Development of Innovative Fluoropolymer Based Coating Solution to Improve the Properties of Fasteners
Year 2025,
Volume: 1 Issue: 2, 1 - 13, 20.12.2025
Etkin Can
,
Metehan Atagür
Abstract
Steel fasteners can be offered to the customer uncoated or marketed with various surface treatments such as polymer coating, zinc plating, galvanization, and chrome plating. These coatings in the market are applied not only to increase corrosion resistance, but also to provide different functions to the products. Topcoat chemicals used in fasteners are one of the best examples of this situation. Topcoat is often used as special requirements must be met that are not inherent in the base coat, such as the inclusion of pigments (e.g. black), high chemical resistance, low coefficient of friction and UV resistance.
In this study, a polyvinylidene fluoride (PVDF) based fluoropolymer composite solution was developed which is operatable for the dip-spin method. Fastener samples were coated with dip-spin method. ISO 4042 torque-tension test was performed to determine the coefficient of friction for each sample. The wettability behavior of the coating was analyzed by contact angle measurement. ISO 9227 salt spray test was performed to determine the red and white rust formation period.
Ethical Statement
"The authors confirm that no ethical approval was required from institutional committees for the completion of this research.
Additionally, the authors also confirm that there are no conflicts of interest related to this study, and all authors have approved the final version of the manuscript submitted for publication.
Supporting Institution
This research was supported by Norm Coating Engineering Department, which provided technical resources, laboratory facilities, and invaluable professional support throughout the duration of the study. The authors gratefully acknowledge Norm Coating for their significant contributions and collaboration that made this work possible.
Thanks
The authors would like to express their sincere gratitude to the Engineering Department of Norm Coating, particularly to Hüseyin Azar, Nedim Uzgur, Ogün Sinan Firuzbay, Yaren Özalpaşan, Dilara Tilkioğlu, Emre Ceylan, Yasemin Kireççi, Erden Yerdelen, İsmail Sürücü, Sercan Pağaçacı, Yiğit Can Yaman, Efe Uslucan, Ceylin Kınık, Ceylan Özçelik, Büşra Nur Erdoğan, Merve Halimler Topçu, and Mehmet Ege Şap, for their invaluable technical support and collaboration throughout this study. Their dedicated efforts and insightful contributions were instrumental in the successful completion of this research.
References
-
Abdallah, Heba. (2017). “A Review on Catalytic Membranes Production and Applications.” Bulletin of Chemical Reaction Engineering & Catalysis 12(2):136–56. doi:10.9767/bcrec.12.2.462.136-156
-
Ali, A. A., Madkour, M., Sagheer, F. A., & Nazeer, A. A. (2021). Alumina lath-like structure-rGO–PVDF hybrid film formation with high-performance corrosion protection for 316L stainless-steel alloy. Journal of Materials Research and Technology, 15, 3694–3707. doi:10.1016/j.jmrt.2021.10.017
-
All-Over Coating. (2014). IST International Surface Technology, 7(1), 8–9. doi:10.1365/s35724-014-0216-9
-
Arcaute, Karina, & Ryan B. Wicker. (2008). “Patient-Specific Compliant Vessel Manufacturing Using DipSpin Coating of Rapid Prototyped Molds.” Journal of Manufacturing Science and Engineering 130(5):0510081–813. doi:10.1115/1.2898839
-
Cai, X., Lei, T., Sun, D., & Lin, L. (2017). A critical analysis of the α, β and γ phases in poly(vinylidene fluoride) using FTIR. RSC Advances, 7(25), 15382–15389. doi:10.1039/c7ra01267e
-
Castanet, E., Thamish, M. A., Hameed, N., Krajewski, A., Dumée, L. F., & Magniez, K. (2016). Zinc Oxide PVDF Nano-Composites-Tuning Interfaces toward Enhanced Mechanical Properties and UV Protection. Advanced Engineering Materials, 19(3), 1600611. doi:10.1002/adem.201600611
-
Elashmawi, I. S., & N. A. Hakeem. (2008). “Effect of PMMA Addition on Characterization and Morphology of PVDF.” Polymer Engineering & Science 48(5):895–901. doi:10.1002/pen.21032
-
Fischer, K. P. (2003). A Review of Offshore Experiences with Bolts and Fasteners. OnePetro. https://onepetro.org/NACECORR/proceedings-abstract/CORR03/AllCORR03/114778
-
Fischer, Karl P. (2009). “Experiences With Bolts and Fasteners Offshore: A Need for R & D.” Proceedings of the International Conference on Offshore Mechanics and Arctic Engineering - OMAE 3:197–204. doi:10.1115/OMAE2002-28218
-
Garcia, Roberto, & José Barboza. (1999). “Coating Trends For Fasteners.” SAE Technical Papers. doi:10.4271/1999-01-3072.
-
Grabon, W. A., M. Osetek, & T. G. Mathia. (2018). “Friction of Threaded Fasteners.” Tribology International 118:408–20. doi:10.1016/j.triboint.2017.10.014
-
ISO 16047:2005. (n.d.). ISO. https://www.iso.org/standard/27788.html
-
ISO 4042:2022. (n.d.). ISO. https://www.iso.org/standard/77913.html
-
ISO 9227:2022. (n.d.). ISO. https://www.iso.org/standard/81744.html
-
Kumar, Mayank. “Friction in Threaded Fasteners : Influence of Materials and Tooling.”
-
Kumar, Mayank, Erik Persson, Ian Sherrington, & Sergei Glavatskih. (2022). “Changes in Friction of Zinc Flake Coated Threaded Fasteners Due to Humidity, Temperature and Storage Duration.” Tribology International 170. doi:10.1016/j.triboint.2022.107498
-
Li, M., Katsouras, I., Piliego, C., Glasser, G., Lieberwirth, I., Blom, P. W. M., & De Leeuw, D. M. (2013). Controlling the microstructure of poly(vinylidene-fluoride) (PVDF) thin films for microelectronics. Journal of Materials Chemistry C, 1(46), 7695. doi:10.1039/c3tc31774a
-
Liu, Zhanjian, Congyuan Zhang, Xiguang Zhang, Chijia Wang, Fatang Liu, Ruixia Yuan, & Huaiyuan Wang. (2021). “Durable Superhydrophobic PVDF/FEVE/GO@TiO2 Composite Coating with Excellent AntiScaling and UV Resistance Properties.” Chemical Engineering Journal 411:128632. doi:10.1016/j.cej.2021.128632
-
Lunkwitz, K., W. Bürger, U. Lappan, H. J. Brink, & A. Ferse. (1995). “Surface Modification of Fluoropolymers.” Journal of Adhesion Science and Technology 9(3):297–310. doi:10.1163/156856195X00518
-
Muchtar, S., Wahab, M. Y., Fang, L.-F., Jeon, S., Rajabzadeh, S., Takagi, R., Mulyati, S., Arahman, N., Riza, M. & Matsuyama, H. 2019. “Polydopamine-Coated Poly(Vinylidene Fluoride) Membranes with High Ultraviolet Resistance and Antifouling Properties for a Photocatalytic Membrane Reactor.” Journal of Applied Polymer Science 136(14). doi:10.1002/app.47312
-
Muchtar, S., Wahab, M., Mulyati, S., Riza, M., & Arahman, N. (2019). Deposition of polydopamine on the surface of Polyvinylidene Fluoride (PVDF) membrane as A UV-Shielding layer. IOP Conference Series Materials Science and Engineering, 523(1), 012017. doi:10.1088/1757-899x/523/1/012017
-
Peng, Qing Yi, Pei Hong Cong, Xu Jun Liu, Tian Xi Liu, Shu Huang, & Tong Sheng Li. (2009). “The Preparation of PVDF/Clay Nanocomposites and the Investigation of Their Tribological Properties.” Wear 266(7–8):713–20. doi:10.1016/j.wear.2008.08.010.
-
Persson, Erik V., Mayank Kumar, Christian Friberg, & Nils Dressler. (2021). “Clamp Force Accuracy in Threaded Fastener Joints Using Different Torque Control Tightening Strategies.” SAE Technical Papers (2021). doi:10.4271/2021-01-5073
-
Radwan, A. Bahgat, Soliman I. El-Hout, M. A. M. Ibrahim, E. Hamed Ismail, & Aboubakr M. A. (2022). “Superior Corrosion and UV-Resistant Highly Porous Poly(Vinylidene Fluoride- CoHexafluoropropylene)/Alumina Superhydrophobic Coating.” ACS Applied Polymer Materials 4(2):1358–67. doi:10.1021/acsapm.1c01710
-
Radwan, A. B., Mohamed, A. M., Abdullah, A. M., & Al-Maadeed, M. A. (2015). Corrosion protection of electrospun PVDF–ZnO superhydrophobic coating. Surface and Coatings Technology, 289, 136– 143. doi:10.1016/j.surfcoat.2015.12.087
-
Landry, V., Blanchet, P., Zotig, L., & Martel, T. (2012). Performance of exterior semitransparent PVDF– acrylic coatings. Journal of Coatings Technology and Research, 10(1), 37–46. doi:10.1007/s11998-012-9421-y
-
Rusz, Stanislav, S Rusz, L. Cizek, & P. Filipec. (2006). “Evaluation of Fatigue of Micro-Alloyed 23MnB4 Steel.” Article in Journal of Achievements of Materials and Manufacturing Engineering.
-
Sakai, Tomotsugu. (1978). “Friction Coefficient of Fasteners.” Bull JSME 21(152):333–40. doi:10.1299/jsme1958.21.333
-
Salimi, A., & A. A. Yousefi. (2003). “Analysis Method FTIR Studies of B-Phase Crystal Formation in Stretched PVDF Films.” Polymer Testing 22:699–704. doi:10.1016/S0142-9418(03)00003-5
-
Saxena, Pooja, & Prashant Shukla. (2021). “A Comprehensive Review on Fundamental Properties and Applications of Poly (Vinylidene Fluoride) (PVDF).” Advanced Composites and Hybrid Materials 4(1):8–26. doi:10.1007/s42114-021-00217-0
-
Theophanides, Theophile. (2012). “Infrared Spectroscopy – Materials Science, Engineering, Edited by Theophile Theophanides.” 524.
-
Wei Wang, Anna Sanchez-Fischer & Todd Hawkins. (2023). "New Ultra-Durable Anti-Corrosion Coating System for Steel Infrastructure in Extreme Environments." Proceedings of the Conference 2023. Denver, Colorado, p:1-7. AMPP. doi:10.5006/C2023-19357
-
Wynn, P. (2003). Fastener Coating Developments. Transactions of the IMF, 81(1), B16–B18. doi:10.1080/00202967.2003.11871475.
-
Xiao, Y., Ji, W., Chang, K., Hsu, K., Yeh, J., & Liu, W. (2017). Sandwich-structured rGO/PVDF/PU multilayer coatings for anti-corrosion application. RSC Advances, 7(54), 33829–33836. doi:10.1039/c7ra05674e
-
Xue, Chao Hua, Xing Li, Shun Tian Jia, Xiao Jing Guo, & Min Li. (2016). “Fabrication of Robust Superhydrophobic Fabrics Based on Coating with PVDF/PDMS.” RSC Advances 6(88):84887–92. doi:10.1039/C6RA11508J
-
Zhou, Junbo, Jianhua Liu, Huajiang Ouyang, Zhenbing Cai, Jinfang Peng, & Minhao Zhu. (2018). “AntiLoosening Performance of Coatings on Fasteners Subjected to Dynamic Shear Load.” Friction 6(1):32– 46. doi:10.1007/s40544-017-0160-z