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Yıl 2021, Cilt 8, Sayı 4, 1179 - 1196, 30.11.2021
https://doi.org/10.18596/jotcsa.900197

Öz

Kaynakça

  • 1. Ebele AJ, Abou-Elwafa Abdallah M, Harrad S. Pharmaceuticals and personal care products (PPCPs) in the freshwater aquatic environment. Emerging Contaminants. 2017 Mar;3(1):1–16.
  • 2. Daughton CG. Pharmaceuticals and the Environment (PiE): Evolution and impact of the published literature revealed by bibliometric analysis. Science of The Total Environment. 2016 Aug;562:391–426.
  • 3. Nazari G, Abolghasemi H, Esmaieli M. Batch adsorption of cephalexin antibiotic from aqueous solution by walnut shell-based activated carbon. Journal of the Taiwan Institute of Chemical Engineers. 2016 Jan;58:357–65.
  • 4. Domínguez JR, González T, Palo P, Cuerda-Correa EM. Removal of common pharmaceuticals present in surface waters by Amberlite XAD-7 acrylic-ester-resin: Influence of pH and presence of other drugs. Desalination. 2011 Mar;269(1–3):231–8.
  • 5. Sophia A. C, Lima EC. Removal of emerging contaminants from the environment by adsorption. Ecotoxicology and Environmental Safety. 2018 Apr;150:1–17.
  • 6. Danalıoğlu ST, Bayazit ŞS, Kerkez Kuyumcu Ö, Salam MA. Efficient removal of antibiotics by a novel magnetic adsorbent: Magnetic activated carbon/chitosan (MACC) nanocomposite. Journal of Molecular Liquids. 2017 Aug;240:589–96.
  • 7. Dai Y, Zhang N, Xing C, Cui Q, Sun Q. The adsorption, regeneration and engineering applications of biochar for removal organic pollutants: A review. Chemosphere. 2019 May;223:12–27.
  • 8. Zhang A, Li X, Xing J, Xu G. Adsorption of potentially toxic elements in water by modified biochar: A review. Journal of Environmental Chemical Engineering. 2020 Aug;8(4):104196.
  • 9. Hao Z, Wang C, Yan Z, Jiang H, Xu H. Magnetic particles modification of coconut shell-derived activated carbon and biochar for effective removal of phenol from water. Chemosphere. 2018 Nov;211:962–9.
  • 10. Dadjo C, Assogbadjo AE, Fandohan B, Glèlè Kakaï R, Chakeredza S, Houehanou TD, et al. Uses and management of black plum ( Vitex doniana Sweet ) in Southern Benin. Fruits. 2012 Jul;67(4):239–48.
  • 11. Ameh PO, Odoh R, Oluwaseye A. Equilibrium study on the adsorption of Zn (II) and Pb (II) ions from aqueous solution onto Vitex doniana nut. Int J Modern Chem. 2012;3(2):82–97.
  • 12. Atolaiye BO, Babalola JO, Adebayo MA, Aremu MO. Equilibrium modeling and pH-dependence of the adsorption capacity of Vitex doniana leaf for metal ions in aqueous solutions. African Journal of Biotechnology. 2009;8(3).
  • 13. Florey K. Analytical profile of drug substances. Academic Press; 1978.
  • 14. Kerkez-Kuyumcu Ö, Bayazit ŞS, Salam MA. Antibiotic amoxicillin removal from aqueous solution using magnetically modified graphene nanoplatelets. Journal of Industrial and Engineering Chemistry. 2016 Apr;36:198–205.
  • 15. Kakavandi B, Rezaei KR, Jonidi JA, Esrafily A, Gholizadeh A, Azari A. Efficiency of powder activated carbon magnetized by Fe3O4 nanoparticles for amoxicillin removal from aqueous solutions: Equilibrium and kinetic studies of adsorption process. 2014; 7(1): 21-34.
  • 16. Bakatula EN, Richard D, Neculita CM, Zagury GJ. Determination of point of zero charge of natural organic materials. Environ Sci Pollut Res. 2018 Mar;25(8):7823–33.
  • 17. Tran HN, You S-J, Hosseini-Bandegharaei A, Chao H-P. Mistakes and inconsistencies regarding adsorption of contaminants from aqueous solutions: A critical review. Water Research. 2017 Sep;120:88–116.
  • 18. Ouasfi N, Zbair M, Bouzikri S, Anfar Z, Bensitel M, Ait Ahsaine H, et al. Selected pharmaceuticals removal using algae derived porous carbon: experimental, modeling and DFT theoretical insights. RSC Adv. 2019;9(17):9792–808.
  • 19. Chen Y, Shi J, Du Q, Zhang H, Cui Y. Antibiotic removal by agricultural waste biochars with different forms of iron oxide. RSC Adv. 2019;9(25):14143–53.
  • 20. Cornell RM, Schwertmann U. The iron oxides: structure, properties, reactions, occurrences, and uses. 2nd, completely rev. and extended ed ed. Weinheim: Wiley-VCH; 2003. 664 p. ISBN: 978-3-527-30274-1.
  • 21. Liu P, Li H, Liu X, Wan Y, Han X, Zou W. Preparation of magnetic biochar obtained from one-step pyrolysis of salix mongolica and investigation into adsorption behavior of sulfadimidine sodium and norfloxacin in aqueous solution. Journal of Dispersion Science and Technology. 2020 Jan 28;41(2):214–26.
  • 22. Yunusa U, Bishir U, Bashir IM. Experimental and quantum chemical investigation for the single and competitive adsorption of cationic dyes onto activated carbon. Alg J Eng Technol. 2021 Feb 4;4:7–21.
  • 23. Devi P, Saroha AK. Simultaneous adsorption and dechlorination of pentachlorophenol from effluent by Ni–ZVI magnetic biochar composites synthesized from paper mill sludge. Chemical Engineering Journal. 2015 Jul;271:195–203.
  • 24. Santhosh C, Daneshvar E, Tripathi KM, Baltrėnas P, Kim T, Baltrėnaitė E, et al. Synthesis and characterization of magnetic biochar adsorbents for the removal of Cr(VI) and Acid orange 7 dye from aqueous solution. Environ Sci Pollut Res. 2020 Sep;27(26):32874–87.
  • 25. Alnajrani MN, Alsager OA. Removal of Antibiotics from Water by Polymer of Intrinsic Microporosity: Isotherms, Kinetics, Thermodynamics, and Adsorption Mechanism. Sci Rep. 2020 Dec;10(1):794.
  • 26. Berges J, Moles S, Ormad MP, Mosteo R, Gómez J. Antibiotics removal from aquatic environments: adsorption of enrofloxacin, trimethoprim, sulfadiazine, and amoxicillin on vegetal powdered activated carbon. Environ Sci Pollut Res. 2021 Feb;28(7):8442–52.
  • 27. Ahmed M, Mashkoor F, Nasar A. Development, characterization, and utilization of magnetized orange peel waste as a novel adsorbent for the confiscation of crystal violet dye from aqueous solution. Groundwater for Sustainable Development. 2020 Apr;10:100322.
  • 28. Mokhati A, Benturki O, Bernardo M, Kecira Z, Matos I, Lapa N, et al. Nanoporous carbons prepared from argan nutshells as potential removal agents of diclofenac and paroxetine. Journal of Molecular Liquids. 2021 Mar;326:115368.
  • 29. Liu H, Hu Z, Liu H, Xie H, Lu S, Wang Q, et al. Adsorption of amoxicillin by Mn-impregnated activated carbons: performance and mechanisms. RSC Adv. 2016;6(14):11454–60.
  • 30. Yunusa U, Usman B, Ibrahi̇M M. Modeling and Regeneration Studies for the Removal of Crystal Violet Using Balanites aegyptiaca Seed Shell Activated Carbon. Journal of the Turkish Chemical Society Section A: Chemistry. 2020 Dec 29;197–210.
  • 31. Umar Y, Abu-Thabit N, Jerabek P, Ramasami P. Experimental FTIR and theoretical investigation of the molecular structure and vibrational spectra of acetanilide using DFT and dispersion correction to DFT. J Theor Comput Chem. 2019 Mar;18(02):1950009.
  • 32. Khan SA, Rizwan K, Shahid S, Noamaan MA, Rasheed T, Amjad H. Synthesis, DFT, computational exploration of chemical reactivity, molecular docking studies of novel formazan metal complexes and their biological applications. Appl Organometal Chem [Internet]. 2020 Mar [cited 2021 Oct 29];34(3).5444, 1-24.

Experimental and DFT Computational Insights on the Adsorption of Selected Pharmaceuticals of Emerging Concern from Water Systems onto Magnetically Modified Biochar

Yıl 2021, Cilt 8, Sayı 4, 1179 - 1196, 30.11.2021
https://doi.org/10.18596/jotcsa.900197

Öz

This work aimed to fabricate a magnetically modified biochar (MBC) through a one-step pyrolysis of Vitex doniana nut at 500 °C and investigate its feasibility for the removal of two pharmaceuticals, namely, amoxicillin (AMX) and trimethoprim (TMT) from aqueous environment. The textural characteristics, chemical composition and magnetic properties of the MBC were analyzed using Brunauer-Emmett-Teller (BET) analysis, scanning electron microscopy (SEM), Fourier Transform Infrared (FTIR) spectroscopy, X-ray diffraction (XRD) and vibrating sample magnetometer (VSM). The results demonstrated the successful incorporation of the magnetic particles in the biochar matrix. The specific surface area and average pore volume of the MBC were obtained as 108.90 m2/g and 2.98 cm3/g, respectively. The adsorption process was observed to be strongly pH-dependent, and equilibrium was attained within 1 h. The kinetic data favors pseudo-second-order model (R2 > 0.999), implying that the most plausible mechanism for the adsorption was chemisorption. The isothermal data was best fitted by the Langmuir model (R2 > 0.985), signifying that the process was mainly monolayer adsorption on homogeneous surface. The maximum adsorption capacity achieved for AMX and TMT was 41.87 and 55.83 mg/g at 303 K, respectively. The thermodynamic examination highlighted that the adsorption was feasible and accompanied with absorption of heat and increase of entropy for both the adsorbates. Furthermore, the MBC exhibited a good recycling capability such that the adsorption capacity decreases by ~ 25% after reuse for six cycles. Besides, the theoretical results based on density functional theory (DFT) calculations demonstrated that the TMT molecules (ΔE = 3.762 eV) are more reactive compared to the AMX molecules (ΔE = 3.855 eV) which correlates with the experimental observations.

Kaynakça

  • 1. Ebele AJ, Abou-Elwafa Abdallah M, Harrad S. Pharmaceuticals and personal care products (PPCPs) in the freshwater aquatic environment. Emerging Contaminants. 2017 Mar;3(1):1–16.
  • 2. Daughton CG. Pharmaceuticals and the Environment (PiE): Evolution and impact of the published literature revealed by bibliometric analysis. Science of The Total Environment. 2016 Aug;562:391–426.
  • 3. Nazari G, Abolghasemi H, Esmaieli M. Batch adsorption of cephalexin antibiotic from aqueous solution by walnut shell-based activated carbon. Journal of the Taiwan Institute of Chemical Engineers. 2016 Jan;58:357–65.
  • 4. Domínguez JR, González T, Palo P, Cuerda-Correa EM. Removal of common pharmaceuticals present in surface waters by Amberlite XAD-7 acrylic-ester-resin: Influence of pH and presence of other drugs. Desalination. 2011 Mar;269(1–3):231–8.
  • 5. Sophia A. C, Lima EC. Removal of emerging contaminants from the environment by adsorption. Ecotoxicology and Environmental Safety. 2018 Apr;150:1–17.
  • 6. Danalıoğlu ST, Bayazit ŞS, Kerkez Kuyumcu Ö, Salam MA. Efficient removal of antibiotics by a novel magnetic adsorbent: Magnetic activated carbon/chitosan (MACC) nanocomposite. Journal of Molecular Liquids. 2017 Aug;240:589–96.
  • 7. Dai Y, Zhang N, Xing C, Cui Q, Sun Q. The adsorption, regeneration and engineering applications of biochar for removal organic pollutants: A review. Chemosphere. 2019 May;223:12–27.
  • 8. Zhang A, Li X, Xing J, Xu G. Adsorption of potentially toxic elements in water by modified biochar: A review. Journal of Environmental Chemical Engineering. 2020 Aug;8(4):104196.
  • 9. Hao Z, Wang C, Yan Z, Jiang H, Xu H. Magnetic particles modification of coconut shell-derived activated carbon and biochar for effective removal of phenol from water. Chemosphere. 2018 Nov;211:962–9.
  • 10. Dadjo C, Assogbadjo AE, Fandohan B, Glèlè Kakaï R, Chakeredza S, Houehanou TD, et al. Uses and management of black plum ( Vitex doniana Sweet ) in Southern Benin. Fruits. 2012 Jul;67(4):239–48.
  • 11. Ameh PO, Odoh R, Oluwaseye A. Equilibrium study on the adsorption of Zn (II) and Pb (II) ions from aqueous solution onto Vitex doniana nut. Int J Modern Chem. 2012;3(2):82–97.
  • 12. Atolaiye BO, Babalola JO, Adebayo MA, Aremu MO. Equilibrium modeling and pH-dependence of the adsorption capacity of Vitex doniana leaf for metal ions in aqueous solutions. African Journal of Biotechnology. 2009;8(3).
  • 13. Florey K. Analytical profile of drug substances. Academic Press; 1978.
  • 14. Kerkez-Kuyumcu Ö, Bayazit ŞS, Salam MA. Antibiotic amoxicillin removal from aqueous solution using magnetically modified graphene nanoplatelets. Journal of Industrial and Engineering Chemistry. 2016 Apr;36:198–205.
  • 15. Kakavandi B, Rezaei KR, Jonidi JA, Esrafily A, Gholizadeh A, Azari A. Efficiency of powder activated carbon magnetized by Fe3O4 nanoparticles for amoxicillin removal from aqueous solutions: Equilibrium and kinetic studies of adsorption process. 2014; 7(1): 21-34.
  • 16. Bakatula EN, Richard D, Neculita CM, Zagury GJ. Determination of point of zero charge of natural organic materials. Environ Sci Pollut Res. 2018 Mar;25(8):7823–33.
  • 17. Tran HN, You S-J, Hosseini-Bandegharaei A, Chao H-P. Mistakes and inconsistencies regarding adsorption of contaminants from aqueous solutions: A critical review. Water Research. 2017 Sep;120:88–116.
  • 18. Ouasfi N, Zbair M, Bouzikri S, Anfar Z, Bensitel M, Ait Ahsaine H, et al. Selected pharmaceuticals removal using algae derived porous carbon: experimental, modeling and DFT theoretical insights. RSC Adv. 2019;9(17):9792–808.
  • 19. Chen Y, Shi J, Du Q, Zhang H, Cui Y. Antibiotic removal by agricultural waste biochars with different forms of iron oxide. RSC Adv. 2019;9(25):14143–53.
  • 20. Cornell RM, Schwertmann U. The iron oxides: structure, properties, reactions, occurrences, and uses. 2nd, completely rev. and extended ed ed. Weinheim: Wiley-VCH; 2003. 664 p. ISBN: 978-3-527-30274-1.
  • 21. Liu P, Li H, Liu X, Wan Y, Han X, Zou W. Preparation of magnetic biochar obtained from one-step pyrolysis of salix mongolica and investigation into adsorption behavior of sulfadimidine sodium and norfloxacin in aqueous solution. Journal of Dispersion Science and Technology. 2020 Jan 28;41(2):214–26.
  • 22. Yunusa U, Bishir U, Bashir IM. Experimental and quantum chemical investigation for the single and competitive adsorption of cationic dyes onto activated carbon. Alg J Eng Technol. 2021 Feb 4;4:7–21.
  • 23. Devi P, Saroha AK. Simultaneous adsorption and dechlorination of pentachlorophenol from effluent by Ni–ZVI magnetic biochar composites synthesized from paper mill sludge. Chemical Engineering Journal. 2015 Jul;271:195–203.
  • 24. Santhosh C, Daneshvar E, Tripathi KM, Baltrėnas P, Kim T, Baltrėnaitė E, et al. Synthesis and characterization of magnetic biochar adsorbents for the removal of Cr(VI) and Acid orange 7 dye from aqueous solution. Environ Sci Pollut Res. 2020 Sep;27(26):32874–87.
  • 25. Alnajrani MN, Alsager OA. Removal of Antibiotics from Water by Polymer of Intrinsic Microporosity: Isotherms, Kinetics, Thermodynamics, and Adsorption Mechanism. Sci Rep. 2020 Dec;10(1):794.
  • 26. Berges J, Moles S, Ormad MP, Mosteo R, Gómez J. Antibiotics removal from aquatic environments: adsorption of enrofloxacin, trimethoprim, sulfadiazine, and amoxicillin on vegetal powdered activated carbon. Environ Sci Pollut Res. 2021 Feb;28(7):8442–52.
  • 27. Ahmed M, Mashkoor F, Nasar A. Development, characterization, and utilization of magnetized orange peel waste as a novel adsorbent for the confiscation of crystal violet dye from aqueous solution. Groundwater for Sustainable Development. 2020 Apr;10:100322.
  • 28. Mokhati A, Benturki O, Bernardo M, Kecira Z, Matos I, Lapa N, et al. Nanoporous carbons prepared from argan nutshells as potential removal agents of diclofenac and paroxetine. Journal of Molecular Liquids. 2021 Mar;326:115368.
  • 29. Liu H, Hu Z, Liu H, Xie H, Lu S, Wang Q, et al. Adsorption of amoxicillin by Mn-impregnated activated carbons: performance and mechanisms. RSC Adv. 2016;6(14):11454–60.
  • 30. Yunusa U, Usman B, Ibrahi̇M M. Modeling and Regeneration Studies for the Removal of Crystal Violet Using Balanites aegyptiaca Seed Shell Activated Carbon. Journal of the Turkish Chemical Society Section A: Chemistry. 2020 Dec 29;197–210.
  • 31. Umar Y, Abu-Thabit N, Jerabek P, Ramasami P. Experimental FTIR and theoretical investigation of the molecular structure and vibrational spectra of acetanilide using DFT and dispersion correction to DFT. J Theor Comput Chem. 2019 Mar;18(02):1950009.
  • 32. Khan SA, Rizwan K, Shahid S, Noamaan MA, Rasheed T, Amjad H. Synthesis, DFT, computational exploration of chemical reactivity, molecular docking studies of novel formazan metal complexes and their biological applications. Appl Organometal Chem [Internet]. 2020 Mar [cited 2021 Oct 29];34(3).5444, 1-24.

Ayrıntılar

Birincil Dil İngilizce
Konular Fizikokimya
Bölüm Makaleler
Yazarlar

Umar YUNUSA (Sorumlu Yazar)
Bayero University, Kano-Nigeria
0000-0002-7970-8639
Nigeria


Umaru UMAR Bu kişi benim
Bayero University, Kano, Nigeria
0000-0002-0405-5362
Nigeria


Sulaiman IDRİSS Bu kişi benim
Fedral Polytechnic Offa, Kwara State
0000-0002-9309-0636
Nigeria


Abdulrahman IBRAHİM Bu kişi benim
Adamawa State University Mubi
0000-0003-2625-3551
Nigeria


Tahir ABDULLAHİ Bu kişi benim
Yobe State University, Damaturu
0000-0001-8705-5052
Nigeria

Yayımlanma Tarihi 30 Kasım 2021
Başvuru Tarihi 20 Mart 2021
Kabul Tarihi 25 Ekim 2021
Yayınlandığı Sayı Yıl 2021, Cilt 8, Sayı 4

Kaynak Göster

Vancouver Yunusa U. , Umar U. , Idriss S. , Ibrahim A. , Abdullahi T. Experimental and DFT Computational Insights on the Adsorption of Selected Pharmaceuticals of Emerging Concern from Water Systems onto Magnetically Modified Biochar. Journal of the Turkish Chemical Society Section A: Chemistry. 2021; 8(4): 1179-1196.
J. Turk. Chem. Soc., Sect. A: Chem.