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Synthesis, characterization and thermal properties of new oxoethyl acrylate containing polymer

Yıl 2020, Cilt: 38 Sayı: 1, 281 - 288, 27.03.2020

Öz

In this study, 2-(bis(cyanomethyl)amino)-2-oxoethyl acrylate (CMA2OEA) monomer, which does not exist in the literature, was synthesized and characterized. Elemental analysis technique, along with classical spectroscopic methods such as FTIR, 1H and 13C NMR, is used in the characterization of the monomer. Further, homopolymer of the CMA2OEA monomer [poly(CMA2OEA)] is synthesized by free radical chain polymerization reaction. Homopolymer synthesized is also characterized by spectroscopic techniques and thermal characterization is investigated by TGA/DTA/DTG thermal analysis methods.

Kaynakça

  • [1] Barım G., Coşkun M. (2012) (2,3-Difenil-1,3-oksazolidin-5-il)metil metakrilat’ın metil metakrilat ile kopolimerlerinin sentezi, karakterizasyonu ve termal özellikleri. Adıyaman Üniversitesi Fen Bilimleri Dergisi. 2 (2), 75-85.
  • [2] Zengin H.B., Basan S., Ekberov O.H. (2005) Maleik Anhidrit–Stiren Kopolimerinin Amid ve İmid Türevlerinin Sentezi ve Isısal Davranışları. Cumhuriyet Üniversitesi Fen Bilimleri Dergisi. 26 (2), 1-21.
  • [3] Soykan C., Yakuphanoglu, F., Sahin, M. (2013) Synthesis, Antimicrobial Activity and Semi-conducting Properties of Novel 2-(4-Chloro-1-Naphtyloxy)-2-Oxoethyl Methacrylate with 2-(Diethylamino)Ethyl Methacrylate Copolymers. Journal of Macromolecular Science, Part A: Pure and Applied Chemistry. 50, 953–965
  • [4] Hemalatha P., Veeraiah M. K., Prasanna Kumar S., Madegowda N. M., Manju M. (2014) Reactivity Ratios of N-Vinylpyrrolidone-Acrylic Acid Copolymer. American Journal of Polymer Science. 4 (1), 16-23.
  • [5] Çankaya N., Besci G. (2018) Synthesis, characterization, thermal properties and reactivity ratios of methacrylate copolymers including methoxy group, Journal of the Faculty of Engineering and Architecture of Gazi University. 33 (3), 1155-1170.
  • [6] Rajdeo K.S., Ponrathnam S., Pardeshi S., Chavan N.N., Bhongale S.S, Harikrishna R. (2015) Ambient Temperature Photocopolymerization of Tetrahydrofurfuryl Methacrylate and Isobornyl Methacrylate: Reactivity Ratios and Thermal Studies. Journal of Macromolecular Science, Part A: Pure and Applied Chemistry. 52, 982-991.
  • [7] Bayram O. (2019) Wettability, optical and chemical characteristics of plasma-polymerized D-limonene thin films. Omer Halis University Journal of Enginering Sciences. 8 (1), 567-575.
  • [8] Ilter Z., Soykan C., Solmaz A. (2015) Copolymers of 7-Methoxy-2-Acetyl Benzofuryl Methylmethacrylate with Styrene: Synthesis, Characterization, Reactivity Ratios and Determination of Kinetic Parameters with Thermogravimetric Analysis. Journal of Macromolecular Science, Part A: Pure and Applied Chemistry. 52, 175–185.
  • [9] Patel J. N., Dolia M. B., Patel K. H., Patel R. M. (2006) Homopolymer of 4-chloro-3-methyl Phenyl Methacrylate and its Copolymers with Butyl Methacrylate: Synthesis, Characterization, Reactivity Ratios and Antimicrobial Activity. Journal of Polymer Research. 13, 219-228.
  • [10] Açıkbaş Y., Çankaya N., Capan R., Erdogan M., Soykan C. (2016) Swelling behavior of the 2-(4-methoxyphenylamino)-2-oxoethyl methacrylate monomer LB thin film exposed to various organic vapors by quartz crystal microbalance technique. Journal of Macromolecular Science, Part A: Pure and Applied Chemistry. 53(1), 18–25.
  • [11] Sas E. B., Çankaya N., Kurt M. (2018) Synthesis of 2-(bis(cyanomethyl)amino)-2-oxoethyl methacrylate monomer molecule and its characterization by experimental and theoretical methods. Journal of Molecular Structure. 1161, 433-441.
  • [12] Yalçın S., Sas E. B., Çankaya N., Ercan F., Kurt M. (2019) The physical studies and interaction with anti-apoptotic proteins of 2-(bis(cyanomethyl)amino)-2-oxoethyl methacrylate molecule. Condensed Matter Physics. 22 (3), 33301, 1–8.
  • [13] Akman F. (2016) Experimental and theoretical investigation of molecular structure, vibrational analysis, chemical reactivity, electrostatic potential of benzyl methacrylate monomer and homopolymer. Can. J. Phys. 94, 1–12.
  • [14] Akman F., Demirelli K. (2016) Dielectric and spectroscopic properties of copolymers based on methacrylate carrying coumarin side group. Ferroelectrics. 505, 74–89,
  • [15] Kurt A., Koca M. (2016) Synthesis, characterization and thermal degradation kinetics of poly(3-acetylcoumarin-7-yl-methacrylate) and its organoclay nanocomposites. Journal of Eng. Research. 4 (4), 46-65.
  • [16] Kurt A., Çağlayan Z., Bektaş H. S. (2014) Preparation of Poly(Methyl Methacrylate)/Clay Nanocomposites and Investigation of Some Physical Properties. Sigma Journal of Engineering and Natural Sciences. 32, 71-80.
  • [17] Bal A., Cevher E., Pabuccuoğlu S K. (2017) Hydroxyl-Functionalized Hyperbranched Aliphatic Polyesters Based on 1,1,1-Tris(Hydroxymethyl)Propane (Tmp) as A Core Molecule: Synthesis and Characterization. Sigma Journal of Engineering and Natural Sciences. 35(2), 239-251.
  • [18] Usta N. (2019) Effects of Kaolin Additions on Thermal Behaviors of Rigid Polyurethane Foams. Journal of Thermal Engineering. 5(2), 70-76.
  • [19] Toroslu A. G. (2020) Effect of recycled Acrylonitrile Butadiene Styrene (ABS) plastic material on moldability. Journal of Polytechnic.
Yıl 2020, Cilt: 38 Sayı: 1, 281 - 288, 27.03.2020

Öz

Kaynakça

  • [1] Barım G., Coşkun M. (2012) (2,3-Difenil-1,3-oksazolidin-5-il)metil metakrilat’ın metil metakrilat ile kopolimerlerinin sentezi, karakterizasyonu ve termal özellikleri. Adıyaman Üniversitesi Fen Bilimleri Dergisi. 2 (2), 75-85.
  • [2] Zengin H.B., Basan S., Ekberov O.H. (2005) Maleik Anhidrit–Stiren Kopolimerinin Amid ve İmid Türevlerinin Sentezi ve Isısal Davranışları. Cumhuriyet Üniversitesi Fen Bilimleri Dergisi. 26 (2), 1-21.
  • [3] Soykan C., Yakuphanoglu, F., Sahin, M. (2013) Synthesis, Antimicrobial Activity and Semi-conducting Properties of Novel 2-(4-Chloro-1-Naphtyloxy)-2-Oxoethyl Methacrylate with 2-(Diethylamino)Ethyl Methacrylate Copolymers. Journal of Macromolecular Science, Part A: Pure and Applied Chemistry. 50, 953–965
  • [4] Hemalatha P., Veeraiah M. K., Prasanna Kumar S., Madegowda N. M., Manju M. (2014) Reactivity Ratios of N-Vinylpyrrolidone-Acrylic Acid Copolymer. American Journal of Polymer Science. 4 (1), 16-23.
  • [5] Çankaya N., Besci G. (2018) Synthesis, characterization, thermal properties and reactivity ratios of methacrylate copolymers including methoxy group, Journal of the Faculty of Engineering and Architecture of Gazi University. 33 (3), 1155-1170.
  • [6] Rajdeo K.S., Ponrathnam S., Pardeshi S., Chavan N.N., Bhongale S.S, Harikrishna R. (2015) Ambient Temperature Photocopolymerization of Tetrahydrofurfuryl Methacrylate and Isobornyl Methacrylate: Reactivity Ratios and Thermal Studies. Journal of Macromolecular Science, Part A: Pure and Applied Chemistry. 52, 982-991.
  • [7] Bayram O. (2019) Wettability, optical and chemical characteristics of plasma-polymerized D-limonene thin films. Omer Halis University Journal of Enginering Sciences. 8 (1), 567-575.
  • [8] Ilter Z., Soykan C., Solmaz A. (2015) Copolymers of 7-Methoxy-2-Acetyl Benzofuryl Methylmethacrylate with Styrene: Synthesis, Characterization, Reactivity Ratios and Determination of Kinetic Parameters with Thermogravimetric Analysis. Journal of Macromolecular Science, Part A: Pure and Applied Chemistry. 52, 175–185.
  • [9] Patel J. N., Dolia M. B., Patel K. H., Patel R. M. (2006) Homopolymer of 4-chloro-3-methyl Phenyl Methacrylate and its Copolymers with Butyl Methacrylate: Synthesis, Characterization, Reactivity Ratios and Antimicrobial Activity. Journal of Polymer Research. 13, 219-228.
  • [10] Açıkbaş Y., Çankaya N., Capan R., Erdogan M., Soykan C. (2016) Swelling behavior of the 2-(4-methoxyphenylamino)-2-oxoethyl methacrylate monomer LB thin film exposed to various organic vapors by quartz crystal microbalance technique. Journal of Macromolecular Science, Part A: Pure and Applied Chemistry. 53(1), 18–25.
  • [11] Sas E. B., Çankaya N., Kurt M. (2018) Synthesis of 2-(bis(cyanomethyl)amino)-2-oxoethyl methacrylate monomer molecule and its characterization by experimental and theoretical methods. Journal of Molecular Structure. 1161, 433-441.
  • [12] Yalçın S., Sas E. B., Çankaya N., Ercan F., Kurt M. (2019) The physical studies and interaction with anti-apoptotic proteins of 2-(bis(cyanomethyl)amino)-2-oxoethyl methacrylate molecule. Condensed Matter Physics. 22 (3), 33301, 1–8.
  • [13] Akman F. (2016) Experimental and theoretical investigation of molecular structure, vibrational analysis, chemical reactivity, electrostatic potential of benzyl methacrylate monomer and homopolymer. Can. J. Phys. 94, 1–12.
  • [14] Akman F., Demirelli K. (2016) Dielectric and spectroscopic properties of copolymers based on methacrylate carrying coumarin side group. Ferroelectrics. 505, 74–89,
  • [15] Kurt A., Koca M. (2016) Synthesis, characterization and thermal degradation kinetics of poly(3-acetylcoumarin-7-yl-methacrylate) and its organoclay nanocomposites. Journal of Eng. Research. 4 (4), 46-65.
  • [16] Kurt A., Çağlayan Z., Bektaş H. S. (2014) Preparation of Poly(Methyl Methacrylate)/Clay Nanocomposites and Investigation of Some Physical Properties. Sigma Journal of Engineering and Natural Sciences. 32, 71-80.
  • [17] Bal A., Cevher E., Pabuccuoğlu S K. (2017) Hydroxyl-Functionalized Hyperbranched Aliphatic Polyesters Based on 1,1,1-Tris(Hydroxymethyl)Propane (Tmp) as A Core Molecule: Synthesis and Characterization. Sigma Journal of Engineering and Natural Sciences. 35(2), 239-251.
  • [18] Usta N. (2019) Effects of Kaolin Additions on Thermal Behaviors of Rigid Polyurethane Foams. Journal of Thermal Engineering. 5(2), 70-76.
  • [19] Toroslu A. G. (2020) Effect of recycled Acrylonitrile Butadiene Styrene (ABS) plastic material on moldability. Journal of Polytechnic.
Toplam 19 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Research Articles
Yazarlar

Nevin Çankaya Bu kişi benim 0000-0002-6079-4987

Yayımlanma Tarihi 27 Mart 2020
Gönderilme Tarihi 6 Kasım 2019
Yayımlandığı Sayı Yıl 2020 Cilt: 38 Sayı: 1

Kaynak Göster

Vancouver Çankaya N. Synthesis, characterization and thermal properties of new oxoethyl acrylate containing polymer. SIGMA. 2020;38(1):281-8.

IMPORTANT NOTE: JOURNAL SUBMISSION LINK https://eds.yildiz.edu.tr/sigma/