New Homodinuclear Alkyl and Aryl Dithiophosphonato Cd(II) and Hg(II) complexes: Syntheses and Characterizations

Year 2020, Volume: 7 Issue: 1, 49 - 64, 15.02.2020

Ertuğrul Gazi Sağlam , Elif Bulat , Nurcan Acar , İbrahim Demirel

https://doi.org/10.18596/jotcsa.565642

Cited By: 2

Abstract

New Cd(II) and Hg(II) complexes of previously
known five dithiophosphonic acids ((p-MeO-C₆H₄)PS(SH)(OR), HLⁿ, (n=
1-5); R= 3-pentyl-, HL¹; R=1-phenyl-1-propyl-,
HL²; R= 4-tert-butyl benzyl-,
HL³; R= diphenylmethyl-, HL⁴;
R= 4-tert- butyl cyclohexyl-, HL⁵) were
prepared and characterized. To do this, the dithiophosphonic
acids involved were treated with stoichiometric amount of the corresponding
metal salts in methyl alcohol. The complexes came of as powdery crystals and were
recrystallized from chloroform. The pure complexes were characterized by using
elemental analyses as well as mas-(ESI), FTIR-, Raman-, NMR- (¹H, ¹³C, ³¹P) spectroscopies.

Keywords

Dithiophosphonic Acid, Phosphonodthioic Acid, Dithiophosphonate Complexes

Supporting Institution

Project Coordination Application and Research Center of Bozok University

Project Number

BAP 6602b-FEN/18-221

Thanks

This study is supported by the Project Coordination Application and Research Center of Bozok University [BAP 6602b-FEN/18-221].

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