Hydrothermal Synthesis and Crystal Structure of Zn(II) Coordination Polymer with the Rigid 4,4'-azobispyridine

Year 2020, Volume: 7 Issue: 1, 43 - 48, 15.02.2020

Figen Arslan Biçer

https://doi.org/10.18596/jotcsa.536258

Cited By: 3

Abstract

The new metal complex with phenylsuccinic acid (H₂psa)
and 4,4'-azobispyridine (4,4’-abpy), {[Zn(psa)(H₂O)₃(µ-4,4'-abpy)](H₂O)}_n
(I), was synthesized by hydrothermally process. The
structure of I has been characterized
by IR spectra, elemental analysis, and single crystal X-ray diffraction. Single
crystal X-ray analysis reveals that the psa ligand O-coordinated to the Zn(II)
ion and distorted octahedral geometry of Zn(II) ion is completed by bridging
4,4’-abpy and three aqua ligands.

Keywords

Coordination polymers, 4'-azobispyridine, phenyl succinic acid

Project Number

KBÜBAP-18-YL-060

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