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Usage of Cellulose Acetate Butyrate Based Oligomeric Structures on Cotton Fabric Coatings

Yıl 2021, Cilt: 8 Sayı: 1, 303 - 310, 28.02.2021
https://doi.org/10.18596/jotcsa.634996

Öz

In this study, the hydroxyl groups of cellulose
acetate butyrate (CAB) oligomer were reacted with toluene diisocyanate-hydroxyethyl
methacrylate (TDI-HEMA) adduct, in order to improve properties of CAB such as
flexibility, thermal stability etc. Then the obtained modified CAB oligomer was
characterized by FTIR and 1H NMR analysis. UV-curable coating
formulations were prepared by using the modified CAB oligomer, and then applied
on cotton fabrics in order to reinforce cotton fabrics and make them durable to
outdoor environments. Cotton fabrics were treated with a commercial washing
detergent, alkali solution, and an enzyme prior to the UV-coating, in order to
increase the adhesion between the cotton fabric and coating layer. Washed and
coated fabrics were evaluated in terms of absorbency, tensile, and adhesion
properties, respectively. Light microscopy was employed to observe the effects
of washing processes on fibre, and to show the abrasion deformation on coated
fabric. Results proved that the best washing process in fibrillation was found
as enzymatic washing due to the having the highest adhesion strength and the
least deformation against abrasion.    

Teşekkür

The extended abstract of this study was orally presented in 31th National Chemistry Congress on 10-13 September 2019, Istanbul (31. Ulusal Kimya Kongresi 10-13 Eylül, 2019, Istanbul).

Kaynakça

  • 1. Çakmakçı E, Güngör A, Kayaman-Apohan N, Kuruca SE, Çetin MB, Dar KA. Cell growth on in situ photo-cross-linked electrospun acrylated cellulose acetate butyrate. Journal of Biomaterials Science, Polymer Edition. 2012;23(7):887-99.
  • 2. Wang X, Huang S, Wang Y, Wei P, Chen Y, Xia Y, et al. Eco-friendly cellulose acetate butyrate/poly (butylene succinate) blends: crystallization, miscibility, thermostability, rheological and mechanical properties. Journal of Polymer Research. 2017;24(2):16.
  • 3. Biniaś W, Biniaś D. Formation of Microfibres from Cellulose Acetate Butyrate by Electrospinning with a Surface Modified in Low-temperature Plasma. Fibres & Textiles in Eastern Europe. 2014.
  • 4. Barszczewska-Rybarek IM. Characterization of urethane-dimethacrylate derivatives as alternative monomers for the restorative composite matrix. Dental Materials. 2014;30(12):1336-44.
  • 5. Lei G, Angeli S, Kristol D, Snyder W. Preparation of new blocked diisocyanate for dental application. Journal of Polymer Science Part A: Polymer Chemistry. 1987;25(2):607-15.
  • 6. Wang SJ, Wang YL, Yang PF, Li TD, editors. Preparation of polyurethane-poly (butyl acrylate) hybrid latexes via miniemulsion polymerization. Applied Mechanics and Materials; 2012: Trans Tech Publ.
  • 7. Wang F, Hu J, Tu W. Study on microstructure of UV-curable polyurethane acrylate films. Progress in organic coatings. 2008;62(3):245-50.
  • 8. Xie J, Zhang N, Guers M, Varadan VK. Ultraviolet-curable polymers with chemically bonded carbon nanotubes for microelectromechanical system applications. Smart materials and structures. 2002;11(4):575.
  • 9. Liu X-D, Sheng D-K, Gao X-M, Li T-B, Yang Y-M. UV-assisted surface modification of PET fiber for adhesion improvement. Applied Surface Science. 2013;264:61-9.
  • 10. Eker P. Farklı Hammaddeler İçeren Lycralı Dokuma Kumaşlarda Biyo-Parlatma ve Biyo-Parlatmanın Kumaş Performansına Etkileri. Adana2012.
  • 11. Ozgen H. Farklı Yöntemlerle Pamuklu Örme Kumaşın Enzimatik Hidrofilleştirilmesi. Bartın2018.
  • 12. Stanescu MD, Dochia M, Radu D, Sirghie C. Green solution for cotton scouring. Fibres & Textiles in Eastern Europe. 2010;18(3):80.
  • 13. SANCAR B, PAKSOY N, BALCI O, KURTOĞLU N. Pamuklu Dokuma Kumaşların Boyamaya Hazırlık İşlemlerinde Enzim Kullanım Olanaklarının İncelenmesi ve Kombine Proses Geliştirilmesi. Tekstil ve Mühendis. 2012;19(86).
  • 14. Toprak T. Pamuklu Kumaşlarda Kombine Enzim Proseslerinin Geliştirilmesi. Bursa2014.
  • 15. Davulcu A. Pamuklu Kumaşların Ön Terbiye Proseslerinin Enzimatik Yöntemlerle Kombine Edilmesi Üzerine Bir Araştırma. Bursa2008.
  • 16. Duran K, Bozacı E, Karahan H. Protein Esaslı Mamüllerin Enzimatik ÖnTerbiyesi. Tekstil ve Konfeksiyon. 2007;3:187-92.
  • 17. Yılmaz B. Selülozik Materyallerin Tek Banyoda Kombine Proses ile Boyanmasında Optimizasyon. Istanbul2004.
  • 18. Donelli I, Freddi G, Nierstrasz VA, Taddei P. Surface structure and properties of poly-(ethylene terephthalate) hydrolyzed by alkali and cutinase. Polymer Degradation and Stability. 2010;95(9):1542-50.
  • 19. AATCC TM79-2018, Absorbency of Textiles. 2018.
  • 20. TS EN ISO 13934-1:Tekstil - Kumaşların gerilme özellikleri - Bölüm 1:En büyük kuvvetin ve en büyük kuvvet altında boyca uzamanın şerit yöntemiyle tayini. 2013.
  • 21. TS EN ISO 5470-2:Lastik veya plastik kaplı kumaşlar-Aşınma dayanımının tayini-Böllüm 2:Martindale aşındırıcı. 2004.
  • 22. TS EN ISO 12947-2:Tekstil - Martindale metoduyla kumaşların aşınmaya karşı dayanımının tayini- Bölüm 2: Numune kopmasının tayini. 2017.
  • 23. ASTM D1876–08: Standard Test Method for Peel Resistance of Adhesives (T-Peel Test). ASTM International: West Conshohocken, PA; 2015.
  • 24. Grepinet B, Pla F, Hobbes P, Swaels P, Monge T. Modeling and simulation of urethane acrylates synthesis. I. Kinetics of uncatalyzed reaction of toluene diisocyanate with a monoalcohol. Journal of applied polymer science. 2000;75(5):705-12.
  • 25. Liao F, Zeng X-r, Li H-q, Lai X-j, Zhao F-c. Synthesis and properties of UV curable polyurethane acrylates based on two different hydroxyethyl acrylates. Journal of Central South University. 2012;19(4):911-7.
  • 26. Tan SZ, Wang Y, Zhang YF, Zhou WL, editors. Preparation of a novel prepolymer of polyurethane acrylate. Advanced Materials Research; 2012: Trans Tech Publ.
  • 27. Dong Y, Edgar KJ. Imparting functional variety to cellulose ethers via olefin cross-metathesis. Polymer Chemistry. 2015;6(20):3816-27.
  • 28. Dong Y, Mosquera-Giraldo LI, Troutman J, Skogstad B, Taylor LS, Edgar KJ. Amphiphilic hydroxyalkyl cellulose derivatives for amorphous solid dispersion prepared by olefin cross-metathesis. Polymer Chemistry. 2016;7(30):4953-63.
  • 29. Kunwong D, Sumanochitraporn N, Kaewpirom S. Curing behavior of a UV-curable coating based on urethane acrylate oligomer: the influence of reactive monomers. Sonklanakarin Journal of Science and Technology. 2011;33(2):201.
Yıl 2021, Cilt: 8 Sayı: 1, 303 - 310, 28.02.2021
https://doi.org/10.18596/jotcsa.634996

Öz

Kaynakça

  • 1. Çakmakçı E, Güngör A, Kayaman-Apohan N, Kuruca SE, Çetin MB, Dar KA. Cell growth on in situ photo-cross-linked electrospun acrylated cellulose acetate butyrate. Journal of Biomaterials Science, Polymer Edition. 2012;23(7):887-99.
  • 2. Wang X, Huang S, Wang Y, Wei P, Chen Y, Xia Y, et al. Eco-friendly cellulose acetate butyrate/poly (butylene succinate) blends: crystallization, miscibility, thermostability, rheological and mechanical properties. Journal of Polymer Research. 2017;24(2):16.
  • 3. Biniaś W, Biniaś D. Formation of Microfibres from Cellulose Acetate Butyrate by Electrospinning with a Surface Modified in Low-temperature Plasma. Fibres & Textiles in Eastern Europe. 2014.
  • 4. Barszczewska-Rybarek IM. Characterization of urethane-dimethacrylate derivatives as alternative monomers for the restorative composite matrix. Dental Materials. 2014;30(12):1336-44.
  • 5. Lei G, Angeli S, Kristol D, Snyder W. Preparation of new blocked diisocyanate for dental application. Journal of Polymer Science Part A: Polymer Chemistry. 1987;25(2):607-15.
  • 6. Wang SJ, Wang YL, Yang PF, Li TD, editors. Preparation of polyurethane-poly (butyl acrylate) hybrid latexes via miniemulsion polymerization. Applied Mechanics and Materials; 2012: Trans Tech Publ.
  • 7. Wang F, Hu J, Tu W. Study on microstructure of UV-curable polyurethane acrylate films. Progress in organic coatings. 2008;62(3):245-50.
  • 8. Xie J, Zhang N, Guers M, Varadan VK. Ultraviolet-curable polymers with chemically bonded carbon nanotubes for microelectromechanical system applications. Smart materials and structures. 2002;11(4):575.
  • 9. Liu X-D, Sheng D-K, Gao X-M, Li T-B, Yang Y-M. UV-assisted surface modification of PET fiber for adhesion improvement. Applied Surface Science. 2013;264:61-9.
  • 10. Eker P. Farklı Hammaddeler İçeren Lycralı Dokuma Kumaşlarda Biyo-Parlatma ve Biyo-Parlatmanın Kumaş Performansına Etkileri. Adana2012.
  • 11. Ozgen H. Farklı Yöntemlerle Pamuklu Örme Kumaşın Enzimatik Hidrofilleştirilmesi. Bartın2018.
  • 12. Stanescu MD, Dochia M, Radu D, Sirghie C. Green solution for cotton scouring. Fibres & Textiles in Eastern Europe. 2010;18(3):80.
  • 13. SANCAR B, PAKSOY N, BALCI O, KURTOĞLU N. Pamuklu Dokuma Kumaşların Boyamaya Hazırlık İşlemlerinde Enzim Kullanım Olanaklarının İncelenmesi ve Kombine Proses Geliştirilmesi. Tekstil ve Mühendis. 2012;19(86).
  • 14. Toprak T. Pamuklu Kumaşlarda Kombine Enzim Proseslerinin Geliştirilmesi. Bursa2014.
  • 15. Davulcu A. Pamuklu Kumaşların Ön Terbiye Proseslerinin Enzimatik Yöntemlerle Kombine Edilmesi Üzerine Bir Araştırma. Bursa2008.
  • 16. Duran K, Bozacı E, Karahan H. Protein Esaslı Mamüllerin Enzimatik ÖnTerbiyesi. Tekstil ve Konfeksiyon. 2007;3:187-92.
  • 17. Yılmaz B. Selülozik Materyallerin Tek Banyoda Kombine Proses ile Boyanmasında Optimizasyon. Istanbul2004.
  • 18. Donelli I, Freddi G, Nierstrasz VA, Taddei P. Surface structure and properties of poly-(ethylene terephthalate) hydrolyzed by alkali and cutinase. Polymer Degradation and Stability. 2010;95(9):1542-50.
  • 19. AATCC TM79-2018, Absorbency of Textiles. 2018.
  • 20. TS EN ISO 13934-1:Tekstil - Kumaşların gerilme özellikleri - Bölüm 1:En büyük kuvvetin ve en büyük kuvvet altında boyca uzamanın şerit yöntemiyle tayini. 2013.
  • 21. TS EN ISO 5470-2:Lastik veya plastik kaplı kumaşlar-Aşınma dayanımının tayini-Böllüm 2:Martindale aşındırıcı. 2004.
  • 22. TS EN ISO 12947-2:Tekstil - Martindale metoduyla kumaşların aşınmaya karşı dayanımının tayini- Bölüm 2: Numune kopmasının tayini. 2017.
  • 23. ASTM D1876–08: Standard Test Method for Peel Resistance of Adhesives (T-Peel Test). ASTM International: West Conshohocken, PA; 2015.
  • 24. Grepinet B, Pla F, Hobbes P, Swaels P, Monge T. Modeling and simulation of urethane acrylates synthesis. I. Kinetics of uncatalyzed reaction of toluene diisocyanate with a monoalcohol. Journal of applied polymer science. 2000;75(5):705-12.
  • 25. Liao F, Zeng X-r, Li H-q, Lai X-j, Zhao F-c. Synthesis and properties of UV curable polyurethane acrylates based on two different hydroxyethyl acrylates. Journal of Central South University. 2012;19(4):911-7.
  • 26. Tan SZ, Wang Y, Zhang YF, Zhou WL, editors. Preparation of a novel prepolymer of polyurethane acrylate. Advanced Materials Research; 2012: Trans Tech Publ.
  • 27. Dong Y, Edgar KJ. Imparting functional variety to cellulose ethers via olefin cross-metathesis. Polymer Chemistry. 2015;6(20):3816-27.
  • 28. Dong Y, Mosquera-Giraldo LI, Troutman J, Skogstad B, Taylor LS, Edgar KJ. Amphiphilic hydroxyalkyl cellulose derivatives for amorphous solid dispersion prepared by olefin cross-metathesis. Polymer Chemistry. 2016;7(30):4953-63.
  • 29. Kunwong D, Sumanochitraporn N, Kaewpirom S. Curing behavior of a UV-curable coating based on urethane acrylate oligomer: the influence of reactive monomers. Sonklanakarin Journal of Science and Technology. 2011;33(2):201.
Toplam 29 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Polimer Bilimi ve Teknolojileri
Bölüm Makaleler
Yazarlar

Zehra Yıldız 0000-0002-1573-2074

Hacer Ayşen Önen Bu kişi benim 0000-0002-7169-608X

Ozan Gazi Dehmen Bu kişi benim 0000-0002-6225-3543

Atilla Güngör Bu kişi benim 0000-0001-9562-6265

Yayımlanma Tarihi 28 Şubat 2021
Gönderilme Tarihi 20 Ekim 2019
Kabul Tarihi 16 Kasım 2020
Yayımlandığı Sayı Yıl 2021 Cilt: 8 Sayı: 1

Kaynak Göster

Vancouver Yıldız Z, Önen HA, Dehmen OG, Güngör A. Usage of Cellulose Acetate Butyrate Based Oligomeric Structures on Cotton Fabric Coatings. JOTCSA. 2021;8(1):303-10.