Determination of Some Pesticides Harmful To Environment and Human Health in Bogazköy(Turkey) Dam Water by LC-MS/MS

Year 2020, Volume: 7 Issue: 3, 801 - 812, 30.10.2020

İbrahim Yılmaz , Gülbin Erdoğan

https://doi.org/10.18596/jotcsa.749021

Cited By: 1

Abstract

Abstract: Pesticides are the most dangerous organic pollutants for human and environmental health. These are substances that are harmful to health, the use of which has increased in recent years, to kill pests in agricultural production. The areas of use of pesticides, apart from agricultural activities, are in the fight against mosquitoes, which cause malaria, which creates a significant health problem for human health, in landscape, construction industry, timber protection, forestry, control of aquatic organisms, industrial insect control, food storage, transportation and community hygiene there are multiple uses such as. Excessive intake of the body leads to many diseases, cancer formation, even death. This study, it was aimed to analyze of Atrazin, Chlorfenvinfos, Chlorpyrifos, Diuron, Isoproturon and Simazin pesticides simultaneously with LC-MS/MS, in Boğazköy Dam in Bursa(Turkey) and the branches that feed the dam in Bursa İnegöl district. The samples were taken from 12 locations and were given to LC-MS / MS device by direct injection. Atrazin, Chlorfenvinfos, Chlorpyrifos, Diuron, Isoproturon and Simazin pesticides, which are among the priority substances for surface water resources, were analyzed in the Surface Water Quality Regulation in the dam waters. Environmental quality standards referred to in this regulation are taken as reference points for calibration. For the accuracy of the method, validation studies such as LOD, LOQ, linearity and recovery were performed. As a result, it has been determined that the pesticide derivatives analyzed in the waters feeding Boğazköy Dam and the dam doesn't exceed the limit values of the Environmental Quality Standards, pose no risk in irrigation of agricultural areas and in surface waters.

Keywords

Pesticides, Water Environment Pollution, Agricultural water, LC-MS/MS, Human Health

Supporting Institution

Marmara Üniversitesi, Bilimsel Araştırma Projeleri Koordinasyon Birimi

Project Number

SAG-C-YLP-110618-0308

Thanks

We would like to thank Marmara University Scientific Research Projects Commission Chair for their support for the thesis with the project numbered SAG-C-YLP-110618-0308 as a master thesis.

References

• Güler, Ç., Çobanoğlu, Z. Pesticides. Environmental Health Basic Resource Series, 52, (1 st Edition), Ilkoz Printing Press (1997) Ankara.
• Açar Çetinkaya, Ö. Pestıcıde analysıs traınıng note T. C. Ministry of Food, Agriculture and Livestock National Food Reference Laboratory Residue / Pesticide Unit, (2015) Ankara.
• Lari, S.Z., Khan, N.A., Gandhi, K.N., Meshram T.S., Thacker, N.P. Comparison of pesticide residues in surface water and ground water of agriculture intensive areas. J. Envıron. Heal. Scı. Eng. 2014; 12(11) https://dx.doi.org/10.1186%2F2052-336X-12-11
• Masiá, A., Ibáñez, M., Blasco, C., Sancho, J.V., Picó, Y., Hernández, F., Combined use of liquid chromatography triple quadrupole mass spectrometry and liquid chromatography quadrupole time-of-flight mass spectrometry in systematic screening of pesticides and other contaminants in water samples, Anal. Chim. Acta, 2013; 761:117–127. https://doi.org/10.1016/j.aca.2012.11.032
• Erdem, Ö., Chromatographic Determination of Organochlorinated Pesticides in Drinking and Using Water in Ayas District [Master Thesis]. [Ankara]: Institute of Science, Gazi University; 2010.
• Aybala Koç, O., Methodology for the Development of Environmental Quality Standards Related to Hazardous Substances in Surface Waters. Ministry of Forestry and Water Management [Master Thesis]. [Ankara]: T. C. Ministry of Forestry and Water Management;2015.
• Tiryaki, O., Canhilal, R., Horuz, S., Pesticides Use and Risks. Erciyes University J.. of Inst. Sci. and Tech.. 2010; 26(2):154-169.
• Kuş F.S., Determination of Organochlorinated Pesticide Residues in Afyonkarahisar Province Drinking Water and Eber and Karamık Lake Water [Master Thesis]. [Afyon]: Afyon Kocatepe University Institute of Science; 2007.
• Almeida, T.B., Madeira, L.S., Watanabe, P.C., Melettib, P.C., and Nixdorf, S.C., Pesticide Determination in Water Samples from a Rural Area by Multi-Target Method Applying Liquid Chromatography-Tandem Mass Spectrometry. J. Brazil Chem Soc, 2019; 30(8):1657-1666, http://orcid.org/0000-0002-6016-8329
• Çakmak Z,., Examination and determination of aclonifen pesticide with electrochemical techniques [Master Thesis]. [Ankara]:Institute of Science, Gazi University; 2013.
• Çağdar, M.G. Pesticide Analysis in Amik Plain Soils with GC-MS and LC-MS / MS Device [Master Thesis]. [Hatay]: Institute of Science, Mustafa Kemal University,; 2014
• Baloglu, Z., Bozkurt, E.N., Binici, A. Determination of pesticides in waters by LC-MS / MS. Turk Hij. Den. Biyol. Derg. 2017; 74(1):41-48, https://dx.doi.org/10.5505/TurkHijyen.2017.09798
• Regulation on Control of Pollution Caused by Hazardous Substances in Water and its Environment (76/464/ AB) (26/11/2005 R.G.No: 26005) Ministry of Forestry and Water Management, Ankara
• Kapsi, M., Tsoutsi, C., Paschalidou, A., Albanis, T., Environmental monitoring and risk assessment of pesticide residues in surface waters of the Louros River (N.W. Greece). Sci. Tot. Environ. 2019; 650: 2188–2198. https://doi.org/10.1016/j.scitotenv.2018.09.185
• Aguilar, J.A.P., Andreu, V., Campo, J., Picó, Y., Masiá, A., Pesticide occurrence in the waters of Júcar River, Spain from different farming landscapes. Sci. Tot. Environ,, 2017; 607-608: 752–760. https://doi.org/10.1016/j.scitotenv.2017.06.176
• Barchaska, H., Baranowska, I. Procedures for analysis of atrazine and simazine in environmental matrices. Reviews of Environmental Contamination and Toxicology, Berlin: Springer, 2019; 53-84. https://doi.org/10.1007/978-1-4419-0028-9_3
• Mmualefe, L.C., Torto, N., Huntsman-Mapila, P., Mbongwe, B. Headspace solid phase microextraction in the determination of pesticides in water samples from the Okavango Delta with gas chromatography-electron capture detection and time-of-flight mass spectrometry. Microchem. J, 2009; 91(2): 239–244. https://doi.org/10.1016/j.microc.2008.12.005
• Poolpak, T., Pokethitiyook, P., Kruatrachue, M., Arjarasirikoon, U., Thanwaniwat, N. Residue analysis of organochlorine pesticides in the Mae Klong river of Central Thailand. J. Hazard. Mater. 2008; 156(1-3): 230–239. https://doi.org/10.1016/j.jhazmat.2007.12.078
• Sun, K., Zhao, Y., Gao, B., Liu, X., Zhang, Z., Xing, B. Organochlorine pesticides and polybrominated diphenyl ethers in irrigated soils of Beijing, China: Levels, inventory and fate. Chemosphere. 2009; 77(9): 1199-1205. https://doi.org/10.1016/j.chemosphere.2009.09.016
• Beale, D.J., Kaserzon, S.L., Porter, N.A., Roddick, F.A., Carpenter, Peter D., Detection of s-triazine pesticides in natural waters by modified large-volume direct injection HPLC. Talanta. 2010; 82(2): 668–674. https://doi.org/10.1016/j.talanta.2010.05.030
• Diaz, L., Llorca-Pórcel, J., Valor. I. Ultra trace determination of 31 pesticides in water samples by direct injection–rapid resolution liquid chromatography-electrospray tandem mass spectrometry. Anal. Chim. Acta, 2008; 624(1):90–96. https://doi.org/10.1016/j.aca.2008.06.053
• Aboveground Water Quality Management Regulation Number:29797 (10.08.2016) Ministry of Forestry and Water Affairs, Ankara.