1. DergiPark
  2. Journal of the Turkish Chemical Society Section A: Chemistry
  3. Arşiv
  4. Cilt 8, Sayı 1
Yıl 2021, Cilt 8 , Sayı 1, Sayfalar 47 - 56 2021-02-28

Calcined Eggshell for Removal of Victoria Blue R Dye from Wastewater Medium by Adsorption

İlknur TOSUN SATIR [1] , Kadir EROL [2]

Öz

In this study, the use of calcined eggshell (CE) as an adsorbent in removing Victoria Blue R (VBR) dyestuff from the solution medium was investigated. For this purpose, pH, interaction time, adsorbate concentration, amount of adsorbent, and salt effect parameters were studied to determine the appropriate adsorption conditions. The highest adsorption yield was obtained in pH 2, 2.0 g/L adsorbent and a stirring time of 5 minutes. 97% of the dye was removed under optimum adsorption conditions. The results obtained from the experimental studies showed that the adsorption mechanism is compatible with the pseudo-second-order kinetic model and the Langmuir isotherm model. SEM and IR analyses were performed for the characterization of calcined eggshells (CE).

Anahtar Kelimeler

Textile dye, calcineted eggshell, water treatment, wastewater, adsorption

Kaynakça

  • 1. Chen C-Y, Wang G-H, Tseng I-H, Chung Y-C. Analysis of bacterial diversity and efficiency of continuous removal of Victoria Blue R from wastewater by using packed-bed bioreactor. Chemosphere. 2016;145:17-24.
  • 2. Vaidya A. Environmental pollution during chemical processing of synthetic fibers. Colourage. 1982;14:3-10.
  • 3. Ayed L, Chaieb K, Cheref A, Bakhrouf A. Biodegradation and decolorization of triphenylmethane dyes by Staphylococcus epidermidis. Desalination. 2010;260(1-3):137-46.
  • 4. Azmi W, Sani RK, Banerjee UC. Biodegradation of triphenylmethane dyes. Enzyme and microbial technology. 1998;22(3):185-91.
  • 5. Belpaire C, Reyns T, Geeraerts C, Van Loco J. Toxic textile dyes accumulate in wild European eel Anguilla anguilla. Chemosphere. 2015;138:784-91.
  • 6. Black JJ, Holmes M, Dymerski PP, Zapisek WF. Fish tumor pathology and aromatic hydrocarbon pollution in a Great Lakes estuary. Hydrocarbons and halogenated hydrocarbons in the aquatic environment: Springer; 1980. p. 559-65.
  • 7. Chen K, Lu C, Chang T, Lai Y, Wu C, Chen C. Comparison of photodegradative efficiencies and mechanisms of Victoria Blue R assisted by Nafion-coated and fluorinated TiO2 photocatalysts. Journal of hazardous materials. 2010;174(1-3):598-609.
  • 8. Cho BP, Yang T, Blankenship LR, Moody JD, Churchwell M, Beland FA, et al. Synthesis and characterization of N-demethylated metabolites of malachite green and leucomalachite green. Chemical research in toxicology. 2003;16(3):285-94.
  • 9. Demirbaş O, Alkan M, Doğan M. The removal of Victoria blue from aqueous solution by adsorption on a low-cost material. Adsorption. 2002;8(4):341-9.
  • 10. Rajabi HR, Khani O, Shamsipur M, Vatanpour V. High-performance pure and Fe3+-ion doped ZnS quantum dots as green nanophotocatalysts for the removal of malachite green under UV-light irradiation. Journal of hazardous materials. 2013;250:370-8.
  • 11. Almeida LC, Silva BF, Zanoni MV. Photoelectrocatalytic/photoelectro-Fenton coupling system using a nanostructured photoanode for the oxidation of a textile dye: kinetics study and oxidation pathway. Chemosphere. 2015;136:63-71.
  • 12. Huang S-T, Jiang Y-R, Chou S-Y, Dai Y-M, Chen C-C. Synthesis, characterization, photocatalytic activity of visible-light-responsive photocatalysts BiOxCly/BiOmBrn by controlled hydrothermal method. Journal of Molecular Catalysis A: Chemical. 2014;391:105-20.
  • 13. Jiang Y-R, Chou S-Y, Chang J-L, Huang S-T, Lin H-P, Chen C-C. Hydrothermal synthesis of bismuth oxybromide–bismuth oxyiodide composites with high visible light photocatalytic performance for the degradation of CV and phenol. RSC Advances. 2015;5(39):30851-60.
  • 14. Lee WW, Lu C-S, Chuang C-W, Chen Y-J, Fu J-Y, Siao C-W, et al. Synthesis of bismuth oxyiodides and their composites: characterization, photocatalytic activity, and degradation mechanisms. RSC Advances. 2015;5(30):23450-63.
  • 15. Rajabi HR, Farsi M. Quantum dot based photocatalytic decolorization as an efficient and green strategy for the removal of anionic dye. Materials Science in Semiconductor Processing. 2015;31:478-86.
  • 16. Roushani M, Mavaei M, Rajabi HR. Graphene quantum dots as novel and green nano-materials for the visible-light-driven photocatalytic degradation of cationic dye. Journal of Molecular Catalysis A: Chemical. 2015;409:102-9.
  • 17. Geetha P, Latha M, Koshy M. Biosorption of malachite green dye from aqueous solution by calcium alginate nanoparticles: equilibrium study. Journal of Molecular Liquids. 2015;212:723-30.
  • 18. Oguntimein GB. Biosorption of dye from textile wastewater effluent onto alkali treated dried sunflower seed hull and design of a batch adsorber. Journal of Environmental Chemical Engineering. 2015;3(4):2647-61.
  • 19. Erol K, Köse K, Köse DA, Sızır Ü, Tosun Satır İ, Uzun L. Adsorption of Victoria Blue R (VBR) dye on magnetic microparticles containing Fe (II)–Co (II) double salt. Desalination and Water Treatment. 2016;57(20):9307-17.
  • 20. Sun D, Zhang X, Wu Y, Liu X. Adsorption of anionic dyes from aqueous solution on fly ash. Journal of hazardous materials. 2010;181(1-3):335-42.
  • 21. Madrakian T, Afkhami A, Ahmadi M. Adsorption and kinetic studies of seven different organic dyes onto magnetite nanoparticles loaded tea waste and removal of them from wastewater samples. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2012;99:102-9.
  • 22. Singh SA, Vemparala B, Madras G. Adsorption kinetics of dyes and their mixtures with Co3O4–ZrO2 composites. Journal of Environmental Chemical Engineering. 2015;3(4):2684-96.
  • 23. Gamoudi S, Srasra E. Adsorption of organic dyes by HDPy+-modified clay: Effect of molecular structure on the adsorption. Journal of Molecular Structure. 2019;1193:522-31.
  • 24. Gupta K, Khatri OP. Fast and efficient adsorptive removal of organic dyes and active pharmaceutical ingredient by microporous carbon: Effect of molecular size and charge. Chemical Engineering Journal. 2019;378:122218.
  • 25. Nyamukamba P, Tichagwa L, Okoh O, Petrik L. Visible active gold/carbon co-doped titanium dioxide photocatalytic nanoparticles for the removal of dyes in water. Materials Science in Semiconductor Processing. 2018;76:25-30.
  • 26. Al-Ghouti MA, Salih NR. Application of eggshell wastes for boron remediation from water. Journal of Molecular Liquids. 2018;256:599-610.
  • 27. Prabakaran K, Rajeswari S. Spectroscopic investigations on the synthesis of nano-hydroxyapatite from calcined eggshell by hydrothermal method using cationic surfactant as template. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2009;74(5):1127-34.
  • 28. Lagergren S, Lagergren S, Lagergren S, Sven K. Zurtheorie der sogenannten adsorption gelösterstoffe. 1898.
  • 29. Ho Y, McKay G. Kinetic models for the sorption of dye from aqueous solution by wood. Trans IChemE. 1998;76(B):183-91.   30. Weber WJ, Morris JC. Kinetics of adsorption on carbon from solution. Journal of the sanitary engineering division. 1963;89(2):31-60.
  • 31. Langmuir I. The adsorption of gases on plane surfaces of glass, mica and platinum. Journal of the American Chemical society. 1918;40(9):1361-403.
  • 32. Freundlich H. Über die adsorption in lösungen. Zeitschrift für physikalische Chemie. 1907;57(1):385-470.
  • 33. Radushkevich M. The equation of the characteristic curve of the activated charcoal USSR Phys. Chem Sect. 1947;55:331.

Ayrıntılar

Birincil Dil en
Konular Kimya, Ortak Disiplinler
Bölüm Makaleler
Yazarlar

Orcid: 0000-0003-3769-8767
Yazar: İlknur TOSUN SATIR (Sorumlu Yazar)
Kurum: HITIT UNIVERSITY
Ülke: Turkey

Orcid: 0000-0001-9158-6091
Yazar: Kadir EROL
Kurum: HITIT UNIVERSITY
Ülke: Turkey
Destekleyen Kurum Hitit University
Proje Numarası FEF01.13.009
Teşekkür This study was supported by the Scientific Research Projects Department of Hitit University (Project no: FEF01.13.009)
Tarihler

Başvuru Tarihi : 29 Haziran 2020
Kabul Tarihi : 9 Kasım 2020
Yayımlanma Tarihi : 28 Şubat 2021

Kaynak Göster

Vancouver Tosun Satır İ , Erol K . Calcined Eggshell for Removal of Victoria Blue R Dye from Wastewater Medium by Adsorption. Journal of the Turkish Chemical Society Section A: Chemistry. 2021; 8(1): 47-56.
Makalenin Yazarları
İlknur TOSUN SATIR [1]
Kadir EROL [2]
Makale Gönder
Kabul Edilmiş Makaleler
Arşiv
Editör Kurulu
İletişim
Scopus
Scopus
TR Dizin
TR Dizin
J. Turk. Chem. Soc., Sect. A: Chem.