Araştırma Makalesi
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Chemical vapor transport synthesis of a selenium-based two-dimensional material

Yıl 2018, Cilt 42, Sayı 3, 293 - 301, 01.06.2018

Öz

Selenium-based layered materials, and in particular transition-metal diselenides (TMDSs), have intriguing properties in the monolayer limit. Materials such as MoSe2, WSe2, and NbSe2 display striking features such as spin-valley coupling at the valence-band edges and offer great potential for optoelectronics applications. Although a dozen of other TMDSs have been realized or proposed, whether two-dimensional chalcogens are possible or not is still an open challenge. In this work, we show the chemical vapor transport synthesis of a novel, atomically thin selenium-based material on oxidized silicon substrates. This new member of the two-dimensional materials family has a unique Raman spectrum similar to that of bulk selenium and has an optical gap of 1.57 eV at room temperature determined by the photoluminescence. No transition metals are found in the stoichiometry of the crystals. Analysis of high-resolution transmission electron micrographs of the monolayers reveals a distinctive set of hexagonal spots indicating a sixfold symmetry of the lattice. Atomic force microscopy measurements show the monolayer thickness to be 0.75 nm.

Kaynakça

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  • Coehoorn, R.; Haas, C.; Groot, R. A. D. Phys. Rev. B 1987 , 35 , 6203-6206.
  • Scheuschner, N.; Ochedowski, O.; Kaulitz, A. M.; Gillen, R.; Schleberger, M.; Maultzsch, J. Phys. Rev. B 2014 , 89 , 125406.
  • Cao, X.; Xie, Y.; Zhang, S.; Li, F. Adv. Mater. 2004 , 16 , 649-653.
  • Wang, J.; Marple, M.; Lee, K.; Sen, S.; Kovnir, K. J. Mater. Chem. A 2016 , 4 , 11276-11283.
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Yıl 2018, Cilt 42, Sayı 3, 293 - 301, 01.06.2018

Öz

Kaynakça

  • Chhowalla, M.; Jena, D.; Zhang, H. Nat. Rev. Mater ., 2016 , 1 , 16052.
  • Schaibley, J. R.; Yu, H,; Clark, G.; Rivera, P.; Ross, J. S.; Seyler, K. L.; Yao, W.; Xu, X. Nat. Rev. Mater. 2016 , 1 , 16055.
  • Jariwala, D.; Marks, T. J.; Hersam, M. C. Nat. Mater. 2017 , 16 , 170-181.
  • Wallace, P. R. Phys. Rev. 1947 , 71 , 622-634.
  • Ataca, C.; Sahin, H.; Ciraci, S. J. Phys. Chem. C 2012 , 116 , 8983-8999.
  • Cahangirov, S.; Topsakal, M.; Akturk, E.; Sahin, H.; Ciraci, S. Phys. Rev. Lett. 2009 , 102 , 236804.
  • Piazza, Z. A.; Hu, H. S.; Li, W. L.; Zhao, Y. F.; Li, J.; Wang, L. S. Nat. Commun. 2014 , 5 , 3113.
  • Geim, A. K.; Grigorieva, I. V. Nature 2013 , 499 , 419-425.
  • Zhu, Z. Y.; Cheng, Y. C.; Schwingenschlogl, U. Phys. Rev. B 2011 , 84 , 153402.
  • Xiao, D.; Liu, G. B.; Feng, W.; Xu, X.; Yao, W. Phys. Rev. Lett. 2012 , 108 , 196802.
  • Rycerz, A.; Tworzyd lo, J.; Beenakker, C. W. J. Nat. Phys. 2007 , 3 , 172-175.
  • Mak, K. F.; He, K.; Shan, J.; Heinz, T. F. Nat. Nanotechnol. 2012 , 7 , 494-498.
  • Fogler, M. M.; Butov, L. V.; Novoselov, K. S. Nat. Commun. 2014 , 5 , 4555.
  • Novoselov, K. S.; Mishchenko, A.; Carvalho, A.; Neto, A. H. C. Science 2016 , 353 , aac9439.
  • Mannix, A. J.; Kiraly, B.; Hersam, M. C.; Guisinger, N. P. Nature Rev. Chem. 2017 , 1 , 0014.
  • Vogt, P.; Padova, P. D.; Quaresima, C.; Avila, J.; Frantzeskakis, E.; Asensio, M. C.; Resta, A.; Ealet, B.; Lay, G. L. Phys. Rev. Lett. 2012 , 108 , 155501.
  • Liu, H.; Neal, A. T.; Zhu, Z.; Luo, Z.; Xu, X.; Tomanek, D.; Ye, P. D. ACS Nano 2014 , 8 , 4033-4041.
  • Li, L.; Lu, S. Z.; Pan, J.; Qin, Z.; Wang, Y. Q.; Wang, Y.; Cao, G. Y.; Du, S.; Gao, H. J. Adv. Mater. 2014 , 26 , 4820-4824.
  • Zhu, F. F.; Chen, W. J.; Xu, Y.; Gao, C. L.; Guan, D. D.; Liu, C. H.; Qian, D.; Zhang, S. C.; Jia, J. F. Nat. Mater. 2015 , 14 , 1020-1025.
  • Mannix, A. J.; Zhou, X. F.; Kiraly, B.; Wood, J. D.; Alducin, D.; Myers, B. D.; Liu, X.; Fisher, B. L.; Santiago, U.; Guest, J. R. et al. Science 2015 , 350 , 1513-1516.
  • Ji, J.; Song, X.; Liu, J.; Yan, Z.; Huo, C.; Zhang, S.; Su, M.; Liao, L.; Wang, W.; Ni, Z. et al. Nat. Commun. 2016 , 7 , 13352.
  • Xian, L.; Paz, A. P.; Bianco, E.; Ajayan, P. M.; Rubio, A. 2D Mater. 2017 , 4 , 041003.
  • Ma, Y.; Qi, L.; Shen, W. Ma, J. Langmuir 2005 , 21 , 6161-6164.
  • Gates, B.; Mayers, B.; Grossman, A.; Xia, Y. Adv. Mater. 2002 , 14 , 1749-1752.
  • Hu, J.; Odom, T. W.; Lieber, C. M. Accounts Chem. Res. 1999 , 32 , 435-445.
  • Schneider, G. F.; Calado, V. E.; Zandbergen, H.; Vandersypen, M. K.; Dekker, C. Nano Lett. 2010 , 10 , 1912-1916.
  • Moulder, J. F.; Stickle, N. F.; Sobol, P. E.; Bomben, K. D., Eds. Handbook of X-ray Photoelectron Spectroscopy ; Physical Electronics Inc.: Eden Prairie, MN, USA, 1995.
  • Zhao, W.; Dong, B.; Guo, Z.; Su, G.; Gao, R.; Wang, W.; Cao, L. Chem. Commun. 2016 , 52 , 9228-9231.
  • Sinha, A. K.; Sasmal, A. K.; Mehetor, S. K.; Pradhan, M.; Pal, T. Chem. Commun. 2014 , 50 , 15733-15736.
  • Cooper, W. C. The Physics of Selenium and Tellurium ; Pergamon Press: Dorking, UK, 1967.
  • Anderson, A.; Sanders, A.; Smith, W. J. Raman Spectrosc. 2000 , 31 , 403-406.
  • Nagata, K; Ishikawa, T.; Miyamoto, Y. Jpn. J. Appl. Phys. 1983 , 22 , 1129.
  • Yu, P. Y.; Amer, N.; Shen, Y. R.; Petroff, Y. Phys. Rev. B 1976 , 14 , 644-652.
  • Coehoorn, R.; Haas, C.; Groot, R. A. D. Phys. Rev. B 1987 , 35 , 6203-6206.
  • Scheuschner, N.; Ochedowski, O.; Kaulitz, A. M.; Gillen, R.; Schleberger, M.; Maultzsch, J. Phys. Rev. B 2014 , 89 , 125406.
  • Cao, X.; Xie, Y.; Zhang, S.; Li, F. Adv. Mater. 2004 , 16 , 649-653.
  • Wang, J.; Marple, M.; Lee, K.; Sen, S.; Kovnir, K. J. Mater. Chem. A 2016 , 4 , 11276-11283.
  • Ren, L.; Zhang, H.; Tan, P.; Chen, Y.; Zhang, Z.; Chang, Y.; Xu, J.; Yang, F.; Yu, D. J. Phys. Chem. B 2004 , 108 , 4627-4630.
  • Pradel, A.; Michel-Lledos, V.; Ribes, M.; Eckert, H. Chem. Mater. 1993 , 5 , 377-380.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Makaleler
Yazarlar

Talip Serkan KASIRGA Bu kişi benim

Yayımlanma Tarihi 1 Haziran 2018
Yayınlandığı Sayı Yıl 2018, Cilt 42, Sayı 3

Kaynak Göster

Bibtex @araştırma makalesi { tbtkphysics490313, journal = {Turkish Journal of Physics}, issn = {1300-0101}, eissn = {1303-6122}, address = {}, publisher = {TÜBİTAK}, year = {2018}, volume = {42}, number = {3}, pages = {293 - 301}, title = {Chemical vapor transport synthesis of a selenium-based two-dimensional material}, key = {cite}, author = {Kasırga, Talip Serkan} }
APA Kasırga, T. S. (2018). Chemical vapor transport synthesis of a selenium-based two-dimensional material . Turkish Journal of Physics , 42 (3) , 293-301 . Retrieved from https://dergipark.org.tr/tr/pub/tbtkphysics/issue/40696/490313
MLA Kasırga, T. S. "Chemical vapor transport synthesis of a selenium-based two-dimensional material" . Turkish Journal of Physics 42 (2018 ): 293-301 <https://dergipark.org.tr/tr/pub/tbtkphysics/issue/40696/490313>
Chicago Kasırga, T. S. "Chemical vapor transport synthesis of a selenium-based two-dimensional material". Turkish Journal of Physics 42 (2018 ): 293-301
RIS TY - JOUR T1 - Chemical vapor transport synthesis of a selenium-based two-dimensional material AU - Talip SerkanKasırga Y1 - 2018 PY - 2018 N1 - DO - T2 - Turkish Journal of Physics JF - Journal JO - JOR SP - 293 EP - 301 VL - 42 IS - 3 SN - 1300-0101-1303-6122 M3 - UR - Y2 - 2018 ER -
EndNote %0 Turkish Journal of Physics Chemical vapor transport synthesis of a selenium-based two-dimensional material %A Talip Serkan Kasırga %T Chemical vapor transport synthesis of a selenium-based two-dimensional material %D 2018 %J Turkish Journal of Physics %P 1300-0101-1303-6122 %V 42 %N 3 %R %U
ISNAD Kasırga, Talip Serkan . "Chemical vapor transport synthesis of a selenium-based two-dimensional material". Turkish Journal of Physics 42 / 3 (Haziran 2018): 293-301 .
AMA Kasırga T. S. Chemical vapor transport synthesis of a selenium-based two-dimensional material. Turkish Journal of Physics. 2018; 42(3): 293-301.
Vancouver Kasırga T. S. Chemical vapor transport synthesis of a selenium-based two-dimensional material. Turkish Journal of Physics. 2018; 42(3): 293-301.
IEEE T. S. Kasırga , "Chemical vapor transport synthesis of a selenium-based two-dimensional material", Turkish Journal of Physics, c. 42, sayı. 3, ss. 293-301, Haz. 2018