mer-[InCl3(C5D5N)3]2·C5D5N: A New d5-pyridine Derivative of Indium(III) Chloride Complex

Year 2025, Volume: 12 Issue: 1, 15 - 22

Ali Tuna , Anastassios Papageorgiou , Anssi Peuronen , Pekka Peljo , Günther Knör

https://doi.org/10.18596/jotcsa.1590991

Abstract

In this study, we report the crystal structure of a meridional octahedral pyridine-indium(III) chloride adduct, mer-trichlorotris(d5-pyridine)indium(III)·0.5(d5-pyridine), InCl3(C5D5N)3·0.5(C5D5N), which exhibits an unreported molecule-to-solvent ratio compared to other substituted and unsubstituted pyridine-indium(III) chloride adducts described in earlier literature. The bonding characteristics of this d5-pyridine complex are compared to analogous complexes that have already been reported. Furthermore, the role of this metal complex in indium insertion into corrole ligands is discussed.

Keywords

indium, d5-pyridine, mer-isomer, solvated-complex, indium corrole

References

• 1. Janiak C, Meyer HJ, Gudat D, Kurz P. Riedel Moderne Anorganische Chemie [Internet]. Riedel E, Meyer HJ, editors. De Gruyter; 2018 [cited 2024 Dec 2]. Available from: https://www.degruyter.com/document/doi/10.1515/9783110441635/html
• 2. Hoffmann R, Beier BF, Muetterties EL, Rossi AR. Seven-coordination. A molecular orbital exploration of structure, stereochemistry, and reaction dynamics. Inorganic Chemistry. 1977;16(3):511–22.
• 3. Ehnbom A, Ghosh SK, Lewis KG, Gladysz JA. Octahedral Werner complexes with substituted ethylenediamine ligands: a stereochemical primer for a historic series of compounds now emerging as a modern family of catalysts. Chem Soc Rev [Internet]. 2016 [cited 2024 Dec 2];45(24):6799–811. Available from: https://xlink.rsc.org/?DOI=C6CS00604C
• 4. Sato H, Yamagishi A. Application of the ΔΛ isomerism of octahedral metal complexes as a chiral source in photochemistry. Journal of Photochemistry and Photobiology C: Photochemistry Reviews [Internet]. 2007 Oct [cited 2024 Dec 2];8(2):67–84. Available from: https://linkinghub.elsevier.com/retrieve/pii/S1389556707000457
• 5. Scharwitz MA, Ott I, Gust R, Kromm A, Sheldrick WS. Synthesis, cellular uptake and structure-activity relationships for potent cytotoxic trichloridoiridium(III) polypyridyl complexes. Journal of Inorganic Biochemistry [Internet]. 2008 Aug [cited 2024 Dec 2];102(8):1623–30. Available from: https://linkinghub.elsevier.com/retrieve/pii/S0162013408000810
• 6. Von Zeiewsky A, Belser P, Hayoz P, Dux R, Hua X, Suckling A, et al. Tailor made coordination compounds for photochemical purposes. Coordination Chemistry Reviews [Internet]. 1994 May [cited 2024 Dec 2];132:75–85. Available from: https://linkinghub.elsevier.com/retrieve/pii/001085459480026X
• 7. Soro B, Stoccoro S, Minghetti G, Zucca A, Cinellu MA, Gladiali S, et al. Synthesis of the First C-2 Cyclopalladated Derivatives of 1,3-Bis(2-pyridyl)benzene. Crystal Structures of [Hg(N-C-N)Cl], [Pd(N-C-N)Cl], and [Pd2 (N-C-N)2 (μ-OAc)]2 [Hg2 Cl6 ]. Catalytic Activity in the Heck Reaction. Organometallics [Internet]. 2005 Jan 1 [cited 2024 Dec 2];24(1):53–61. Available from: https://pubs.acs.org/doi/10.1021/om040102o
• 8. Hietkamp S, Stufkens DJ, Vrieze K. Activation of CH bonds by transition metals. Journal of Organometallic Chemistry [Internet]. 1979 Mar [cited 2024 Dec 2];168(3):351–61. Available from: https://linkinghub.elsevier.com/retrieve/pii/S0022328X00832167
• 9. Gouterman M, Sayer P, Shankland E, Smith JP. Porphyrins. 41. Phosphorus mesoporphyrin and phthalocyanine. Inorganic Chemistry. 1981;20(1):87–92.
• 10. Knör G. Photophysik und Photochemie von Porphyrinkomplexen des Antimons: Entwicklung homogener photokatalytischer Modellsysteme zur Nutzung, Umwandlung und Speicherung von Solarenergie [Doctoral Thesis]. [Regensburg, Germany]: University of Regensburg; 1994.
• 11. Paolesse R, Licoccia S, Boschi T. Towards the periodic table of metallocorrolates: synthesis and characterization of main group metal complexes of octamethylcorrole. Inorganica Chimica Acta [Internet]. 1990 Dec [cited 2024 Dec 2];178(1):9–12. Available from: https://linkinghub.elsevier.com/retrieve/pii/S0020169300881256
• 12. Weaver JJ. CORROLES [Internet] [Doctoral Thesis]. [California, USA]: California Institute of Technology; 2005. Available from: https://core.ac.uk/download/pdf/11810364.pdf
• 13. Tuna A, Peljo P, Paolesse R, Knör G. Tris(pentafluorophenyl)corrolatoindium(III) – A Long-awaited Metallocorrole: Synthesis and Characterization. Journal of the Turkish Chemical Society Section A: Chemistry [Internet]. 2024 May 15 [cited 2024 Dec 2];11(2):803–12. Available from: http://dergipark.org.tr/en/doi/10.18596/jotcsa.1425456
• 14. Jeffs SE, Small RWH, Worrall IJ. Structure of the 4:1 complexes formed by pyridine and the Group III halides InCl3 and TlCl3: mer-trichlorotris(pyridine)indium(III)–pyridine (1/1), [InCl3(C5H5N)3].C5H5N, and mer-trichlorotris(pyridine)thallium(III)–pyridine (1/1), [TlCl3(C5H5N)3].C5H5N. Acta Crystallogr C Cryst Struct Commun [Internet]. 1984 Aug 15 [cited 2024 Dec 2];40(8):1329–31. Available from: https://scripts.iucr.org/cgi-bin/paper?S010827018400785X
• 15. Hepp AF, Schuff JD, Williams JN, Duraj SA, Fanwick PE. Preparation and Single-Crystal X-Ray Structures of Four Related Mixed-Ligand 4-Methylpyridine Indium Halide Complexes [Internet]. NASA; 2013. Available from: https://ntrs.nasa.gov/api/citations/20130011563/downloads/20130011563.pdf
• 16. Green M, Norager S, Moriarty P, Motevalli M, O’Brien P. On the synthesis and manipulation of InAs quantum dots. Journal of Materials Chemistry. 2000;10(8):1939–43.
• 17. Groom CR, Bruno IJ, Lightfoot MP, Ward SC. The Cambridge Structural Database. Acta Crystallogr B Struct Sci Cryst Eng Mater [Internet]. 2016 Apr 1 [cited 2024 Dec 2];72(2):171–9. Available from: https://scripts.iucr.org/cgi-bin/paper?S2052520616003954
• 18. Paolesse, R., Nardis, S., Sagone, F., Khoury R. G. Synthesis and functionalization of meso-aryl-substituted corroles. J. Org. Chem. 2001, 66, 550–556.
• 19. CrysAlisPro: An All-in-one Software Package for Single Crystal X-ray Diffraction [Internet]. Rigaku, Inc.; Available from: https://rigaku.com/products/crystallography/x-ray-diffraction/application-notes/px018-crysalispro-software-package-single-crystal
• 20. Dolomanov OV, Bourhis LJ, Gildea RJ, Howard JAK, Puschmann H. OLEX2 : a complete structure solution, refinement and analysis program. J Appl Crystallogr [Internet]. 2009 Apr 1 [cited 2024 Dec 2];42(2):339–41. Available from: https://scripts.iucr.org/cgi-bin/paper?S0021889808042726
• 21. Sheldrick GM. SHELXT–Integrated space-group and crystal-structure determination. Acta Crystallographica Section A: Foundations and Advances. 2015;71(1):3–8.