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HİDROJEN PEROKSİDİN DERİ İŞLEM BASAMAKLARINDA KULLANIMI VE DERİ ÖZELLİKLERİNE ETKİSİ

Year 2010, Volume: 20 Issue: 3, 236 - 240, 01.12.2010

Abstract

Bu çalışmada; deri işlem basamaklarında hidrojen peroksidin alkali ortamda Na2S’ün yerine kullanılması ile yüksek oranda kirlilik yüküne sahip geleneksel kıl giderme-kireçlik işlem basamaklarının yanında enzimatik sama işleminede alternatif olup olmayacağı, mamul deri özellikleri üzerine etkisi ve atık sularındaki atık yükleri araştırılmıştır. Hidrojen peroksidin kıl giderme/kireçlik ile lif açılımı performansının yeterli olduğu, derilerin fiziksel özelliklerinin ve hava geçirgenliği değerlerinin geleneksel yöntemlerle işlenen deriler kadar iyi olduğu ve işlentiler sonunda atıksulardaki KOİ ve sülfit değerlerinin son derece düşük olduğu tespit edilmiştir

References

  • 1. Bitcover, J.,E., Cooper, J.E., Bailey, D.,G., 1980, “Pilot-Plant Study of Flocculation of Suspended Solids in Lime-Sulfide Unhairing Effluents”, Journal of the American Leather Chemist Association, Vol. 75, p:108-118.
  • 2. Thorstensen, T., C., 1993, Practical Leather Technology, Unhairing, p: 95, Fourth edition, Kieger Publishing Company, Malabar, Florida, ISBN 0-8946-689-3.
  • 3. Marsal, A., Morera, J.,M., Borras, M, D., 1999, “Study on a Unhairing Process with Hydrogen Peroxide and Amines”, Journal of the American Leather Chemist Association, Vol. 94, p:1-10.
  • 4. Şengül, F., Müezzinoğlu, A., 1993, Çevre Kimyası, Dokuz Eylül Üni. Mühendislik Fakültesi Basım Ünitesi, Bornova, İzmir
  • 5. Anon, 1991, Röhm and The Environment Leather, Vol. 193, No:4595.
  • 6. Anon, 1994, “Water Pollution and Automation”, Leather, p: 228-230.
  • 7. Marsal, A., Cot, J., Bartoli, E., 2000, “Oxidizing Unhairing Process with Hair Recovery”, Journal of the Society of Leather Technologists and Chemists, Vol.86, p: 30-33.
  • 8. Marmer, W. Et al., 2003, “Rapid Oxidative Unhairing with Alkaline Hydrogen Peroxide”, Journal of the American Leather Chemist Association, Vol.98.
  • 9. Morrera, J., M., Bartoli, E., Borras, M., D., 1997, “Liming Process Using Hydrogen Peroxide”, Journal of the Society of Leather Technologists and Chemists, p70-73.
  • 10. El Baba, H., A., M., Covington, A., D., Davighi, D., 1999, The Effects of Hair Shaving Unhairing Reactions: Part 1: Environmental Impact, Journal of the Society of Leather Technologists and Chemists, Vol. 83, p:200.
  • 11. Cantera, C.,S., “Hair Saving Unhairing Process Part 2: Immunization Phenomenon”, Journal of the Society of Leather Technologists and Chemist , Vol. 85, p:47.
  • 12. Turkish Standard, 2006, TS EN ISO 2418, “Leather-Chemical, Physical and Mechanical and Fastness Tests - Sampling Location.”
  • 13. Turkish Standard, 2006, TS 4119 EN ISO 3376, “Leather–Physical and Mechanical Tests - Determination of Tensile Strength and Percentage Extension”.
  • 14. Turkish Standard, 1985, TS 4134, “Leather-Determination of Nitrogen Content and Hide Substance" - Titrimetric Method.”
  • 15. Turkish Standard, 1985, TS 4126, “Leather-Determination of Chromic Oxide (Cr2O3).”
  • 16. Turkish Standard, 2006, TS EN ISO 2419, “Leather-Conditioning of Test Pieces for Physical Tests.”
  • 17. Şen, B., H., 2005, “Hücre Kültürü Teknolojisinde SEM Uygulamaları”, Ege Üniversitesi Bilim Tek. Araştırma ve Uygulama Merkezi (EBİLTEM), Bornova, İzmir- Türkiye
  • 18. Zengin, G., 2007, “An Investigation of Factors Caused Fatty Spue Appeared Leather Surfaces by Chromatographic Methods”, Doctoral Dissertation, Ege Univ. Graduate School of Natural and Applied Sciences, Bornova, Izmir-Turkey, p: 62-64.
  • 19. Çolak, S., 1999, “A Study on Comparative Research on Various Liming Processes in View of Environmental Pollution”, Doctoral Dissertation, Ege Univ. Graduate School of Natural and Applied Sciences, Turkey, p:75-76
  • 20. Turkish Standard, 2000, TS 2789 ISO 6060, Water quality- Determination of the chemical oxygen demand.
  • 21. Shi, B., Xingfang, L. and Sun, D., 2003, “Further Investigations of Oxidative Unhairing Using Hydrogen Peroxide”, Journal of the American Leather Chemist Association, Vol 98, p: 185-192.
  • 22. Anon., 1996, Acceptable Quality Standards In The Leather And Footwear Industry. General Studies Series, The United Nations Industrial Development Organization (UNIDO), ISBN: 92-1-106301-9.

USAGE OF HYDROGEN PEROXIDE IN LEATHER MANUFACTURING PROCESSES AND ITS EFFECTS ON LEATHER CHARACTERISTICS

Year 2010, Volume: 20 Issue: 3, 236 - 240, 01.12.2010

Abstract

In this study, hydrogen peroxide usage instead of sodium sulphide (Na2S) under alkaline condition in leather manufacturing was investigated, whether hydrogen peroxide could be an alternative to high pollutant conventional unhairing-liming process or not. Besides, the effect of hydrogen peroxide on leather properties and the pollution load of liming wastewater were studied. The results indicated that the unhairing and fiber opening performance of hydrogen peroxide were satisfactory and the physical characteristics of the leathers as well as the air permeability values were comparable to those obtained by conventional unhairing-liming process. In addition, the chemical oxygen demand (COD) and the sulfide values of the waste water were also lower than the conventional one

References

  • 1. Bitcover, J.,E., Cooper, J.E., Bailey, D.,G., 1980, “Pilot-Plant Study of Flocculation of Suspended Solids in Lime-Sulfide Unhairing Effluents”, Journal of the American Leather Chemist Association, Vol. 75, p:108-118.
  • 2. Thorstensen, T., C., 1993, Practical Leather Technology, Unhairing, p: 95, Fourth edition, Kieger Publishing Company, Malabar, Florida, ISBN 0-8946-689-3.
  • 3. Marsal, A., Morera, J.,M., Borras, M, D., 1999, “Study on a Unhairing Process with Hydrogen Peroxide and Amines”, Journal of the American Leather Chemist Association, Vol. 94, p:1-10.
  • 4. Şengül, F., Müezzinoğlu, A., 1993, Çevre Kimyası, Dokuz Eylül Üni. Mühendislik Fakültesi Basım Ünitesi, Bornova, İzmir
  • 5. Anon, 1991, Röhm and The Environment Leather, Vol. 193, No:4595.
  • 6. Anon, 1994, “Water Pollution and Automation”, Leather, p: 228-230.
  • 7. Marsal, A., Cot, J., Bartoli, E., 2000, “Oxidizing Unhairing Process with Hair Recovery”, Journal of the Society of Leather Technologists and Chemists, Vol.86, p: 30-33.
  • 8. Marmer, W. Et al., 2003, “Rapid Oxidative Unhairing with Alkaline Hydrogen Peroxide”, Journal of the American Leather Chemist Association, Vol.98.
  • 9. Morrera, J., M., Bartoli, E., Borras, M., D., 1997, “Liming Process Using Hydrogen Peroxide”, Journal of the Society of Leather Technologists and Chemists, p70-73.
  • 10. El Baba, H., A., M., Covington, A., D., Davighi, D., 1999, The Effects of Hair Shaving Unhairing Reactions: Part 1: Environmental Impact, Journal of the Society of Leather Technologists and Chemists, Vol. 83, p:200.
  • 11. Cantera, C.,S., “Hair Saving Unhairing Process Part 2: Immunization Phenomenon”, Journal of the Society of Leather Technologists and Chemist , Vol. 85, p:47.
  • 12. Turkish Standard, 2006, TS EN ISO 2418, “Leather-Chemical, Physical and Mechanical and Fastness Tests - Sampling Location.”
  • 13. Turkish Standard, 2006, TS 4119 EN ISO 3376, “Leather–Physical and Mechanical Tests - Determination of Tensile Strength and Percentage Extension”.
  • 14. Turkish Standard, 1985, TS 4134, “Leather-Determination of Nitrogen Content and Hide Substance" - Titrimetric Method.”
  • 15. Turkish Standard, 1985, TS 4126, “Leather-Determination of Chromic Oxide (Cr2O3).”
  • 16. Turkish Standard, 2006, TS EN ISO 2419, “Leather-Conditioning of Test Pieces for Physical Tests.”
  • 17. Şen, B., H., 2005, “Hücre Kültürü Teknolojisinde SEM Uygulamaları”, Ege Üniversitesi Bilim Tek. Araştırma ve Uygulama Merkezi (EBİLTEM), Bornova, İzmir- Türkiye
  • 18. Zengin, G., 2007, “An Investigation of Factors Caused Fatty Spue Appeared Leather Surfaces by Chromatographic Methods”, Doctoral Dissertation, Ege Univ. Graduate School of Natural and Applied Sciences, Bornova, Izmir-Turkey, p: 62-64.
  • 19. Çolak, S., 1999, “A Study on Comparative Research on Various Liming Processes in View of Environmental Pollution”, Doctoral Dissertation, Ege Univ. Graduate School of Natural and Applied Sciences, Turkey, p:75-76
  • 20. Turkish Standard, 2000, TS 2789 ISO 6060, Water quality- Determination of the chemical oxygen demand.
  • 21. Shi, B., Xingfang, L. and Sun, D., 2003, “Further Investigations of Oxidative Unhairing Using Hydrogen Peroxide”, Journal of the American Leather Chemist Association, Vol 98, p: 185-192.
  • 22. Anon., 1996, Acceptable Quality Standards In The Leather And Footwear Industry. General Studies Series, The United Nations Industrial Development Organization (UNIDO), ISBN: 92-1-106301-9.
There are 22 citations in total.

Details

Other ID JA88BC64AJ
Journal Section Articles
Authors

Gökhan Zengin This is me

Selime Menteş Çolak This is me

Hasan Özgünay This is me

Publication Date December 1, 2010
Submission Date December 1, 2010
Published in Issue Year 2010 Volume: 20 Issue: 3

Cite

APA Zengin, G., Çolak, S. M., & Özgünay, H. (2010). USAGE OF HYDROGEN PEROXIDE IN LEATHER MANUFACTURING PROCESSES AND ITS EFFECTS ON LEATHER CHARACTERISTICS. Textile and Apparel, 20(3), 236-240.

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