. Inhibition of mild steel corrosion in acidic medium by vanillin cationic surfactants. J. Mol. Liq. 2015 Mar; 203:20–8.
• 25. Fuchs-Godec R, Pavlovic MG. Synergistic effect between non-ionic surfactant and halide ions in the forms of inorganic or organic salts for the corrosion inhibition of stainless-steel X4Cr13 in sulphuric acid, Corros. Sci. 2012 May; 58:192-201.
• 26. Athareh D, Fatemeh B. A new synthesized corrosion inhibitor for mild steel in 0.5 M H2SO4. Gazi University Journal of Science (GU J Sci). 2011; 24:219–26.
• 27. Tawfik SM, Negm NA. Vanillin-derived non-ionic surfactants as green corrosion inhibitors for carbon steel in acidic environments. Res. Chem. Intermed. 2016 Apr; 42:3579–607.
• 28. Paria S, Khilar KC. A review on experimental studies of surfactant adsorption at the hydrophilic solid–water interface. Adv. Colloid Interface Sci. 2004 Aug; 110:75– 95.
• 29. Ramachandran S, Jovancicevic V. Molecular modeling of the inhibition of mild steel carbon dioxide corrosion by imidazolines. Corrosion. 1999 Jun; 55:259-67.
• 30. Mahmoud S S, Ahmed M M, Marie A H, El-Kasaby R A. Pitting Corrosion Inhibition of Some Copper Alloys in Neutral Solutions by Straight Chain Carboxylates. Portugaliae Electrochim. Acta. 2007; 25:453-70.