BibTex RIS Kaynak Göster

SULU DİETİLEN GLİKOL ORTAMINDA POLİPİROL SENTEZİ VE KARAKTERİZASYONU

Yıl 2014, Cilt: 2 Sayı: 2, 1 - 8, 01.06.2014

Öz

Bu çalışmada, polipirol(Ppy) sulu dietilen glikol çözeltisi ortamında pirolün kimyasal yükseltgenme polimerleşmesi yöntemi ile ilk kez sentezlenmiştir. Sentezlenen polimer Fourier transform infrared spektroskopisi(FTIR), UV-Görünür bölge absorpsiyon spektroskopisi(UV-vis), taramalı elektron mikroskobu(SEM) analizleri ile yapısal ve morfolojik olarak incelenmiş ve dört nokta yöntemi ile elektriksel iletkenlik ölçümleri yapılmıştır. Sentezlenen polipirolün homojen dağılımlı küresel yapıda olduğu ve elektriksel iletkenliğinin 3,64x10-3 Scm-1 olduğu belirlenmiştir.

Kaynakça

  • Bagheri, H., Ayazi, Z., Naderi M., 2013, “Conductive polymer-based microextraction methods: A review”, Analytical Chimica A, Cilt 767, ss. 1–13.
  • Bai, Y., Xu, Y., Wang, J., Gao, M., Wang, J., 2014, “Interface effect on the electropolymerizated polypyrrole films with hollow micro/nanohorn arrays”, Aplied Materials&Interfaces, Cilt 6, ss. 4693-4704.
  • Biswas, S., Dutta, B., Bhattacharya, S., 2013, “Dependence of the carrier mobility and trapped charge limited conduction on silver nanoparticles embedment in doped polypyrrole nanostructures”, Journal Applied Physics, Cilt 114, ss. 143701.
  • Carrillo, I., Sanchez, E., Fierro, J.L.G., Raso, M.A., Acción, F., Enciso, E., Redondo, M.I., 2013, “Conductivity and long term stability of polypyrrole poly(styrene-co-methacrylic acid) core– shell particles at different polypyrrole loadings”, Thin Solid Films, Cilt 539, ss. 154–160
  • Cheng, Q., He, Y., Pavlinek, V., Li, C., Saha, P., 2008, “Surfactant-assisted polypyrrole/titanate composite nanofibers: Morphology, structure and electrical properties”, Synthetic Metals, Cilt 158, ss. 953– 957.
  • Coelho, E.C.S., Nascimento, V.B., Ribeiro, A.S., Navarro, M., 2014, “Electrochemical and optical properties of new electrochromic andfluorescent nitrobenzoyl polypyrrole derivatives”, Electrochimica Acta, Cilt 123, ss. 441– 449.
  • Çetiner, S., Karakas, H., Ciobanu, R., Olariu, M., Kaya, U., Unsal, C., Kalaoglu, F., Sarac, A.S., 2010,
  • “Polymerization of pyrrole derivatives on polyacrylonitrile matrix, FTIR–ATR and dielectric spectroscopic characterization of composite thin films”, Synthetics Metals, Cilt.160, ss.1189– 1196.
  • Deivanayaki, S., Ponnuswamy, V., Mariappan, R., Jayamurugan P., 2013, “Synthesis and characterization of polypyrrole/TiO2 composites by chemical oxidative method”, International Journal for Light and Electron Optics, Cilt 124, ss. 1089-1091.
  • Ding, B., Lu, X., Yuan, C., Yang, S., Han Y., 2012, “One step electrochemical composite polymerization of polypyrrole integrated with functionalized graphene/carbon nanotubes nanostructured composite film for electrochemical capacitors” , Electrochimica Acta, Cilt 62, ss. 132-139.
  • Du, X., Hao, X., Wang, Z., Ma, X., Guan, G., Abuliti, A., Ma, G., Liu, S., 2013, “Highly stable polypyrrole film prepared by unipolar pulse electro-polymerization method as electrode for electrochemical supercapacitor”, Synthetics Metals, Cilt 175, ss. 138– 145.
  • Duan, F., Zhang, Q., Shi, D., Chen, M., 2013, “Enhanced visible light photocatalytic activity of Bi2WO6 via modification with polypyrrole”, Applied Surface Science, Cilt 268, ss. 129– 135.
  • Ferenets, M., Harlin, A., 2007, “Chemical in situ polymerization of polypyrrole on poly(methyl metacrylate) substrate”, Thin Solid Films, Vol. 515, pp. 5324-5328.
  • Ferrere, S., Zaban, A., Gregg, B.A., 1997, “Dye Sensitization of Nanocrystalline Tin Oxide by Perylene Derivatives”, Journal Physics Chemistry B, Cilt 101, ss. 4490-4493.
  • Jadhav, N., Vetter, C.A., Gelling, V.J., 2013, “The effect of polymer morphology on the performance of a corrosion inhibiting polypyrrole/aluminum flake composite pigment”, Electrochimica Acta, Cilt 102, ss. 28-43.
  • Joshi, A., Gangal, S.A., Gupta, S.K., 2011, “Ammonia sensing properties of polypyrrole thin films at room temperature” Sensors and Actuators B: Chemical, Cilt 156, ss. 938-942.
  • Kang, H.C., Geckeler, K.E., 2000, “Enhanced electrical conductivity of polypyrrole prepared by chemical oxidative polymerization: effect of the preparation technique and polymer additive”, Polymer, Cilt 41, ss. 6931-6934.
  • Hossein Karimian, Mohammad Reza Moghbeli, 2013, “Conducting Poly(styrene-codivinylbenzene)/Polypyrrole PolyHIPE Composite Foam Prepared by Chemical Oxidative Polymerization”, Journal of Applied Polymer Science, Cilt 127, ss. 804-811
  • Li, Q., Zhang, C., Li, J., 2011, “Photocatalytic and microwave absorbing properties of polypyrrole/Fedoped TiO2 composite by in situ polymerization method”, Journal of Alloys and Compounds, Cilt 509, ss.1953–1957.
  • Li, Q., Zhang, C., Li, J., 2013, “Photocatalytic and microwave absorbing properties of polypyrrole/Fedoped TiO2 composite by in situ polymerization method”, Journal of Alloys and Compounds, Cilt 509, ss. 1953-1957.
  • Lu, G., Li, C., Shi, G., 2006, “Polypyrrole micro- and nanowires synthesized by electrochemical polymerization of pyrrole in the aqueous solutions of pyrenesulfonic acid”, Polymer, Cilt 47, ss. 1778-1784.
  • Moreno, J.S., Panero, S., Scrosati, B., 2008, “Electrochemical polymerization of polypyrrole–heparin nanotubes: Kinetics and morphological properties”, Electrochimica Acta, Cilt 53, ss. 2154-2160.
  • Omastova, M., Trchova, M., Pionteck, J., Prokes, J., Stejskal, J., 2004, “Effect of polymerization conditions on the properties of polypyrrole prepared in the presence of sodium bis(2-ethylhexyl) sulfosuccinate”, Synthetics Metals, Cilt 143, ss. 153-161.
  • Omostova, M., Mucusik, M., 2011, “Polypyrrole coating of inorganic and organic materials by chemical oxidative polymerisation”, Chemical Papers, Cilt 66, ss. 392-414.
  • Pankove, J.I., Optical Processes in Semiconductors, Prentice-Hall, Englewood Cliffs, New Jersey, 1971.
  • Park, H., Kim, K., Lee, S., Park, D., Hong, Y., Joo, J., 2008, “Electrochemical polymerization of polypyrrole (PPy) and poly(3-hexylthiophene) (P3HT) using functionalized single-wall carbon nanotubes”, Colloids and Surfaces A: Physicochemical and Engineering Aspects, Cilt 313–314, ss. 72– 76.
  • Turhan, M.C., Weiser, M., Jha, H., Virtanen, S., 2011, “Optimization of electrochemical polymerization parameters of polypyrrole on Mg–Al alloy (AZ91D) electrodes and corrosion performance” , Electrochimica Acta, Cilt 56, ss.5347–5354.
  • Shaheen, S.E., Brabec, C.J., Sarıçiftçi, N.S., Padinger, F., Fromherz, T., Hummelen, J.C., 2001, “2.5% Efficient Organic Plastic Solar Cells”, Applied Physics Letters, Cilt 78, pp. 841-843.
  • Shinde, S.S., Gund, G.S., Dubal, D.P., Jambure, S.B., Lokhande, C.D., 2014, “Morphological modulation of polypyrrole thin films through oxidizing agents and their concurrent effect on supercapacitor performance”, Electrochimica Acta, Cilt 119, ss. 1–10.
  • Singh, N., Prasad, A., Sinha, R.K., 2006, “Synthesis, characterization and conducting properties of complex salts and heterobimetallic coordination polymers of the cyanodithioimidocarbonato ligand”, Inorganic Chemistry Communications, Cilt 9, ss. 1058-1062.
  • Sookhakian, M., Amin, Y.M., Baradaran, S., Tajabadi, M.T., Moradi Golsheikh, A., Basirun, W.J., 2014, “A layer-by-layer assembled graphene/zinc sulfide/polypyrrole thin-film electrode via electrophoretic deposition for solar cells”, Thin Solid Films, Cilt 552, ss. 204–211.
  • Wang, X., Yang, C., Liu, P., 2011, “Well-defined polypyrrole nanoflakes via chemical oxidative polymerization in the presence of sodium alkane sulfonate”, Materials Letters, Cilt 65, ss. 1448- 1450.
  • Wang, B., Li, C., Pang, J., Qing, X., Zhai, J., Li, Q., 2012, “Novel polypyrrole-sensitized hollow TiO2/fly ash cenospheres: Synthesis, characterization, and photocatalytic ability under visible light”, Applied Surface Science, Cilt 258, ss. 9989-9996.
  • Yalçınkaya, S., Tuken, T., Yazıcı, B., Erbil, M., 2010, “Electrochemical synthesis and corrosion behaviour of poly(pyrrole-co-o-anisidine-co-o-toluidine)”, Current Applied Physics, Cilt10, ss. 783-789.
  • Zhang, C., Li, Q., Li, J., 2010, “Synthesis and characterization of polypyrrole/TiO2 composite by in situ polymerization method”, Synth. Met. Vol. 160, pp.1699–1703.
  • Zhang, S., Chen, Q., Wang, Y., Guo, L., 2012, “Synthesis and photoactivity of CdS photocatalysts modified by polypyrrole”, International Journal of Hydrogen Energy, Cilt 37, ss. 13030-13036.
  • Zhang, X., Zeng, X., Yang, M., Qi, Y., 2014, “Investigation of a Branchlike MoO3/Polypyrrole Hybrid with Enhanced Electrochemical Performance Used as an Electrode in Supercapacitors”, Applied Materials&Interfaces, Cilt 6, ss.1125−1130.

Synthesis of Polypyrrole in Aqueous Diethylene Glycol Solution

Yıl 2014, Cilt: 2 Sayı: 2, 1 - 8, 01.06.2014

Öz

In this study, the polypyrrole(Ppy) was synthesized firstly in aqueous diethylene glycol solution via chemical oxidative polymerization. Synthesized polymer was characterized by fourier transform infrared spectroscopy(FTIR), UV-Vis absorption spectroscopy(UV-vis) and scanning electron microscopy(SEM) and electrical conductivity of the samples was measured by four point AC conductivity method. It was found that the synthesized Ppy has homogeneous spherical shaped and its electrical conductivity was 3.64x10-3 Scm-1 .

Kaynakça

  • Bagheri, H., Ayazi, Z., Naderi M., 2013, “Conductive polymer-based microextraction methods: A review”, Analytical Chimica A, Cilt 767, ss. 1–13.
  • Bai, Y., Xu, Y., Wang, J., Gao, M., Wang, J., 2014, “Interface effect on the electropolymerizated polypyrrole films with hollow micro/nanohorn arrays”, Aplied Materials&Interfaces, Cilt 6, ss. 4693-4704.
  • Biswas, S., Dutta, B., Bhattacharya, S., 2013, “Dependence of the carrier mobility and trapped charge limited conduction on silver nanoparticles embedment in doped polypyrrole nanostructures”, Journal Applied Physics, Cilt 114, ss. 143701.
  • Carrillo, I., Sanchez, E., Fierro, J.L.G., Raso, M.A., Acción, F., Enciso, E., Redondo, M.I., 2013, “Conductivity and long term stability of polypyrrole poly(styrene-co-methacrylic acid) core– shell particles at different polypyrrole loadings”, Thin Solid Films, Cilt 539, ss. 154–160
  • Cheng, Q., He, Y., Pavlinek, V., Li, C., Saha, P., 2008, “Surfactant-assisted polypyrrole/titanate composite nanofibers: Morphology, structure and electrical properties”, Synthetic Metals, Cilt 158, ss. 953– 957.
  • Coelho, E.C.S., Nascimento, V.B., Ribeiro, A.S., Navarro, M., 2014, “Electrochemical and optical properties of new electrochromic andfluorescent nitrobenzoyl polypyrrole derivatives”, Electrochimica Acta, Cilt 123, ss. 441– 449.
  • Çetiner, S., Karakas, H., Ciobanu, R., Olariu, M., Kaya, U., Unsal, C., Kalaoglu, F., Sarac, A.S., 2010,
  • “Polymerization of pyrrole derivatives on polyacrylonitrile matrix, FTIR–ATR and dielectric spectroscopic characterization of composite thin films”, Synthetics Metals, Cilt.160, ss.1189– 1196.
  • Deivanayaki, S., Ponnuswamy, V., Mariappan, R., Jayamurugan P., 2013, “Synthesis and characterization of polypyrrole/TiO2 composites by chemical oxidative method”, International Journal for Light and Electron Optics, Cilt 124, ss. 1089-1091.
  • Ding, B., Lu, X., Yuan, C., Yang, S., Han Y., 2012, “One step electrochemical composite polymerization of polypyrrole integrated with functionalized graphene/carbon nanotubes nanostructured composite film for electrochemical capacitors” , Electrochimica Acta, Cilt 62, ss. 132-139.
  • Du, X., Hao, X., Wang, Z., Ma, X., Guan, G., Abuliti, A., Ma, G., Liu, S., 2013, “Highly stable polypyrrole film prepared by unipolar pulse electro-polymerization method as electrode for electrochemical supercapacitor”, Synthetics Metals, Cilt 175, ss. 138– 145.
  • Duan, F., Zhang, Q., Shi, D., Chen, M., 2013, “Enhanced visible light photocatalytic activity of Bi2WO6 via modification with polypyrrole”, Applied Surface Science, Cilt 268, ss. 129– 135.
  • Ferenets, M., Harlin, A., 2007, “Chemical in situ polymerization of polypyrrole on poly(methyl metacrylate) substrate”, Thin Solid Films, Vol. 515, pp. 5324-5328.
  • Ferrere, S., Zaban, A., Gregg, B.A., 1997, “Dye Sensitization of Nanocrystalline Tin Oxide by Perylene Derivatives”, Journal Physics Chemistry B, Cilt 101, ss. 4490-4493.
  • Jadhav, N., Vetter, C.A., Gelling, V.J., 2013, “The effect of polymer morphology on the performance of a corrosion inhibiting polypyrrole/aluminum flake composite pigment”, Electrochimica Acta, Cilt 102, ss. 28-43.
  • Joshi, A., Gangal, S.A., Gupta, S.K., 2011, “Ammonia sensing properties of polypyrrole thin films at room temperature” Sensors and Actuators B: Chemical, Cilt 156, ss. 938-942.
  • Kang, H.C., Geckeler, K.E., 2000, “Enhanced electrical conductivity of polypyrrole prepared by chemical oxidative polymerization: effect of the preparation technique and polymer additive”, Polymer, Cilt 41, ss. 6931-6934.
  • Hossein Karimian, Mohammad Reza Moghbeli, 2013, “Conducting Poly(styrene-codivinylbenzene)/Polypyrrole PolyHIPE Composite Foam Prepared by Chemical Oxidative Polymerization”, Journal of Applied Polymer Science, Cilt 127, ss. 804-811
  • Li, Q., Zhang, C., Li, J., 2011, “Photocatalytic and microwave absorbing properties of polypyrrole/Fedoped TiO2 composite by in situ polymerization method”, Journal of Alloys and Compounds, Cilt 509, ss.1953–1957.
  • Li, Q., Zhang, C., Li, J., 2013, “Photocatalytic and microwave absorbing properties of polypyrrole/Fedoped TiO2 composite by in situ polymerization method”, Journal of Alloys and Compounds, Cilt 509, ss. 1953-1957.
  • Lu, G., Li, C., Shi, G., 2006, “Polypyrrole micro- and nanowires synthesized by electrochemical polymerization of pyrrole in the aqueous solutions of pyrenesulfonic acid”, Polymer, Cilt 47, ss. 1778-1784.
  • Moreno, J.S., Panero, S., Scrosati, B., 2008, “Electrochemical polymerization of polypyrrole–heparin nanotubes: Kinetics and morphological properties”, Electrochimica Acta, Cilt 53, ss. 2154-2160.
  • Omastova, M., Trchova, M., Pionteck, J., Prokes, J., Stejskal, J., 2004, “Effect of polymerization conditions on the properties of polypyrrole prepared in the presence of sodium bis(2-ethylhexyl) sulfosuccinate”, Synthetics Metals, Cilt 143, ss. 153-161.
  • Omostova, M., Mucusik, M., 2011, “Polypyrrole coating of inorganic and organic materials by chemical oxidative polymerisation”, Chemical Papers, Cilt 66, ss. 392-414.
  • Pankove, J.I., Optical Processes in Semiconductors, Prentice-Hall, Englewood Cliffs, New Jersey, 1971.
  • Park, H., Kim, K., Lee, S., Park, D., Hong, Y., Joo, J., 2008, “Electrochemical polymerization of polypyrrole (PPy) and poly(3-hexylthiophene) (P3HT) using functionalized single-wall carbon nanotubes”, Colloids and Surfaces A: Physicochemical and Engineering Aspects, Cilt 313–314, ss. 72– 76.
  • Turhan, M.C., Weiser, M., Jha, H., Virtanen, S., 2011, “Optimization of electrochemical polymerization parameters of polypyrrole on Mg–Al alloy (AZ91D) electrodes and corrosion performance” , Electrochimica Acta, Cilt 56, ss.5347–5354.
  • Shaheen, S.E., Brabec, C.J., Sarıçiftçi, N.S., Padinger, F., Fromherz, T., Hummelen, J.C., 2001, “2.5% Efficient Organic Plastic Solar Cells”, Applied Physics Letters, Cilt 78, pp. 841-843.
  • Shinde, S.S., Gund, G.S., Dubal, D.P., Jambure, S.B., Lokhande, C.D., 2014, “Morphological modulation of polypyrrole thin films through oxidizing agents and their concurrent effect on supercapacitor performance”, Electrochimica Acta, Cilt 119, ss. 1–10.
  • Singh, N., Prasad, A., Sinha, R.K., 2006, “Synthesis, characterization and conducting properties of complex salts and heterobimetallic coordination polymers of the cyanodithioimidocarbonato ligand”, Inorganic Chemistry Communications, Cilt 9, ss. 1058-1062.
  • Sookhakian, M., Amin, Y.M., Baradaran, S., Tajabadi, M.T., Moradi Golsheikh, A., Basirun, W.J., 2014, “A layer-by-layer assembled graphene/zinc sulfide/polypyrrole thin-film electrode via electrophoretic deposition for solar cells”, Thin Solid Films, Cilt 552, ss. 204–211.
  • Wang, X., Yang, C., Liu, P., 2011, “Well-defined polypyrrole nanoflakes via chemical oxidative polymerization in the presence of sodium alkane sulfonate”, Materials Letters, Cilt 65, ss. 1448- 1450.
  • Wang, B., Li, C., Pang, J., Qing, X., Zhai, J., Li, Q., 2012, “Novel polypyrrole-sensitized hollow TiO2/fly ash cenospheres: Synthesis, characterization, and photocatalytic ability under visible light”, Applied Surface Science, Cilt 258, ss. 9989-9996.
  • Yalçınkaya, S., Tuken, T., Yazıcı, B., Erbil, M., 2010, “Electrochemical synthesis and corrosion behaviour of poly(pyrrole-co-o-anisidine-co-o-toluidine)”, Current Applied Physics, Cilt10, ss. 783-789.
  • Zhang, C., Li, Q., Li, J., 2010, “Synthesis and characterization of polypyrrole/TiO2 composite by in situ polymerization method”, Synth. Met. Vol. 160, pp.1699–1703.
  • Zhang, S., Chen, Q., Wang, Y., Guo, L., 2012, “Synthesis and photoactivity of CdS photocatalysts modified by polypyrrole”, International Journal of Hydrogen Energy, Cilt 37, ss. 13030-13036.
  • Zhang, X., Zeng, X., Yang, M., Qi, Y., 2014, “Investigation of a Branchlike MoO3/Polypyrrole Hybrid with Enhanced Electrochemical Performance Used as an Electrode in Supercapacitors”, Applied Materials&Interfaces, Cilt 6, ss.1125−1130.
Toplam 37 adet kaynakça vardır.

Ayrıntılar

Diğer ID JA47BT48BA
Bölüm Makaleler
Yazarlar

Bircan Haspulat Bu kişi benim

Özge Çınar Bu kişi benim

Handan Kamış Bu kişi benim

Yayımlanma Tarihi 1 Haziran 2014
Yayımlandığı Sayı Yıl 2014 Cilt: 2 Sayı: 2

Kaynak Göster

APA Haspulat, B., Çınar, Ö., & Kamış, H. (2014). SULU DİETİLEN GLİKOL ORTAMINDA POLİPİROL SENTEZİ VE KARAKTERİZASYONU. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi, 2(2), 1-8.
AMA Haspulat B, Çınar Ö, Kamış H. SULU DİETİLEN GLİKOL ORTAMINDA POLİPİROL SENTEZİ VE KARAKTERİZASYONU. sujest. Haziran 2014;2(2):1-8.
Chicago Haspulat, Bircan, Özge Çınar, ve Handan Kamış. “SULU DİETİLEN GLİKOL ORTAMINDA POLİPİROL SENTEZİ VE KARAKTERİZASYONU”. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi 2, sy. 2 (Haziran 2014): 1-8.
EndNote Haspulat B, Çınar Ö, Kamış H (01 Haziran 2014) SULU DİETİLEN GLİKOL ORTAMINDA POLİPİROL SENTEZİ VE KARAKTERİZASYONU. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi 2 2 1–8.
IEEE B. Haspulat, Ö. Çınar, ve H. Kamış, “SULU DİETİLEN GLİKOL ORTAMINDA POLİPİROL SENTEZİ VE KARAKTERİZASYONU”, sujest, c. 2, sy. 2, ss. 1–8, 2014.
ISNAD Haspulat, Bircan vd. “SULU DİETİLEN GLİKOL ORTAMINDA POLİPİROL SENTEZİ VE KARAKTERİZASYONU”. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi 2/2 (Haziran 2014), 1-8.
JAMA Haspulat B, Çınar Ö, Kamış H. SULU DİETİLEN GLİKOL ORTAMINDA POLİPİROL SENTEZİ VE KARAKTERİZASYONU. sujest. 2014;2:1–8.
MLA Haspulat, Bircan vd. “SULU DİETİLEN GLİKOL ORTAMINDA POLİPİROL SENTEZİ VE KARAKTERİZASYONU”. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi, c. 2, sy. 2, 2014, ss. 1-8.
Vancouver Haspulat B, Çınar Ö, Kamış H. SULU DİETİLEN GLİKOL ORTAMINDA POLİPİROL SENTEZİ VE KARAKTERİZASYONU. sujest. 2014;2(2):1-8.

MAKALELERINIZI 

http://sujest.selcuk.edu.tr

uzerinden gonderiniz