VİSKON KUMAŞLARIN BİO-PARLATILMASINDA TİCARİ SELÜLAZ ENZİMLERİNİN KULLANIMI
Year 2010,
Volume: 20 Issue: 1, 57 - 64, 01.06.2010
M. İbrahim Bahtiyari
Kerim Duran
Ayşegül Ekmekçi Körlü
Seher Perincek
Abstract
Uzun süreden beri tekstil terbiyesinde kullanılan selülazlar üzerine yoğun araştırmalar mevcuttur. Selülazların pamuk, jüt, keten rami ve diğer selüloz esaslı lifleri hidrolize ettiği ve temiz parlak tekstil yüzeylerinin elde edilmesini sağladıkları iyi bilinmektedir. Selülaz enzimi ayrıca denim giysilerde taşlanmış ve giyinmiş efekti için de kullanılmaktadırlar. Selulazların kullanım alanlarını arttırmak mümkündür. Fakat selülazların, viskon kumaşların bio-parlatmasında kullanılmasında sorunlar mevcuttur. Bio-parlatma sonrası viskon kumaşlarda mukavemet kaybı gözlemlenirken kumaş yüzeyindeki pilling ve tüylülük yeterli miktarda azalmamaktadır. Bu ikilem nedeniyle farklı ticari enzimlerle farklı süre ve konsantrasyonlarda istatistiksel bir araştırma yapılmıştır. En iyi sonucun Sellobiohidrolaz (CBH) esaslı selülaz enzimi ile elde edildiği tespit edilmiştir
References
- 1. Kroschwitz, I. J., Polymers; Fibers and Textiles, A Compendium New York: Wiley Interscience Publication; 1990. p. 746-757. 1990
- 2. Müller M., Riekel C., Vuong R., 2000, “Skin/core micro-structure in viscose rayon fibres analysed by X-ray microbeam and electron diffraction mapping”, Polymer, Vol. 41, pp. 2627-2632.
- 3. Smole, M. S., Persin, Z., Kreze, 2003, “X-ray Study of Pre-treated Regenerated Cellulose Fibers”, Materials Research Innovations, Vol. 7, pp. 275-282.
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- 5. Cavaco-Paulo A., Almeida L., 1996, “Cellulase Activities And Finishing Effects”, Textile Chemist and Colorist, Vol. 28, pp.28-32.
- 6. Cavaco-Paulo A., Almeida L., 1994, “Cellulase hydrolysis of cotton cellulose: the effects of mechanical action, enzyme concentration and dyed substrates”, Biocatalysis, Vol. 10, pp. 353-360.
- 7. Heikinheimo L., Miettinen-Oinonen A., Cavaco-Paulo A., 2003, “Effect of Purified Trichoderma Reesei Cellulases on Formation of Cotton Powder from Cotton Fabric”, Journal of Applied Polymer Science, Vol. 90, pp. 1917–1922.
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- 9. Heikinheimo L., Buchert J., Miettinen-Oinonen A., 2000, “Treating Denim Fabrics with Trichoderma Reesei Cellulases”, Textile Research Journal, Vol. 70, Issue 11, pp.969-973.
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- 14. Duran K., Ayaz Ö., 2000, "Selülazların Rejenere Selüloz Liflerinde Kullanımıyla Alternatif Terbiye Prosesleri" Tekstil ve Konfeksiyon, Sayı: 1-2, s: 34-37
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- 19. Sandgren M., Stahlberg J. and Mitchinson C., 2005, “Structural and biochemical studies of GH family 12 cellulases: improved thermal stability, and ligand complexes”, Progress in Biophysics and Molecular Biology, Vol. 89, pp.246-291.
- 20. Kleywegt, G.J., Zou J. Y., Divne C., Davies G. J., 1997, “The Crystal Structure of the Catalytic Core Domain of Endoglucanase I from Trichoderma reesei at 3.6 A° Resolution, and a Comparison with Related Enzymes”, Journal of Molecular Biology, Vol. 272, pp.383- 397.
- 21. Nemeth A., Kamondi S., Szilagyi A, 2002, “Increasing the thermal stability of cellulase C using rules learned from thermophilic proteins: a pilot study”, Biophysical Chemistry, Vol.132, pp.229-241.
USAGE OF COMMERCIAL CELLULASES IN BIOPOLISHING OF VISCOSE FABRICS
Year 2010,
Volume: 20 Issue: 1, 57 - 64, 01.06.2010
M. İbrahim Bahtiyari
Kerim Duran
Ayşegül Ekmekçi Körlü
Seher Perincek
Abstract
Cellulases which have been in use for a long time in textile finishing were studied deeply. It is well known that cellulases can hydrolyze cotton, jute, linen, ramie and other cellulose based fiber and ensure a clean polished textile surfaces. Moreover cellulase enzyme is also used for worn and stone washed effect in denim cloths. It is possible to expand its usages. But there is a draw back in the use of cellulases for biopolishing of viscose based fabrics. Although strength loss during biopolishing of viscose fabrics was evident, the pilling and fuzz of surface did not decreased sufficiently. Because of this dilemma, a statistical research was carried out with the use of different commercial cellulase enzymes in different time and concentration. It was found that the best results were obtained from the use of CBH based Cellulase
References
- 1. Kroschwitz, I. J., Polymers; Fibers and Textiles, A Compendium New York: Wiley Interscience Publication; 1990. p. 746-757. 1990
- 2. Müller M., Riekel C., Vuong R., 2000, “Skin/core micro-structure in viscose rayon fibres analysed by X-ray microbeam and electron diffraction mapping”, Polymer, Vol. 41, pp. 2627-2632.
- 3. Smole, M. S., Persin, Z., Kreze, 2003, “X-ray Study of Pre-treated Regenerated Cellulose Fibers”, Materials Research Innovations, Vol. 7, pp. 275-282.
- 4. Cavaco-Paulo, A., 1998, “Mechanism of cellulase action in textile processes”, Carbohydrate Polymers, Vol. 37, pp. 273-277.
- 5. Cavaco-Paulo A., Almeida L., 1996, “Cellulase Activities And Finishing Effects”, Textile Chemist and Colorist, Vol. 28, pp.28-32.
- 6. Cavaco-Paulo A., Almeida L., 1994, “Cellulase hydrolysis of cotton cellulose: the effects of mechanical action, enzyme concentration and dyed substrates”, Biocatalysis, Vol. 10, pp. 353-360.
- 7. Heikinheimo L., Miettinen-Oinonen A., Cavaco-Paulo A., 2003, “Effect of Purified Trichoderma Reesei Cellulases on Formation of Cotton Powder from Cotton Fabric”, Journal of Applied Polymer Science, Vol. 90, pp. 1917–1922.
- 8. Morgado, J. Cavaco-Paulo, A. Rousselle, M.-A, 2000, “Enzymatic Treatment of Lyocell-Clarification of Depilling Mechanisms”, Textile Research Journal, Vol. 70, Issue 8, pp. 696-699.
- 9. Heikinheimo L., Buchert J., Miettinen-Oinonen A., 2000, “Treating Denim Fabrics with Trichoderma Reesei Cellulases”, Textile Research Journal, Vol. 70, Issue 11, pp.969-973.
- 10. Cortez J.M., Ellis J., Bishop D.P., 2001, “Cellulase finishing of woven, cotton fabrics in jet and winch machines”, Journal of Biotechnology, Vol. 89, pp.239–245.
- 11. Ibrahim N. A., Fahmy H. M., Hassan T. M., 2005, “Effect of cellulase treatment on the extent of post-finishing and dyeing of cotton fabrics”, Journal of Materials Processing Technology, Vol. 160, pp.99-106.
- 12. Cavaco-Paulo A., Almeida L., Bishop D., 1998, “Hydrolysis of Cotton Cellulose by Engineered Cellulases from Trichoderma Reesei”, Textile Research Journal, Vol. 68, Issue 4, pp. 273-80.
- 13. Körlü A. E., Duran K., Bahtiyari M. İ., 2008, “Selülaz Enziminin Selülozik Esaslı Kumaşlar Üzerine Etkisi”, Tekstil ve Konfeksiyon, Yıl:18(1), s:35-40.
- 14. Duran K., Ayaz Ö., 2000, "Selülazların Rejenere Selüloz Liflerinde Kullanımıyla Alternatif Terbiye Prosesleri" Tekstil ve Konfeksiyon, Sayı: 1-2, s: 34-37
- 15. Duran K., Öneş M., 1994, "Tekstil Terbiyesinde Enzimler ve Kullanımı", Tekstil ve Konfeksiyon, Sayı: 4 s: 318-328.
- 16. Ng, T.B., 2004, Peptides and proteins from fungi, Peptides, Vol. 25, pp.1055-1073.
- 17. Bhat, M.K., Bhat S., 1997, “Cellulose degrading enzymes and their potential industrial applications”, Biotechnology Advances, Vol. 15, pp. 583-620.
- 18. Heikinheimo L., 2002, “Trichoderma reesei cellulases in processing of cotton”, VTT Biotechnology, Espoo., VTT Publications No: 483, pp.11-61.
- 19. Sandgren M., Stahlberg J. and Mitchinson C., 2005, “Structural and biochemical studies of GH family 12 cellulases: improved thermal stability, and ligand complexes”, Progress in Biophysics and Molecular Biology, Vol. 89, pp.246-291.
- 20. Kleywegt, G.J., Zou J. Y., Divne C., Davies G. J., 1997, “The Crystal Structure of the Catalytic Core Domain of Endoglucanase I from Trichoderma reesei at 3.6 A° Resolution, and a Comparison with Related Enzymes”, Journal of Molecular Biology, Vol. 272, pp.383- 397.
- 21. Nemeth A., Kamondi S., Szilagyi A, 2002, “Increasing the thermal stability of cellulase C using rules learned from thermophilic proteins: a pilot study”, Biophysical Chemistry, Vol.132, pp.229-241.