Research Article

IMPACTS OF NANOSCALE INCLUSIONS ON FIRE RETARDANCY, THERMAL STABILITY, AND MECHANICAL PROPERTIES OF POLYMERIC PVC NANOCOMPOSITES

Volume: 3 Number: 4 July 21, 2017
EN

IMPACTS OF NANOSCALE INCLUSIONS ON FIRE RETARDANCY, THERMAL STABILITY, AND MECHANICAL PROPERTIES OF POLYMERIC PVC NANOCOMPOSITES

Abstract

A number of different nanoscale inclusions including nanoclay, nanotalc, and graphene were incorporated with polyvinyl chloride (PVC), dispersed in N,N-Dimethylacetmide (DMAC) and cast in rectangular aluminum (Al) molds prior to the testing. The fire retardancy, thermal stability, and mechanical properties of the PVC nanocomposites were determined using the ASTM UL 94 standard, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and microtensile test units. Surface morphology studies of the resultant materials were also carried out using scanning electron microscopy (SEM). Test results showed that the fire retardancy, thermal stability, and mechanical properties of the PVC nanocomposites were significantly enhanced in the presence of nanoscale inclusions. Among the inclusions, graphene had the major impact on improving the physical properties, which may be because of its higher thermal conductivity, mechanical strength, size, and shape. Polymers have a wide range of applications in daily life, but they are highly flammable and mechanically not stable for different applications. This study has shown that the weakness of the PVC could be significantly enhanced by incorporating nanoscale inclusions for various industrial purposes.

Keywords

References

  1. [1] R. Horrocks and D. Price, Fire Retardant Materials, Woodhead Publishing Limited, England, 2001.
  2. [2] F. Laoutid, L. Bonnaud, M. Alexandre, J.-M. Lopez-Cuesta, and P. Dubois, “New Prospects in Flame Retardant Polymer Materials: From Fundamentals to Nanocomposites,” Materials Science and Engineering: R: Reports, 2009, Vol. 63(3), pp. 100–125.
  3. [3] T. Hull, A. A. Stec, and S. Nazare, “Fire Retardant Effects of Polymer Nanocomposites,” Journal of Nanoscience and Nanotechnology, 2009, Vol. 9(7), pp. 4478–4486.
  4. [4] Ghazinezami, A. Jabbarnia, S. Soltani, N. Nuraje, and R. Asmatulu, “Improving the Fire Retardancy of Polymeric Structures via Additions of Nanoclay and Graphene Nanoflakes,” The V International Workshop on Technology and New Materials for Industry, Environment and Health Protection, Issyk-Kul, Kyrgyzstan, September 16–18, 2013, 9 pages.
  5. [5] M. Alexandre and P. Dubois, “Polymer-Layered Silicate Nanocomposites: Preparation, Properties and Uses of a New Class of Materials,” Materials Science and Engineering: R: Reports, 2000, Vol. 28(1), pp. 1–63.
  6. [6] B.H. Cipiriano, T. Kashiwagi, S. R. Raghavan, Y. Yang, E. A. Grulke, K. Yamamoto, J. R. Sheilds, and J. F. Douglas, “Effects of Aspect Ratio of MWNT on the Flammability Properties of Polymer Nanocomposites,” Polymer, 2007, 48(20), pp. 6086–6096.
  7. [7] A.Ghazinezami, “Fire Retardancy, Thermal Stability and Mechanical Properties of Polymeric Based Nanocomposites,” M.S. Thesis, Wichita State University, December, 2013.
  8. [8] P. H. Nam, P. Maiti, M. Okamoto, T. Kotaka, N. Hasegawa, and A. Usuki, “A Hierarchical Structure and Properties of Intercalated Polypropylene/Clay Nanocomposites,” Polymer, 2001, Vol. 42(23), pp. 9633–9640.

Details

Primary Language

English

Subjects

Engineering

Journal Section

Research Article

Publication Date

July 21, 2017

Submission Date

May 10, 2016

Acceptance Date

August 23, 2016

Published in Issue

Year 2017 Volume: 3 Number: 4

APA
Asmatulu, R. (2017). IMPACTS OF NANOSCALE INCLUSIONS ON FIRE RETARDANCY, THERMAL STABILITY, AND MECHANICAL PROPERTIES OF POLYMERIC PVC NANOCOMPOSITES. Journal of Thermal Engineering, 3(4), 1308-1318. https://doi.org/10.18186/journal-of-thermal-engineering.330150
AMA
1.Asmatulu R. IMPACTS OF NANOSCALE INCLUSIONS ON FIRE RETARDANCY, THERMAL STABILITY, AND MECHANICAL PROPERTIES OF POLYMERIC PVC NANOCOMPOSITES. Journal of Thermal Engineering. 2017;3(4):1308-1318. doi:10.18186/journal-of-thermal-engineering.330150
Chicago
Asmatulu, Ramazan. 2017. “IMPACTS OF NANOSCALE INCLUSIONS ON FIRE RETARDANCY, THERMAL STABILITY, AND MECHANICAL PROPERTIES OF POLYMERIC PVC NANOCOMPOSITES”. Journal of Thermal Engineering 3 (4): 1308-18. https://doi.org/10.18186/journal-of-thermal-engineering.330150.
EndNote
Asmatulu R (July 1, 2017) IMPACTS OF NANOSCALE INCLUSIONS ON FIRE RETARDANCY, THERMAL STABILITY, AND MECHANICAL PROPERTIES OF POLYMERIC PVC NANOCOMPOSITES. Journal of Thermal Engineering 3 4 1308–1318.
IEEE
[1]R. Asmatulu, “IMPACTS OF NANOSCALE INCLUSIONS ON FIRE RETARDANCY, THERMAL STABILITY, AND MECHANICAL PROPERTIES OF POLYMERIC PVC NANOCOMPOSITES”, Journal of Thermal Engineering, vol. 3, no. 4, pp. 1308–1318, July 2017, doi: 10.18186/journal-of-thermal-engineering.330150.
ISNAD
Asmatulu, Ramazan. “IMPACTS OF NANOSCALE INCLUSIONS ON FIRE RETARDANCY, THERMAL STABILITY, AND MECHANICAL PROPERTIES OF POLYMERIC PVC NANOCOMPOSITES”. Journal of Thermal Engineering 3/4 (July 1, 2017): 1308-1318. https://doi.org/10.18186/journal-of-thermal-engineering.330150.
JAMA
1.Asmatulu R. IMPACTS OF NANOSCALE INCLUSIONS ON FIRE RETARDANCY, THERMAL STABILITY, AND MECHANICAL PROPERTIES OF POLYMERIC PVC NANOCOMPOSITES. Journal of Thermal Engineering. 2017;3:1308–1318.
MLA
Asmatulu, Ramazan. “IMPACTS OF NANOSCALE INCLUSIONS ON FIRE RETARDANCY, THERMAL STABILITY, AND MECHANICAL PROPERTIES OF POLYMERIC PVC NANOCOMPOSITES”. Journal of Thermal Engineering, vol. 3, no. 4, July 2017, pp. 1308-1, doi:10.18186/journal-of-thermal-engineering.330150.
Vancouver
1.Ramazan Asmatulu. IMPACTS OF NANOSCALE INCLUSIONS ON FIRE RETARDANCY, THERMAL STABILITY, AND MECHANICAL PROPERTIES OF POLYMERIC PVC NANOCOMPOSITES. Journal of Thermal Engineering. 2017 Jul. 1;3(4):1308-1. doi:10.18186/journal-of-thermal-engineering.330150

Cited By

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