Colorimetric Detection of Hydrogen Peroxide with Cellulose Nanocrystals Obtained From Waste Paper/ Silver Nanoparticles Nanocomposite Sensor

Abstract

This study includes the results of the studies of the production of cellulose nanocrystals (CNC) from waste paper by the acid hydrolysis method, the synthesis of nanocomposite material CNC/AgNPs as a result of mixing the produced CNC and AgNO3 solution and then reducing the Ag+ ions to Ag0 by adding NaBH4 to the medium, the characterization of CNC/AgNPs by UV-vis spectroscopy, DLS, SEM, EDX and XRD methods, and its usability as a sensor in the colorimetric detection of H2O2. For the quantitative analysis of H2O2 with CNC/AgNPs nanocomposite, a calibration line was created in the range of 0.001-1.0 mM H2O2 concentration, and the minimum detection limit for H2O2 of CNC/AgNPs was determined as 0.7864 μM. In order to determine the selectivity of CNC/AgNPs to H2O2, the studies of the colorimetric detection of H2O2 with CNC/AgNPs was carried out in the presence of various components; it was concluded that CNC/AgNPs can be used effectively in the colorimetric detection of H2O2 in the presence of KCl, Al(NO3)3, oxalic acid, lactic acid, glucose, lactose, maltose, fructose, sucrose, urea components.

Keywords

• Waste paper
• cellulose nanocrystals
• silver nanoparticles
• nanocomposite material
• H₂O₂ detection
• colorimetric sensor

ATIK KAĞITTAN ELDE EDİLMİŞ SELÜLOZ NANOKRİSTALLERİ/GÜMÜŞ NANOPARTİKÜLLERİ NANOKOMPOZİT SENSÖRÜ İLE HİDROJEN PEROKSİTİN KOLORİMETRİK TESPİTİ

Abstract

Bu çalışma; asit hidrolizi yöntemi ile atık kâğıtlardan selüloz nanokristallerinin (CNC) üretimi, üretilen CNC ve AgNO3 çözeltisinin karıştırılması ve ortama NaBH4 ilavesi ile Ag+ iyonlarının Ag0’a indirgenmesi sonucu CNC/AgNPs nanokompozit malzemenin sentezlenmesi, CNC/AgNPs malzemesinin UV-vis spektroskopisi, DLS, SEM, EDX ve XRD yöntemleri ile karakterizasyonu ve H2O2’nin kolorimetrik tespitinde sensör olarak kullanılabilirliği çalışmalarının sonuçlarını içermektedir. CNC/AgNPs nanokompoziti ile H2O2’nin nicel analizi için 0,001-1,0 mM H2O2 derişimi aralığında bir kalibrasyon doğrusu oluşturulmuş, CNC/AgNPs’nin H2O2’yi minimum tespit sınırı 0,7864 μM olarak belirlenmiştir. CNC/AgNPs’nin H2O2’ye seçiciliğinin belirlenmesi amacıyla çeşitli bileşenlerin varlığında CNC/AgNPs ile H2O2’nin kolorimetrik tespiti çalışmaları gerçekleştirilmiş; KCl, Al(NO3)3, oksalik asit, laktik asit, glikoz, laktoz, maltoz, fruktoz, sakkaroz, üre bileşenlerinin varlığında CNC/AgNPs’nin H2O2’nin kolorimetrik tespitinde etkin bir şekilde kullanılabileceği sonucuna varılmıştır.

Keywords

• Atık kâğıt
• selüloz nanokristalleri
• gümüş nanopartikülleri
• nanokompozit malzeme
• H₂O₂ tespiti
• kolorimetrik sensör

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