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Yıl 2023, , 175 - 182, 12.02.2024
https://doi.org/10.30797/madencilik.1364137

Öz

Kaynakça

  • Alexander, L.T., Faust, G.T., Hendricks, S.B., Insley, H., McMurdie, H.F. 1943. Relationship of the clay minerals halloysite and endellite. American Mineralogist 28, 1-18.
  • Ambikadevi, V.R., Lalithambika, M. 2000. Effect of organic acids on ferric iron removal from iron-stained kaolinite. Applied Clay Science 16, 133-145. https://doi.org/10.1016/S0169-1317(99)00038-1 Andromeda Metals. 2019. An emerging force in industrial minerals.
  • https://announcements.asx.com.au/asxpdf/20191009/pdf/449bcwl4mzfpck. pdf [Accessed October 12, 2023].
  • Baba A.A, Mosobalaje M.A., Ibrahim A.S., Girigisu S., Eletta O.A.A, Aluko F.I., Adekola F.A. 2015. Bleaching of a Nigerian kaolin by oxalic acid leaching. Journal of Chemical Technology and Metallurgy 50(5), 623-630.
  • Başara, B., Saklar, S. 2015. Halloysite intercalation of northwest Anatolia. Bulletin of the Mineral Research and Exploration 150, 121-130.
  • https://doi.org/10.19111/bmre.44287
  • Belkassa K., Bessaha F., Marouf K., Batonneau I., Comparot J., Khelifa A. 2013. Physicochemical and adsorptive properties of a heat-treated and acid-leached Algerian halloysite. Colloids and Surfaces A: Physicochemical and Engineering Aspects 421, 26-33. https://doi. org/10.1016/j.colsurfa.2012.12.048 Berthier, P. 1826. Analyse de l’halloysite. Annales de Chimie et de Physique 32, 332-335.
  • Bidwell, J.I. 1970. Separation of minerals. United States Patent No:3539003. Boden, T., Vanden Berg, M., Krahulec, K., Tabet, D. 2012. Utah’s extractive resource industries 2012: Utah Geological Survey. Natural Resources Map and Bookstore, Salt Lake City, ISBN: 978-1-55791-884-0.
  • Bordeepong, S., Bhongsuwan, D., Pungrassami, T., Bhongsuwan, T. 2011. Characterization of halloysite from Thung Yai District, Nakhon Si Thammarat Province, in Southern Thailand. Songklanakarin Journal of Science and Technology 33(5), 599-607.
  • Bordeepong, S., Bhongsuwan, D., Pungrassami, T., Bhongsuwan, T. 2012. Mineralogy, chemical composition and ceramic properties of clay deposits in southern Thailand. Kasetsart Journal - Natural Science 46(3), 485-500.
  • Brindley G.W. 1961. Kaolin, serpentine and kindred minerals. pp. 51-131 in: The X-ray identification and crystal structures of clay minerals (G. Brown, Editor). Mineralogical Society, London.
  • Carr, R.M., Chaikum, N., Patterson, N. 1978. Intercalation of Salts in Halloysite. Clays and Clay Minerals 26(2), 144-152. https://doi. org/10.1346/CCMN.1978.0260210
  • Churchman, G.J., Carr, R.M. 1975. The definition and nomenclature of halloysites. Clays and Clay Minerals 23(5), 382-388. https://doi. org/10.1346/CCMN.1975.0230510
  • Churchman, G.J., Theng, B.K.G. 1984. Interactions of halloysites with amides: mineralogical factors affecting complex formation. Clay Minerals 19(2), 161-175. https://doi.org/10.1180/claymin.1984.019.2.04
  • Churchman G.J., Whitton J.S., Claridge G.G.C., Theng B.K.G. 1984. Intercalation method using formamide for differentiating halloysite from kaolinite. Clays and Clay Minerals 32(4), 241-248. https://doi. org/10.1346/CCMN.1984.0320401
  • Churchman, G.J., Pasbakhsh, P., Lowe, D.J., Theng, B.K.G. 2016. Unique but diverse: some observations on the formation, structure and morphology of halloysite. Clay Minerals 51, 395-416. https://doi.org/10.1180/ claymin.2016.051.3.14
  • Chorover, J., Sposito, G., 1995. Surface charge characteristics of kaolinitic tropical soils. Geochimica et Cosmochimica Acta 59, 875-884. https:// doi.org/10.1016/0016-7037(94)00357-2
  • Clarke, G. 2008. Tubular clays. Industrial Minerals. March, 58-59.
  • Cravero, F., Maiza, P.J., Marfil, S.A. 2012. Halloysite in Argentinian deposits: origin and textural constraints. Clay Minerals 47(3), 329-340. https:// doi.org/10.1180/claymin.2012.047.3.04
  • Delvaux, B., Tessier, D., Herbillon, A., Burtin, G., Jaunet, A.-M., Vielvoye, L. 1992. Morphology, texture, and microstructure of halloysitic soil clays as related to weathering and exchangeable cation. Clays and Clay Minerals 40(4), 446-456. https://doi.org/10.1346/CCMN.1992.0400409
  • Demir, T.U., Altaş A. 2017. Determination of Tabanköy halloysite’s characteristics. 17.National Clay Symposium, 4-7 October 2017 Muğla, Muğla Sıtkı Koçman University, e-ISBN: 978-605-4397-62-4.
  • Dixon, J.B., McKee, T.R. 1974. Internal and external morphology of tubular and spheroidal halloysite particles. Clays and Clay Minerals 22, 127- 137. https://doi.org/10.1346/CCMN.1974.0220118
  • Durgut, E., Çınar, M., Terzi, M., Ünver, I.K., Yıldırım, Y., Özdemir, O. 2022a.
  • Evaluation of different dispersants on the dispersion/sedimentation behavior of halloysite, kaolinite, and quartz suspensions in the enrichment of halloysite ore by mechanical dispersion. Minerals 20(11), 1426. https://doi.org/10.3390/min12111426
  • Durgut, E., Çınar, M., Terzi, M., Ünver, I.K., Yıldırım, Y., Boylu. F., Özdemir, O. 2022b. Effect of blunging/dispersion parameters on separation of halloysite nanotubes from gangue minerals. Minerals 12(6), 683. https:// doi.org/10.3390/min12060683
  • Ece, O.I., Schroeder, P.A. 2007. Clay mineralogy and chemistry of halloysite and alunite deposits in the Turplu area, Balikesir, Turkey. Clays and Clay Minerals 55(1), 18-35. https://doi.org/10.1346/CCMN.2007.0550102
  • Ece, O.I., Schroeder, P.A., Smilley, M.J., Wampler, J.M. 2008. Acid-sulphate hydrothermal alteration of andesitic tuffs and genesis of halloysite and alunite deposits in the Biga Peninsula, Turkey. Clay Minerals 43(2), 281-315. https://doi.org/10.1180/claymin.2008.043.2.10
  • Franco, F., Ruiz Cruz, M.D. 2004. Factors influencing the intercalation degree (‘reactivity’) of kaolin minerals with potassium acetate, formamide, dimethylsulphoxide and hydrazine. Clay Minerals 39(2), 193- 205. https://doi.org/10.1180/0009855043920130
  • Frost, R.L., Kristof, J. 1997. Intercalation of halloysite: A Raman spectroscopic study. Clays and Clay Minerals 45(4), 551-563. https://doi. org/10.1346/CCMN.1997.0450407
  • Garcia de Oliveira, M. T., Furtado, S. M., Formoso, M.L.L., Eggleton, R.A., Dani, N. 2007. Coexistence of halloysite and kaolinite - a study on the genesis of kaolin clays of Campo Alegre Basin, Santa Catarina State, Brazil.
  • Anais da Academia Brasileira de Ciências 79(4),665-681. https://doi. org/10.1590/S0001-37652007000400008
  • General Directorate of Mining and Petroleum Affairs. 2019. http://www. mapeg.gov.tr/Duyurular/duyuru_dukuman/obsf/2018-IV-A%20 Grubu%20OBSF.pdf (Accessed February 17, 2021).
  • Genç, C.Ş. 1998. Evolution of the Bayramic, magmatic complex, northwestern Anatolia. Journal of Volcanology and Geothermal Research 85, 233-249. https://doi.org/10.1016/S0377-0273(98)00057-2 Grim, R.E. 1968. Clay Mineralogy. McGraw-Hill, New York.
  • Hart, R.D., Gilkes, R.J., Siradz, S., Singh, B. 2002. The nature of soil kaolins from Indonesia and Western Australia. Clay and Clay Minerals 50(2), 198-207. https://doi.org/10.1346/000986002760832793
  • Hillier, S., Ryan, P.C. 2002. Identification of halloysite (7 Å) by ethylene glycol solvation: the ‘MacEwan effect’. Clay Minerals 37(3), 487-496. https://doi.org/10.1180/0009855023730047 https://www.grandviewresearch.com/industry-analysis/halloysite-market (Accessed February 18, 2021).
  • Jeong, G.J. 1998. Vermicular kaolinite epitactic on primary phyllosilicates in the weathering profiles of anorthosite. Clays and Clay Minerals 46, 509-520. https://doi.org/10.1346/CCMN.1998.0460504
  • Joussein, E. 2016. Geology and mineralogy of nanosized tubular halloysite, Nanosized Tubular Clay Minerals Halloysite and Imogolite. In: Yuan P., Thill A., Bergaya F. (ed.), Chapter 2, Elsevier, Amsterdam, ISBN: 978-0- 08-100293-3, 12-49.
  • Emrah Durgut, Mustafa Çınar, Orhan Özdemir / Scientific Mining Journal, 2023, 62(4), 175-182 182 Joussein, E., Petit, S., Churchman, J., Theng, B., Righi, D., Delvaux, B. 2005.
  • Halloysite clay minerals-A review. Clay Minerals 40(4), 383-426. https://doi.org/10.1180/0009855054040180
  • Joussein, E., Petit, S., Fialips C., Vieillard P., Righi D. 2006. Differences in the dehydration-rehydration behavior of halloysites: New evidence and interpretations. Clays and Clay Minerals 54(4), 473-484. https://doi. org/10.1346/CCMN.2006.0540408
  • Joussein, E., Petit, S., Delvaux, B. 2007. Behaviour of halloysite clay under formamide treatment. Applied Clay Science 35(1), 17-24. https://doi. org/10.1016/j.clay.2006.07.002
  • Keeling, J.L. 2015. The mineralogy, geology and occurrences of halloysite, Natural Mineral Nanotubes: Properties and Applications, In: Pasbakhsh P., Churchman G.J. (ed.), Chapter 5, Apple Academic Press, New York, eBook ISBN: 9780429172359, 95-117.
  • Khan, A.M. Kim, S.J. 1991. Mineralogy of halloysite from Suryun, Korea.
  • Geological Bulletin-University of Peshawar. 24, 63-70.
  • Kogure, T., Mori, K., Drits, V.A., Takai, Y. 2013. Structure of prismatic halloysite. American Mineralogist 98, 1008-1016. https://doi. org/10.2138/am.2013.4385
  • Kogure, T. 2016. Characterisation of halloysite by electron microscopy. Yuan, P., Thill, Antoine., Bergaya, F. (Ed.). Nanosized Tubular Clay Minerals, Elsevier Publications. Netherlands, 92-114.
  • Kunze, G., Bradley, W. 1963. Occurrence of a tabular halloysite in a Texas soil. Clay and Clay Minerals 12, 523-527. https://doi.org/10.1346/ CCMN.1963.0120145 Laçin, D., Yeniyol, M. 2006. An example to the halloysite deposits formed associated with the andesitic pyroclastics: Soğucak halloysite deposit (Yenice-Çanakkale). Istanbul Earth Sciences Review 19(1), 27-41. Ma, C., Eggleton, R.A. 1999. Cation exchange capacity of kaolinite. Clays and Clay Minerals 47(2), 174-180. https://doi.org/10.1346/ CCMN.1999.0470207
  • MacEwan, D.M.C. 1947. The nomenclature of the halloysite minerals. Mineralogical Magazine and Journal of the Mineralogical Society 28(196), 36-44. https://doi.org/10.1180/minmag.1947.028.196.08
  • Miller, W.D., Keller, W.D. 1963. Differentiation between endellite halloysite and kaolinite by treatment with potassium acetate and ethylene glycol. Clays and Clay Minerals 10(1), 244-253. https://doi.org/10.1346/ CCMN.1961.0100120
  • Murray, H.H. 2006. Applied Clay Mineralogy. Occurrences, Processing and Application of Kaolins, Bentonites, Palygorskite-Sepiolite, and Common Clays, Edited by Haydn H. Murray, Volume 2, Pages 1-180 (2006).
  • Murray, H.H. 2007. Applied Clay Mineralogy: Developments in Clay Science 2, Elsevier, Amsterdam.
  • Norrish, K. 1993. An unusual fibrous halloysite. Clays-Controlling the environment. pp. 275-284. In G.J. Churchman et al. (ed.) 10. Int. Clay Conf., Adelaide, Australia, CSIRO Publ.
  • Pasbakhsh, P., Churchman, G.J., Keeling, J.L. 2013. Characterisation of properties of various halloysites relevant to their use as nanotubes and microfibre fillers. Applied Clay Science 74, 47-57. https://doi. org/10.1016/j.clay.2012.06.014
  • Range, K.J., Range, A., Weiss, A. 1969. Fire-clay kaolinite or fire-clay mineral? Experimental classification of kaolinite-halloysite minerals. pp. 3-13 in: Proceedings of the International Clay Conference 1969, Tokyo (L. Heller, editor). Israel University Press, Jerusalem.
  • Robertson, I.D.M., Eggleton, R.A. 1991. Weathering of granitic muscovite to kaolinite and halloysite and plagioclase-derived kaolinite to halloysite. Clays and Clay Minerals 39, 113-126. https://doi.org/10.1346/ CCMN.1991.0390201
  • Ross, T.J., Kerr, P.F. 1934. Halloysite and allophane. US Geological Survey, Department of the Interior. 185-G, 135-148.
  • Saigusa, M., Shoji, S., Kato, T. 1978. Origin and nature of halloysite in Ando soils from Towada tephra, Japan. Geoderma 20, 115-129. https://doi. org/10.1016/0016-7061(78)90039-3
  • Sakiewicz, P., Lutynski, M. A. 2016. Purification of Dunino halloysite by H2SO4 leaching and magnetic separation, E3S Web of Conferences 8, 25-28 September 2016 Swieradow-Zdroj, Poland, EDP Sciences, eISSN: 2267-1242, 1-6.
  • Sakiewicz, P., Lutynski, M., Soltys, J., Pytlinski, A. 2016. Purification of halloysite by magnetic separation. Physicochemical Problems of Mineral Processing 52(2), 991-1001. http://dx.doi.org/10.5277/ppmp160236 Saklar, S., Ağrılı, H., Zimitoğlu, O., Başara, B., Kaan, U. 2012a. The characterization studies of the Northwest Anatolian halloysites/kaolinites.
  • Bulletin of the Mineral Research and Exploration 145, 48-61. Saklar, S., Ergün, Ş.L., Gülsoy, Ö.Y. 2012b. Beneficiation studies of halloysite and halloysite/kaolinite ores from Northwestern Anatolia. Bilimsel Madencilik Dergisi 51(1), 23-33.
  • Saklar, S.,Yorukoglu, A. 2015. Effects of acid leaching on halloysite. Physicochemical Problems of Mineral Processing 51(1), 83-94. https://doi. org/10.5277/ppmp150108 Santos, P.S., Brindley, G.W., Santos, H.D. 1965. Mineralogical Studies of Kaolinite-Halloysite Clays Part III. A Fibrous Kaolin Mineral from Piedade, Sáo Paulo, Brazil. American Mineralogist 50(5-6), 619-628.
  • Singh, B., Gilkes, R. 1992. An electron optical investigation of the alteration of kaolinite to halloysite. Clays and Clay Minerals 40(2), 212-229. https://doi.org/10.1346/CCMN.1992.0400211 Sudo, T., Takahashi, H. 1955. Shapes of halloysite particles in Japanese clays. Clays Clay Minerals 4, 67-79. https://doi.org/10.1346/ CCMN.1955.0040110
  • Takahashi, H. 1957. Effect of dry grinding on kaolin minerals. Clays and Clay Minerals 6(1), 279-291. https://doi.org/10.1346/ CCMN.1957.0060121
  • Takahashi, H. 1959a. Effect of dry grinding on kaolin minerals. III. Halloysite. Bulletin of the Chemical Society of Japan 32(10), 252-263. https://doi.org/10.1246/bcsj.32.252 Takahashi, H., 1959b. Wet grinding on kaolin minerals. Bulletin of the Chemical Society of Japan 32(4), 381-387. https://doi.org/10.1246/ bcsj.32.381
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An overview of halloysite mineral

Yıl 2023, , 175 - 182, 12.02.2024
https://doi.org/10.30797/madencilik.1364137

Öz

Halloysite is a type of clay mineral found in the kaolin group together with kaolinite, dickite, and nacrite minerals. Kaolinite is the most common mineral in this group, while dickite, nacrite, and halloysite are rarer. Although halloysite is primarily used in ceramic production, application in other industries is increasing and gaining economic value due to its unique properties. The use of halloysite is determined by the degree of purity and the properties of the nano-sized tubular structure. Naturally obtained halloysite mineral has a key position in the field of nanotechnology due to its unique physicochemical properties originating from its tubular structure. Also, due to its reserves in many parts of the world, halloysite is a more economical material for the sectors compared to artificially produced nanomaterials. And, they find many different application areas because of these features (morphological and physicochemical). Halloysite reserves known in Türkiye are located in the Çanakkale and Balıkesir regions. Although there are many useful studies on halloysite in different, additional studies are needed to understand the nano-sized properties of halloysite ore and to ensure its use that will provide maximum benefit. This study aimed to contribute to the studies on halloysite in terms of literature by compiling studies on the characterization of halloysite minerals, reserve information, physicochemical properties, enrichment methods, and usage areas.

Kaynakça

  • Alexander, L.T., Faust, G.T., Hendricks, S.B., Insley, H., McMurdie, H.F. 1943. Relationship of the clay minerals halloysite and endellite. American Mineralogist 28, 1-18.
  • Ambikadevi, V.R., Lalithambika, M. 2000. Effect of organic acids on ferric iron removal from iron-stained kaolinite. Applied Clay Science 16, 133-145. https://doi.org/10.1016/S0169-1317(99)00038-1 Andromeda Metals. 2019. An emerging force in industrial minerals.
  • https://announcements.asx.com.au/asxpdf/20191009/pdf/449bcwl4mzfpck. pdf [Accessed October 12, 2023].
  • Baba A.A, Mosobalaje M.A., Ibrahim A.S., Girigisu S., Eletta O.A.A, Aluko F.I., Adekola F.A. 2015. Bleaching of a Nigerian kaolin by oxalic acid leaching. Journal of Chemical Technology and Metallurgy 50(5), 623-630.
  • Başara, B., Saklar, S. 2015. Halloysite intercalation of northwest Anatolia. Bulletin of the Mineral Research and Exploration 150, 121-130.
  • https://doi.org/10.19111/bmre.44287
  • Belkassa K., Bessaha F., Marouf K., Batonneau I., Comparot J., Khelifa A. 2013. Physicochemical and adsorptive properties of a heat-treated and acid-leached Algerian halloysite. Colloids and Surfaces A: Physicochemical and Engineering Aspects 421, 26-33. https://doi. org/10.1016/j.colsurfa.2012.12.048 Berthier, P. 1826. Analyse de l’halloysite. Annales de Chimie et de Physique 32, 332-335.
  • Bidwell, J.I. 1970. Separation of minerals. United States Patent No:3539003. Boden, T., Vanden Berg, M., Krahulec, K., Tabet, D. 2012. Utah’s extractive resource industries 2012: Utah Geological Survey. Natural Resources Map and Bookstore, Salt Lake City, ISBN: 978-1-55791-884-0.
  • Bordeepong, S., Bhongsuwan, D., Pungrassami, T., Bhongsuwan, T. 2011. Characterization of halloysite from Thung Yai District, Nakhon Si Thammarat Province, in Southern Thailand. Songklanakarin Journal of Science and Technology 33(5), 599-607.
  • Bordeepong, S., Bhongsuwan, D., Pungrassami, T., Bhongsuwan, T. 2012. Mineralogy, chemical composition and ceramic properties of clay deposits in southern Thailand. Kasetsart Journal - Natural Science 46(3), 485-500.
  • Brindley G.W. 1961. Kaolin, serpentine and kindred minerals. pp. 51-131 in: The X-ray identification and crystal structures of clay minerals (G. Brown, Editor). Mineralogical Society, London.
  • Carr, R.M., Chaikum, N., Patterson, N. 1978. Intercalation of Salts in Halloysite. Clays and Clay Minerals 26(2), 144-152. https://doi. org/10.1346/CCMN.1978.0260210
  • Churchman, G.J., Carr, R.M. 1975. The definition and nomenclature of halloysites. Clays and Clay Minerals 23(5), 382-388. https://doi. org/10.1346/CCMN.1975.0230510
  • Churchman, G.J., Theng, B.K.G. 1984. Interactions of halloysites with amides: mineralogical factors affecting complex formation. Clay Minerals 19(2), 161-175. https://doi.org/10.1180/claymin.1984.019.2.04
  • Churchman G.J., Whitton J.S., Claridge G.G.C., Theng B.K.G. 1984. Intercalation method using formamide for differentiating halloysite from kaolinite. Clays and Clay Minerals 32(4), 241-248. https://doi. org/10.1346/CCMN.1984.0320401
  • Churchman, G.J., Pasbakhsh, P., Lowe, D.J., Theng, B.K.G. 2016. Unique but diverse: some observations on the formation, structure and morphology of halloysite. Clay Minerals 51, 395-416. https://doi.org/10.1180/ claymin.2016.051.3.14
  • Chorover, J., Sposito, G., 1995. Surface charge characteristics of kaolinitic tropical soils. Geochimica et Cosmochimica Acta 59, 875-884. https:// doi.org/10.1016/0016-7037(94)00357-2
  • Clarke, G. 2008. Tubular clays. Industrial Minerals. March, 58-59.
  • Cravero, F., Maiza, P.J., Marfil, S.A. 2012. Halloysite in Argentinian deposits: origin and textural constraints. Clay Minerals 47(3), 329-340. https:// doi.org/10.1180/claymin.2012.047.3.04
  • Delvaux, B., Tessier, D., Herbillon, A., Burtin, G., Jaunet, A.-M., Vielvoye, L. 1992. Morphology, texture, and microstructure of halloysitic soil clays as related to weathering and exchangeable cation. Clays and Clay Minerals 40(4), 446-456. https://doi.org/10.1346/CCMN.1992.0400409
  • Demir, T.U., Altaş A. 2017. Determination of Tabanköy halloysite’s characteristics. 17.National Clay Symposium, 4-7 October 2017 Muğla, Muğla Sıtkı Koçman University, e-ISBN: 978-605-4397-62-4.
  • Dixon, J.B., McKee, T.R. 1974. Internal and external morphology of tubular and spheroidal halloysite particles. Clays and Clay Minerals 22, 127- 137. https://doi.org/10.1346/CCMN.1974.0220118
  • Durgut, E., Çınar, M., Terzi, M., Ünver, I.K., Yıldırım, Y., Özdemir, O. 2022a.
  • Evaluation of different dispersants on the dispersion/sedimentation behavior of halloysite, kaolinite, and quartz suspensions in the enrichment of halloysite ore by mechanical dispersion. Minerals 20(11), 1426. https://doi.org/10.3390/min12111426
  • Durgut, E., Çınar, M., Terzi, M., Ünver, I.K., Yıldırım, Y., Boylu. F., Özdemir, O. 2022b. Effect of blunging/dispersion parameters on separation of halloysite nanotubes from gangue minerals. Minerals 12(6), 683. https:// doi.org/10.3390/min12060683
  • Ece, O.I., Schroeder, P.A. 2007. Clay mineralogy and chemistry of halloysite and alunite deposits in the Turplu area, Balikesir, Turkey. Clays and Clay Minerals 55(1), 18-35. https://doi.org/10.1346/CCMN.2007.0550102
  • Ece, O.I., Schroeder, P.A., Smilley, M.J., Wampler, J.M. 2008. Acid-sulphate hydrothermal alteration of andesitic tuffs and genesis of halloysite and alunite deposits in the Biga Peninsula, Turkey. Clay Minerals 43(2), 281-315. https://doi.org/10.1180/claymin.2008.043.2.10
  • Franco, F., Ruiz Cruz, M.D. 2004. Factors influencing the intercalation degree (‘reactivity’) of kaolin minerals with potassium acetate, formamide, dimethylsulphoxide and hydrazine. Clay Minerals 39(2), 193- 205. https://doi.org/10.1180/0009855043920130
  • Frost, R.L., Kristof, J. 1997. Intercalation of halloysite: A Raman spectroscopic study. Clays and Clay Minerals 45(4), 551-563. https://doi. org/10.1346/CCMN.1997.0450407
  • Garcia de Oliveira, M. T., Furtado, S. M., Formoso, M.L.L., Eggleton, R.A., Dani, N. 2007. Coexistence of halloysite and kaolinite - a study on the genesis of kaolin clays of Campo Alegre Basin, Santa Catarina State, Brazil.
  • Anais da Academia Brasileira de Ciências 79(4),665-681. https://doi. org/10.1590/S0001-37652007000400008
  • General Directorate of Mining and Petroleum Affairs. 2019. http://www. mapeg.gov.tr/Duyurular/duyuru_dukuman/obsf/2018-IV-A%20 Grubu%20OBSF.pdf (Accessed February 17, 2021).
  • Genç, C.Ş. 1998. Evolution of the Bayramic, magmatic complex, northwestern Anatolia. Journal of Volcanology and Geothermal Research 85, 233-249. https://doi.org/10.1016/S0377-0273(98)00057-2 Grim, R.E. 1968. Clay Mineralogy. McGraw-Hill, New York.
  • Hart, R.D., Gilkes, R.J., Siradz, S., Singh, B. 2002. The nature of soil kaolins from Indonesia and Western Australia. Clay and Clay Minerals 50(2), 198-207. https://doi.org/10.1346/000986002760832793
  • Hillier, S., Ryan, P.C. 2002. Identification of halloysite (7 Å) by ethylene glycol solvation: the ‘MacEwan effect’. Clay Minerals 37(3), 487-496. https://doi.org/10.1180/0009855023730047 https://www.grandviewresearch.com/industry-analysis/halloysite-market (Accessed February 18, 2021).
  • Jeong, G.J. 1998. Vermicular kaolinite epitactic on primary phyllosilicates in the weathering profiles of anorthosite. Clays and Clay Minerals 46, 509-520. https://doi.org/10.1346/CCMN.1998.0460504
  • Joussein, E. 2016. Geology and mineralogy of nanosized tubular halloysite, Nanosized Tubular Clay Minerals Halloysite and Imogolite. In: Yuan P., Thill A., Bergaya F. (ed.), Chapter 2, Elsevier, Amsterdam, ISBN: 978-0- 08-100293-3, 12-49.
  • Emrah Durgut, Mustafa Çınar, Orhan Özdemir / Scientific Mining Journal, 2023, 62(4), 175-182 182 Joussein, E., Petit, S., Churchman, J., Theng, B., Righi, D., Delvaux, B. 2005.
  • Halloysite clay minerals-A review. Clay Minerals 40(4), 383-426. https://doi.org/10.1180/0009855054040180
  • Joussein, E., Petit, S., Fialips C., Vieillard P., Righi D. 2006. Differences in the dehydration-rehydration behavior of halloysites: New evidence and interpretations. Clays and Clay Minerals 54(4), 473-484. https://doi. org/10.1346/CCMN.2006.0540408
  • Joussein, E., Petit, S., Delvaux, B. 2007. Behaviour of halloysite clay under formamide treatment. Applied Clay Science 35(1), 17-24. https://doi. org/10.1016/j.clay.2006.07.002
  • Keeling, J.L. 2015. The mineralogy, geology and occurrences of halloysite, Natural Mineral Nanotubes: Properties and Applications, In: Pasbakhsh P., Churchman G.J. (ed.), Chapter 5, Apple Academic Press, New York, eBook ISBN: 9780429172359, 95-117.
  • Khan, A.M. Kim, S.J. 1991. Mineralogy of halloysite from Suryun, Korea.
  • Geological Bulletin-University of Peshawar. 24, 63-70.
  • Kogure, T., Mori, K., Drits, V.A., Takai, Y. 2013. Structure of prismatic halloysite. American Mineralogist 98, 1008-1016. https://doi. org/10.2138/am.2013.4385
  • Kogure, T. 2016. Characterisation of halloysite by electron microscopy. Yuan, P., Thill, Antoine., Bergaya, F. (Ed.). Nanosized Tubular Clay Minerals, Elsevier Publications. Netherlands, 92-114.
  • Kunze, G., Bradley, W. 1963. Occurrence of a tabular halloysite in a Texas soil. Clay and Clay Minerals 12, 523-527. https://doi.org/10.1346/ CCMN.1963.0120145 Laçin, D., Yeniyol, M. 2006. An example to the halloysite deposits formed associated with the andesitic pyroclastics: Soğucak halloysite deposit (Yenice-Çanakkale). Istanbul Earth Sciences Review 19(1), 27-41. Ma, C., Eggleton, R.A. 1999. Cation exchange capacity of kaolinite. Clays and Clay Minerals 47(2), 174-180. https://doi.org/10.1346/ CCMN.1999.0470207
  • MacEwan, D.M.C. 1947. The nomenclature of the halloysite minerals. Mineralogical Magazine and Journal of the Mineralogical Society 28(196), 36-44. https://doi.org/10.1180/minmag.1947.028.196.08
  • Miller, W.D., Keller, W.D. 1963. Differentiation between endellite halloysite and kaolinite by treatment with potassium acetate and ethylene glycol. Clays and Clay Minerals 10(1), 244-253. https://doi.org/10.1346/ CCMN.1961.0100120
  • Murray, H.H. 2006. Applied Clay Mineralogy. Occurrences, Processing and Application of Kaolins, Bentonites, Palygorskite-Sepiolite, and Common Clays, Edited by Haydn H. Murray, Volume 2, Pages 1-180 (2006).
  • Murray, H.H. 2007. Applied Clay Mineralogy: Developments in Clay Science 2, Elsevier, Amsterdam.
  • Norrish, K. 1993. An unusual fibrous halloysite. Clays-Controlling the environment. pp. 275-284. In G.J. Churchman et al. (ed.) 10. Int. Clay Conf., Adelaide, Australia, CSIRO Publ.
  • Pasbakhsh, P., Churchman, G.J., Keeling, J.L. 2013. Characterisation of properties of various halloysites relevant to their use as nanotubes and microfibre fillers. Applied Clay Science 74, 47-57. https://doi. org/10.1016/j.clay.2012.06.014
  • Range, K.J., Range, A., Weiss, A. 1969. Fire-clay kaolinite or fire-clay mineral? Experimental classification of kaolinite-halloysite minerals. pp. 3-13 in: Proceedings of the International Clay Conference 1969, Tokyo (L. Heller, editor). Israel University Press, Jerusalem.
  • Robertson, I.D.M., Eggleton, R.A. 1991. Weathering of granitic muscovite to kaolinite and halloysite and plagioclase-derived kaolinite to halloysite. Clays and Clay Minerals 39, 113-126. https://doi.org/10.1346/ CCMN.1991.0390201
  • Ross, T.J., Kerr, P.F. 1934. Halloysite and allophane. US Geological Survey, Department of the Interior. 185-G, 135-148.
  • Saigusa, M., Shoji, S., Kato, T. 1978. Origin and nature of halloysite in Ando soils from Towada tephra, Japan. Geoderma 20, 115-129. https://doi. org/10.1016/0016-7061(78)90039-3
  • Sakiewicz, P., Lutynski, M. A. 2016. Purification of Dunino halloysite by H2SO4 leaching and magnetic separation, E3S Web of Conferences 8, 25-28 September 2016 Swieradow-Zdroj, Poland, EDP Sciences, eISSN: 2267-1242, 1-6.
  • Sakiewicz, P., Lutynski, M., Soltys, J., Pytlinski, A. 2016. Purification of halloysite by magnetic separation. Physicochemical Problems of Mineral Processing 52(2), 991-1001. http://dx.doi.org/10.5277/ppmp160236 Saklar, S., Ağrılı, H., Zimitoğlu, O., Başara, B., Kaan, U. 2012a. The characterization studies of the Northwest Anatolian halloysites/kaolinites.
  • Bulletin of the Mineral Research and Exploration 145, 48-61. Saklar, S., Ergün, Ş.L., Gülsoy, Ö.Y. 2012b. Beneficiation studies of halloysite and halloysite/kaolinite ores from Northwestern Anatolia. Bilimsel Madencilik Dergisi 51(1), 23-33.
  • Saklar, S.,Yorukoglu, A. 2015. Effects of acid leaching on halloysite. Physicochemical Problems of Mineral Processing 51(1), 83-94. https://doi. org/10.5277/ppmp150108 Santos, P.S., Brindley, G.W., Santos, H.D. 1965. Mineralogical Studies of Kaolinite-Halloysite Clays Part III. A Fibrous Kaolin Mineral from Piedade, Sáo Paulo, Brazil. American Mineralogist 50(5-6), 619-628.
  • Singh, B., Gilkes, R. 1992. An electron optical investigation of the alteration of kaolinite to halloysite. Clays and Clay Minerals 40(2), 212-229. https://doi.org/10.1346/CCMN.1992.0400211 Sudo, T., Takahashi, H. 1955. Shapes of halloysite particles in Japanese clays. Clays Clay Minerals 4, 67-79. https://doi.org/10.1346/ CCMN.1955.0040110
  • Takahashi, H. 1957. Effect of dry grinding on kaolin minerals. Clays and Clay Minerals 6(1), 279-291. https://doi.org/10.1346/ CCMN.1957.0060121
  • Takahashi, H. 1959a. Effect of dry grinding on kaolin minerals. III. Halloysite. Bulletin of the Chemical Society of Japan 32(10), 252-263. https://doi.org/10.1246/bcsj.32.252 Takahashi, H., 1959b. Wet grinding on kaolin minerals. Bulletin of the Chemical Society of Japan 32(4), 381-387. https://doi.org/10.1246/ bcsj.32.381
  • Takahashi, T., Dahlgren, R.A., Theng, B.K.G., Whitton, J.S., Soma, M. 2001. Potassium-selective, halloysite-rich soils formed in volcanic materials from northern California. Soil Science Society of America Journal 65(2), 516-.526. https://doi.org/10.2136/sssaj2001.652516x
  • Uvarov, V.S., Vovk, N.E. 1971. Flotation of alunite and clay minerals. Soviet Mining Science 7, 436-437. https://doi.org/10.1007/BF02501579 Uygun, A. 1999. Geology and origin of same carbonate-hosted halloysite deposits in Nw - Anatolia. Bulletin of the Mineral Research and Exploration 121, 141-151.
  • Wada, K. 1961. Lattice expansion of kaolin minerals by treatment with potassium acetate. American Mineralogist 46(1-2), 78-91.
  • Wilson, I.R., 2004. Kaolin and halloysite deposits of China. Clay Minerals 39(1), 1-15. https://doi.org/10.1180/000985543910116 Wilson, I.R., de Souza Santos, H., de Souza Santos, P. 2006. Kaolin and halloysite deposits of Brazil. Clay Minerals 41(3), 697-716. https://doi. org/10.1180/0009855064130213
  • Wu, H., Watanabe, H., Ma, W., Fujimoto, A., Higuchi, T., Uesugi, K., Takeuchi, A., Suzuki, Y., Jinnai, H., Takahara, A. 2013. Robust liquid marbles stabilized with surface-modified halloysite nanotubes. Langmuir 29(48), 14971-14975. https://doi.org/10.1021/la4041858
  • Yapa, N. 1993. Beneficiation of alunite bearing kaolinite, Ph.D. Thesis, Institute of Science and Technology, Istanbul Technical University.
Toplam 70 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Kimyasal-Biyolojik Kazanma Teknikleri ve Cevher Hazırlama
Bölüm Derleme
Yazarlar

Emrah Durgut 0000-0002-4637-7087

Mustafa Çınar 0000-0001-9553-423X

Orhan Özdemir 0000-0002-4408-546X

Yayımlanma Tarihi 12 Şubat 2024
Gönderilme Tarihi 21 Eylül 2023
Yayımlandığı Sayı Yıl 2023

Kaynak Göster

APA Durgut, E., Çınar, M., & Özdemir, O. (2024). An overview of halloysite mineral. Bilimsel Madencilik Dergisi, 62(4), 175-182. https://doi.org/10.30797/madencilik.1364137
AMA Durgut E, Çınar M, Özdemir O. An overview of halloysite mineral. Madencilik. Şubat 2024;62(4):175-182. doi:10.30797/madencilik.1364137
Chicago Durgut, Emrah, Mustafa Çınar, ve Orhan Özdemir. “An Overview of Halloysite Mineral”. Bilimsel Madencilik Dergisi 62, sy. 4 (Şubat 2024): 175-82. https://doi.org/10.30797/madencilik.1364137.
EndNote Durgut E, Çınar M, Özdemir O (01 Şubat 2024) An overview of halloysite mineral. Bilimsel Madencilik Dergisi 62 4 175–182.
IEEE E. Durgut, M. Çınar, ve O. Özdemir, “An overview of halloysite mineral”, Madencilik, c. 62, sy. 4, ss. 175–182, 2024, doi: 10.30797/madencilik.1364137.
ISNAD Durgut, Emrah vd. “An Overview of Halloysite Mineral”. Bilimsel Madencilik Dergisi 62/4 (Şubat 2024), 175-182. https://doi.org/10.30797/madencilik.1364137.
JAMA Durgut E, Çınar M, Özdemir O. An overview of halloysite mineral. Madencilik. 2024;62:175–182.
MLA Durgut, Emrah vd. “An Overview of Halloysite Mineral”. Bilimsel Madencilik Dergisi, c. 62, sy. 4, 2024, ss. 175-82, doi:10.30797/madencilik.1364137.
Vancouver Durgut E, Çınar M, Özdemir O. An overview of halloysite mineral. Madencilik. 2024;62(4):175-82.

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