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Pesticide residues in water and sediment of ergene river and tributaries in Turkey

Yıl 2020, Cilt: 38 Sayı: 1, 361 - 370, 27.03.2020

Öz

Ergene River is located in the north-west part of Turkey and it is the most significant river ecosystem of Thrace Region. It is also the most important tributaries of Meriç River that is the longest river in Balkans. Despite such great importance of Ergene River, it is being exposed to an intensive pollution by means of especially agricultural, industrial and domestic activities conducted around its watershed.
The aim of this study was to determine the pesticide residues in water-sediment of Meriç and Ergene Rivers and its 10 significant tributaries. Water-sediment samples were collected in spring season (rainy) of 2018 from 21 stations and pesticide concentrations (total of 174 different pesticide varieties) were investigated in water and sediment samples by using LC/MS.
According to detected data, the concentration of pesticide residues ranged from 0.0034ppb (propamocarb-hydrochloride in Safaalan Creek) to 12.0250ppb (carbendazim in Çorlu Stream) for water samples and from 0.0244ppb (acetamiprid in Çorlu Stream) to 1173.5320ppb (prochlorazin in Ahmetbey Creek) for sediment samples. It was also determined that pesticide accumulations detected in the Ergene River Basin, especially in Çorlu Stream and Ergene River, were found to be in quite high levels and the system has II–III. Class water quality in terms of total pesticide accumulations, in general.
There were clear dominances of carbendazim (in water) and prochloraz (in sediment) of the entire investigated basin. Çorlu Stream (in terms of water) and Ahmetbey Creek (in terms of sediment) were recorded as the most contaminated aquatic components of the system.

Kaynakça

  • [1] Ccanccapa, A., Masia, A., Navarro-Ortega, A., Pico, Y., Barcel, D. (2016). Pesticides in the Ebro River basin: Occurrence and risk assessment. Environmental Pollution, 211: 414-424.
  • [2] Chopra, A. K., Sharma, M. K., Chamoli, S. (2010). Bioaccumulation of organochlorine pesticides in aquatic system—an overview. Environmental Monitoring and Assessment, 173: 905–916.
  • [3] Erkmen, B., Kolankaya, D. (2006). Determination of organochlorine pesticide residues in water, sediment, and fish samples from the Meriç Delta, Turkey, International Journal of Environmental Analytical Chemistry, 86:1-2, 161-169, 2006.
  • [4] Masia, A., Ibanez, M., Blasco, C., Sancho, J. V., Pico, Y., Hernandez, F. (2013). Combined use of liquid chromatography triple quadrupole mass spectrometry and liquid chromatography quadrupole time-of-flight mass spectrometry in systematic screening of pesticides and other contaminants in water samples. Analytica Chimica Acta, 761: 117–127.
  • [5] Ogbeide, O., Tongo, I., Ezemonye, L. (2015). Risk assessment of agricultural pesticides in water, sediment, and fish from Owan River, Edo State, Nigeria. Environ Monit Assess, 187: 654.
  • [6] Ogunfowokan, A. O., Oyekunle, J. A. O., Torto, N., Akanni, M. S. (2012). A study on persistent organochlorine pesticide residues in fish tissues and water from an agricultural fish pond. Emirates Journal of Food and Agriculture, 24(2): 165–184.
  • [7] Sari, E., Cukrov, N., Frančišković-Bilinski, S., Kurt, M. A., Halli, M. (2016). Contamination assessment of ecotoxic metals in recent sediments from the Ergene River, Turkey. Environ Earth Sci, 75: 1051.
  • [8] Schenck, F. J., Hobbs, J. E. (2004). Evaluation of the quick, easy, cheap, effective, rugged, and safe (QuEChERS) approach to pesticide residue analysis. Bulletin of Environmental Contamination and Toxicology (New York: Springer), 73 (1): 24–30.
  • [9] Sungur, A., Soylak, M., Yilmaz, S., Özcan, H. (2014). Determination of heavy metals in sediments of the Ergene River by BCR sequential extraction method. Environmental Earth Sciences, Volume 72 (9): 3293–3305.
  • [10] Tokatli, C. (2014). Drinking water quality of a rice land in Turkey by a statistical and GIS perspective: İpsala District. Polish Journal of Environmental Studies, 23 (6): 2247-2258.
  • [11] Tokatli, C. (2015). Assessment of the water quality in the Meriç River: As an element of the ecosystem in the Thrace Region of Turkey. Polish Journal of Environmental Studies, 24 (5): 2205-2211.
  • [12] Tokatli, C. (2017). Bio – Ecological and statistical risk assessment of toxic metals in sediments of a worldwide important wetland: Gala Lake National Park (Turkey). Archives of Environmental Protection, 43 (1): 34-47.
  • [13] Tokatli, C. (2018). Essential and Toxic Element Bioaccumulations in Fishes of Gala and Sığırcı Lakes (Meriç River Delta, Turkey). Acta Alimentaria, 47 (4): 470-478.
  • [14] Tokatli, C., Baştatli, Y. (2016). Trace and toxic element levels in river sediments. Polish Journal of Environmental Studies, 25 (4): 1715-1720.
  • [15] Tokatli, C., Gürbüz, E. (2014). Socioeconomical and socioecological assessment on the perceptions of local people of the Enez and Yeni Karpuzlu Districts (Edirne) on the Gala Lake National Park. International Journal of Social and Economic Sciences, 4 (2): 01-05.
  • [16] Turkish Regulations (2015). Yüzeysel su kalitesi yönetimi yönetmeliği, 15 Nisan 2015 tarihli Resmi Gazete, Sayı: 29327, http://suyonetimiormansu.gov.tr.
  • [17] Wang, L., Jia, H. L., Liu, X. J., Sun, Y. Q., Yang, M., Hong, W. J., Qi, H., Li, Y. F. (2013). Historical contamination and ecological risk of organochlorine pesticides in sediment core in northeastern Chinese river. Ecotoxicol. Environ. Saf. 93, 112-120.
Yıl 2020, Cilt: 38 Sayı: 1, 361 - 370, 27.03.2020

Öz

Kaynakça

  • [1] Ccanccapa, A., Masia, A., Navarro-Ortega, A., Pico, Y., Barcel, D. (2016). Pesticides in the Ebro River basin: Occurrence and risk assessment. Environmental Pollution, 211: 414-424.
  • [2] Chopra, A. K., Sharma, M. K., Chamoli, S. (2010). Bioaccumulation of organochlorine pesticides in aquatic system—an overview. Environmental Monitoring and Assessment, 173: 905–916.
  • [3] Erkmen, B., Kolankaya, D. (2006). Determination of organochlorine pesticide residues in water, sediment, and fish samples from the Meriç Delta, Turkey, International Journal of Environmental Analytical Chemistry, 86:1-2, 161-169, 2006.
  • [4] Masia, A., Ibanez, M., Blasco, C., Sancho, J. V., Pico, Y., Hernandez, F. (2013). Combined use of liquid chromatography triple quadrupole mass spectrometry and liquid chromatography quadrupole time-of-flight mass spectrometry in systematic screening of pesticides and other contaminants in water samples. Analytica Chimica Acta, 761: 117–127.
  • [5] Ogbeide, O., Tongo, I., Ezemonye, L. (2015). Risk assessment of agricultural pesticides in water, sediment, and fish from Owan River, Edo State, Nigeria. Environ Monit Assess, 187: 654.
  • [6] Ogunfowokan, A. O., Oyekunle, J. A. O., Torto, N., Akanni, M. S. (2012). A study on persistent organochlorine pesticide residues in fish tissues and water from an agricultural fish pond. Emirates Journal of Food and Agriculture, 24(2): 165–184.
  • [7] Sari, E., Cukrov, N., Frančišković-Bilinski, S., Kurt, M. A., Halli, M. (2016). Contamination assessment of ecotoxic metals in recent sediments from the Ergene River, Turkey. Environ Earth Sci, 75: 1051.
  • [8] Schenck, F. J., Hobbs, J. E. (2004). Evaluation of the quick, easy, cheap, effective, rugged, and safe (QuEChERS) approach to pesticide residue analysis. Bulletin of Environmental Contamination and Toxicology (New York: Springer), 73 (1): 24–30.
  • [9] Sungur, A., Soylak, M., Yilmaz, S., Özcan, H. (2014). Determination of heavy metals in sediments of the Ergene River by BCR sequential extraction method. Environmental Earth Sciences, Volume 72 (9): 3293–3305.
  • [10] Tokatli, C. (2014). Drinking water quality of a rice land in Turkey by a statistical and GIS perspective: İpsala District. Polish Journal of Environmental Studies, 23 (6): 2247-2258.
  • [11] Tokatli, C. (2015). Assessment of the water quality in the Meriç River: As an element of the ecosystem in the Thrace Region of Turkey. Polish Journal of Environmental Studies, 24 (5): 2205-2211.
  • [12] Tokatli, C. (2017). Bio – Ecological and statistical risk assessment of toxic metals in sediments of a worldwide important wetland: Gala Lake National Park (Turkey). Archives of Environmental Protection, 43 (1): 34-47.
  • [13] Tokatli, C. (2018). Essential and Toxic Element Bioaccumulations in Fishes of Gala and Sığırcı Lakes (Meriç River Delta, Turkey). Acta Alimentaria, 47 (4): 470-478.
  • [14] Tokatli, C., Baştatli, Y. (2016). Trace and toxic element levels in river sediments. Polish Journal of Environmental Studies, 25 (4): 1715-1720.
  • [15] Tokatli, C., Gürbüz, E. (2014). Socioeconomical and socioecological assessment on the perceptions of local people of the Enez and Yeni Karpuzlu Districts (Edirne) on the Gala Lake National Park. International Journal of Social and Economic Sciences, 4 (2): 01-05.
  • [16] Turkish Regulations (2015). Yüzeysel su kalitesi yönetimi yönetmeliği, 15 Nisan 2015 tarihli Resmi Gazete, Sayı: 29327, http://suyonetimiormansu.gov.tr.
  • [17] Wang, L., Jia, H. L., Liu, X. J., Sun, Y. Q., Yang, M., Hong, W. J., Qi, H., Li, Y. F. (2013). Historical contamination and ecological risk of organochlorine pesticides in sediment core in northeastern Chinese river. Ecotoxicol. Environ. Saf. 93, 112-120.
Toplam 17 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Research Articles
Yazarlar

Cem Tokatlı Bu kişi benim 0000-0003-2080-7920

Yayımlanma Tarihi 27 Mart 2020
Gönderilme Tarihi 4 Mart 2019
Yayımlandığı Sayı Yıl 2020 Cilt: 38 Sayı: 1

Kaynak Göster

Vancouver Tokatlı C. Pesticide residues in water and sediment of ergene river and tributaries in Turkey. SIGMA. 2020;38(1):361-70.

IMPORTANT NOTE: JOURNAL SUBMISSION LINK https://eds.yildiz.edu.tr/sigma/