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Ethanol electro-oxidation on Pd nanoparticle-decorated CeO₂ nanostructures

Year 2025, Volume: 5 Issue: 2, 67 - 70, 31.12.2025
https://izlik.org/JA77JF78EU

Abstract

Direct alcohol fuel cells stand out as a good alternative to fossil fuels in terms of energy efficiency. In this study, electrochemical synthesis of CeO2 nanostructures was performed on the surfaces of pencil graphite electrodes (PGEs). The prepared CeO2 nanostructures were characterized using various techniques, and their surfaces were then decorated with Pd nanoparticles via electrochemical methods. Pd nanoparticles decorated-CeO2 (Pd@CeO2) nanostructures were characterized by Field emission scanning electron microscopy (FESEM), Energy dispersive spectroscopy (EDS), Electrochemical impedance spectroscopy (EIS) technique. The activity of Pd nanoparticle-added CeO2 nanostructures in the electro-oxidation of ethanol was investigated, and an approximately 16-fold increase in the oxidation current density of ethanol was observed compared to CeO2.

Supporting Institution

Ataturk University

Project Number

FBA-2024-13889

References

  • 1. Dincer I. Renewable energy and sustainable development: a crucial review. Renew Sustain Energy Rev. 2000;4(2):157-175. doi:10.1016/S1364-0321(99)00011-8
  • 2. Kaur J, Gupta RK, Kumar A. Electrocatalytic ethanol oxidation reaction: recent progress, challenges, and future prospects. Discov Nano. 2024;19(1):137. doi:10.1186/s11671-024-04067-9
  • 3. Kamarudin SK, Achmad F, Daud WRW. Overview on the application of direct methanol fuel cell (DMFC) for portable electronic devices. Int J Hydrogen Energy. 2009;34(16):6902-6916. doi:10.1016/j.ijhydene.2009.06.013
  • 4. Li G, Jiang L, Jiang Q, Wang S, Sun G. Preparation and characterization of PdxAgy/C electrocatalysts for ethanol electrooxidation reaction in alkaline media. Electrochim Acta. 2011;56(22):7703-7711. doi:10.1016/j.electacta.2011.06.036
  • 5. Awasthi R, Singh RN. Graphene-supported Pd–Ru nanoparticles with superior methanol electrooxidation activity. Carbon N Y. 2013;51:282-289. doi:10.1016/j.carbon.2012.08.055
  • 6. Yousaf A Bin, Popelka A, Rogach AL, Kasak P. Copper (I) oxide nanocubes loaded with a low-content binary PtIr alloy enable enhanced methanol/ ethanol oxidation. Int J Hydrogen Energy. 2025;113:441-450. doi:10.1016/j.ijhydene.2025.02.394
  • 7. Nagaraju DH, Devaraj S, Balaya P. Palladium nanoparticles anchored on graphene nanosheets: Methanol, ethanol oxidation reactions and their kinetic studies. Mater Res Bull. 2014;60:150-157. doi:10.1016/j.materresbull.2014.08.027
  • 8. Rao L, Jiang Y, Zhang B, You L, Li Z, Sun S. Electrocatalytic oxidation of ethanol. Prog Chem. 2014;26(05):727-736. doi:10.7536/PC131015
  • 9. Wang LL, Li QX, Zhan TY, Xu QJ. A Review of Pd-Basedn Electrocatalyst for the Ethanol Oxidation Reaction in Alkaline Medium. Adv Mater Res. 2013;860-863:826-830. doi:10.4028/www.scientific.net/AMR.860-863.826
  • 10. Julkapli NM, Bagheri S. Graphene supported heterogeneous catalysts: An overview. Int J Hydrogen Energy. 2015;40(2):948-979. doi:10.1016/j.ijhydene.2014.10.129
  • 11. Gong L, Yang Z, Li K, Xing W, Liu C, Ge J. Recent development of methanol electrooxidation catalysts for direct methanol fuel cell. J Energy Chem. 2018;27(6):1618- 1628. doi:10.1016/j.jechem.2018.01.029
  • 12. Zhou WJ, Li WZ, Song SQ, et al. Bi- and tri-metallic Pt-based anode catalysts for direct ethanol fuel cells. J Power Sources. 2004;131(1-2):217-223. doi:10.1016/j.jpowsour.2003.12.040
  • 13. Borg H, Zámbó D, Bessel P, et al. Tailoring Bimetallic Pt/Pd Cryogels for Efficient Ethanol Electro‐Oxidation. ChemElectroChem. 2025;12(3). doi:10.1002/celc.202400552
  • 14. Li S, Ma Y, Li Y. Strain engineering of PtMn alloy enclosed by high-indexed facets boost ethanol electrooxidation. J Colloid Interface Sci. 2025;677:416-424. doi:10.1016/j.jcis.2024.07.254
  • 15. Qiao Y, Li CM. Nanostructured catalysts in fuel cells. J Mater Chem. 2011;21(12):4027-4036. doi:10.1039/C0JM02871A 16. Waszczuk P, Solla-Gullón J, Kim HS, et al. Methanol Electrooxidation on Platinum/Ruthenium Nanoparticle Catalysts. J Catal. 2001;203(1):1-6. doi:10.1006/jcat.2001.3389
  • 17. Hoseini SJ, Bahrami M, Samadi Fard Z, et al. Designing of some platinum or palladium-based nanoalloys as effective electrocatalysts for methanol oxidation reaction. Int J Hydrogen Energy. 2018;43(32):15095-15111. doi:10.1016/j.ijhydene.2018.06.062
  • 18. Xu Y, Zhou Y, Li Y, Liu Y, Ding Z. Advances in cerium dioxide nanomaterials: Synthesis strategies, property modulation, and multifunctional applications. J Environ Chem Eng. 2024;12(5):113719. doi:10.1016/j.jece.2024.113719
  • 19. Çelebi N, Temur E, Öztürk Doğan H, Kavaz Yüksel A. The electrochemical fabrication of Cu@CeO2-rGO electrode for high-performance electrochemical nitrite sensor. Diam Relat Mater. 2024;143:110907. doi:10.1016/j.diamond.2024.110907
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Details

Primary Language English
Subjects Nanoelectronics
Journal Section Research Article
Authors

Neslihan Çelebi

Project Number FBA-2024-13889
Submission Date November 26, 2025
Acceptance Date December 29, 2025
Publication Date December 31, 2025
DOI https://doi.org/10.5281/zenodo.18105761
IZ https://izlik.org/JA77JF78EU
Published in Issue Year 2025 Volume: 5 Issue: 2

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