Research Article
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Removal of Methylene Blue Dye from Aqueous Solution Using Trichlorovinylsilane Chitosan–g–polyacrylamide Hydrogel

Year 2023, Volume: 10 Issue: 4, 1009 - 1018, 11.11.2023
https://doi.org/10.18596/jotcsa.1292604

Abstract

A new hydrogel based on vinylsilane-chitosan and acrylamide was synthesized as VSi-CTS-g-PAAm and was used to remove methylene blue (MB) from aqueous solution using batch adsorption technique. The VSi-CTS-PAAm hydrogel interacted with methylene blue (MB) dye solution at different mass-liquid ratios, pH, and temperature. The amount of MB dye removal was estimated using a UV-Vis spectrophotometer at an optical density of λmax= 665 nm. The MB dye removal was most effective at pH 12, with about 98 % removal at 50 °C. The study's findings also indicated that the equilibrium data exhibited the highest degree of conformity with the Langmuir isotherm model. Additionally, the adsorption process adhered to the pseudo-second-order kinetics and was characterized as endothermic. Therefore, our study suggests that the utilization of prepared materials may have potential advantages in treating wastewater containing dyes.

References

  • 1. Ogugbue CJ, Sawidis T. Bioremediation and detoxification of synthetic wastewater containing triarylmethane dyes by Aeromonas hydrophila Isolated from Industrial Effluent. Biotechnol Res Int [Internet]. 2011 Jul 25;2011:967925. Available from: <URL>.
  • 2. Samchetshabam G, Hussan A, Choudhury TG. Impact of textile dyes waste on aquatic environments and its treatment revival of fisheries cooperatives and fisheries federation of Assam View project Hilsa Project View project. Environ Ecol [Internet]. 2017;35(3C):2349–53. Available from: <URL>.
  • 3. Cai J, Zhang D, Xu W, Ding W-P, Zhu Z-Z, He J-R, et al. Polysaccharide-based hydrogels derived from cellulose: the architecture change from nanofibers to hydrogels for a putative dual function in dye wastewater treatment. J Agric Food Chem [Internet]. 2020 Sep 9;68(36):9725–32. Available from: <URL>.
  • 4. Hameed BH. Spent tea leaves: A new non-conventional and low-cost adsorbent for removal of basic dye from aqueous solutions. J Hazard Mater [Internet]. 2009 Jan 30;161(2–3):753–9. Available from: <URL>.
  • 5. Salleh MAM, Mahmoud DK, Karim WAWA, Idris A. Cationic and anionic dye adsorption by agricultural solid wastes: A comprehensive review. Desalination [Internet]. 2011 Oct 3;280(1–3):1–13. Available from: <URL>.
  • 6. Bhatti HN, Akhtar N, Saleem N. Adsorptive Removal of Methylene Blue by Low-Cost Citrus sinensis Bagasse: Equilibrium, Kinetic and Thermodynamic Characterization. Arab J Sci Eng [Internet]. 2012 Jan 13;37(1):9–18. Available from: <URL>.
  • 7. Bhatti HN, Safa Y. Removal of anionic dyes by rice milling waste from synthetic effluents: equilibrium and thermodynamic studies. Desalin Water Treat [Internet]. 2012 Oct;48(1–3):267–77. Available from: <URL>.
  • 8. Mittal A, Jain R, Mittal J, Varshney S, Sikarwar S. Removal of Yellow ME 7 GL from industrial effluent using electrochemical and adsorption techniques. Int J Environ Pollut [Internet]. 2010;43(4):308–23. Available from: <URL>.
  • 9. Daraei H, Mittal A, Noorisepehr M, Mittal J. Separation of chromium from water samples using eggshell powder as a low-cost sorbent: kinetic and thermodynamic studies. Desalin Water Treat [Internet]. 2015 Jan 2;53(1):214–20. Available from: <URL>.
  • 10. Noreen S, Bhatti HN, Nausheen S, Sadaf S, Ashfaq M. Batch and fixed bed adsorption study for the removal of Drimarine Black CL-B dye from aqueous solution using a lignocellulosic waste: A cost affective adsorbent. Ind Crops Prod [Internet]. 2013 Oct 1;50:568–79. Available from: <URL>.
  • 11. Puoci F, Iemma F, Spizzirri UG, Cirillo G, Curcio M, Picci N. Polymer in Agriculture: a Review. Am J Agric Biol Sci [Internet]. 2008 Jan 1;3(1):299–314. Available from: <URL>.
  • 12. Kosemund K, Schlatter H, Ochsenhirt JL, Krause EL, Marsman DS, Erasala GN. Safety evaluation of superabsorbent baby diapers. Regul Toxicol Pharmacol [Internet]. 2009 Mar 1;53(2):81–9. Available from: <URL>.
  • 13. Buenger D, Topuz F, Groll J. Hydrogels in sensing applications. Prog Polym Sci [Internet]. 2012 Dec 1;37(12):1678–719. Available from: <URL>.
  • 14. Holback H, Yeo Y, Park K. Hydrogel swelling behavior and its biomedical applications. In: Biomedical Hydrogels [Internet]. Elsevier; 2011. p. 3–24. Available from: <URL>.
  • 15. Grade S, Eberhard J, Neumeister A, Wagener P, Winkel A, Stiesch M, et al. Serum albumin reduces the antibacterial and cytotoxic effects of hydrogel-embedded colloidal silver nanoparticles. RSC Adv [Internet]. 2012 Jul 30;2(18):7190. Available from: <URL>.
  • 16. Li S, Dong S, Xu W, Tu S, Yan L, Zhao C, et al. Antibacterial Hydrogels. Adv Sci [Internet]. 2018 May 1;5(5):1700527. Available from: <URL>.
  • 17. Yang J, Chen Y, Zhao L, Feng Z, Peng K, Wei A, et al. Preparation of a chitosan/carboxymethyl chitosan/AgNPs polyelectrolyte composite physical hydrogel with self-healing ability, antibacterial properties, and good biosafety simultaneously, and its application as a wound dressing. Compos Part B Eng [Internet]. 2020 Sep 15;197:108139. Available from: <URL>.
  • 18. Lu H, Wang X, Shi X, Yu K, Fu YQ. A phenomenological model for dynamic response of double-network hydrogel composite undergoing transient transition. Compos Part B Eng [Internet]. 2018 Oct 15;151:148–53. Available from: <URL>.
  • 19. Jana S, Pradhan SS, Tripathy T. Poly(N,N-dimethylacrylamide-co-acrylamide) Grafted hydroxyethyl cellulose hydrogel: a useful congo red dye remover. J Polym Environ [Internet]. 2018 Jul 13;26(7):2730–47. Available from: <URL>.
  • 20. Ravi Kumar MN. A review of chitin and chitosan applications. React Funct Polym [Internet]. 2000 Nov 1;46(1):1–27. Available from: <URL>.
  • 21. Al-Harby NF, Albahly EF, Mohamed NA. Synthesis and characterization of novel uracil-modified chitosan as a promising adsorbent for efficient removal of congo red dye. Polymers (Basel) [Internet]. 2022 Jan 10;14(2):271. Available from: <URL>.
  • 22. Mohamed NA, Abd El-Ghany NA. Synthesis, characterization, and antimicrobial activity of carboxymethyl chitosan-graft-poly(n-acryloyl,n′-cyanoacetohydrazide) copolymers. J Carbohydr Chem [Internet]. 2012 Mar 1;31(3):220–40. Available from: <URL>.
  • 23. Abraham A, Soloman PA, Rejini VO. Preparation of chitosan-polyvinyl alcohol blends and studies on thermal and mechanical properties. Procedia Technol [Internet]. 2016 Jan 1;24:741–8. Available from: <URL>.
  • 24. Elmehbad NY, Mohamed NA. Terephthalohydrazido cross-linked chitosan hydrogels: synthesis, characterization and applications. Int J Polym Mater Polym Biomater [Internet]. 2022 Sep 2;71(13):969–82. Available from: <URL>.
  • 25. Elsayed NH, Monier M, Youssef I. Fabrication of photo-active trans -3-(4-pyridyl)acrylic acid modified chitosan. Carbohydr Polym [Internet]. 2017 Sep 15;172:1–10. Available from: <URL>.
  • 26. Anwar J, Shafique U, Waheed-uz-Zaman, Salman M, Dar A, Anwar S. Removal of Pb(II) and Cd(II) from water by adsorption on peels of banana. Bioresour Technol [Internet]. 2010 Mar 1;101(6):1752–5. Available from: <URL>.
  • 27. Elaigwu SE, Rocher V, Kyriakou G, Greenway GM. Removal of Pb2+ and Cd2+ from aqueous solution using chars from pyrolysis and microwave-assisted hydrothermal carbonization of Prosopis africana shell. J Ind Eng Chem [Internet]. 2014 Sep 25;20(5):3467–73. Available from: <URL>.
  • 28. Olgun A, Atar N. Equilibrium, thermodynamic and kinetic studies for the adsorption of lead (II) and nickel (II) onto clay mixture containing boron impurity. J Ind Eng Chem [Internet]. 2012 Sep 25;18(5):1751–7. Available from: <URL>.
  • 29. Shokry A, El Tahan A, Ibrahim H, Soliman M, Ebrahim S. Polyaniline/akaganeite superparamagnetic nanocomposite for cadmium uptake from polluted water. Desalin Water Treat [Internet]. 2019;171:205–15. Available from: <URL>.
  • 30. Bamgbose JT, Elaigwu SE, Adimula VO, Okeowo HO, Olayemi VT, Ameen OA, et al. Green route synthesis and adsorption studies of copper-benzimidazole coordination polymer for removal of methyl orange from water. Chem Africa [Internet]. 2023 Apr 14;Article in Press:1–12. Available from: <URL>.
  • 31. Tella AC, Bamgbose JT, Adimula VO, Omotoso M, Elaigwu SE, Olayemi VT, et al. Synthesis of metal–organic frameworks (MOFs) MIL-100(Fe) functionalized with thioglycolic acid and ethylenediamine for removal of eosin B dye from aqueous solution. SN Appl Sci [Internet]. 2021 Jan 13;3(1):136. Available from: <URL>.
  • 32. Al-qudah YHF, Mahmoud GA, Abdel Khalek MA. Radiation crosslinked poly (vinyl alcohol)/acrylic acid copolymer for removal of heavy metal ions from aqueous solutions. J Radiat Res Appl Sci [Internet]. 2014 Apr 1;7(2):135–45. Available from: <URL>.
  • 33. Chen X, Chen G, Chen L, Chen Y, Lehmann J, McBride MB, et al. Adsorption of copper and zinc by biochars produced from pyrolysis of hardwood and corn straw in aqueous solution. Bioresour Technol [Internet]. 2011 Oct 1;102(19):8877–84. Available from: <URL>.
  • 34. Elkady MF, El-Aassar MR, Hassan HS. Adsorption profile of basic dye onto novel fabricated carboxylated functionalized co-polymer nanofibers. Polymers (Basel) [Internet]. 2016 Apr 29 [cited 2023 Sep 5];8(5):177. Available from: <URL>.
Year 2023, Volume: 10 Issue: 4, 1009 - 1018, 11.11.2023
https://doi.org/10.18596/jotcsa.1292604

Abstract

References

  • 1. Ogugbue CJ, Sawidis T. Bioremediation and detoxification of synthetic wastewater containing triarylmethane dyes by Aeromonas hydrophila Isolated from Industrial Effluent. Biotechnol Res Int [Internet]. 2011 Jul 25;2011:967925. Available from: <URL>.
  • 2. Samchetshabam G, Hussan A, Choudhury TG. Impact of textile dyes waste on aquatic environments and its treatment revival of fisheries cooperatives and fisheries federation of Assam View project Hilsa Project View project. Environ Ecol [Internet]. 2017;35(3C):2349–53. Available from: <URL>.
  • 3. Cai J, Zhang D, Xu W, Ding W-P, Zhu Z-Z, He J-R, et al. Polysaccharide-based hydrogels derived from cellulose: the architecture change from nanofibers to hydrogels for a putative dual function in dye wastewater treatment. J Agric Food Chem [Internet]. 2020 Sep 9;68(36):9725–32. Available from: <URL>.
  • 4. Hameed BH. Spent tea leaves: A new non-conventional and low-cost adsorbent for removal of basic dye from aqueous solutions. J Hazard Mater [Internet]. 2009 Jan 30;161(2–3):753–9. Available from: <URL>.
  • 5. Salleh MAM, Mahmoud DK, Karim WAWA, Idris A. Cationic and anionic dye adsorption by agricultural solid wastes: A comprehensive review. Desalination [Internet]. 2011 Oct 3;280(1–3):1–13. Available from: <URL>.
  • 6. Bhatti HN, Akhtar N, Saleem N. Adsorptive Removal of Methylene Blue by Low-Cost Citrus sinensis Bagasse: Equilibrium, Kinetic and Thermodynamic Characterization. Arab J Sci Eng [Internet]. 2012 Jan 13;37(1):9–18. Available from: <URL>.
  • 7. Bhatti HN, Safa Y. Removal of anionic dyes by rice milling waste from synthetic effluents: equilibrium and thermodynamic studies. Desalin Water Treat [Internet]. 2012 Oct;48(1–3):267–77. Available from: <URL>.
  • 8. Mittal A, Jain R, Mittal J, Varshney S, Sikarwar S. Removal of Yellow ME 7 GL from industrial effluent using electrochemical and adsorption techniques. Int J Environ Pollut [Internet]. 2010;43(4):308–23. Available from: <URL>.
  • 9. Daraei H, Mittal A, Noorisepehr M, Mittal J. Separation of chromium from water samples using eggshell powder as a low-cost sorbent: kinetic and thermodynamic studies. Desalin Water Treat [Internet]. 2015 Jan 2;53(1):214–20. Available from: <URL>.
  • 10. Noreen S, Bhatti HN, Nausheen S, Sadaf S, Ashfaq M. Batch and fixed bed adsorption study for the removal of Drimarine Black CL-B dye from aqueous solution using a lignocellulosic waste: A cost affective adsorbent. Ind Crops Prod [Internet]. 2013 Oct 1;50:568–79. Available from: <URL>.
  • 11. Puoci F, Iemma F, Spizzirri UG, Cirillo G, Curcio M, Picci N. Polymer in Agriculture: a Review. Am J Agric Biol Sci [Internet]. 2008 Jan 1;3(1):299–314. Available from: <URL>.
  • 12. Kosemund K, Schlatter H, Ochsenhirt JL, Krause EL, Marsman DS, Erasala GN. Safety evaluation of superabsorbent baby diapers. Regul Toxicol Pharmacol [Internet]. 2009 Mar 1;53(2):81–9. Available from: <URL>.
  • 13. Buenger D, Topuz F, Groll J. Hydrogels in sensing applications. Prog Polym Sci [Internet]. 2012 Dec 1;37(12):1678–719. Available from: <URL>.
  • 14. Holback H, Yeo Y, Park K. Hydrogel swelling behavior and its biomedical applications. In: Biomedical Hydrogels [Internet]. Elsevier; 2011. p. 3–24. Available from: <URL>.
  • 15. Grade S, Eberhard J, Neumeister A, Wagener P, Winkel A, Stiesch M, et al. Serum albumin reduces the antibacterial and cytotoxic effects of hydrogel-embedded colloidal silver nanoparticles. RSC Adv [Internet]. 2012 Jul 30;2(18):7190. Available from: <URL>.
  • 16. Li S, Dong S, Xu W, Tu S, Yan L, Zhao C, et al. Antibacterial Hydrogels. Adv Sci [Internet]. 2018 May 1;5(5):1700527. Available from: <URL>.
  • 17. Yang J, Chen Y, Zhao L, Feng Z, Peng K, Wei A, et al. Preparation of a chitosan/carboxymethyl chitosan/AgNPs polyelectrolyte composite physical hydrogel with self-healing ability, antibacterial properties, and good biosafety simultaneously, and its application as a wound dressing. Compos Part B Eng [Internet]. 2020 Sep 15;197:108139. Available from: <URL>.
  • 18. Lu H, Wang X, Shi X, Yu K, Fu YQ. A phenomenological model for dynamic response of double-network hydrogel composite undergoing transient transition. Compos Part B Eng [Internet]. 2018 Oct 15;151:148–53. Available from: <URL>.
  • 19. Jana S, Pradhan SS, Tripathy T. Poly(N,N-dimethylacrylamide-co-acrylamide) Grafted hydroxyethyl cellulose hydrogel: a useful congo red dye remover. J Polym Environ [Internet]. 2018 Jul 13;26(7):2730–47. Available from: <URL>.
  • 20. Ravi Kumar MN. A review of chitin and chitosan applications. React Funct Polym [Internet]. 2000 Nov 1;46(1):1–27. Available from: <URL>.
  • 21. Al-Harby NF, Albahly EF, Mohamed NA. Synthesis and characterization of novel uracil-modified chitosan as a promising adsorbent for efficient removal of congo red dye. Polymers (Basel) [Internet]. 2022 Jan 10;14(2):271. Available from: <URL>.
  • 22. Mohamed NA, Abd El-Ghany NA. Synthesis, characterization, and antimicrobial activity of carboxymethyl chitosan-graft-poly(n-acryloyl,n′-cyanoacetohydrazide) copolymers. J Carbohydr Chem [Internet]. 2012 Mar 1;31(3):220–40. Available from: <URL>.
  • 23. Abraham A, Soloman PA, Rejini VO. Preparation of chitosan-polyvinyl alcohol blends and studies on thermal and mechanical properties. Procedia Technol [Internet]. 2016 Jan 1;24:741–8. Available from: <URL>.
  • 24. Elmehbad NY, Mohamed NA. Terephthalohydrazido cross-linked chitosan hydrogels: synthesis, characterization and applications. Int J Polym Mater Polym Biomater [Internet]. 2022 Sep 2;71(13):969–82. Available from: <URL>.
  • 25. Elsayed NH, Monier M, Youssef I. Fabrication of photo-active trans -3-(4-pyridyl)acrylic acid modified chitosan. Carbohydr Polym [Internet]. 2017 Sep 15;172:1–10. Available from: <URL>.
  • 26. Anwar J, Shafique U, Waheed-uz-Zaman, Salman M, Dar A, Anwar S. Removal of Pb(II) and Cd(II) from water by adsorption on peels of banana. Bioresour Technol [Internet]. 2010 Mar 1;101(6):1752–5. Available from: <URL>.
  • 27. Elaigwu SE, Rocher V, Kyriakou G, Greenway GM. Removal of Pb2+ and Cd2+ from aqueous solution using chars from pyrolysis and microwave-assisted hydrothermal carbonization of Prosopis africana shell. J Ind Eng Chem [Internet]. 2014 Sep 25;20(5):3467–73. Available from: <URL>.
  • 28. Olgun A, Atar N. Equilibrium, thermodynamic and kinetic studies for the adsorption of lead (II) and nickel (II) onto clay mixture containing boron impurity. J Ind Eng Chem [Internet]. 2012 Sep 25;18(5):1751–7. Available from: <URL>.
  • 29. Shokry A, El Tahan A, Ibrahim H, Soliman M, Ebrahim S. Polyaniline/akaganeite superparamagnetic nanocomposite for cadmium uptake from polluted water. Desalin Water Treat [Internet]. 2019;171:205–15. Available from: <URL>.
  • 30. Bamgbose JT, Elaigwu SE, Adimula VO, Okeowo HO, Olayemi VT, Ameen OA, et al. Green route synthesis and adsorption studies of copper-benzimidazole coordination polymer for removal of methyl orange from water. Chem Africa [Internet]. 2023 Apr 14;Article in Press:1–12. Available from: <URL>.
  • 31. Tella AC, Bamgbose JT, Adimula VO, Omotoso M, Elaigwu SE, Olayemi VT, et al. Synthesis of metal–organic frameworks (MOFs) MIL-100(Fe) functionalized with thioglycolic acid and ethylenediamine for removal of eosin B dye from aqueous solution. SN Appl Sci [Internet]. 2021 Jan 13;3(1):136. Available from: <URL>.
  • 32. Al-qudah YHF, Mahmoud GA, Abdel Khalek MA. Radiation crosslinked poly (vinyl alcohol)/acrylic acid copolymer for removal of heavy metal ions from aqueous solutions. J Radiat Res Appl Sci [Internet]. 2014 Apr 1;7(2):135–45. Available from: <URL>.
  • 33. Chen X, Chen G, Chen L, Chen Y, Lehmann J, McBride MB, et al. Adsorption of copper and zinc by biochars produced from pyrolysis of hardwood and corn straw in aqueous solution. Bioresour Technol [Internet]. 2011 Oct 1;102(19):8877–84. Available from: <URL>.
  • 34. Elkady MF, El-Aassar MR, Hassan HS. Adsorption profile of basic dye onto novel fabricated carboxylated functionalized co-polymer nanofibers. Polymers (Basel) [Internet]. 2016 Apr 29 [cited 2023 Sep 5];8(5):177. Available from: <URL>.
There are 34 citations in total.

Details

Primary Language English
Subjects Physical Chemistry, Polymer Science and Technologies
Journal Section RESEARCH ARTICLES
Authors

Anthony U Awode This is me

Sunday Elaigwu 0000-0002-6411-1995

Akeem A Oladipo This is me

Osman Yılmaz This is me

Mustafa Gazi This is me

Publication Date November 11, 2023
Submission Date May 4, 2023
Acceptance Date August 21, 2023
Published in Issue Year 2023 Volume: 10 Issue: 4

Cite

Vancouver Awode AU, Elaigwu S, Oladipo AA, Yılmaz O, Gazi M. Removal of Methylene Blue Dye from Aqueous Solution Using Trichlorovinylsilane Chitosan–g–polyacrylamide Hydrogel. JOTCSA. 2023;10(4):1009-18.