An application on fish bones by chemical modification of histidine as amino acid

Year 2015, Volume: 4 Issue: 1, 19 - 23, 10.07.2015

Bayram Kizilkaya Hasan Basri Ormanci Alkan Oztekin Evren Tan Nail Ucyol Gulen Turker Ahmet Adem Tekinay Ali Bilici

Abstract

In this study, fish bones as a waste in fish processing was investigated whether they could be used as multi-functional materials by chemical modification. Histidine was used and modified on the surface of bone particle by esterification method. The reaction was carried out in water. The results showed that the surface modification of bone particles was performed successfully. Histidine bonded on the surface of bone was calculated as 110.83 µmol/g. The point of zero charge (PZC) of bone apatite (H) and modified bone (HA4) was investigated and determined as 7.25 and 6.98, respectively. SEM-EDX spectrums showed that nitrogen element of histidine on the surface of HA4 could be observed in EDS spectrum clearly. According to EDS spectrum analysis, nitrogen amount of HA4 which was formed to the one of histidine composition was detected as 16.2 %., nitrogen amount of Hand HA5 was detected as 8.037% and 8.565 %, respectively.

Keywords

Fish Bone, Histidine, Surface Modification

References

• Corami, A., D’Acapito, F., Mignardi, S. and V. Ferini. 2008. Removal of Cu from aqueous solutions by synthetic hydroxyapatite: EXAFS investigation. Materials Science and Engineering B, 149:209–213
• Dimovic, S., Smiciklas, I., Plecas, I., Antonovic, D. and M. Mitric. 2009. Comparative study of differently treated animal bones for Co2+ removal. Journal of Hazardous Materials, 164:279–287.
• El Hammari, L., Laghzizil, A, Saoiabi, A., Barboux, P. and M. Meyer. 2006. Chemical modification of porous calcium hydroxyapatite surfaces by grafting phenylphosphonic and phenylphosphite acids. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 289:84–88.
• Janq, S.H., Jeonq, Y.G., Min, B.G., Lyoo, W.S. and S.C. Lee. 2008. Preparation and lead ion removal property of hydroxyapatite/polyacrylamide composite hydrogels. Journal of Hazardous Materials, 159:294–299.
• Kizilkaya, B. and A.A. Tekinay. 2011. Comparative study and removal of Co and Ni (II) ions from aqueous solutions using fish bones. Science of Advanced Materials, 3:949–961.
• Kizilkaya, B., Tekinay, A.A. and Y. Dilgin. 2010. Adsorption and removal of Cu (II) ions from aqueous solution using pretreated fish bones. Desalination, 264:37–47.
• Li, Y. and W. Weng. 2008. Surface modification of hydroxyapatite by stearic acid: Characterization and in vitro behaviours. Journal of Materials Science: Materials in Medicine, 19:19– 25
• Murugan, R. and S. Ramakrishna. 2004. Coupling of therapeutic molecules onto surface modified coralline hydroxyapatite. Biomaterials, 25:3073–3080.
• Qiu, X., Chen, L., Hu, J., Sun, J., Hong, Z., Lıu, A., Chen, X. and X. Jing, 2005. Surface-modified hydroxyapatite linked by L- lactic acid oligomer in the absence of catalyst. Journal of Polymer Science Part A: Polymer Chemistry, 43:5177–5185.
• Smiciklas, I., Dimovic, S., Plecas, I. and M. Mitric. 2006. Removal of Co2+ from aqueous solutions by hydroxyapatite. Water Research, 40:2267–2274.
• Tan, E., Kızılkaya, B., Üçyol, N., Ormancı, H.B. and A. Oral. 2014. Surface modification with P-aminohippuric acid on biogenic apatite (fish bones) particles. Marine Science and Technology Bulletin, 3(2):45-50.
• Zhu, R., Yu, R., Yao, J., Mao, D., Xing, C. and D. Wanga. 2008. Removal of Cd2+ from aqueous solutions by hydroxyapatite, Catalysis Today, 139:94–99.