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THE EFFECT of MINOR Ti and Sr ADDITION on the MICROSTRUCTURAL, MECHANICAL, and CORROSION PROPERTIES of a BIODEGRADABLE Mg-5Sn-3Al ALLOY

Yıl 2022, Sayı: 049, 171 - 183, 30.06.2022

Öz

In this study, the microstructural, mechanical, and corrosion properties of the alloys obtained by adding Al-15Ti and Al-15Sr master alloys to the Mg-5Sn alloy were investigated. Microstructural properties of the alloys were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), and optical microscopy (OM). The mechanical properties of the alloys were analyzed by performing tensile tests, macrohardness tests, and nanoindentation tests. Corrosion behavior of both alloys was investigated by determining the corrosion rates with both electrochemical techniques and immersion techniques in Hanks Balanced Salt Solution (HBSS). When the microstructure results were examined, it was observed that minor Ti and Sr have a significant effect on reducing magnesium grain size, with Ti being more effective in grain refining. When compared to Al-15Sr, the addition of Al-15Ti to Mg-5Sn improves both mechanical and corrosion properties more effectively.

Teşekkür

There is no funding body the author could acknowledge.

Kaynakça

  • [1] Witte, F., Hort, N., Vogt, C., Cohen, S., Kainer, K.U., Willumeit, R., Feyerabend, F., (2008), Degradable biomaterials based on magnesium corrosion, Curr. Opin. Solid State Mater. Sci., 12, 63 -72.
  • [2] Moravej, M. and Mantovani, D., (2011), Biodegradable metals for cardiovascular stent application: interests and new opportunities,” International journal of molecular sciences, 12 (7), 4250-4270.
  • [3] Kirkland, N.T., Birbilis, N. and Staiger, M.P., (2012), Assessing the corrosion of biodegradable magnesium implants: a critical review of current methodologies and their limitations. Acta biomaterialia, 8 (3), 925-936.
  • [4] Staiger, M.P., Pietak, A.M., Huadmai, J. and Dias, G., (2006), Magnesium and its alloys as orthopedic biomaterials: a review, Biomaterials, 27 (9), 1728-1734.
  • [5] Uddin, M.S., Hall, C., Murphy, P. (2015), Surface treatments for controlling corrosion rate of biodegradable Mg and Mg-based alloy implants,” Science and technology of advanced materials, 16 (5), 053501.
  • [6] Johnson, A.R., Munoz, A., Gottlieb J.L. and Jarrard, D.F., (2007), High dose zinc increases hospital admissions due to genitourinary complications, The Journal of urology, 177 (2), 639-643.
  • [7] Gu, X., Zheng, Y., Cheng, Y., Zhong, S. and Xi, T., (2009), In vitro corrosion and biocompatibility of binary magnesium alloys, Biomaterials, 30 (4), 484-498.
  • [8] Song, G., Control of biodegradation of biocompatable magnesium alloys (2007), Corrosion science, 49 (4), 1696-1701.
  • [9] Liu, X., Sun, J., Yang, Y., Pu, Z., Zheng, Y., (2015), In vitro investigation of ultra-pure Zn and its mini-tube as potential bioabsorbable stent material, Mater. Lett., 161, 53-56.
  • [10] Liu, H., Chen, Y., Tang, Y., Wei, S. and Niu, G., (2007), The microstructure, tensile properties, and creep behavior of as-cast Mg-(1–10)% Sn alloys, Journal of Alloys and Compounds, 440 (1-2). 122-126.
  • [11] Marya, M., Hector, L.G., Verma, R., Tong, W., (2006), Microstructural effects of AZ31 magnesium alloy on its tensile deformation and failure behaviors, Mater. Sci. Eng., A, 418, 341-356.
  • [12] Zheng, Y.F., Gu, X.N., Witte, F., (2014), Biodegradable metals, Mater. Sci. Eng. R. Rep., 77, 1-34.
  • [13] Homayun, B. Afshar, A., (2014), Microstructure, mechanical properties, corrosion behavior and cytotoxicity of Mg–Zn–Al–Ca alloys as biodegradable materials, J. Alloys Compd., 607, 1-10.
  • [14] Sunil, B.R., Kumar, T.S.S., Chakkingal, U., Nandakumar, V., Doble, M., et al. (2016), In vitro and in vivo studies of biodegradable fine grained AZ31 magnesium alloy produced by equal channel angular pressing, Mater. Sci. Eng. C, 59, 356-367.
  • [15] Sun, W., Zhang, G, Tan, L., Yang, K., Ai, H., (2016), The fluoride coated AZ31B magnesium alloy improves corrosion resistance and stimulates bone formation in rabbit model, Mater. Sci. Eng. C, 63, 506-511.
  • [16] Huang, Z.H., Zhou, N., Xu, J., Li, Y.D. and Li, W.R., (2017), Microstructure and Mechanical Property of Mg-Sn-Al Wrought Magnesium Alloys, In Materials Science Forum Trans Tech Publications Ltd., 898, 97-103.
  • [17] Bowles, A.L., Blawert, C., Hort, N. and Kainer, K.U., (2004), Microstructural investigations of the Mg-Sn and Mg-Sn-Al alloy systems, Magnesium Technology, ss.307-310.
  • [18] Koltygin, A., Bazhenov, V. and Mahmadiyorov, U., (2017), Influence of Al–5Ti–1B master alloy addition on the grain size of AZ91 alloy, Journal of magnesium and alloys, 5(3), 313-319,
  • [19] Luo, A.A., (2013), Magnesium casting technology for structural applications, Journal of Magnesium and Alloys, 1 (1), 2-22.
  • [20] Banerjee, A., (2013), Process-Structure Relationships of Magnesium Alloys, The University of Western Ontario Graduate Program in Mechanical and Materials Engineering Master thesis.
  • [21] Ralston, K.D. and Birbilis, N., (2010), Effect of grain size on corrosion: a review, Corrosion, 66 (7), 075005-075005.
  • [22] Bahmani, A., Arthanari, S. and Shin, K.S., (2020), Formulation of corrosion rate of magnesium alloys using microstructural parameters, Journal of Magnesium and Alloys, 8 (1), 134-149.
  • [23] Chao, H.Y. Yang, Y. Wang, X. and Wang, E.D., (2011), Effect of grain size distribution and texture on the cold extrusion behavior and mechanical properties of AZ31 Mg alloy, Materials Science and Engineering: A, 528 (9), 3428-3434.
  • [24] Oliver, W. C. and Pharr, G. M., (2004), Measurement of hardness and elastic modulus by instrumented indentation: Advances in understanding and refinements to methodology, Journal of materials research, 19 (1), 3-20.
  • [25] Murray, J.L., (1982), The Al− Mg (aluminum− magnesium) system. Journal of Phase Equilibria, 3 (1), 60-74.
  • [26] Dieter, G.E. and Bacon, D.J., (1986), Mechanical metallurgy (Vol. 3). New York: McGraw-hill.
  • [27] Wang, Y., Zeng, X., Ding, W., Luo, A. A., Sachdev, A. K., (2007), Grain refinement of AZ31 magnesium alloy by titanium and low-frequency electromagnetic casting. Metallurgical and Materials Transactions A, 38(6), 1358-1366.
  • [28] Chen, T. J., Wang, R. Q., Ma, Y., Hao, Y., Grain refinement of AZ91D magnesium alloy by Al–Ti–B master alloy and its effect on mechanical properties. Materials & Design, 34, 637-648.
  • [29] Naik, G. M., Gote, G. D., Narendranath, S., Kumar, S. S., (2012), Effect of grain refinement on the performance of AZ80 Mg alloys during wear and corrosion. Advances in Materials Research, 7(2), 105, 2018.
  • [30] Kaya, A.A., Çelik, Ç., Türe, Y., Ataman, A., Arkın, E., Palumbo, G., Sorgente, D. and Turan, D., (2017), Elasticity modulus and damping in some novel magnesium alloys, In Proceedings of the 6th International Conference on Magnesium.
  • [31] Kaya, A.A., Çelik, Ç., Türe, Y., Ataman, A., Arkın, E., Palumbo, G., Sorgente, D. and Turan, D., (2017), New Magnesium Alloys with High Elastic Modulus, International Materials Technologies and Metallurgy Conference Istanbul.
  • [32] Özarslan, S., Şevik, H. and Sorar, İ., (2019), Microstructure, mechanical and corrosion properties of novel Mg-Sn-Ce alloys produced by high pressure die casting, Materials Science and Engineering: C, 105, 110064.
  • [33] Cui, Q., Ti, D., Wang, H., Zhang, J., Xu, J., Wang, B., (2019), Effects of grain size and secondary phase on corrosion behavior and electrochemical performance of Mg-3Al-5Pb-1Ga-Y sacrificial anode, J. Rare Earths.
  • [34] Aung, N.N. Zhou, W., (2010), Effect of grain size and twins on corrosion behaviour of AZ31B magnesium alloy, Corros. Sci., 52, 589.
  • [35] Öteyaka, M. Ö., Ghali, E., & Tremblay, R. (2012), Corrosion behaviour of AZ and ZA magnesium alloys in alkaline chloride media, International Journal of Corrosion.
Yıl 2022, Sayı: 049, 171 - 183, 30.06.2022

Öz

Kaynakça

  • [1] Witte, F., Hort, N., Vogt, C., Cohen, S., Kainer, K.U., Willumeit, R., Feyerabend, F., (2008), Degradable biomaterials based on magnesium corrosion, Curr. Opin. Solid State Mater. Sci., 12, 63 -72.
  • [2] Moravej, M. and Mantovani, D., (2011), Biodegradable metals for cardiovascular stent application: interests and new opportunities,” International journal of molecular sciences, 12 (7), 4250-4270.
  • [3] Kirkland, N.T., Birbilis, N. and Staiger, M.P., (2012), Assessing the corrosion of biodegradable magnesium implants: a critical review of current methodologies and their limitations. Acta biomaterialia, 8 (3), 925-936.
  • [4] Staiger, M.P., Pietak, A.M., Huadmai, J. and Dias, G., (2006), Magnesium and its alloys as orthopedic biomaterials: a review, Biomaterials, 27 (9), 1728-1734.
  • [5] Uddin, M.S., Hall, C., Murphy, P. (2015), Surface treatments for controlling corrosion rate of biodegradable Mg and Mg-based alloy implants,” Science and technology of advanced materials, 16 (5), 053501.
  • [6] Johnson, A.R., Munoz, A., Gottlieb J.L. and Jarrard, D.F., (2007), High dose zinc increases hospital admissions due to genitourinary complications, The Journal of urology, 177 (2), 639-643.
  • [7] Gu, X., Zheng, Y., Cheng, Y., Zhong, S. and Xi, T., (2009), In vitro corrosion and biocompatibility of binary magnesium alloys, Biomaterials, 30 (4), 484-498.
  • [8] Song, G., Control of biodegradation of biocompatable magnesium alloys (2007), Corrosion science, 49 (4), 1696-1701.
  • [9] Liu, X., Sun, J., Yang, Y., Pu, Z., Zheng, Y., (2015), In vitro investigation of ultra-pure Zn and its mini-tube as potential bioabsorbable stent material, Mater. Lett., 161, 53-56.
  • [10] Liu, H., Chen, Y., Tang, Y., Wei, S. and Niu, G., (2007), The microstructure, tensile properties, and creep behavior of as-cast Mg-(1–10)% Sn alloys, Journal of Alloys and Compounds, 440 (1-2). 122-126.
  • [11] Marya, M., Hector, L.G., Verma, R., Tong, W., (2006), Microstructural effects of AZ31 magnesium alloy on its tensile deformation and failure behaviors, Mater. Sci. Eng., A, 418, 341-356.
  • [12] Zheng, Y.F., Gu, X.N., Witte, F., (2014), Biodegradable metals, Mater. Sci. Eng. R. Rep., 77, 1-34.
  • [13] Homayun, B. Afshar, A., (2014), Microstructure, mechanical properties, corrosion behavior and cytotoxicity of Mg–Zn–Al–Ca alloys as biodegradable materials, J. Alloys Compd., 607, 1-10.
  • [14] Sunil, B.R., Kumar, T.S.S., Chakkingal, U., Nandakumar, V., Doble, M., et al. (2016), In vitro and in vivo studies of biodegradable fine grained AZ31 magnesium alloy produced by equal channel angular pressing, Mater. Sci. Eng. C, 59, 356-367.
  • [15] Sun, W., Zhang, G, Tan, L., Yang, K., Ai, H., (2016), The fluoride coated AZ31B magnesium alloy improves corrosion resistance and stimulates bone formation in rabbit model, Mater. Sci. Eng. C, 63, 506-511.
  • [16] Huang, Z.H., Zhou, N., Xu, J., Li, Y.D. and Li, W.R., (2017), Microstructure and Mechanical Property of Mg-Sn-Al Wrought Magnesium Alloys, In Materials Science Forum Trans Tech Publications Ltd., 898, 97-103.
  • [17] Bowles, A.L., Blawert, C., Hort, N. and Kainer, K.U., (2004), Microstructural investigations of the Mg-Sn and Mg-Sn-Al alloy systems, Magnesium Technology, ss.307-310.
  • [18] Koltygin, A., Bazhenov, V. and Mahmadiyorov, U., (2017), Influence of Al–5Ti–1B master alloy addition on the grain size of AZ91 alloy, Journal of magnesium and alloys, 5(3), 313-319,
  • [19] Luo, A.A., (2013), Magnesium casting technology for structural applications, Journal of Magnesium and Alloys, 1 (1), 2-22.
  • [20] Banerjee, A., (2013), Process-Structure Relationships of Magnesium Alloys, The University of Western Ontario Graduate Program in Mechanical and Materials Engineering Master thesis.
  • [21] Ralston, K.D. and Birbilis, N., (2010), Effect of grain size on corrosion: a review, Corrosion, 66 (7), 075005-075005.
  • [22] Bahmani, A., Arthanari, S. and Shin, K.S., (2020), Formulation of corrosion rate of magnesium alloys using microstructural parameters, Journal of Magnesium and Alloys, 8 (1), 134-149.
  • [23] Chao, H.Y. Yang, Y. Wang, X. and Wang, E.D., (2011), Effect of grain size distribution and texture on the cold extrusion behavior and mechanical properties of AZ31 Mg alloy, Materials Science and Engineering: A, 528 (9), 3428-3434.
  • [24] Oliver, W. C. and Pharr, G. M., (2004), Measurement of hardness and elastic modulus by instrumented indentation: Advances in understanding and refinements to methodology, Journal of materials research, 19 (1), 3-20.
  • [25] Murray, J.L., (1982), The Al− Mg (aluminum− magnesium) system. Journal of Phase Equilibria, 3 (1), 60-74.
  • [26] Dieter, G.E. and Bacon, D.J., (1986), Mechanical metallurgy (Vol. 3). New York: McGraw-hill.
  • [27] Wang, Y., Zeng, X., Ding, W., Luo, A. A., Sachdev, A. K., (2007), Grain refinement of AZ31 magnesium alloy by titanium and low-frequency electromagnetic casting. Metallurgical and Materials Transactions A, 38(6), 1358-1366.
  • [28] Chen, T. J., Wang, R. Q., Ma, Y., Hao, Y., Grain refinement of AZ91D magnesium alloy by Al–Ti–B master alloy and its effect on mechanical properties. Materials & Design, 34, 637-648.
  • [29] Naik, G. M., Gote, G. D., Narendranath, S., Kumar, S. S., (2012), Effect of grain refinement on the performance of AZ80 Mg alloys during wear and corrosion. Advances in Materials Research, 7(2), 105, 2018.
  • [30] Kaya, A.A., Çelik, Ç., Türe, Y., Ataman, A., Arkın, E., Palumbo, G., Sorgente, D. and Turan, D., (2017), Elasticity modulus and damping in some novel magnesium alloys, In Proceedings of the 6th International Conference on Magnesium.
  • [31] Kaya, A.A., Çelik, Ç., Türe, Y., Ataman, A., Arkın, E., Palumbo, G., Sorgente, D. and Turan, D., (2017), New Magnesium Alloys with High Elastic Modulus, International Materials Technologies and Metallurgy Conference Istanbul.
  • [32] Özarslan, S., Şevik, H. and Sorar, İ., (2019), Microstructure, mechanical and corrosion properties of novel Mg-Sn-Ce alloys produced by high pressure die casting, Materials Science and Engineering: C, 105, 110064.
  • [33] Cui, Q., Ti, D., Wang, H., Zhang, J., Xu, J., Wang, B., (2019), Effects of grain size and secondary phase on corrosion behavior and electrochemical performance of Mg-3Al-5Pb-1Ga-Y sacrificial anode, J. Rare Earths.
  • [34] Aung, N.N. Zhou, W., (2010), Effect of grain size and twins on corrosion behaviour of AZ31B magnesium alloy, Corros. Sci., 52, 589.
  • [35] Öteyaka, M. Ö., Ghali, E., & Tremblay, R. (2012), Corrosion behaviour of AZ and ZA magnesium alloys in alkaline chloride media, International Journal of Corrosion.
Toplam 35 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Research Articles
Yazarlar

Selma Özarslan 0000-0002-7225-1613

Yayımlanma Tarihi 30 Haziran 2022
Gönderilme Tarihi 29 Mart 2022
Yayımlandığı Sayı Yıl 2022 Sayı: 049

Kaynak Göster

IEEE S. Özarslan, “THE EFFECT of MINOR Ti and Sr ADDITION on the MICROSTRUCTURAL, MECHANICAL, and CORROSION PROPERTIES of a BIODEGRADABLE Mg-5Sn-3Al ALLOY”, JSR-A, sy. 049, ss. 171–183, Haziran 2022.