Electrochemical Detection of Cadmium and Lead in Rice on Manganese dioxide Reinforced Carboxylated Graphene Oxide Nanofilm

İlknur Üstündağ; Aslı Erkal; Zafer Üstündağ; Ali Osman Solak

EN

Electrochemical Detection of Cadmium and Lead in Rice on Manganese dioxide Reinforced Carboxylated Graphene Oxide Nanofilm

Abstract

Manganese dioxide decorated carboxylated graphene oxide (Mn-GO-COOH) attached onto the glassy carbon (GC) electrode to develop a new method for the simultaneous determination of Cd²⁺ and Pb²⁺ ions in rice samples. Graphene oxide (GO) was attached on 4-aminophenyl covalently modified glassy carbon surface via amide reaction. As-prepared modified material was characterized with XPS, SEM and electrochemical methods. A novel differential pulse anodic stripping voltammetric (DPASV) method was developed for the simultaneous determination of Cd²⁺ and Pb²⁺ on the GC/Mn-GO-COOH nanoplatform electrode. A linear response was found for the heavy metals in the range from 5 to 100 mg/L. The limit of detections (LODs) of Cd²⁺and Pb²⁺ were 0.04 mg/L and 0.08 mg/L respectively. Manganese dioxide decorated carboxylated graphene oxide electrode was applied to the detection of Cd²⁺and Pb²⁺ present in different rice samples by developed voltammetric method, and the accessed results were found to be in accordance with that of ICP-OES.

Keywords

: Heavy metals,food analysis,differential pulse anodic stripping voltammetry

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Details

Primary Language

English

Subjects

Engineering

Journal Section

Research Article

Authors

İlknur Üstündağ This is me
Türkiye

Aslı Erkal This is me
Türkiye

Zafer Üstündağ ^*
Türkiye

Ali Osman Solak

Publication Date

December 24, 2018

Submission Date

December 13, 2018

Acceptance Date

December 24, 2018

Published in Issue

Year 2018 Volume: 6 Number: 2

IZ

https://izlik.org/JA85JJ67HJ

APA

Üstündağ, İ., Erkal, A., Üstündağ, Z., & Solak, A. O. (2018). Electrochemical Detection of Cadmium and Lead in Rice on Manganese dioxide Reinforced Carboxylated Graphene Oxide Nanofilm. MANAS Journal of Engineering, 6(2), 96-109. https://izlik.org/JA85JJ67HJ

AMA

1.Üstündağ İ, Erkal A, Üstündağ Z, Solak AO. Electrochemical Detection of Cadmium and Lead in Rice on Manganese dioxide Reinforced Carboxylated Graphene Oxide Nanofilm. MJEN. 2018;6(2):96-109. https://izlik.org/JA85JJ67HJ

Chicago

Üstündağ, İlknur, Aslı Erkal, Zafer Üstündağ, and Ali Osman Solak. 2018. “Electrochemical Detection of Cadmium and Lead in Rice on Manganese Dioxide Reinforced Carboxylated Graphene Oxide Nanofilm”. MANAS Journal of Engineering 6 (2): 96-109. https://izlik.org/JA85JJ67HJ.

EndNote

Üstündağ İ, Erkal A, Üstündağ Z, Solak AO (December 1, 2018) Electrochemical Detection of Cadmium and Lead in Rice on Manganese dioxide Reinforced Carboxylated Graphene Oxide Nanofilm. MANAS Journal of Engineering 6 2 96–109.

IEEE

[1]İ. Üstündağ, A. Erkal, Z. Üstündağ, and A. O. Solak, “Electrochemical Detection of Cadmium and Lead in Rice on Manganese dioxide Reinforced Carboxylated Graphene Oxide Nanofilm”, MJEN, vol. 6, no. 2, pp. 96–109, Dec. 2018, [Online]. Available: https://izlik.org/JA85JJ67HJ

ISNAD

Üstündağ, İlknur - Erkal, Aslı - Üstündağ, Zafer - Solak, Ali Osman. “Electrochemical Detection of Cadmium and Lead in Rice on Manganese Dioxide Reinforced Carboxylated Graphene Oxide Nanofilm”. MANAS Journal of Engineering 6/2 (December 1, 2018): 96-109. https://izlik.org/JA85JJ67HJ.

JAMA

1.Üstündağ İ, Erkal A, Üstündağ Z, Solak AO. Electrochemical Detection of Cadmium and Lead in Rice on Manganese dioxide Reinforced Carboxylated Graphene Oxide Nanofilm. MJEN. 2018;6:96–109.

MLA

Üstündağ, İlknur, et al. “Electrochemical Detection of Cadmium and Lead in Rice on Manganese Dioxide Reinforced Carboxylated Graphene Oxide Nanofilm”. MANAS Journal of Engineering, vol. 6, no. 2, Dec. 2018, pp. 96-109, https://izlik.org/JA85JJ67HJ.

Vancouver

1.İlknur Üstündağ, Aslı Erkal, Zafer Üstündağ, Ali Osman Solak. Electrochemical Detection of Cadmium and Lead in Rice on Manganese dioxide Reinforced Carboxylated Graphene Oxide Nanofilm. MJEN [Internet]. 2018 Dec. 1;6(2):96-109. Available from: https://izlik.org/JA85JJ67HJ

Manas Journal of Engineering

16155

Electrochemical Detection of Cadmium and Lead in Rice on Manganese dioxide Reinforced Carboxylated Graphene Oxide Nanofilm

Abstract

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References

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