Synthesize of montmorillonite supported hydroxyapatite and determination of adsorption capacity by tetracycline removal

Yıl 2022, Cilt: 10 Sayı: 2, 179 - 186, 31.12.2022

Pelin Baran

https://doi.org/10.51354/mjen.1175145

Öz

In this study, removal of organic pollutants in wastewater using HA/MMT composite material was studied. Tetracycline (TC) antibiotic was used as an organic pollutant. HA/MMT composites were synthesized in a ball mill at different ratios (1:1, 1:2 and 2:1). The synthesis time was fixed at 5 hours. As a result of the experiments, it was concluded that 1:2 ratio of HA/MMT composite has the highest adsorption capacity (147 mg g-1) among the others. The isotherm experiments showed that the Langmuir isotherm model was compatible with the experimental data, and the maximum adsorption capacity was obtained as 150 mg g-1, which indicated that TC was adsorbed to create a monolayer coverage on HA/MMT adsorption cites. In the light of kinetic data, pseudo-second-order kinetic model was the best suitable model for TC adsorption; moreover the calculated adsorption capacity (qe = 227.27 mg g-1) was found suitable with experimental (qe = 223.47 mg g-1). In addition, it has been observed that intra-particle diffusion takes place as a rate-determining step. It has been concluded that TC adsorption of HA/MMT composite was an endothermic (ΔHo = +39.85 kJ mol-1) and spontaneous process thermodynamically. It has been concluded that the synthesized HA/MMT composite has high adsorption capacity and can be used for the removal of organic pollutants such as TC from wastewater.

Anahtar Kelimeler

Hydroxyapatite, montmorillonite, clay composites, removal of antibiotics

Kaynakça

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