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Studies on the Sorption of Basic Dye by Rubber (Hevea brasiliensis) Seed Shell

Yıl 2008, Cilt 32, Sayı 3, 143 - 152, 01.03.2008

Öz

The present study investigated the ability of rubber seed shell (RSS) to abstract methylene blue (MB) from aqueous solution. The process of sorption of methylene blue from solution was analysed using 5 different isotherm models (Langmuir, Freundlich, Temkin, Harkins--Jura, and Halsey isotherm equations). The highest values of r2 were obtained when the experimental data were fitted into Freundlich and Halsey isotherm equations (0.999). The RSS/MB system was found to be affected by the sorbent dose and initial dye solution. The kinetic data showed that the sorption capacity of RSS for the dye increased with increasing initial dye concentration, while a reverse trend was observed when the effect of sorbent dosage was studied. Analysis of the data obtained from the different sorption studies revealed that the data fitted better to the pseudo-second order model than any other kinetic model, indicating that the sorption process will include chemisorptions of methylene blue dye on rubber seed shell.

Kaynakça

  • Ho, Y.S. “Adsorption of Heavy Metals from Waste Streams by Peat”. PhD Thesis, University of Birming- ham, Birmingham, U.K., 1995.
  • Ho, Y.S. and McKay, G.A., “Kinetic Study of Dye Sorp- tion by Biosorbent Waste Product Pith”, Resour. Con- serv. Recycl. 253, 171-193, 1999.
  • Ho, Y.S. and McKay, G. “Sorption of Dye from Aque- ous Solution by Peat”, Chemical Engineering Journal, 70, 115-124, 1998.
  • Ho, Y.S. and McKay, G. “Batch Sorber Design Using Equilibrium and Contact Time Data for the Removal of Lead”, Water, Air, Soil Pollution, 124, 141-153, 2000.
  • Ho, Y.S., Ng, J.C.Y. and McKay, G. “Kinetics of Pol- lutant Sorption by Biosorbents: Review”. Sep. Purif. Methods, 29, 189-232, 2002.
  • Ho, Y.S. and McKay, G. “Sorption of Dye from Aque- ous Solution by Peat”. Chemical Engineering Journal, 70, 115-124, 1998.
  • Ho Y.S., Chiu, W.T. and Wang, C.C. “Regression Anal- ysis for the Sorption Isotherms of Basic Dyes on Sugar- cane Dust”. Bioresource Technology, 96, 1285-91, 2005. Kumar, M.N.V.R., Sridhari, T.R., Bhavani, K.D. and Dutta, P.K. “Trends in Colour Removal from Textile Mill Effluents”. Colorage 40, 25-34, 1998.
  • Kumar, K,V., Ramamurthi, V. and Sivanesan, S., “Modelling the Mechanism Involved During the Sorp- tion of Methylene Blue onto Fly Ash”. J. Colloid Inter- face Sci. 1; 284, 14-21, 2005.
  • Lazaridis, N.K. and Asouhidou, D.D. “Kinetics of Sorp- tive Removal of Chromium (VI) from Aqueous Solution by Calcined Mg-Al-CO3Hydrotalcite”. Wat. Res. 37, 2875-2882, 2003.
  • Low, K.S., Lee, C.K. and Heng, L.L. “Sorption of Basic Dyes by Hydrilla verticillata”. Environmental Toxicol- ogy 14, 115-124, 1993.
  • Low, K.S., Lee, C.K. and Tan, K.K. “Biosorption of Ba- sic Dyes by Water Hyacinth Roots”. Bioresource Tech- nology 52, 79-83, 1995.
  • Mall, I.D., Srivastava, V.C. and Agarwal, N.K. “Re- moval of Orange G and Methyl Violet Dyes by Adsorp- tion onto Bagasse Fly Ash-Kinetic Study and Equilib- rium Isotherm Analyses”. Dyes and Pigments, 69, 210- 223, 2006.
  • McKay, G., Blair H.S. and Garden, J.R. “Adsorption of Dyes on Chitin: Equilibrium Studies”. J. Appl. Polym. Sci. 27, 3043-3057, 1992.
  • Namasivayam, C. and Ranganathan, K., “Removal of Cd(II) From Wastewater by Adsorption On ”Waste” Fe(II)/Cr(II) Hydroxide”. Wat. Res. 29, 1737-1744, 1995.
  • Nasar, M.M., “Intraparticle Diffusion of Basic Red and Basic Yellow Dyes On Palm Fruit Bunch.” Wat. Sci. Techn. 40, 133-139, 1999.
  • Nigam, P., Armour, G., Banat, I.M., Singh, D. and Marchant, R., “Physical Removal of Textile Dyes and Solid State Fermentation of Dye Adsorbed by Agri- cultural Residues. Bioresource”. Technol. 72, 219-226, 2000.
  • Ofomaja, A.E., “Kinetic Study and Sorption Mecha- nism of Methylene Blue and Methyl Violet onto Man- sonia Wood Sawdust, Chem. Eng. J. (2008), doi: 10.1016/j.cej. 12,019, 2007.
  • Oladoja, N.A., Aboluwoye, C.O., Oladimeji, Y.B., Ashogbon, A.O. and Otemuyiwa, I.O., “Studies on Cas- tor Seed Shell as a Sorbent in Basic Dye Contaminated Wastewater Remediation”. Desalination 227, 190-203, 2008.
  • Quek, S.Y., Wase, D.A.J. and Forster, C.F., “The Use of Sago Waste for the Sorption of Lead and Copper”. Water S.A., 24, 251-256, 1998.
  • Rengaraj, S., Seung-Hyeon, M., Sivabalan, R., Banu- mathi, A. and Murugesan, V., “Removal of Phenol from Aqueous Solution and Resin Manufacturing Industry Wastewater Using an Agricultural Waste: Rubber Seed Coat”. J. of Hazardous Materials. B89, 185-196, 2002. Temkin, M.I. and Pyzhev, V., “Kinetic of Ammonia Synthesis on Promoted Iron Catalysts”, Acta Phys- iochim. URSS 12, 327-356, 1940.
  • Vadivelan, V. and Kumar, KV., Equilibrium, Kinet- ics, Mechanism, and Process Design for The Sorption of Methylene Blue Onto Rice Husk. J Colloid Interface Sci. 1; 286, 90-100, 2005.
  • Waranusantigul, P., Pokethitiyook, P., Kruatrachue, M. and Upatham, E.S., “Kinetics of Basic Dyes (Methy- lene Blue) Biosorption by Giant Duckweed (Spirodela polyrrhiza )”. Environmental Pollution. 125, 385-392, 2003.
  • Weber, W.J. and Morris, J.C., “Kinetics of Adsorption on Carbon from Solution”, J. Sanit. Eng. Div. ASCE 89, 31-59, 1963.

Studies on the Sorption of Basic Dye by Rubber (Hevea brasiliensis) Seed Shell

Yıl 2008, Cilt 32, Sayı 3, 143 - 152, 01.03.2008

Öz

The present study investigated the ability of rubber seed shell (RSS) to abstract methylene blue (MB) from aqueous solution. The process of sorption of methylene blue from solution was analysed using 5 different isotherm models (Langmuir, Freundlich, Temkin, Harkins--Jura, and Halsey isotherm equations). The highest values of r2 were obtained when the experimental data were fitted into Freundlich and Halsey isotherm equations (0.999). The RSS/MB system was found to be affected by the sorbent dose and initial dye solution. The kinetic data showed that the sorption capacity of RSS for the dye increased with increasing initial dye concentration, while a reverse trend was observed when the effect of sorbent dosage was studied. Analysis of the data obtained from the different sorption studies revealed that the data fitted better to the pseudo-second order model than any other kinetic model, indicating that the sorption process will include chemisorptions of methylene blue dye on rubber seed shell.

Kaynakça

  • Ho, Y.S. “Adsorption of Heavy Metals from Waste Streams by Peat”. PhD Thesis, University of Birming- ham, Birmingham, U.K., 1995.
  • Ho, Y.S. and McKay, G.A., “Kinetic Study of Dye Sorp- tion by Biosorbent Waste Product Pith”, Resour. Con- serv. Recycl. 253, 171-193, 1999.
  • Ho, Y.S. and McKay, G. “Sorption of Dye from Aque- ous Solution by Peat”, Chemical Engineering Journal, 70, 115-124, 1998.
  • Ho, Y.S. and McKay, G. “Batch Sorber Design Using Equilibrium and Contact Time Data for the Removal of Lead”, Water, Air, Soil Pollution, 124, 141-153, 2000.
  • Ho, Y.S., Ng, J.C.Y. and McKay, G. “Kinetics of Pol- lutant Sorption by Biosorbents: Review”. Sep. Purif. Methods, 29, 189-232, 2002.
  • Ho, Y.S. and McKay, G. “Sorption of Dye from Aque- ous Solution by Peat”. Chemical Engineering Journal, 70, 115-124, 1998.
  • Ho Y.S., Chiu, W.T. and Wang, C.C. “Regression Anal- ysis for the Sorption Isotherms of Basic Dyes on Sugar- cane Dust”. Bioresource Technology, 96, 1285-91, 2005. Kumar, M.N.V.R., Sridhari, T.R., Bhavani, K.D. and Dutta, P.K. “Trends in Colour Removal from Textile Mill Effluents”. Colorage 40, 25-34, 1998.
  • Kumar, K,V., Ramamurthi, V. and Sivanesan, S., “Modelling the Mechanism Involved During the Sorp- tion of Methylene Blue onto Fly Ash”. J. Colloid Inter- face Sci. 1; 284, 14-21, 2005.
  • Lazaridis, N.K. and Asouhidou, D.D. “Kinetics of Sorp- tive Removal of Chromium (VI) from Aqueous Solution by Calcined Mg-Al-CO3Hydrotalcite”. Wat. Res. 37, 2875-2882, 2003.
  • Low, K.S., Lee, C.K. and Heng, L.L. “Sorption of Basic Dyes by Hydrilla verticillata”. Environmental Toxicol- ogy 14, 115-124, 1993.
  • Low, K.S., Lee, C.K. and Tan, K.K. “Biosorption of Ba- sic Dyes by Water Hyacinth Roots”. Bioresource Tech- nology 52, 79-83, 1995.
  • Mall, I.D., Srivastava, V.C. and Agarwal, N.K. “Re- moval of Orange G and Methyl Violet Dyes by Adsorp- tion onto Bagasse Fly Ash-Kinetic Study and Equilib- rium Isotherm Analyses”. Dyes and Pigments, 69, 210- 223, 2006.
  • McKay, G., Blair H.S. and Garden, J.R. “Adsorption of Dyes on Chitin: Equilibrium Studies”. J. Appl. Polym. Sci. 27, 3043-3057, 1992.
  • Namasivayam, C. and Ranganathan, K., “Removal of Cd(II) From Wastewater by Adsorption On ”Waste” Fe(II)/Cr(II) Hydroxide”. Wat. Res. 29, 1737-1744, 1995.
  • Nasar, M.M., “Intraparticle Diffusion of Basic Red and Basic Yellow Dyes On Palm Fruit Bunch.” Wat. Sci. Techn. 40, 133-139, 1999.
  • Nigam, P., Armour, G., Banat, I.M., Singh, D. and Marchant, R., “Physical Removal of Textile Dyes and Solid State Fermentation of Dye Adsorbed by Agri- cultural Residues. Bioresource”. Technol. 72, 219-226, 2000.
  • Ofomaja, A.E., “Kinetic Study and Sorption Mecha- nism of Methylene Blue and Methyl Violet onto Man- sonia Wood Sawdust, Chem. Eng. J. (2008), doi: 10.1016/j.cej. 12,019, 2007.
  • Oladoja, N.A., Aboluwoye, C.O., Oladimeji, Y.B., Ashogbon, A.O. and Otemuyiwa, I.O., “Studies on Cas- tor Seed Shell as a Sorbent in Basic Dye Contaminated Wastewater Remediation”. Desalination 227, 190-203, 2008.
  • Quek, S.Y., Wase, D.A.J. and Forster, C.F., “The Use of Sago Waste for the Sorption of Lead and Copper”. Water S.A., 24, 251-256, 1998.
  • Rengaraj, S., Seung-Hyeon, M., Sivabalan, R., Banu- mathi, A. and Murugesan, V., “Removal of Phenol from Aqueous Solution and Resin Manufacturing Industry Wastewater Using an Agricultural Waste: Rubber Seed Coat”. J. of Hazardous Materials. B89, 185-196, 2002. Temkin, M.I. and Pyzhev, V., “Kinetic of Ammonia Synthesis on Promoted Iron Catalysts”, Acta Phys- iochim. URSS 12, 327-356, 1940.
  • Vadivelan, V. and Kumar, KV., Equilibrium, Kinet- ics, Mechanism, and Process Design for The Sorption of Methylene Blue Onto Rice Husk. J Colloid Interface Sci. 1; 286, 90-100, 2005.
  • Waranusantigul, P., Pokethitiyook, P., Kruatrachue, M. and Upatham, E.S., “Kinetics of Basic Dyes (Methy- lene Blue) Biosorption by Giant Duckweed (Spirodela polyrrhiza )”. Environmental Pollution. 125, 385-392, 2003.
  • Weber, W.J. and Morris, J.C., “Kinetics of Adsorption on Carbon from Solution”, J. Sanit. Eng. Div. ASCE 89, 31-59, 1963.

Ayrıntılar

Birincil Dil Türkçe
Bölüm Makaleler
Yazarlar

N. A. OLADOJA Bu kişi benim

Yayımlanma Tarihi 1 Mart 2008
Yayınlandığı Sayı Yıl 2008, Cilt 32, Sayı 3

Kaynak Göster

Bibtex @ { tbtkengineering145027, journal = {Turkish Journal of Engineering and Environmental Sciences}, issn = {1300-0160}, eissn = {1303-6157}, address = {}, publisher = {TÜBİTAK}, year = {2008}, volume = {32}, number = {3}, pages = {143 - 152}, title = {Studies on the Sorption of Basic Dye by Rubber (Hevea brasiliensis) Seed Shell}, key = {cite}, author = {Oladoja, N. A.} }
APA Oladoja, N. A. (2008). Studies on the Sorption of Basic Dye by Rubber (Hevea brasiliensis) Seed Shell . Turkish Journal of Engineering and Environmental Sciences , 32 (3) , 143-152 . Retrieved from https://dergipark.org.tr/tr/pub/tbtkengineering/issue/12139/145027
MLA Oladoja, N. A. "Studies on the Sorption of Basic Dye by Rubber (Hevea brasiliensis) Seed Shell" . Turkish Journal of Engineering and Environmental Sciences 32 (2008 ): 143-152 <https://dergipark.org.tr/tr/pub/tbtkengineering/issue/12139/145027>
Chicago Oladoja, N. A. "Studies on the Sorption of Basic Dye by Rubber (Hevea brasiliensis) Seed Shell". Turkish Journal of Engineering and Environmental Sciences 32 (2008 ): 143-152
RIS TY - JOUR T1 - Studies on the Sorption of Basic Dye by Rubber (Hevea brasiliensis) Seed Shell AU - N. A.Oladoja Y1 - 2008 PY - 2008 N1 - DO - T2 - Turkish Journal of Engineering and Environmental Sciences JF - Journal JO - JOR SP - 143 EP - 152 VL - 32 IS - 3 SN - 1300-0160-1303-6157 M3 - UR - Y2 - 2022 ER -
EndNote %0 Turkish Journal of Engineering and Environmental Sciences Studies on the Sorption of Basic Dye by Rubber (Hevea brasiliensis) Seed Shell %A N. A. Oladoja %T Studies on the Sorption of Basic Dye by Rubber (Hevea brasiliensis) Seed Shell %D 2008 %J Turkish Journal of Engineering and Environmental Sciences %P 1300-0160-1303-6157 %V 32 %N 3 %R %U
ISNAD Oladoja, N. A. . "Studies on the Sorption of Basic Dye by Rubber (Hevea brasiliensis) Seed Shell". Turkish Journal of Engineering and Environmental Sciences 32 / 3 (Mart 2008): 143-152 .
AMA Oladoja N. A. Studies on the Sorption of Basic Dye by Rubber (Hevea brasiliensis) Seed Shell. Turkish Journal of Engineering and Environmental Sciences. 2008; 32(3): 143-152.
Vancouver Oladoja N. A. Studies on the Sorption of Basic Dye by Rubber (Hevea brasiliensis) Seed Shell. Turkish Journal of Engineering and Environmental Sciences. 2008; 32(3): 143-152.
IEEE N. A. Oladoja , "Studies on the Sorption of Basic Dye by Rubber (Hevea brasiliensis) Seed Shell", Turkish Journal of Engineering and Environmental Sciences, c. 32, sayı. 3, ss. 143-152, Mar. 2008