SYNTHESIS AND THERMAL PROPERTIES OF NOVEL MALEONITRILES

Year 2016, Volume: 34 Issue: 2, 153 - 158, 01.06.2016

Ali Erdoğmuş

Abstract

In this study, the synthesis and thermal properties of two novel maleonitriles bearing 8-membered heterocyclic derivatives is described first time. New maleonitriles, benzo-(1,2-bis-methylthio)maleonitrile and [Benzo-15-crown-5]-(4,5-bis-methylthio)maleonitrile have been prepared by the reaction of different alkyl halides such as 1,2-bis(brommethyl)benzene and 4,5-bis-(brommethyl)[benzo-15-crown-5] with dithiomaleonitrile disodium salt. Both compounds are characterized by IR, Mass, NMR spectroscopy as well as elemental analysis.

Keywords

Macrocycle, maleonitrile, crown ethers, thermal properties.

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