This
article describes the synthesis of isonitrosomethyl-p-tolyl
ketone [HL] as
the starting material and then we prepared the schiff base ligand from the reactions
of the amine compounds with o-phenylenediamine [H2L1]. A new series of mono-, homo and heterodinuclear copper(II)/nickel(II)
complexes have been synthesized using an oxime ligand. The complexes were
characterized by IR, elemental analysis, magnetic moment measurements, molar
conductivity, mass spectra and TGA studies. The free ligand were also described
13C and 1H-NMR spectra. For complexes using
stoichiometric and spectroscopic data of the metal complexes showed that metal:ligand
ratio of mononuclear copper(II) complex was found to be 1:1 while this ratio
was 2:1 in homo- and heterodinuclear copper(II) complex and 3:2 in the
trinuclear copper (II) complex and metal ions are coordinated to the imine and
oxime nitrogen atoms.
Birincil Dil | İngilizce |
---|---|
Konular | Kimya Mühendisliği |
Bölüm | Makaleler |
Yazarlar | |
Yayımlanma Tarihi | 1 Ocak 2018 |
Gönderilme Tarihi | 30 Haziran 2017 |
Kabul Tarihi | 6 Mayıs 2018 |
Yayımlandığı Sayı | Yıl 2018 Cilt: 5 Sayı: 2 |