Araştırma Makalesi
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Yıl 2020, Cilt: 38 Sayı: 3, 1121 - 1132, 05.10.2021

Öz

Kaynakça

  • [1] Smith, R. A., (2000) Boric oxide, boric acid, and borates, Ullmann's Encyclopedia of Industrial Chemistry, Weinheim, Germany.
  • [2] Louër, D., Louër, M., Touboul, M., (1992) Crystal structure determination of lithium diborate hydrate, LiB2O3(OH).H2O, from X-ray powder diffraction data collected with a curved position-sensitive detector, Journal of applied crystallography 25(5), 617-623.
  • [3] Cecil, E. C., Scott, E. L., (1960) Production of lithium tetraborate from lithium hydroxide monohydrate and boric acid, U.S. Patent No. 2,952,512.
  • [4] Touboul, M., Bétourné, E., (1996) Dehydration process of lithium borates, Solid State Ionics 84(3-4), 189-197.
  • [5] Balasubramanian, R., Lakshmi Narasimhan, T. S., Viswanathan, R., Nalini, S., (2008) Investigation of the vaporization of boric acid by transpiration thermogravimetry and Knudsen effusion mass spectrometry, The Journal of Physical Chemistry B 112(44), 13873-13884.
  • [6] Lima, H. R. B. R., Nascimento, D. S., Sussuchi, E. M., d’Errico, F., de Souza, S. O., (2017) Synthesis of MgB4O7 and Li2B4O7 crystals by proteic sol–gel and Pechini methods, Journal of Sol-gel Science and Technology 81(3), 797-805.
  • [7] Loubser, M., Strydom, C., Potgieter, H., (2004) A thermogravimetric analysis study of volatilization of flux mixtures used in XRF sample preparation, X Ray Spectrometry: An International Journal 33(3), 212-215.
  • [8] Annalakshmi, O., Jose, M. T., Madhusoodanan, U., Venkatraman, B., Amarendra, G., (2013) Kinetic parameters of lithium tetraborate based TL materials, Journal of luminescence 141, 60-66.
  • [9] Khalilzadeh, N., Saion, E. B., Mirabolghasemi, H., Shaari, A. H. B., Hashim, M. B., Ahmad, M. B. H., Dehzangi, A., (2016) Single step thermal treatment synthesis and characterization of lithium tetraborate nanophosphor, Journal of Materials Research and Technology 5(1), 37-44.
  • [10] Pradhan, A. S., (1981) Thermoluminescence dosimetry and its applications, Radiation Protection Dosimetry 1(3), 153-167.
  • [11] Furetta, C., Pellegrini, R., (1981) Some dosimetric properties of Li2O7: Mn (Tld-800), Radiation Effects 58(1-2), 17-23.
  • [12] Ignatovych, M., Holovey, V., Vidoczy, T., Baranyai, P., Kelemen, A., (2007) Spectral study on manganese-and silver-doped lithium tetraborate phosphors, Radiation Physics and Chemistry 76(8-9), 1527-1530.
  • [13] Pekpak, E., Yılmaz, A., Özbayoğlu, G., (2011) The effect of synthesis and doping procedures on thermoluminescent response of lithium tetraborate, Journal of Alloys and Compounds 509(5), 2466-2472.
  • [14] Robertson, D. S., Young, I. M., (1982) The growth and growth mechanism of lithium tetraborate, Journal of Materials Science 17(6), 1729-1738.
  • [15] İzgi, M.S., Demir, H., Baytar, O., Adıgüzel, V., Demirci, S., (2017) Production of lithium tetraborate tetrahydrate by spray drier method and determination of production conditions, International Conference on Applications in Chemistry and Chemical Engineering, 27-32.
  • [16] Beyer, H., Meini, S., Tsiouvaras, N., Piana, M., Gasteiger, H. A., (2013) Thermal and electrochemical decomposition of lithium peroxide in non-catalyzed carbon cathodes for Li–air batteries, Physical Chemistry Chemical Physics 15(26), 11025-11037.
  • [17] Duran, R. R., Falsetti, P. E., Muhr, L., Privat, R., Barth, D., (2018) Phase Equilibrium Study of the Ternary System CO2+ H2O+ Ethanol At Elevated Pressure: Thermodynamic Model Selection. Application to Supercritical Extraction of Polar Compounds, The Journal of Supercritical Fluids 138, 17-28.
  • [18] Lide, D. R., (2003) CRC Handbook of Chemistry and Physics, Boca Raton, CRC Press
  • [19] Kayhan, M., Yilmaz, A., (2011) Effects of synthesis, doping methods and metal content on thermoluminescence glow curves of lithium tetraborate, Journal of alloys and compounds 509(30), 7819-7825.
  • [20] Jun, L., Shuping, X., Shiyang, G., (1995) FT-IR and Raman spectroscopic study of hydrated borates, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 51(4), 519-532.
  • [21] Khalilzadeh, N., Saion, E. B., Mirabolghasemi, H., Crouse, K. A., Shaari, A. H. B., Hashim, M. B., (2015) Preparation and characterization of ultrafine nanoparticles of Cu doped lithium tetraborate, Results in Physics 5, 324-330.
  • [22] Çelik, M. G., (2016) Synthesis and characterization of lithium tetraborate and lithium triborate phosphors doped with metals and their thermoluminescence properties, Master Thesis, Graduate School of Natural and Applied Sciences, Middle East Technical University, Ankara Turkey.
  • [23] Senyshyn, A., Boysen, H., Niewa, R., Banys, J., Kinka, M., Burak, Y., Fuess, H., (2012) High-temperature properties of lithium tetraborate Li2B4O7, Journal of Physics D: Applied Physics 45(17), 175305.

LITHIUM TETRABORATE PRODUCTION FROM THE REACTION OF BORIC ACID AND LITHIUM CARBONATE USING CARBON DIOXIDE

Yıl 2020, Cilt: 38 Sayı: 3, 1121 - 1132, 05.10.2021

Öz

In this study, the synthesis of lithium tetraborate in the presence of carbon dioxide (CO2) in an aqueous phase was investigated. A two-step process has been developed in the present study. The first step includes an aqueous phase reaction of lithium carbonate and boric acid in the presence of CO2 at different pressures. The second step involves the crystallization and thermal treating of the product obtained from step one at the temperatures between 300 and 400°C for 1 hour. Characterizations of the samples were performed by Fourier Transform Infrared Spectroscopy (FTIR), X-Ray Diffraction (XRD), Thermogravimetric Analysis (TGA) and Scanning Electron Microscopy (SEM). It was characterized that amorphous lithium tetraborate of Li2B4O7.3H2O was synthesized in the first step and then it was converted into Li2B4O7 in the second step. The use of CO2 as a modifying agent in lithium tetraborate synthesis has enhanced the dissolution rate of reactants that induced a fast-aqueous phase reaction.

Kaynakça

  • [1] Smith, R. A., (2000) Boric oxide, boric acid, and borates, Ullmann's Encyclopedia of Industrial Chemistry, Weinheim, Germany.
  • [2] Louër, D., Louër, M., Touboul, M., (1992) Crystal structure determination of lithium diborate hydrate, LiB2O3(OH).H2O, from X-ray powder diffraction data collected with a curved position-sensitive detector, Journal of applied crystallography 25(5), 617-623.
  • [3] Cecil, E. C., Scott, E. L., (1960) Production of lithium tetraborate from lithium hydroxide monohydrate and boric acid, U.S. Patent No. 2,952,512.
  • [4] Touboul, M., Bétourné, E., (1996) Dehydration process of lithium borates, Solid State Ionics 84(3-4), 189-197.
  • [5] Balasubramanian, R., Lakshmi Narasimhan, T. S., Viswanathan, R., Nalini, S., (2008) Investigation of the vaporization of boric acid by transpiration thermogravimetry and Knudsen effusion mass spectrometry, The Journal of Physical Chemistry B 112(44), 13873-13884.
  • [6] Lima, H. R. B. R., Nascimento, D. S., Sussuchi, E. M., d’Errico, F., de Souza, S. O., (2017) Synthesis of MgB4O7 and Li2B4O7 crystals by proteic sol–gel and Pechini methods, Journal of Sol-gel Science and Technology 81(3), 797-805.
  • [7] Loubser, M., Strydom, C., Potgieter, H., (2004) A thermogravimetric analysis study of volatilization of flux mixtures used in XRF sample preparation, X Ray Spectrometry: An International Journal 33(3), 212-215.
  • [8] Annalakshmi, O., Jose, M. T., Madhusoodanan, U., Venkatraman, B., Amarendra, G., (2013) Kinetic parameters of lithium tetraborate based TL materials, Journal of luminescence 141, 60-66.
  • [9] Khalilzadeh, N., Saion, E. B., Mirabolghasemi, H., Shaari, A. H. B., Hashim, M. B., Ahmad, M. B. H., Dehzangi, A., (2016) Single step thermal treatment synthesis and characterization of lithium tetraborate nanophosphor, Journal of Materials Research and Technology 5(1), 37-44.
  • [10] Pradhan, A. S., (1981) Thermoluminescence dosimetry and its applications, Radiation Protection Dosimetry 1(3), 153-167.
  • [11] Furetta, C., Pellegrini, R., (1981) Some dosimetric properties of Li2O7: Mn (Tld-800), Radiation Effects 58(1-2), 17-23.
  • [12] Ignatovych, M., Holovey, V., Vidoczy, T., Baranyai, P., Kelemen, A., (2007) Spectral study on manganese-and silver-doped lithium tetraborate phosphors, Radiation Physics and Chemistry 76(8-9), 1527-1530.
  • [13] Pekpak, E., Yılmaz, A., Özbayoğlu, G., (2011) The effect of synthesis and doping procedures on thermoluminescent response of lithium tetraborate, Journal of Alloys and Compounds 509(5), 2466-2472.
  • [14] Robertson, D. S., Young, I. M., (1982) The growth and growth mechanism of lithium tetraborate, Journal of Materials Science 17(6), 1729-1738.
  • [15] İzgi, M.S., Demir, H., Baytar, O., Adıgüzel, V., Demirci, S., (2017) Production of lithium tetraborate tetrahydrate by spray drier method and determination of production conditions, International Conference on Applications in Chemistry and Chemical Engineering, 27-32.
  • [16] Beyer, H., Meini, S., Tsiouvaras, N., Piana, M., Gasteiger, H. A., (2013) Thermal and electrochemical decomposition of lithium peroxide in non-catalyzed carbon cathodes for Li–air batteries, Physical Chemistry Chemical Physics 15(26), 11025-11037.
  • [17] Duran, R. R., Falsetti, P. E., Muhr, L., Privat, R., Barth, D., (2018) Phase Equilibrium Study of the Ternary System CO2+ H2O+ Ethanol At Elevated Pressure: Thermodynamic Model Selection. Application to Supercritical Extraction of Polar Compounds, The Journal of Supercritical Fluids 138, 17-28.
  • [18] Lide, D. R., (2003) CRC Handbook of Chemistry and Physics, Boca Raton, CRC Press
  • [19] Kayhan, M., Yilmaz, A., (2011) Effects of synthesis, doping methods and metal content on thermoluminescence glow curves of lithium tetraborate, Journal of alloys and compounds 509(30), 7819-7825.
  • [20] Jun, L., Shuping, X., Shiyang, G., (1995) FT-IR and Raman spectroscopic study of hydrated borates, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 51(4), 519-532.
  • [21] Khalilzadeh, N., Saion, E. B., Mirabolghasemi, H., Crouse, K. A., Shaari, A. H. B., Hashim, M. B., (2015) Preparation and characterization of ultrafine nanoparticles of Cu doped lithium tetraborate, Results in Physics 5, 324-330.
  • [22] Çelik, M. G., (2016) Synthesis and characterization of lithium tetraborate and lithium triborate phosphors doped with metals and their thermoluminescence properties, Master Thesis, Graduate School of Natural and Applied Sciences, Middle East Technical University, Ankara Turkey.
  • [23] Senyshyn, A., Boysen, H., Niewa, R., Banys, J., Kinka, M., Burak, Y., Fuess, H., (2012) High-temperature properties of lithium tetraborate Li2B4O7, Journal of Physics D: Applied Physics 45(17), 175305.
Toplam 23 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Research Articles
Yazarlar

Ali Yalçın Bu kişi benim 0000-0002-8722-4159

Mehmet Gönen Bu kişi benim 0000-0001-5780-4622

Yayımlanma Tarihi 5 Ekim 2021
Gönderilme Tarihi 26 Şubat 2020
Yayımlandığı Sayı Yıl 2020 Cilt: 38 Sayı: 3

Kaynak Göster

Vancouver Yalçın A, Gönen M. LITHIUM TETRABORATE PRODUCTION FROM THE REACTION OF BORIC ACID AND LITHIUM CARBONATE USING CARBON DIOXIDE. SIGMA. 2021;38(3):1121-32.

IMPORTANT NOTE: JOURNAL SUBMISSION LINK https://eds.yildiz.edu.tr/sigma/