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KİTOSAN/ter(GMA-MA-NTBA) POLİMER İLE MİKROKAPSÜL HAZIRLAMA VE KARAKTERİZASYONU

Yıl 2019, Cilt: 7 Sayı: 2, 524 - 535, 01.06.2019
https://doi.org/10.15317/Scitech.2019.216

Öz

Bu
çalışmada, glisidil metakrilat (GMA), maleik anhidrit (MA), N-ter-butilakrilamid (NTBA) monomerlerinden
ter(GMA-MA-NTBA) polimer ilk kez sentezlenmiştir. Polimerin kimyasal yapısı FT‐IR
spektroskopisi, Nükleer Manyetik Rezonans (1H-NMR) spektroskopisi,
asit sayısı ve viskozite ölçümleri ile yüzey morfolojisi taramalı elektron
mikroskobu (SEM) ile çalışılmıştır. Sentezlenen ter(GMA-MA-NTBA) polimerin
farklı oranlarını içeren kitosan tabanlı mikrokapsüller haz
ırlanmış ve yapısal kararlılığı optimize edilmiştir. Polimer-kitosan mikrokapsüller gluteraldehit çapraz bağlayıcı ile daha dayanıklı hale getirilmiştir. Mikrokapsüllerin kimyasal
yapıları FT‐IR spektroskopisi ile yüzey morfolojileri SEM ile belirlenmiştir. Kitosan/ter(GMA-MA-NTBA)
polimer kompozit mikrokapsüller farklı adsorpsiyon, ilaç taşıma ya da kontrollü
salınım uygulamalarında denenebilir. 

Kaynakça

  • Abou El-Reash Y. G., Otto M., Kenawy I. M., Ouf A. M., 2011, “Adsorption of Cr(VI) and As(V) Ions by Modified Magnetic Chitosan Chelating Resin”, International Journal of Biological Macromolecules, Cilt 49, ss. 513-522.
  • Agnihotri S. A., Aminabhavi T. M., 2006, “Novel Interpenetrating Network Chitosan-Poly(ethylene oxide-g-acrylamide) Hydrogel Microspheres for the Controlled Release of Capecitabine”, International Journal of Pharmaceutics, Cilt 324, ss. 103-115.
  • Akkaya R., Ulusoy U., 2008, “Adsorptive Features of Chitosan Entrapped in Polyacrylamide Hydrogel for Pb2+, UO22+, and Th4+”, Journal of Hazardous Materials, Cilt 151, ss. 380-388.
  • Anirudhan T. S., Rijith S., 2009, “Glutaraldehyde Cross-linked Epoxyaminated Chitosan as an Adsorbent for the Removal and Recovery of Copper(II) from Aqueous Media”, Colloids and Surfaces A: Physicochemical and Engineering Aspects, Cilt 351, ss. 52-59.
  • Atia A. A., 2005, “Studies on the Interaction of Mercury(II) and Uranyl(II) with Modified Chitosan Resins”, Hydrometallurgy, Cilt 80, ss. 13-22.
  • Babu V. R., Hosamani K. M., Aminabhavi T. M., 2008, “Preparation and in vitro Release of Chlorothiazide Novel pH-sensitive Chitosan-N,N’-dimethylacrylamide Semi-Interpenetrating Network Microspheres”, Carbohydrate Polymers, Cilt 71, ss. 208-217.
  • Bayramoglu G., Arica M. Y., Bektas S., 2007, “Removal of Cd(II), Hg(II), and Pb(II) Ions from Aqueous Solution Using p(HEMA/Chitosan) Membranes”, Journal of Applied Polymer Science, Cilt 106, ss. 169-177.
  • Chen J., Sun J., Yang L., Zhang Q., Zhu H., Wu H., Hoffman A. S., Kaetsu I., 2007 “Preparation and Characterization of a Novel IPN Hydrogel Membrane of Poly(N-isopropylacrylamide)/carboxymethyl Chitosan (PNIPAAM/CMCS)”, Radiation Physics and Chemistry, Cilt 76, ss. 1425-1429.
  • Chen C. Y., Chang T. H., Kuo J. T., Chen Y. F., Chung Y. C., 2008, “Characteristics of Molybdate-impregnated Chitosan Beads (MICB) in Terms of Arsenic Removal from Water and the Application of a MICB-packed Column to Remove Arsenic from Wastewater”, Bioresource Technology, Cilt 99, ss. 7487-7494.
  • Dinçer S., Köseli V., Kesim H., Rzaev Z. M. O. Pişkin E., 2002, “Radical Copolymerization of N-Isopropylacrylamide with Anhydrides of Maleic and Citraconic Acids”, European Polymer Journal, Cilt 38, ss. 2143–2152.
  • Don T. M., Chen H. R., 2005, “Synthesis and Characterization of AB-crosslinked Graft Copolymers Based on Maleilated Chitosan and N-isopropylacrylamide”, Carbohydrate Polymers, Cilt 61, ss. 334-347.
  • Dotto G. L., Moura J. M., Cadaval T. R. S., Pinto L. A. A., 2013, “Application of Chitosan Films for the Removal of Food Dyes from Aqueous Solutions by Adsorption”, Chemical Engineering Journal, Cilt 214, ss. 8-16.
  • Dragan E. S., Lazar M. M., Dinu M. V., Doroftei F., 2012a, “Macroporous Composite IPN Hydrogels Based on Poly(acrylamide) and Chitosan with Tuned Swelling and Sorption of Cationic Dyes”, Chemical Engineering Journal, Cilt 204-206, ss. 198-209.
  • Dragan E. S., Perju M. M., Dinu M. V., 2012b, “Preparation and Characterization of IPN Composite Hydrogels Based on Polyacrylamide and Chitosan and their Interaction with Ionic Dyes”, Carbohydrate Polymers, Cilt 88, ss. 270-281.
  • Ekberov, O. H., Basan, S., 1995, Polimer Kimyası Laboratuvarı, 1. Baskı, Cumhuriyet Üniversitesi Yayınları, No: 58, Sivas.
  • Guibal E., Jansson-Charrier M., Saecudo I., Le Cloirec P., 1995, “Enhancement of Metal Ion Sorption Performances of Chitosan: Effect of the Structure on the Diffusion Properties”, Langmuir, Cilt 11, ss. 591-598.
  • Hassan, M. A., Omer, A. M., Abbas, E., Baset, W. M. A., Tamer, T. M., 2018, “Preparation, Physicochemical Characterization and Antimicrobial Activities of Novel Two Phenolic Chitosan Schiff Base Derivatives”, Scientific Reports, Cilt 8, ss. 11416.
  • Kaplan Can H., Rzaev Z. M. O., 2012, “H-Bonding Effect in Radical Terpolymerization of Maleic Anhydride, Acrylic acid(Methyl acrylate) and Vinyl Acetate”, Hacettepe Journal of Biology & Chemistry, Cilt 40, Sayı 4, ss. 427-443.
  • Karasakal A., 2015, Aromatik Yapı İçeren Polimerlerin Sentezi ve Karakterizasyonu, Yüksek Lisans Tezi, Selçuk Üniversitesi, Fen Bilimleri Enstitüsü, Konya.
  • Kestwal D. B, Kestwal R. M., Chiang B. H., Karve M. S., 2011, “Development of Dip-strip Sucrose Sensors: Application of Plant Invertase Immobilized in Chitosan–Guar Gum, Gelatin and Poly-acrylamide Films”, Sensors and Actuators B, Cilt 160, ss. 1026-1033.
  • Klumperman B., 2010, “Mechanistic Considerations on Styrene – Maleic Anhydride Copolymerization Reactions”, Polymer Chemistry, Cilt 1, ss. 558-562.
  • Kumar M. N. V. R., Muzzarelli R. A. A., Muzzarelli C., Sashiwa H., Domb A.J., 2004, “Chitosan Chemistry and Pharmaceutical Perspectives”, Chemical Reviews, Cilt 104, ss. 6017-6084.
  • Kumar M., Bijay P. T., Vinod K. S., 2009, “Crosslinked Chitosan/Polyvinyl Alcohol Blend Beads for Removal and Recovery of Cd(II) from Wastewater”, Journal of Hazardous Materials, Cilt 172, ss. 1041-1048.
  • Liu T., Wang Z. L., Zhao L., Yang X., 2012, “Enhanced Chitosan/Fe0-nanoparticles Beads for Hexavalent Chromium Removal from Wastewater”, Chemical Engineering Journal, Cilt 189–190, ss. 196-202.
  • Ma L., Lu W., Wen J., 2009, “Encapsulation of Lactate Dehydrogenase in Carbon Nanotube Doped Alginate–Chitosan Capsules”, Journal of Molecular Catalysis B: Enzymatic, Cilt 56, ss. 102-107.
  • Nie F. Q., Xu, Z. K., Wan, L. S., Ye, P., W, J., 2004, “Acrylonitrile-based Copolymers Containing Reactive Groups: Synthesis and Preparation of Ultrafiltration Membranes”, Journal of Membrane Science, Cilt 230, ss. 1-11.
  • Pal A., Pan S., Saha S., 2013, “Synergistically Improved Adsorption of Anionic Surfactant and Crystal Violet on Chitosan Hydrogel Beads”, Chemical Engineering Journal, Cilt 217, ss. 426-434.
  • Pillai C. K. S., Paul W., Sharma C. P., 2009, “Chitin and Chitosan Polymers: Chemistry, Solubility and Fiber Formation”, Progress in Polymer Science, Cilt 34, ss. 641-678.
  • Piron E., Accominoti M., Domard A., 1997, “Interaction between Chitosan and Uranyl Ions. Role of Physical and Physicochemical Parameters on the Kinetics of Sorption”, Langmuir, Cilt 13, ss. 1653-1658.
  • Rzaev Z. M. O., 1999, “Complex-radical Terpolymerization of Glycidyl(Methyl) Methacrylates, Styrene, and Maleic Anhydride”, Journal of Polymer Science: Part A: Polymer Chemistry, Cilt 37, ss. 1095–1102.
  • Rokhade A. P., Patil S. A., Aminabhavi T. M., 2007, “Synthesis and Characterization of Semi-Interpenetrating Polymer Network Microspheres of Acrylamide Grafted Dextran and Chitosan for Controlled Release of Acyclovir”, Carbohydrate Polymers, Cilt 67, ss. 605-613.
  • Sargın I., Arslan G., 2015, “Chitosan/Sporopollenin Microcapsules: Preparation, Characterisation and Application in Heavy Metal Removal”, International Journal of Biological Macromolecules, Cilt 75, ss. 230-238.
  • Sargın I., Kaya M., Arslan G., Baran T., Ceter T., 2015, “Preparation and Characterisation of Biodegradable Pollen–Chitosan Microcapsules and its Application in Heavy Metal Removal”, Bioresource Technology, Cilt 177, ss. 1-7.
  • Sharmin N., Khan R. A., Dussault D., Salmieri S., Akter N., Lacroix M., 2012, “Effectiveness of Silane Monomer and Gamma Radiation on Chitosan Films and PCL-Based Composites”, Radiation Physics and Chemistry, Cilt 81, ss. 932-935.
  • Şengöz O., 2014, Maleik Anhidrit İçeren Kopolimerlerin Sentezi, Karakterizasyonu ve Modifikasyonu, Yüksek Lisans Tezi, Selçuk Üniversitesi, Fen Bilimleri Enstitüsü Konya.
  • Tirkistani, F. A. A., 1998, “Thermal Analysis of Some Chitosan Schiff Bases”, Polymer Degradation and Stability, Cilt 60, ss. 67-70.
  • Tran C. D., Duri S., Ambra Delneri A., Franko M., 2013, “Chitosan-Cellulose Composite Materials: Preparation, Characterization and Application for Removal of Microcystin”, Journal of Hazardous Materials, Cilt 252-253, ss. 355-366.
  • Wang W. B., Huang D. J., Kang Y. R., Wang A. Q., 2013, “One-step in situ Fabrication of a Granular Semi-IPN Hydrogel Based on Chitosan and Gelatin for Fast and Efficient Adsorption of Cu2+ Ion”, Colloids and Surfaces B: Biointerfaces, Cilt 106, ss. 51-59.
  • Wei Z., Wang C., Zou S., Liu H., Tong Z., 2012, “Chitosan Nanoparticles as Particular Emulsifier for Preparation of Novel pH-responsive Pickering Emulsions and PLGA Microcapsules”, Polymer, Cilt 53, ss. 1229-1235.
  • Won S. L., Lee H. C., Jeong Y. G., Min B. G., Lee S. C., 2009, “Preparation and Acid Dye Adsorption Behavior of Polyurethane/Chitosan Composite Foams”, Fibers and Polymers, Cilt 10, ss. 636-642.
  • Wu L. G., Shen J. N., Chen H. L., Gao C. J., 2006. “CO2 Facilitated Transport Through an Acrylamide and Maleic Anhydride Copolymer Membrane”, Desalination, Cilt 193, ss. 313-320.
  • Xu R., Zhou Q., Li F., Zhang B., 2013, “Laccase Immobilization on Chitosan/poly(vinylalcohol) Composite Nanofibrous Membranes for 2,4-dichlorophenol Removal”, Chemical Engineering Journal, Cilt 222, ss. 321-329.
  • Yin L., Fei L., Cui F., Tang C., Yin C., 2007, “Superporous Hydrogels Containing Poly(acrylic acid-co-acrylamide)/O-carboxymethyl Chitosan Interpenetrating Polymer Networks”, Biomaterials, Cilt 28, ss. 1258-1266.
  • Zhao S., Zhou F., Li L., Cao M., Zuo D., Liu H., 2012, “Removal of Anionic Dyes from Aqueous Solutions by Adsorption of Chitosan-based Semi-IPN Hydrogel Composites”, Composites: Part B, Cilt 43, ss. 1570-1578.
  • Zhou C., Wu Q., 2011, “A Novel Polyacrylamide Nanocomposite Hydrogel Reinforced with Natural Chitosan Nanofibers”, Colloids and Surfaces B: Biointerfaces, Cilt 84, ss. 155-162.

Preparation and Characterization of Chitosan/ter(GMA-MA-NTBA) Polymer Microcapsules

Yıl 2019, Cilt: 7 Sayı: 2, 524 - 535, 01.06.2019
https://doi.org/10.15317/Scitech.2019.216

Öz

In
this study, ter(GMA-MA-NTBA) polymer was synthesized from glycidyl
methacrylate(GA); maleic anhydride (MA) and N-tert-butylacrylamide
(NTBA) monomers for the first time. Chemical structure of the polymer was studied
using FT-IR spectroscopy, Nuclear Magnetic Resonance (1H-NMR)
spectroscopy, acidic group number and viscosity measurements and its surface
morphology using scanning electron microscopy (SEM). Chitosan-based
microcapsules containing different ratios of the synthesized ter(GMA-MA-NTBA)
polymer were prepared and their structural stability was optimized. The
microcapsules were cross-linked with glutaraldehyde to make them mechanically
stronger. Chemical structure of the microcapsules was determined using FT-IR
spectroscopy and their surface their surface morphology using SEM. Chitosan/ter(GMA-MA-NTBA)
polymer composite microcapsules can be tested in adsorption, drug delivery and
controlled release applications.

Kaynakça

  • Abou El-Reash Y. G., Otto M., Kenawy I. M., Ouf A. M., 2011, “Adsorption of Cr(VI) and As(V) Ions by Modified Magnetic Chitosan Chelating Resin”, International Journal of Biological Macromolecules, Cilt 49, ss. 513-522.
  • Agnihotri S. A., Aminabhavi T. M., 2006, “Novel Interpenetrating Network Chitosan-Poly(ethylene oxide-g-acrylamide) Hydrogel Microspheres for the Controlled Release of Capecitabine”, International Journal of Pharmaceutics, Cilt 324, ss. 103-115.
  • Akkaya R., Ulusoy U., 2008, “Adsorptive Features of Chitosan Entrapped in Polyacrylamide Hydrogel for Pb2+, UO22+, and Th4+”, Journal of Hazardous Materials, Cilt 151, ss. 380-388.
  • Anirudhan T. S., Rijith S., 2009, “Glutaraldehyde Cross-linked Epoxyaminated Chitosan as an Adsorbent for the Removal and Recovery of Copper(II) from Aqueous Media”, Colloids and Surfaces A: Physicochemical and Engineering Aspects, Cilt 351, ss. 52-59.
  • Atia A. A., 2005, “Studies on the Interaction of Mercury(II) and Uranyl(II) with Modified Chitosan Resins”, Hydrometallurgy, Cilt 80, ss. 13-22.
  • Babu V. R., Hosamani K. M., Aminabhavi T. M., 2008, “Preparation and in vitro Release of Chlorothiazide Novel pH-sensitive Chitosan-N,N’-dimethylacrylamide Semi-Interpenetrating Network Microspheres”, Carbohydrate Polymers, Cilt 71, ss. 208-217.
  • Bayramoglu G., Arica M. Y., Bektas S., 2007, “Removal of Cd(II), Hg(II), and Pb(II) Ions from Aqueous Solution Using p(HEMA/Chitosan) Membranes”, Journal of Applied Polymer Science, Cilt 106, ss. 169-177.
  • Chen J., Sun J., Yang L., Zhang Q., Zhu H., Wu H., Hoffman A. S., Kaetsu I., 2007 “Preparation and Characterization of a Novel IPN Hydrogel Membrane of Poly(N-isopropylacrylamide)/carboxymethyl Chitosan (PNIPAAM/CMCS)”, Radiation Physics and Chemistry, Cilt 76, ss. 1425-1429.
  • Chen C. Y., Chang T. H., Kuo J. T., Chen Y. F., Chung Y. C., 2008, “Characteristics of Molybdate-impregnated Chitosan Beads (MICB) in Terms of Arsenic Removal from Water and the Application of a MICB-packed Column to Remove Arsenic from Wastewater”, Bioresource Technology, Cilt 99, ss. 7487-7494.
  • Dinçer S., Köseli V., Kesim H., Rzaev Z. M. O. Pişkin E., 2002, “Radical Copolymerization of N-Isopropylacrylamide with Anhydrides of Maleic and Citraconic Acids”, European Polymer Journal, Cilt 38, ss. 2143–2152.
  • Don T. M., Chen H. R., 2005, “Synthesis and Characterization of AB-crosslinked Graft Copolymers Based on Maleilated Chitosan and N-isopropylacrylamide”, Carbohydrate Polymers, Cilt 61, ss. 334-347.
  • Dotto G. L., Moura J. M., Cadaval T. R. S., Pinto L. A. A., 2013, “Application of Chitosan Films for the Removal of Food Dyes from Aqueous Solutions by Adsorption”, Chemical Engineering Journal, Cilt 214, ss. 8-16.
  • Dragan E. S., Lazar M. M., Dinu M. V., Doroftei F., 2012a, “Macroporous Composite IPN Hydrogels Based on Poly(acrylamide) and Chitosan with Tuned Swelling and Sorption of Cationic Dyes”, Chemical Engineering Journal, Cilt 204-206, ss. 198-209.
  • Dragan E. S., Perju M. M., Dinu M. V., 2012b, “Preparation and Characterization of IPN Composite Hydrogels Based on Polyacrylamide and Chitosan and their Interaction with Ionic Dyes”, Carbohydrate Polymers, Cilt 88, ss. 270-281.
  • Ekberov, O. H., Basan, S., 1995, Polimer Kimyası Laboratuvarı, 1. Baskı, Cumhuriyet Üniversitesi Yayınları, No: 58, Sivas.
  • Guibal E., Jansson-Charrier M., Saecudo I., Le Cloirec P., 1995, “Enhancement of Metal Ion Sorption Performances of Chitosan: Effect of the Structure on the Diffusion Properties”, Langmuir, Cilt 11, ss. 591-598.
  • Hassan, M. A., Omer, A. M., Abbas, E., Baset, W. M. A., Tamer, T. M., 2018, “Preparation, Physicochemical Characterization and Antimicrobial Activities of Novel Two Phenolic Chitosan Schiff Base Derivatives”, Scientific Reports, Cilt 8, ss. 11416.
  • Kaplan Can H., Rzaev Z. M. O., 2012, “H-Bonding Effect in Radical Terpolymerization of Maleic Anhydride, Acrylic acid(Methyl acrylate) and Vinyl Acetate”, Hacettepe Journal of Biology & Chemistry, Cilt 40, Sayı 4, ss. 427-443.
  • Karasakal A., 2015, Aromatik Yapı İçeren Polimerlerin Sentezi ve Karakterizasyonu, Yüksek Lisans Tezi, Selçuk Üniversitesi, Fen Bilimleri Enstitüsü, Konya.
  • Kestwal D. B, Kestwal R. M., Chiang B. H., Karve M. S., 2011, “Development of Dip-strip Sucrose Sensors: Application of Plant Invertase Immobilized in Chitosan–Guar Gum, Gelatin and Poly-acrylamide Films”, Sensors and Actuators B, Cilt 160, ss. 1026-1033.
  • Klumperman B., 2010, “Mechanistic Considerations on Styrene – Maleic Anhydride Copolymerization Reactions”, Polymer Chemistry, Cilt 1, ss. 558-562.
  • Kumar M. N. V. R., Muzzarelli R. A. A., Muzzarelli C., Sashiwa H., Domb A.J., 2004, “Chitosan Chemistry and Pharmaceutical Perspectives”, Chemical Reviews, Cilt 104, ss. 6017-6084.
  • Kumar M., Bijay P. T., Vinod K. S., 2009, “Crosslinked Chitosan/Polyvinyl Alcohol Blend Beads for Removal and Recovery of Cd(II) from Wastewater”, Journal of Hazardous Materials, Cilt 172, ss. 1041-1048.
  • Liu T., Wang Z. L., Zhao L., Yang X., 2012, “Enhanced Chitosan/Fe0-nanoparticles Beads for Hexavalent Chromium Removal from Wastewater”, Chemical Engineering Journal, Cilt 189–190, ss. 196-202.
  • Ma L., Lu W., Wen J., 2009, “Encapsulation of Lactate Dehydrogenase in Carbon Nanotube Doped Alginate–Chitosan Capsules”, Journal of Molecular Catalysis B: Enzymatic, Cilt 56, ss. 102-107.
  • Nie F. Q., Xu, Z. K., Wan, L. S., Ye, P., W, J., 2004, “Acrylonitrile-based Copolymers Containing Reactive Groups: Synthesis and Preparation of Ultrafiltration Membranes”, Journal of Membrane Science, Cilt 230, ss. 1-11.
  • Pal A., Pan S., Saha S., 2013, “Synergistically Improved Adsorption of Anionic Surfactant and Crystal Violet on Chitosan Hydrogel Beads”, Chemical Engineering Journal, Cilt 217, ss. 426-434.
  • Pillai C. K. S., Paul W., Sharma C. P., 2009, “Chitin and Chitosan Polymers: Chemistry, Solubility and Fiber Formation”, Progress in Polymer Science, Cilt 34, ss. 641-678.
  • Piron E., Accominoti M., Domard A., 1997, “Interaction between Chitosan and Uranyl Ions. Role of Physical and Physicochemical Parameters on the Kinetics of Sorption”, Langmuir, Cilt 13, ss. 1653-1658.
  • Rzaev Z. M. O., 1999, “Complex-radical Terpolymerization of Glycidyl(Methyl) Methacrylates, Styrene, and Maleic Anhydride”, Journal of Polymer Science: Part A: Polymer Chemistry, Cilt 37, ss. 1095–1102.
  • Rokhade A. P., Patil S. A., Aminabhavi T. M., 2007, “Synthesis and Characterization of Semi-Interpenetrating Polymer Network Microspheres of Acrylamide Grafted Dextran and Chitosan for Controlled Release of Acyclovir”, Carbohydrate Polymers, Cilt 67, ss. 605-613.
  • Sargın I., Arslan G., 2015, “Chitosan/Sporopollenin Microcapsules: Preparation, Characterisation and Application in Heavy Metal Removal”, International Journal of Biological Macromolecules, Cilt 75, ss. 230-238.
  • Sargın I., Kaya M., Arslan G., Baran T., Ceter T., 2015, “Preparation and Characterisation of Biodegradable Pollen–Chitosan Microcapsules and its Application in Heavy Metal Removal”, Bioresource Technology, Cilt 177, ss. 1-7.
  • Sharmin N., Khan R. A., Dussault D., Salmieri S., Akter N., Lacroix M., 2012, “Effectiveness of Silane Monomer and Gamma Radiation on Chitosan Films and PCL-Based Composites”, Radiation Physics and Chemistry, Cilt 81, ss. 932-935.
  • Şengöz O., 2014, Maleik Anhidrit İçeren Kopolimerlerin Sentezi, Karakterizasyonu ve Modifikasyonu, Yüksek Lisans Tezi, Selçuk Üniversitesi, Fen Bilimleri Enstitüsü Konya.
  • Tirkistani, F. A. A., 1998, “Thermal Analysis of Some Chitosan Schiff Bases”, Polymer Degradation and Stability, Cilt 60, ss. 67-70.
  • Tran C. D., Duri S., Ambra Delneri A., Franko M., 2013, “Chitosan-Cellulose Composite Materials: Preparation, Characterization and Application for Removal of Microcystin”, Journal of Hazardous Materials, Cilt 252-253, ss. 355-366.
  • Wang W. B., Huang D. J., Kang Y. R., Wang A. Q., 2013, “One-step in situ Fabrication of a Granular Semi-IPN Hydrogel Based on Chitosan and Gelatin for Fast and Efficient Adsorption of Cu2+ Ion”, Colloids and Surfaces B: Biointerfaces, Cilt 106, ss. 51-59.
  • Wei Z., Wang C., Zou S., Liu H., Tong Z., 2012, “Chitosan Nanoparticles as Particular Emulsifier for Preparation of Novel pH-responsive Pickering Emulsions and PLGA Microcapsules”, Polymer, Cilt 53, ss. 1229-1235.
  • Won S. L., Lee H. C., Jeong Y. G., Min B. G., Lee S. C., 2009, “Preparation and Acid Dye Adsorption Behavior of Polyurethane/Chitosan Composite Foams”, Fibers and Polymers, Cilt 10, ss. 636-642.
  • Wu L. G., Shen J. N., Chen H. L., Gao C. J., 2006. “CO2 Facilitated Transport Through an Acrylamide and Maleic Anhydride Copolymer Membrane”, Desalination, Cilt 193, ss. 313-320.
  • Xu R., Zhou Q., Li F., Zhang B., 2013, “Laccase Immobilization on Chitosan/poly(vinylalcohol) Composite Nanofibrous Membranes for 2,4-dichlorophenol Removal”, Chemical Engineering Journal, Cilt 222, ss. 321-329.
  • Yin L., Fei L., Cui F., Tang C., Yin C., 2007, “Superporous Hydrogels Containing Poly(acrylic acid-co-acrylamide)/O-carboxymethyl Chitosan Interpenetrating Polymer Networks”, Biomaterials, Cilt 28, ss. 1258-1266.
  • Zhao S., Zhou F., Li L., Cao M., Zuo D., Liu H., 2012, “Removal of Anionic Dyes from Aqueous Solutions by Adsorption of Chitosan-based Semi-IPN Hydrogel Composites”, Composites: Part B, Cilt 43, ss. 1570-1578.
  • Zhou C., Wu Q., 2011, “A Novel Polyacrylamide Nanocomposite Hydrogel Reinforced with Natural Chitosan Nanofibers”, Colloids and Surfaces B: Biointerfaces, Cilt 84, ss. 155-162.
Toplam 45 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Konular Mühendislik
Bölüm Makaleler
Yazarlar

İdris Sargın Bu kişi benim

Yayımlanma Tarihi 1 Haziran 2019
Yayımlandığı Sayı Yıl 2019 Cilt: 7 Sayı: 2

Kaynak Göster

APA Sargın, İ. (2019). KİTOSAN/ter(GMA-MA-NTBA) POLİMER İLE MİKROKAPSÜL HAZIRLAMA VE KARAKTERİZASYONU. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi, 7(2), 524-535. https://doi.org/10.15317/Scitech.2019.216
AMA Sargın İ. KİTOSAN/ter(GMA-MA-NTBA) POLİMER İLE MİKROKAPSÜL HAZIRLAMA VE KARAKTERİZASYONU. sujest. Haziran 2019;7(2):524-535. doi:10.15317/Scitech.2019.216
Chicago Sargın, İdris. “KİTOSAN/Ter(GMA-MA-NTBA) POLİMER İLE MİKROKAPSÜL HAZIRLAMA VE KARAKTERİZASYONU”. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi 7, sy. 2 (Haziran 2019): 524-35. https://doi.org/10.15317/Scitech.2019.216.
EndNote Sargın İ (01 Haziran 2019) KİTOSAN/ter(GMA-MA-NTBA) POLİMER İLE MİKROKAPSÜL HAZIRLAMA VE KARAKTERİZASYONU. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi 7 2 524–535.
IEEE İ. Sargın, “KİTOSAN/ter(GMA-MA-NTBA) POLİMER İLE MİKROKAPSÜL HAZIRLAMA VE KARAKTERİZASYONU”, sujest, c. 7, sy. 2, ss. 524–535, 2019, doi: 10.15317/Scitech.2019.216.
ISNAD Sargın, İdris. “KİTOSAN/Ter(GMA-MA-NTBA) POLİMER İLE MİKROKAPSÜL HAZIRLAMA VE KARAKTERİZASYONU”. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi 7/2 (Haziran 2019), 524-535. https://doi.org/10.15317/Scitech.2019.216.
JAMA Sargın İ. KİTOSAN/ter(GMA-MA-NTBA) POLİMER İLE MİKROKAPSÜL HAZIRLAMA VE KARAKTERİZASYONU. sujest. 2019;7:524–535.
MLA Sargın, İdris. “KİTOSAN/Ter(GMA-MA-NTBA) POLİMER İLE MİKROKAPSÜL HAZIRLAMA VE KARAKTERİZASYONU”. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi, c. 7, sy. 2, 2019, ss. 524-35, doi:10.15317/Scitech.2019.216.
Vancouver Sargın İ. KİTOSAN/ter(GMA-MA-NTBA) POLİMER İLE MİKROKAPSÜL HAZIRLAMA VE KARAKTERİZASYONU. sujest. 2019;7(2):524-35.

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