Research Article
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Year 2024, Volume: 12 Issue: 2, 215 - 223, 27.12.2024
https://doi.org/10.51354/mjen.1557799

Abstract

Project Number

PYO.MUH.1901.18.002

References

  • [1]. Adegoke, K.A. and O.S. Bello, "Dye sequestration using agricultural wastes as adsorbents", Water Resources and Industry, 12, (2015), 8-24.
  • [2]. Mahmoodi, N.M., O. Masrouri, and F. Najafi, "Dye removal using polymeric adsorbent from wastewater containing mixture of two dyes", Fibers and Polymers, 15, (2014), 1656-1668.
  • [3]. Sen, N.E. and Z.M. Senol, "Effective removal of Allura red food dye from water using cross-linked chitosan-diatomite composite beads", Int J Biol Macromol, 253, (2023), 126632.
  • [4]. You, X., et al., "Adsorption of dyes methyl violet and malachite green from aqueous solution on multi- step modified rice husk powder in single and binary systems: Characterization, adsorption behavior and physical interpretations", J Hazard Mater, 430, (2022), 128445.
  • [5]. Basakcilardan Kabakci, S. and S.S. Baran, "Hydrothermal carbonization of various lignocellulosics: Fuel characteristics of hydrochars and surface characteristics of activated hydrochars", Waste Manag, 110, (2019), 259-268.
  • [6]. Yahav Spitzer, R., et al., "Biocrude extraction from human-excreta-derived hydrochar for sustainable energy and agricultural applications", Environ Res, 247, (2024), 118287.
  • [7]. Amarasinghe, H.A.H.I., S.K. Gunathilake, and A.K. Karunarathna, "Ascertaining of Optimum Pyrolysis Conditions in Producing Refuse Tea Biochar as a Soil Amendment", Procedia Food Science, 6, (2016), 97-102.
  • [8]. Krishna Veni, D., et al., "Biochar from green waste for phosphate removal with subsequent disposal", Waste Manag, 68, (2017), 752-759.
  • [9]. Zi, W., et al., "Pyrolysis, morphology and microwave absorption properties of tobacco stem materials", Sci Total Environ, 683, (2019), 341-350.
  • [10]. Wang, Y., R. Yin, and R. Liu, "Characterization of biochar from fast pyrolysis and its effect on chemical properties of the tea garden soil", Journal of Analytical and Applied Pyrolysis, 110, (2014), 375-381.
  • [11]. Zhang, P., et al., "Characteristics of tetracycline adsorption by cow manure biochar prepared at different pyrolysis temperatures", Bioresour Technol, 285, (2019), 121348.
  • [12]. Jalilian, M., et al., "A review: Hydrochar as potential adsorbents for wastewater treatment and CO(2) adsorption", Sci Total Environ, 914, (2024), 169823.
  • [13]. Goel, C., et al., "CO2 adsorption by KOH-activated hydrochar derived from banana peel waste", Chemical Papers, 78, (2024), 3845-3856.
  • [14]. Zhou, N., et al., "Effect of pyrolysis condition on the adsorption mechanism of heavy metals on tobacco stem biochar in competitive mode", Environ Sci Pollut Res Int, 26, (2019), 26947-26962.
  • [15]. Kibet, J.K., A. Jebet, and T. Kinyanjui, "Molecular oxygenates from the thermal degradation of tobacco and material characterization of tobacco char", Scientific African, (2019), 5.
  • [16]. Wei, M., et al., "Extraction of Nitrogen Compounds from Tobacco Waste via Thermal Treatment", Energies, 13, (2020), 18.
  • [17]. Onorevoli, B., et al., "Characterization of feedstock and biochar from energetic tobacco seed waste pyrolysis and potential application of biochar as an adsorbent", Journal of Environmental Chemical Engineering, 6, (2018), 1279-1287.
  • [18]. Blankenship, L.S. and R. Mokaya, "Cigarette butt-derived carbons have ultra-high surface area and unprecedented hydrogen storage capacity", Energy & Environmental Science, 10, (2017), 2552-2562.
  • [19]. Lima, H.H.C., et al., "Hydrochars based on cigarette butts as a recycled material for the adsorption of pollutants", Journal of Environmental Chemical Engineering, 6, (2018), 7054-7061.
  • [20]. Calabuig, E., N. Juárez-Serrano, and A. Marcilla, "TG-FTIR study of evolved gas in the decomposition of different types of tobacco", Effect of the addition of SBA-15. Thermochimica Acta, 671, (2019), 209-219.
  • [21]. Sevilla, M., J.A. Maciá-Agulló, and A.B. Fuertes, "Hydrothermal carbonization of biomass as a route for the sequestration of CO2: Chemical and structural properties of the carbonized products", Biomass and Bioenergy, 35, (2011), 3152-3159.
  • [22]. Tomczyk, A., et al., "Purification of Aqueous Media by Biochars: Feedstock Type Effect on Silver Nanoparticles Removal", Molecules, 25, (2020), 12.
  • [23]. Pathy, A., et al., "Malachite green removal using algal biochar and its composites with kombucha SCOBY: An integrated biosorption and phycoremediation approach", Surfaces and Interfaces, (2022), 30.
  • [24]. Donat, R., et al., "Thermodynamic parameters and sorption of U(VI) on ACSD", Journal of Radioanalytical and Nuclear Chemistry, 279, (2008), 271-280.
  • [25]. Zhang, X., et al., "Adsorption-reduction removal of Cr(VI) by tobacco petiole pyrolytic biochar: Batch experiment, kinetic and mechanism studies", Bioresour Technol, 268, (2018), 149-157.
  • [26]. Haladu, S.A., "Highly efficient adsorption of malachite green dye onto a cross-linked pH-responsive cycloterpolymer resin: Kinetic, equilibrium and thermodynamic studies", Journal of Molecular Liquids, (2022), 357.

Hydrochar Production from Cigarette Butts and Tobacco for Dye Adsorption

Year 2024, Volume: 12 Issue: 2, 215 - 223, 27.12.2024
https://doi.org/10.51354/mjen.1557799

Abstract

In this study, tobacco waste generated from cigarette and cigar production, as well as discarded cigarette butts resulting from cigarette use, were recycled and their use as adsorbent materials was investigated. For this purpose, both products underwent various thermal and chemical treatments and were converted into hydrochar form. Chemically activated hydrochar was used in dye removal experiments due to its high surface area and adsorbent properties. Malachite green was selected as the dye material for the project. Adsorption experiments were conducted at different initial concentrations, adsorbent doses, and contact times. In experiments on the removal of malachite green with butts and tobacco waste hydrochars, removal rates as high as 99% were obtained. As a result of adsorption experiments carried out with both hydrochars, it was observed that the adsorption fits the Langmuir isotherm model and the Pseudo-Second-Order kinetic model. Tobacco waste and discarded cigarette butts, which are cheap, readily available, and abundant, were found to be effective alternative adsorbents for malachite green removal.

Ethical Statement

not required

Supporting Institution

Ondokuz Mayıs University

Project Number

PYO.MUH.1901.18.002

Thanks

Ondokuz Mayıs University, Scientific Research Projects Coordination Unit

References

  • [1]. Adegoke, K.A. and O.S. Bello, "Dye sequestration using agricultural wastes as adsorbents", Water Resources and Industry, 12, (2015), 8-24.
  • [2]. Mahmoodi, N.M., O. Masrouri, and F. Najafi, "Dye removal using polymeric adsorbent from wastewater containing mixture of two dyes", Fibers and Polymers, 15, (2014), 1656-1668.
  • [3]. Sen, N.E. and Z.M. Senol, "Effective removal of Allura red food dye from water using cross-linked chitosan-diatomite composite beads", Int J Biol Macromol, 253, (2023), 126632.
  • [4]. You, X., et al., "Adsorption of dyes methyl violet and malachite green from aqueous solution on multi- step modified rice husk powder in single and binary systems: Characterization, adsorption behavior and physical interpretations", J Hazard Mater, 430, (2022), 128445.
  • [5]. Basakcilardan Kabakci, S. and S.S. Baran, "Hydrothermal carbonization of various lignocellulosics: Fuel characteristics of hydrochars and surface characteristics of activated hydrochars", Waste Manag, 110, (2019), 259-268.
  • [6]. Yahav Spitzer, R., et al., "Biocrude extraction from human-excreta-derived hydrochar for sustainable energy and agricultural applications", Environ Res, 247, (2024), 118287.
  • [7]. Amarasinghe, H.A.H.I., S.K. Gunathilake, and A.K. Karunarathna, "Ascertaining of Optimum Pyrolysis Conditions in Producing Refuse Tea Biochar as a Soil Amendment", Procedia Food Science, 6, (2016), 97-102.
  • [8]. Krishna Veni, D., et al., "Biochar from green waste for phosphate removal with subsequent disposal", Waste Manag, 68, (2017), 752-759.
  • [9]. Zi, W., et al., "Pyrolysis, morphology and microwave absorption properties of tobacco stem materials", Sci Total Environ, 683, (2019), 341-350.
  • [10]. Wang, Y., R. Yin, and R. Liu, "Characterization of biochar from fast pyrolysis and its effect on chemical properties of the tea garden soil", Journal of Analytical and Applied Pyrolysis, 110, (2014), 375-381.
  • [11]. Zhang, P., et al., "Characteristics of tetracycline adsorption by cow manure biochar prepared at different pyrolysis temperatures", Bioresour Technol, 285, (2019), 121348.
  • [12]. Jalilian, M., et al., "A review: Hydrochar as potential adsorbents for wastewater treatment and CO(2) adsorption", Sci Total Environ, 914, (2024), 169823.
  • [13]. Goel, C., et al., "CO2 adsorption by KOH-activated hydrochar derived from banana peel waste", Chemical Papers, 78, (2024), 3845-3856.
  • [14]. Zhou, N., et al., "Effect of pyrolysis condition on the adsorption mechanism of heavy metals on tobacco stem biochar in competitive mode", Environ Sci Pollut Res Int, 26, (2019), 26947-26962.
  • [15]. Kibet, J.K., A. Jebet, and T. Kinyanjui, "Molecular oxygenates from the thermal degradation of tobacco and material characterization of tobacco char", Scientific African, (2019), 5.
  • [16]. Wei, M., et al., "Extraction of Nitrogen Compounds from Tobacco Waste via Thermal Treatment", Energies, 13, (2020), 18.
  • [17]. Onorevoli, B., et al., "Characterization of feedstock and biochar from energetic tobacco seed waste pyrolysis and potential application of biochar as an adsorbent", Journal of Environmental Chemical Engineering, 6, (2018), 1279-1287.
  • [18]. Blankenship, L.S. and R. Mokaya, "Cigarette butt-derived carbons have ultra-high surface area and unprecedented hydrogen storage capacity", Energy & Environmental Science, 10, (2017), 2552-2562.
  • [19]. Lima, H.H.C., et al., "Hydrochars based on cigarette butts as a recycled material for the adsorption of pollutants", Journal of Environmental Chemical Engineering, 6, (2018), 7054-7061.
  • [20]. Calabuig, E., N. Juárez-Serrano, and A. Marcilla, "TG-FTIR study of evolved gas in the decomposition of different types of tobacco", Effect of the addition of SBA-15. Thermochimica Acta, 671, (2019), 209-219.
  • [21]. Sevilla, M., J.A. Maciá-Agulló, and A.B. Fuertes, "Hydrothermal carbonization of biomass as a route for the sequestration of CO2: Chemical and structural properties of the carbonized products", Biomass and Bioenergy, 35, (2011), 3152-3159.
  • [22]. Tomczyk, A., et al., "Purification of Aqueous Media by Biochars: Feedstock Type Effect on Silver Nanoparticles Removal", Molecules, 25, (2020), 12.
  • [23]. Pathy, A., et al., "Malachite green removal using algal biochar and its composites with kombucha SCOBY: An integrated biosorption and phycoremediation approach", Surfaces and Interfaces, (2022), 30.
  • [24]. Donat, R., et al., "Thermodynamic parameters and sorption of U(VI) on ACSD", Journal of Radioanalytical and Nuclear Chemistry, 279, (2008), 271-280.
  • [25]. Zhang, X., et al., "Adsorption-reduction removal of Cr(VI) by tobacco petiole pyrolytic biochar: Batch experiment, kinetic and mechanism studies", Bioresour Technol, 268, (2018), 149-157.
  • [26]. Haladu, S.A., "Highly efficient adsorption of malachite green dye onto a cross-linked pH-responsive cycloterpolymer resin: Kinetic, equilibrium and thermodynamic studies", Journal of Molecular Liquids, (2022), 357.
There are 26 citations in total.

Details

Primary Language English
Subjects Waste Management, Reduction, Reuse and Recycling, Environmentally Sustainable Engineering, Solid and Hazardous Wastes
Journal Section Research Article
Authors

Sevda Esma Darama 0000-0002-6747-4679

Semra Çoruh 0000-0002-8306-1890

Selim Ceylan 0000-0001-7258-6205

Elif Hatice Gürkan 0000-0003-3868-181X

Project Number PYO.MUH.1901.18.002
Publication Date December 27, 2024
Submission Date September 29, 2024
Acceptance Date December 18, 2024
Published in Issue Year 2024 Volume: 12 Issue: 2

Cite

APA Darama, S. E., Çoruh, S., Ceylan, S., Gürkan, E. H. (2024). Hydrochar Production from Cigarette Butts and Tobacco for Dye Adsorption. MANAS Journal of Engineering, 12(2), 215-223. https://doi.org/10.51354/mjen.1557799
AMA Darama SE, Çoruh S, Ceylan S, Gürkan EH. Hydrochar Production from Cigarette Butts and Tobacco for Dye Adsorption. MJEN. December 2024;12(2):215-223. doi:10.51354/mjen.1557799
Chicago Darama, Sevda Esma, Semra Çoruh, Selim Ceylan, and Elif Hatice Gürkan. “Hydrochar Production from Cigarette Butts and Tobacco for Dye Adsorption”. MANAS Journal of Engineering 12, no. 2 (December 2024): 215-23. https://doi.org/10.51354/mjen.1557799.
EndNote Darama SE, Çoruh S, Ceylan S, Gürkan EH (December 1, 2024) Hydrochar Production from Cigarette Butts and Tobacco for Dye Adsorption. MANAS Journal of Engineering 12 2 215–223.
IEEE S. E. Darama, S. Çoruh, S. Ceylan, and E. H. Gürkan, “Hydrochar Production from Cigarette Butts and Tobacco for Dye Adsorption”, MJEN, vol. 12, no. 2, pp. 215–223, 2024, doi: 10.51354/mjen.1557799.
ISNAD Darama, Sevda Esma et al. “Hydrochar Production from Cigarette Butts and Tobacco for Dye Adsorption”. MANAS Journal of Engineering 12/2 (December 2024), 215-223. https://doi.org/10.51354/mjen.1557799.
JAMA Darama SE, Çoruh S, Ceylan S, Gürkan EH. Hydrochar Production from Cigarette Butts and Tobacco for Dye Adsorption. MJEN. 2024;12:215–223.
MLA Darama, Sevda Esma et al. “Hydrochar Production from Cigarette Butts and Tobacco for Dye Adsorption”. MANAS Journal of Engineering, vol. 12, no. 2, 2024, pp. 215-23, doi:10.51354/mjen.1557799.
Vancouver Darama SE, Çoruh S, Ceylan S, Gürkan EH. Hydrochar Production from Cigarette Butts and Tobacco for Dye Adsorption. MJEN. 2024;12(2):215-23.

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