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IMPROVEMENT OF FLAME RETARDANT CHARACTERISTIC OF RAW SILK FABRIC

Year 2018, Volume: 28 Issue: 3, 199 - 206, 01.10.2018

Abstract

In this study, organophosphorus based flame retardant (FR) agent was used in pad-dry-cure-wash treatment in order to enhance the flame retardant characteristics of raw silk fabrics. Silk material is composed of two cores of fibrion surrounded by a layer of sericin which has to be removed from the whole before any chemical finishing treatment. In order to improve the poor wetting capability arising from hydrophobic character of raw silk fabric, degumming process has been widely used for a long time as a necessary process which consume high amount water, chemicals and energy while causing significant weight-loss after the treatment. In today’s conditions, water/chemical-saving methods take important part in textile finishing treatments because of environmental concerns. For this aim; lowtemperature plasma treatment with various gases at different exposure times in different exposure power were applied on some of the raw silk fabrics before FR finishing process while some of the raw silk fabrics were undergone through conventional degumming processes. Flame retardancy, hydrophilicty, weight losses of the samples were tested, respectively. Morphological analyses of samples were tested by SEM and chemical structures of the fabrics were analyzed by FTIR-ATR. According to LOI test results, it was determined that especially nitrogen plasma pre-treatment had a significant improvement in flame retardancy of raw silk fabric. It was concluded as an output of this study that plasma treatment as a pre-treatment improved the flame retardancy of raw silk fabrics and had a significant effect on increasing wettability properties of raw silk fabrics without the necessity of conventional degumming process. 

References

  • 1. Cheng, Xian-Wei, et al. 2018, "Flame retardant and hydrophobic properties of novel sol-gel derived phytic acid/silica hybrid organic-inorganic coatings for silk fabric." Applied Surface Science, 427, pp: 69-80.
  • 2. Zhang, Qiang-hua, et al. 2016,"Durable flame retardant finish for silk fabric using boron hybrid silica sol." Applied Surface Science, 387, pp: 446-453.
  • 3. Ömeroğulları, Z., and D.Kut. 2012, "Application of low-frequency oxygen plasma treatment to polyester fabric to reduce the amount of flame retardant agent." Textile Research Journal 82(6), pp: 613-621.
  • 4. Guan, Jin‐Ping, and Guo‐Qiang Chen. 2006, "Flame retardancy finish with an organophosphorus retardant on silk fabrics." Fire and Materials 30(6), pp: 415-424.
  • 5. Guan, J., & Chen, G. (2008). Flame resistant modification of silk fabric with vinyl phosphate. Fibers and Polymers, 9(4), 438.
  • 6. Long, Jia-Jie, et al. 2008, "Application of low-pressure plasma pretreatment in silk fabric degumming process." Plasma Chemistry and Plasma Processing, 28(6), pp: 701-713.
  • 7. Inbakumar, S. 2010, "Effect of plasma treatment on surface of protein fabrics." Journal of Physics: Conference Series. vol. 208(1) IOP Publishing, pp:1-11.
  • 8. Nultsch, Kira, and Oliver Germershaus, 2017,"Silk fibroin degumming affects scaffold structure and release of macromolecular drugs." European Journal of Pharmaceutical Sciences 106, pp: 254-261.
  • 9. Duran, K., et al., 2007, "İpek liflerindeki serisinin enzimatik olarak uzaklaştırılması.", Tekstil ve Konfeksiyon, 3(1), pp: 182-186.
  • 10. Duran K., Bozacı E., Karahan H. A., 2007, “Protein Esaslı Mamüllerin Enzimatik ÖnTerbiyesi”, Tekstil ve Konfeksiyon, 17(2), pp:187-192.
  • 11. Genç G., Bayraktar O., Başal G., 2009,“A Research On The Production Of Silk Sericin Powders By Using Spray Drying Method”, Tekstil ve Konfeksiyon, 19(4), pp: 273-279.
  • 12. Freddi, Giuliano, Raffaella Mossotti, and Riccardo Innocenti, 2003,"Degumming of silk fabric with several proteases." Journal of Biotechnology, 106(1),pp: 101-112.
  • 13. Gulrajani, M. L., et al. 2000,"Degumming of silk with lipase and protease."Indian Journal of Fibre & Textile Research, 25(1), pp: 69-74.
  • 14. Van der Merwe, Ismari, et al. 2017, "The physical fibre properties of Gonometapostica after degumming the cocoons with different methods." Journal of Consumer Sciences, 45, pp:1-11.
  • 15. Lee, Suhyun, and Chung Hee Park., 2017, "Influence of alkaline treatment on surface roughness and wetting properties of hydrophobized silk fabrics." Textile Research Journal, Vol. 88(7), pp: 777–789.
  • 16. More, Snehal V., SakalyaChavan, and Asmita A. Prabhune, 2018, "Silk Degumming and Utilization of Silk Sericin by Hydrolysis Using Alkaline Protease from Beauveria Sp.(MTCC 5184): A Green Approach." Journal of Natural Fibers, 15(3), pp: 373-383.
  • 17. Zhao, Zhi-Lin, et al. 2018, "Using of hydrated lime water as a novel degumming agent of silk and sericin recycling from wastewater." Journal of Cleaner Production, 172, pp: 2090-2096.
  • 18. Arami, Mokhtar, et al. 2007, "Degumming of Persian silk with mixed proteolytic enzymes." Journal of Applied Polymer Science 106(1), pp: 267-275.
  • 19. Gogoi, D., et al. 2011, "Enhancement of hydrophobicity and tensile strength of muga silk fiber by radiofrequency Ar plasma discharge." Applied Surface Science 258(1), pp: 126-135.
  • 20. Canal, C., et al. 2009, "Studies on antibacterial dressings obtained by fluorinated post-discharge plasma." International Journal of Pharmaceutics 367(1-2), pp: 155-161.
  • 21. Iriyama, Yu, et al. 2002, "Plasma treatment of silk fabrics for better dyeability." Journal of Photopolymer Science and Technology 15(2), pp: 299-306.
  • 22. Jeong, Lim, et al. 2009, "Plasma-treated silk fibroin nanofibers for skin regeneration." International Journal of Biological Macromolecules 44(3), pp: 222228.
  • 23. Ribeiro, Viviana P., et al. 2016, "Influence of different surface modification treatments on silk biotextiles for tissue engineering applications." Journal of Biomedical Materials Research Part B: Applied Biomaterials 104(3) pp: 496-507.
  • 24. Sargunamani, D., and N. Selvakumar, 2007, "Effects of ozone treatment on the properties of raw and degummed tassar silk fabrics." Journal of Applied Polymer Science 104(1) pp: 147-155.
  • 25. Navik, Rahul, et al. 2017, "Effect of dielectric barrier discharge parameters on properties of mulberry silk fibre." Indian Journal of Fibre& Textile Research (IJFTR) 42(4) pp: 391-398.
  • 26. Costa, T. H. C., et al. 2006, "Effects of gas composition during plasma modification of polyester fabrics." Journal of Materials Processing Technology 173(1), pp: 40-43.
Year 2018, Volume: 28 Issue: 3, 199 - 206, 01.10.2018

Abstract

References

  • 1. Cheng, Xian-Wei, et al. 2018, "Flame retardant and hydrophobic properties of novel sol-gel derived phytic acid/silica hybrid organic-inorganic coatings for silk fabric." Applied Surface Science, 427, pp: 69-80.
  • 2. Zhang, Qiang-hua, et al. 2016,"Durable flame retardant finish for silk fabric using boron hybrid silica sol." Applied Surface Science, 387, pp: 446-453.
  • 3. Ömeroğulları, Z., and D.Kut. 2012, "Application of low-frequency oxygen plasma treatment to polyester fabric to reduce the amount of flame retardant agent." Textile Research Journal 82(6), pp: 613-621.
  • 4. Guan, Jin‐Ping, and Guo‐Qiang Chen. 2006, "Flame retardancy finish with an organophosphorus retardant on silk fabrics." Fire and Materials 30(6), pp: 415-424.
  • 5. Guan, J., & Chen, G. (2008). Flame resistant modification of silk fabric with vinyl phosphate. Fibers and Polymers, 9(4), 438.
  • 6. Long, Jia-Jie, et al. 2008, "Application of low-pressure plasma pretreatment in silk fabric degumming process." Plasma Chemistry and Plasma Processing, 28(6), pp: 701-713.
  • 7. Inbakumar, S. 2010, "Effect of plasma treatment on surface of protein fabrics." Journal of Physics: Conference Series. vol. 208(1) IOP Publishing, pp:1-11.
  • 8. Nultsch, Kira, and Oliver Germershaus, 2017,"Silk fibroin degumming affects scaffold structure and release of macromolecular drugs." European Journal of Pharmaceutical Sciences 106, pp: 254-261.
  • 9. Duran, K., et al., 2007, "İpek liflerindeki serisinin enzimatik olarak uzaklaştırılması.", Tekstil ve Konfeksiyon, 3(1), pp: 182-186.
  • 10. Duran K., Bozacı E., Karahan H. A., 2007, “Protein Esaslı Mamüllerin Enzimatik ÖnTerbiyesi”, Tekstil ve Konfeksiyon, 17(2), pp:187-192.
  • 11. Genç G., Bayraktar O., Başal G., 2009,“A Research On The Production Of Silk Sericin Powders By Using Spray Drying Method”, Tekstil ve Konfeksiyon, 19(4), pp: 273-279.
  • 12. Freddi, Giuliano, Raffaella Mossotti, and Riccardo Innocenti, 2003,"Degumming of silk fabric with several proteases." Journal of Biotechnology, 106(1),pp: 101-112.
  • 13. Gulrajani, M. L., et al. 2000,"Degumming of silk with lipase and protease."Indian Journal of Fibre & Textile Research, 25(1), pp: 69-74.
  • 14. Van der Merwe, Ismari, et al. 2017, "The physical fibre properties of Gonometapostica after degumming the cocoons with different methods." Journal of Consumer Sciences, 45, pp:1-11.
  • 15. Lee, Suhyun, and Chung Hee Park., 2017, "Influence of alkaline treatment on surface roughness and wetting properties of hydrophobized silk fabrics." Textile Research Journal, Vol. 88(7), pp: 777–789.
  • 16. More, Snehal V., SakalyaChavan, and Asmita A. Prabhune, 2018, "Silk Degumming and Utilization of Silk Sericin by Hydrolysis Using Alkaline Protease from Beauveria Sp.(MTCC 5184): A Green Approach." Journal of Natural Fibers, 15(3), pp: 373-383.
  • 17. Zhao, Zhi-Lin, et al. 2018, "Using of hydrated lime water as a novel degumming agent of silk and sericin recycling from wastewater." Journal of Cleaner Production, 172, pp: 2090-2096.
  • 18. Arami, Mokhtar, et al. 2007, "Degumming of Persian silk with mixed proteolytic enzymes." Journal of Applied Polymer Science 106(1), pp: 267-275.
  • 19. Gogoi, D., et al. 2011, "Enhancement of hydrophobicity and tensile strength of muga silk fiber by radiofrequency Ar plasma discharge." Applied Surface Science 258(1), pp: 126-135.
  • 20. Canal, C., et al. 2009, "Studies on antibacterial dressings obtained by fluorinated post-discharge plasma." International Journal of Pharmaceutics 367(1-2), pp: 155-161.
  • 21. Iriyama, Yu, et al. 2002, "Plasma treatment of silk fabrics for better dyeability." Journal of Photopolymer Science and Technology 15(2), pp: 299-306.
  • 22. Jeong, Lim, et al. 2009, "Plasma-treated silk fibroin nanofibers for skin regeneration." International Journal of Biological Macromolecules 44(3), pp: 222228.
  • 23. Ribeiro, Viviana P., et al. 2016, "Influence of different surface modification treatments on silk biotextiles for tissue engineering applications." Journal of Biomedical Materials Research Part B: Applied Biomaterials 104(3) pp: 496-507.
  • 24. Sargunamani, D., and N. Selvakumar, 2007, "Effects of ozone treatment on the properties of raw and degummed tassar silk fabrics." Journal of Applied Polymer Science 104(1) pp: 147-155.
  • 25. Navik, Rahul, et al. 2017, "Effect of dielectric barrier discharge parameters on properties of mulberry silk fibre." Indian Journal of Fibre& Textile Research (IJFTR) 42(4) pp: 391-398.
  • 26. Costa, T. H. C., et al. 2006, "Effects of gas composition during plasma modification of polyester fabrics." Journal of Materials Processing Technology 173(1), pp: 40-43.
There are 26 citations in total.

Details

Primary Language English
Journal Section Articles
Authors

Zeynep Ömeroğulları Başyiğit

Publication Date October 1, 2018
Submission Date May 22, 2018
Acceptance Date September 5, 2018
Published in Issue Year 2018 Volume: 28 Issue: 3

Cite

APA Ömeroğulları Başyiğit, Z. (2018). IMPROVEMENT OF FLAME RETARDANT CHARACTERISTIC OF RAW SILK FABRIC. Textile and Apparel, 28(3), 199-206.

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