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Separation of co(ii) and se(vi) from a metal and glass industry wastes using graphene oxide-mangane oxide nanocomposite

Yıl 2020, Cilt: 38 Sayı: 1, 29 - 46, 27.03.2020

Öz

Co(II) and Se(VI) were not removed with conventional biological treatments, adsorption and chemical processes. Graphene oxide and mangane are excellent adsorbent for heavy metal remediation since their negative surface charge at an alkaline pH. Therefore, in this study, by doping the mangane oxide to the the graphene oxide Co(II) and Se(VI) were removed. XRD pattern of graphene oxide-mangane oxide samples showed that this nanocomposite exhibits poor cristallinity and contained MnO in Birnessite form. EDS analysis results showed that the graphene oxide has the lowest surface area (32 m2/g) and pore volume (0.11 cm3/g) with an average pore size of 17.3 nm. As the pH was increased from 2,0 to 9,0; the negativity of the zeta potantial of graphene oxide- mangane oxide nanocomposite decreased. Tthe narrow O 1s XPS spectra of mangane oxide-graphene oxide nanocomposite contained MnO2.The FTIR spectra of the nanocomposite showed that hydroxyl and carboxyl groups were present. For maximum Se(VI) and Co(II) adsorptions (98% and 98%); the optimum graphene oxide–mangane oxide concentration was found as 4 mg/L, at a pH of 8.9 at 21 0C after 20 min contacting time. The adsorption of Co(II) and Se(VI) was explained by the pseudo-first order kinetic model while the maximum adsorption capacities of Co(II) and Se(VI) were 256 mg/g and 289 mg/g, respectively. Graphene oxide–mangane oxide nanocomposite was reused with the percentages of 86% and 90% for Co(II) and Se(VI), respectively after four sequential utilisation. This, reduce the treatment cost by 48% for Se(VI) and by 43% for Co(II).

Kaynakça

  • [1] Lawson S., Macy J.M., (1995) Bioremediation of selenite inoil refinerywastewater, Appl.Microbiol. Biotechnol. 43 (4) 762–765.
  • [2] Peak D., (2006) Adsorption mechanisms of selenium oxyanions at the aluminum oxide/water interface, J. Colloid Interface Sci. 303 337–345.
  • [3] Das J., Das D., Dash G.P., Parida K.M., (2002) Studies on Mg/Fe hydrotalcite-likecompound (HTlc). I. Removal of inorganic selenite (SeO32−) from aqueous medium, J. Colloid Interface Sci. 251 (1) 26–32.
  • [4] Duc M., Lefèvre G., Fédoroff M., (2006) Sorption of selenite ions on hematite, J. Colloid Interface Sci. 298 (2) 556–563.
  • [5] Afkhami A., (2002) Kinetic-spectrophotometric determination of selenium in natural water after preconcentration of elemental selenium on activated carbon, Talanta 58, 311–317.
  • [6] El-Shafey E.I., (2007) Removal of Se(IV) from aqueous solution using sulphuric acidtreated peanut shell, J. Environ. Manage. 84, 620–627.
  • [7] Martínez M., Giménez J., Pablo J., Rovira M., Duro L., (2006) Sorption of selenium (IV) and selenium (VI) ontomagnetite, Appl. Surf. Sci. 252 (10) 3767–3773.
  • [8] Wan S., Wu J., He F., Zhou S., Wang R., Gao B., Chen J ., (2017) Hosphate removal by leadexhausted bioadsorbents simultaneously achieving lead stabilization, Chemosphere 168, 748–755. [9] Wan S, Ding W, Wu J, Gu Y, He F., (2018) Manganese oxide nanoparticles impregnated graphene oxide aggregates for cadmium and copper remediation, Chemical Engineering Journal, 350, 1135-114.
  • [10] Swann S.Jr., Appel E.G., Kistler S.S., (1934) Thoria aerogel catalyst: aliphatic esters to ketones Ind, Eng. Chem. 26, 1014–1014.
  • [11] Adebajo M., Frost R., Kloprogge J., Carmody O., Kokot S., (2003) Porous materials for oil spill cleanup: a review of synthesis and absorbing properties, J. Porous Mater. 10 159–170.
  • [12] Long J.W., Fischer A.E., McEvoy T.M., Bourg M.E., Lytle J.C., Rolison D., (2008) Selflimiting electropolymerization en route to ultrathin, conformal polymer coatings for energy storage applications, PMSE Prepr. 99 772–773.
  • [13] Latthe S.S., Digambar Y.N., Rao A.V., (2009) TMOS based water repellent silica thin films by co-precursor method using TMES as a hydrophobic agent, Appl. Surf. Sci. 255 3600–3604.
  • [14] Fan H., Anderson P., (2005) Copper and cadmium removal by Mn oxide-coated granular activated carbon, Sep. Purif. Technol. 45, 61–67.
  • [15] Boujelben J.B.N., Elouear Z., (2009) Removal of lead (II) Ions from aqueous solutions using manganese oxide-coated adsorbents: characterization and kinetic study, Adsorpt. Sci. Technol. 27, 177–191.
  • [16] Wang L., Han C., Nadagouda M.N., Dionysiou D.D., (2016) An innovative zinc oxide-coated zeolite adsorbent for removal of humic acid, J. Hazard. Mater. 313, 283–290.
  • [17] Ali I., (2012) New generation adsorbents for water treatment, Chem. Rev. 112, 5073–5091.
  • [18] Zhang Q., Du Q., Hua M., Jiao T., Gao F., Pan B., (2013) Sorption enhancement of lead ions from water by surface charged polystyrene-supported nano-zirconium oxide composites, Environ. Sci. Technol. 47, 6536–6544.
  • [19] Liu Z., Robinson J.T., Sun X., Dai H., (2008) PEGylated nanographene oxide for delivery of water-insoluble cancer drugs, J. Am. Chem. Soc 130, 10876–10877.
  • [20] Shen Y., Chen B., (2015) Sulfonated graphene nanosheets as a superb adsorbent for various environmental pollutants in water, Environ. Sci. Technol. 49, 7364–7372.
  • [21] Sun Y., Tang J ., Zhang K ., Yuan J ., Li J ., Zhu D.M., Ozawa K., Qin L.C., (2017) Comparison of reduction products from graphite oxide and graphene oxide for anode applications in lithium-ion batteries and sodium-ion batteries, Nanoscale 9, 2585–2595.
  • [22] Whitby R.L.D., Gun’ko V.M., Korobeinyk A., Busquets R., Cundy AB., Laíszlo K., Skubiszewska-Zie J., Kovacs K., Mikhalovsky S.V., (2012) Driving forces of conformational changes in single-layer graphene oxide, ACS Nano 5, 3967–3973.
  • [23] Wan S., Qu N., He F., Wang M., Liu G., He H., (2015) Tea waste-supported hydrated manganese dioxide (HMO) for enhanced removal of typical toxic metal ions from water, RSC Adv. 5, 88900–88907.
  • [24] Wan W., Zhao Z., Timothy C.H., Qian B., Peng S., Hao X., Qiu J., (2015) Graphene oxide liquid crystal Pickering emulsions and their assemblies, Carbon 85 16–23.
  • [25] Jamali M.R., Soleimani B., Rahnama R., Rahimi S.H.A., (2012) Development of an in situ solvent formation microextraction and preconcentration method based on ionic liquids for the determination of trace cobalt (II) in water samples by flame atomic absorption spectrometry, http://dx.doi.org/10.1016/j.arabjc.2012.08.004.
  • [26] Ma J., Liu C., Li R., Wang J., (2012) Properties and structural characterization of oxide starch/chitosan/graphene oxide biodegradable nanocomposites, J. Appl. Polym. Sci. 123, 2933–2944. [27] Li Y., Du Q., Liu T., Peng X., Wang J., Sun J., Wang Y., Wu S., Wang Z., Xia Y., Xia L., (2013) Comparative study of methylene blue dye adsorption onto activated carbon, graphene oxide, and carbon nanotubes, Chemical Engineering Research and Design, 91, 2, 361-368, https://doi.org/10.1016/j.cherd.2012.07.007. [28] Amir F.Z., Pham V.H., Schultheis E.M., Dickerson J.H., (2018) Flexible, all-solid-state, high-cell potential supercapacitors based on holey reduced graphene oxide/manganese dioxide nanosheets, Electrochimica Acta, 260, 944-951, https://doi.org/10.1016/j.electacta.2017.12.071.
  • [29] Jasinski J.B., Ziolkowska D., Michalska M., Kaminska M., (2013)Novel graphene oxide/manganese oxide Nanocomposites, RSC Advances 3(45):22857-22862, DOI:10.1039/C3RA42254B. [30] Park S. K. , Hoon D., Ho S., Park S., (2016) Electrochemical assembly of reduced graphene oxide/manganese dioxide nanocomposites into hierarchical sea urchin-like structures for supercapacitive electrodes, Journal of Alloys and Compounds, 668, 146-151,https://doi.org/10.1016/j.jallcom.2016.01.214. [31] Pan N, Li L, Ding J, Li S., Wang R., Jin Y., Wang X., Xia., (2016) Preparation of graphene oxide-manganese dioxide for highly efficient adsorption and separation of Th(IV)/U(VI), Journal of Hazardous Materials 309, 107-115, https://doi.org/10.1016/j.jhazmat.2016.02.012.
  • [32] Chou T., Doong R., Hu C. C., Zhang B., Su D.S., (2014) Hierarchically Porous Carbon with Manganese Oxides as Highly Efficient Electrode for Asymmetric Supercapacitors, ChemSusChem, 7, 3, https://doi.org/10.1002/cssc.201301014.
  • [33] She X., Zhang X., Liu J., Li L., Yu X., Huang Z., Shang S., (2015) Microwave-assisted synthesis of Mn3O4 nanoparticles@reduced graphene oxide nanocomposites for high performance supercapacitors, Materials Research Bulletin, 70, 945-950, https://doi.org/10.1016/j.materresbull.2015.06.044. [34] Qu J., Gao F., Zhou Q., Wang Z., Hu H., Li B., Wan W., Wang X., Qiu J., (2013) Highly atom-economic synthesis of graphene/Mn3O4 hybrid composites for electrochemical supercapacitors, Nanoscale, 5, 7, 2999-3005.
  • [35] Somiya S., Yamamato N., Yanagina H., (1988)Science and Technology of Zirconia (III), 24A and 24B, American Ceramic Society, Westerville.
  • [36] Matias T., Marques J., Quina M.J., Gando-Ferreira L., Valente A.J.M., Portugal A., Durães L., (2015) Silica-based aerogels as adsorbents for phenol-derivative compounds, Colloids Surf. A 480, 260–269.
  • [37] Caiping Y., (2010) Adsorption and desorption properties of D151 resin for Ce(III), Journal of rare earths, 28, Spec. Issue, Dec. p. 183 DOI: 10.1016/S1002-0721(10)60324-9.
  • [38] Jiang L., Liu Y., Zeng G., Xiao F., Hu X., Hu X., Wang H., Li T., Zhou L., Tan X., (2016) Removal of 17β-estradiol by few-layered graphene oxide nanosheets from aqueous solutions: External influence and adsorption mechanism, Xiao-fei, Chem. Eng. J. 284 93–102, http://doi.org/10.1016/j.cej.2015.08.139.
  • [39] Wan S., Wu J., Zhou S., Wang R., Gao B., He F. (2018) Enhanced lead and cadmium removal using biochar-supported hydrated manganese oxide (HMO) nanoparticles: Behavior and mechanism, Sci. Total Environ. 616–617, 1298–1306.
Yıl 2020, Cilt: 38 Sayı: 1, 29 - 46, 27.03.2020

Öz

Kaynakça

  • [1] Lawson S., Macy J.M., (1995) Bioremediation of selenite inoil refinerywastewater, Appl.Microbiol. Biotechnol. 43 (4) 762–765.
  • [2] Peak D., (2006) Adsorption mechanisms of selenium oxyanions at the aluminum oxide/water interface, J. Colloid Interface Sci. 303 337–345.
  • [3] Das J., Das D., Dash G.P., Parida K.M., (2002) Studies on Mg/Fe hydrotalcite-likecompound (HTlc). I. Removal of inorganic selenite (SeO32−) from aqueous medium, J. Colloid Interface Sci. 251 (1) 26–32.
  • [4] Duc M., Lefèvre G., Fédoroff M., (2006) Sorption of selenite ions on hematite, J. Colloid Interface Sci. 298 (2) 556–563.
  • [5] Afkhami A., (2002) Kinetic-spectrophotometric determination of selenium in natural water after preconcentration of elemental selenium on activated carbon, Talanta 58, 311–317.
  • [6] El-Shafey E.I., (2007) Removal of Se(IV) from aqueous solution using sulphuric acidtreated peanut shell, J. Environ. Manage. 84, 620–627.
  • [7] Martínez M., Giménez J., Pablo J., Rovira M., Duro L., (2006) Sorption of selenium (IV) and selenium (VI) ontomagnetite, Appl. Surf. Sci. 252 (10) 3767–3773.
  • [8] Wan S., Wu J., He F., Zhou S., Wang R., Gao B., Chen J ., (2017) Hosphate removal by leadexhausted bioadsorbents simultaneously achieving lead stabilization, Chemosphere 168, 748–755. [9] Wan S, Ding W, Wu J, Gu Y, He F., (2018) Manganese oxide nanoparticles impregnated graphene oxide aggregates for cadmium and copper remediation, Chemical Engineering Journal, 350, 1135-114.
  • [10] Swann S.Jr., Appel E.G., Kistler S.S., (1934) Thoria aerogel catalyst: aliphatic esters to ketones Ind, Eng. Chem. 26, 1014–1014.
  • [11] Adebajo M., Frost R., Kloprogge J., Carmody O., Kokot S., (2003) Porous materials for oil spill cleanup: a review of synthesis and absorbing properties, J. Porous Mater. 10 159–170.
  • [12] Long J.W., Fischer A.E., McEvoy T.M., Bourg M.E., Lytle J.C., Rolison D., (2008) Selflimiting electropolymerization en route to ultrathin, conformal polymer coatings for energy storage applications, PMSE Prepr. 99 772–773.
  • [13] Latthe S.S., Digambar Y.N., Rao A.V., (2009) TMOS based water repellent silica thin films by co-precursor method using TMES as a hydrophobic agent, Appl. Surf. Sci. 255 3600–3604.
  • [14] Fan H., Anderson P., (2005) Copper and cadmium removal by Mn oxide-coated granular activated carbon, Sep. Purif. Technol. 45, 61–67.
  • [15] Boujelben J.B.N., Elouear Z., (2009) Removal of lead (II) Ions from aqueous solutions using manganese oxide-coated adsorbents: characterization and kinetic study, Adsorpt. Sci. Technol. 27, 177–191.
  • [16] Wang L., Han C., Nadagouda M.N., Dionysiou D.D., (2016) An innovative zinc oxide-coated zeolite adsorbent for removal of humic acid, J. Hazard. Mater. 313, 283–290.
  • [17] Ali I., (2012) New generation adsorbents for water treatment, Chem. Rev. 112, 5073–5091.
  • [18] Zhang Q., Du Q., Hua M., Jiao T., Gao F., Pan B., (2013) Sorption enhancement of lead ions from water by surface charged polystyrene-supported nano-zirconium oxide composites, Environ. Sci. Technol. 47, 6536–6544.
  • [19] Liu Z., Robinson J.T., Sun X., Dai H., (2008) PEGylated nanographene oxide for delivery of water-insoluble cancer drugs, J. Am. Chem. Soc 130, 10876–10877.
  • [20] Shen Y., Chen B., (2015) Sulfonated graphene nanosheets as a superb adsorbent for various environmental pollutants in water, Environ. Sci. Technol. 49, 7364–7372.
  • [21] Sun Y., Tang J ., Zhang K ., Yuan J ., Li J ., Zhu D.M., Ozawa K., Qin L.C., (2017) Comparison of reduction products from graphite oxide and graphene oxide for anode applications in lithium-ion batteries and sodium-ion batteries, Nanoscale 9, 2585–2595.
  • [22] Whitby R.L.D., Gun’ko V.M., Korobeinyk A., Busquets R., Cundy AB., Laíszlo K., Skubiszewska-Zie J., Kovacs K., Mikhalovsky S.V., (2012) Driving forces of conformational changes in single-layer graphene oxide, ACS Nano 5, 3967–3973.
  • [23] Wan S., Qu N., He F., Wang M., Liu G., He H., (2015) Tea waste-supported hydrated manganese dioxide (HMO) for enhanced removal of typical toxic metal ions from water, RSC Adv. 5, 88900–88907.
  • [24] Wan W., Zhao Z., Timothy C.H., Qian B., Peng S., Hao X., Qiu J., (2015) Graphene oxide liquid crystal Pickering emulsions and their assemblies, Carbon 85 16–23.
  • [25] Jamali M.R., Soleimani B., Rahnama R., Rahimi S.H.A., (2012) Development of an in situ solvent formation microextraction and preconcentration method based on ionic liquids for the determination of trace cobalt (II) in water samples by flame atomic absorption spectrometry, http://dx.doi.org/10.1016/j.arabjc.2012.08.004.
  • [26] Ma J., Liu C., Li R., Wang J., (2012) Properties and structural characterization of oxide starch/chitosan/graphene oxide biodegradable nanocomposites, J. Appl. Polym. Sci. 123, 2933–2944. [27] Li Y., Du Q., Liu T., Peng X., Wang J., Sun J., Wang Y., Wu S., Wang Z., Xia Y., Xia L., (2013) Comparative study of methylene blue dye adsorption onto activated carbon, graphene oxide, and carbon nanotubes, Chemical Engineering Research and Design, 91, 2, 361-368, https://doi.org/10.1016/j.cherd.2012.07.007. [28] Amir F.Z., Pham V.H., Schultheis E.M., Dickerson J.H., (2018) Flexible, all-solid-state, high-cell potential supercapacitors based on holey reduced graphene oxide/manganese dioxide nanosheets, Electrochimica Acta, 260, 944-951, https://doi.org/10.1016/j.electacta.2017.12.071.
  • [29] Jasinski J.B., Ziolkowska D., Michalska M., Kaminska M., (2013)Novel graphene oxide/manganese oxide Nanocomposites, RSC Advances 3(45):22857-22862, DOI:10.1039/C3RA42254B. [30] Park S. K. , Hoon D., Ho S., Park S., (2016) Electrochemical assembly of reduced graphene oxide/manganese dioxide nanocomposites into hierarchical sea urchin-like structures for supercapacitive electrodes, Journal of Alloys and Compounds, 668, 146-151,https://doi.org/10.1016/j.jallcom.2016.01.214. [31] Pan N, Li L, Ding J, Li S., Wang R., Jin Y., Wang X., Xia., (2016) Preparation of graphene oxide-manganese dioxide for highly efficient adsorption and separation of Th(IV)/U(VI), Journal of Hazardous Materials 309, 107-115, https://doi.org/10.1016/j.jhazmat.2016.02.012.
  • [32] Chou T., Doong R., Hu C. C., Zhang B., Su D.S., (2014) Hierarchically Porous Carbon with Manganese Oxides as Highly Efficient Electrode for Asymmetric Supercapacitors, ChemSusChem, 7, 3, https://doi.org/10.1002/cssc.201301014.
  • [33] She X., Zhang X., Liu J., Li L., Yu X., Huang Z., Shang S., (2015) Microwave-assisted synthesis of Mn3O4 nanoparticles@reduced graphene oxide nanocomposites for high performance supercapacitors, Materials Research Bulletin, 70, 945-950, https://doi.org/10.1016/j.materresbull.2015.06.044. [34] Qu J., Gao F., Zhou Q., Wang Z., Hu H., Li B., Wan W., Wang X., Qiu J., (2013) Highly atom-economic synthesis of graphene/Mn3O4 hybrid composites for electrochemical supercapacitors, Nanoscale, 5, 7, 2999-3005.
  • [35] Somiya S., Yamamato N., Yanagina H., (1988)Science and Technology of Zirconia (III), 24A and 24B, American Ceramic Society, Westerville.
  • [36] Matias T., Marques J., Quina M.J., Gando-Ferreira L., Valente A.J.M., Portugal A., Durães L., (2015) Silica-based aerogels as adsorbents for phenol-derivative compounds, Colloids Surf. A 480, 260–269.
  • [37] Caiping Y., (2010) Adsorption and desorption properties of D151 resin for Ce(III), Journal of rare earths, 28, Spec. Issue, Dec. p. 183 DOI: 10.1016/S1002-0721(10)60324-9.
  • [38] Jiang L., Liu Y., Zeng G., Xiao F., Hu X., Hu X., Wang H., Li T., Zhou L., Tan X., (2016) Removal of 17β-estradiol by few-layered graphene oxide nanosheets from aqueous solutions: External influence and adsorption mechanism, Xiao-fei, Chem. Eng. J. 284 93–102, http://doi.org/10.1016/j.cej.2015.08.139.
  • [39] Wan S., Wu J., Zhou S., Wang R., Gao B., He F. (2018) Enhanced lead and cadmium removal using biochar-supported hydrated manganese oxide (HMO) nanoparticles: Behavior and mechanism, Sci. Total Environ. 616–617, 1298–1306.
Toplam 33 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Research Articles
Yazarlar

Sevil Akçağlar Bu kişi benim 0000-0002-5386-1862

Yayımlanma Tarihi 27 Mart 2020
Gönderilme Tarihi 19 Şubat 2019
Yayımlandığı Sayı Yıl 2020 Cilt: 38 Sayı: 1

Kaynak Göster

Vancouver Akçağlar S. Separation of co(ii) and se(vi) from a metal and glass industry wastes using graphene oxide-mangane oxide nanocomposite. SIGMA. 2020;38(1):29-46.

IMPORTANT NOTE: JOURNAL SUBMISSION LINK https://eds.yildiz.edu.tr/sigma/