Research Article
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Year 2017, , 1308 - 1318, 21.07.2017
https://doi.org/10.18186/journal-of-thermal-engineering.330150

Abstract

References

  • [1] R. Horrocks and D. Price, Fire Retardant Materials, Woodhead Publishing Limited, England, 2001.
  • [2] F. Laoutid, L. Bonnaud, M. Alexandre, J.-M. Lopez-Cuesta, and P. Dubois, “New Prospects in Flame Retardant Polymer Materials: From Fundamentals to Nanocomposites,” Materials Science and Engineering: R: Reports, 2009, Vol. 63(3), pp. 100–125.
  • [3] T. Hull, A. A. Stec, and S. Nazare, “Fire Retardant Effects of Polymer Nanocomposites,” Journal of Nanoscience and Nanotechnology, 2009, Vol. 9(7), pp. 4478–4486.
  • [4] Ghazinezami, A. Jabbarnia, S. Soltani, N. Nuraje, and R. Asmatulu, “Improving the Fire Retardancy of Polymeric Structures via Additions of Nanoclay and Graphene Nanoflakes,” The V International Workshop on Technology and New Materials for Industry, Environment and Health Protection, Issyk-Kul, Kyrgyzstan, September 16–18, 2013, 9 pages.
  • [5] M. Alexandre and P. Dubois, “Polymer-Layered Silicate Nanocomposites: Preparation, Properties and Uses of a New Class of Materials,” Materials Science and Engineering: R: Reports, 2000, Vol. 28(1), pp. 1–63.
  • [6] B.H. Cipiriano, T. Kashiwagi, S. R. Raghavan, Y. Yang, E. A. Grulke, K. Yamamoto, J. R. Sheilds, and J. F. Douglas, “Effects of Aspect Ratio of MWNT on the Flammability Properties of Polymer Nanocomposites,” Polymer, 2007, 48(20), pp. 6086–6096.
  • [7] A.Ghazinezami, “Fire Retardancy, Thermal Stability and Mechanical Properties of Polymeric Based Nanocomposites,” M.S. Thesis, Wichita State University, December, 2013.
  • [8] P. H. Nam, P. Maiti, M. Okamoto, T. Kotaka, N. Hasegawa, and A. Usuki, “A Hierarchical Structure and Properties of Intercalated Polypropylene/Clay Nanocomposites,” Polymer, 2001, Vol. 42(23), pp. 9633–9640.
  • [9] R. Verdejo, M. M. Bernal, L. J. Romasanta, and M. A. Lopez-Manchado, “Graphene Filled Polymer Nanocomposites,” Journal of Materials Chemistry, 2011, Vol. 21(10), pp. 3301–3310.
  • [10] Szentes, C. S. Varga, G. Horvath, Z. Konya, J. Szel, and A. Kukovecz, “Electrical Resistivity and Thermal Properties of Compatibilized Multi-Walled Carbon Nanotube/Polypropylene Composites,” eXPRESS Polymer Letters, 2012, Vol. 6(6), pp. 494–502.
  • [11] L. Wang, L. Zhang, and M. Tian, “Improved Polyvinylpyrrolidone (PVP)/Graphite Nanocomposites by Solution Compounding and Spray Drying,” Polymers for Advanced Technologies, 2012, Vol. 23(3), pp. 652–659.
  • [12] P. Estelle, S. Halelfadl, and T. Mare, “Thermal Conductivity of CNT Water based Nanofluids: Experminetal Trends and Models Overview,” Journal of Thermal Engineering, 2015, Vol. 1, pp. 381-390.
  • [13]W. S. Khan., R. Asmatulu., and M. Eltabey, “Electrical and Thermal Characterization of Electrospun PVP Nanocomposite Fibers,” Journal of Nanomaterials, 2013, Volume 2013, 9 pages.
  • [14] R. F. Zinati, M. R. Razfar, and H. Nazockdast, “Numerical and experimental investigation of FSP of PA 6/MWCNT composite,” Journal of Materials Processing Technology, 2014, Vol. 214, pp. 2300-2315. [15] S. Ramesh, G. B. Teh, R. Louh, Y. K. Hou, P. Y. Sin, and L. J. Yi, “Preparation and Characterization of Plasticized High Molecular Weight PVC-Based Polymer Electrolytes,” Indian Academy of Science, 2010, Vol. 35(1), pp. 87–95.
  • [16] M. Stephan, S. G Kumar, N. G. Renganathan, and M. A Kulandainathan, “Characterization of Poly(Vinylidene Fluoride–hexafluoropropylene) (PVdF–HFP) Electrolytes Complexed with Different Lithium Salts,” European Polymer Journal, 2005, Vol. 41, pp. 15–21.
  • [17] Hitachi High-Tech Dcience Corporation, Thermal Analysis of Polyvinyl Chloride, TA No. 65, 1995.
  • [18] M. Abu-Abdeen, “Static and Dynamic Mechanical Properties of Poly(Vinyl Chloride) Loaded with Aluminum Oxide Nanopowder,” Materials and Design, 2012, Vol. 33, pp. 523–528.
  • [19] W. B. Xu, Z. F. Zhou, M. L. Ge, and W. P. Pan, “Polyvinyl Chloride/Montmorillonite Nanocomposites: Glass Transition Temperature and Mechanical Properties,” Journal of Thermal Analysis and Calorimetry, 2004, Vol 78 (1), pp. 1–9.
  • [20] M. Polaskova, T. Sedlacek , A. Kharlamov, R. Pivokonsky, and P. Saha, “Polyvinylchloride Filled with Bismuth Oxychloride Powder,” Polymer Processing Society Conference,” Larnaca, Cyprus, 2009, p. 97–105.
  • [21] Chen, J.H., Gunes, F., Kim, B.H., and Lee, J.M. “Graphene and 2D Materials: From Synthesis to Applications,” Journal of Nanomaterials, 2016 (in press).
  • [22] B. Yin and M. Hakkarainen, “Flexible and Strong Ternary Blends of Poly(Vinyl Chloride), Poly(Butylene Adipate) and Nanoparticle-Plasticizers,” Material Chemistry and Physics, 2013, Vol.139(2-3) , pp.734–740.
  • [23] Liu, Y. F. Luo, Z. X. Jia, B. C. Zhong, S. Q. Li, B. C. Guo1, and D. M. Jia, “Enhancement of Mechanical Properties of Poly(Vinyl Chloride) with Polymethyl Methacrylate-grafted Halloysite Nanotube,” eXPRESS Polymer Letters, 2011, Vol.5(7), pp. 591–603.
  • [24] Ghazinezami, A. Jabbarnia, and R. Asmatulu, “Fire Retardancy of Polymeric Materials Incorporated with Nanoscale Inclusions,” ASME International Mechanical Engineering Congress and Exposition, San Diego, CA, November 15–21, 2013, 6 pages.
  • [25] M. Zhang, P. Ding, B. Qu, and A. Guan, “A new method to prepare flame retardant polymer composites,” Journal of Materials Processing Technology, 2012, Vol. 208, pp. 342-347. [26] A. Liu and L. A. Berglund, “Fire-Retardant and Ductile Clay Nanopaper Biocomposites Based on Montmorrilonite in Matrix of Cellulose Nanofibers and Carboxymethyl Cellulose,” European Polymer Journal, 2013, Vol. 49, pp. 940–949 . [27] W.S. Khan, R. Asmatulu, I. Ahmed, and T.S. Ravigururajan “Thermal Conductivities of Electrospun PAN and PVP Nanocomposite Fibers Incorporated with MWCNTs and NiZn Ferrite Nanoparticles,” International Journal of Thermal Sciences, 2013, Vol. 71, pp. 74-79.
  • [28] Y. Arao, Flame Retardancy of Polymer Nanocomposite, Springer, Switzerland, 2015.
  • [29] G. Beyer. “ Flame Retardancy of Nanocomposites – from Research to Technical Products,”Journal of Fire Science, Vol.5, 2005, pp.75-87.
  • [30] P. Estelle, S. Halelfadl, T. Mare, “Thermal Conductivity of CNT Water Based Nanofluids: Experimental Trends and Models Overview”, Journal of Thermal Engineering, Yildiz Technical University Press, Istanbul, Turkey, Vol. 1, Issue No. 2, pp. 381-390, April 2015.
  • [31] B. Decker, Y. Gan, S. Calderon, “Thermoelectric Properties of Bismuth Telluride Filled Silicone”, Journal of Thermal Engineering, Yildiz Technical University Press, Istanbul, Turkey, Vol. 1, Special Issue 3, No. 6, pp. 402-407, May, 2015.
  • [32] Uysal, “Relation Between Drill Bit Temperature And Chip Forms In Drilling Of Carbon Black Reinforced Polyamide”, Journal of Thermal Engineering, Yildiz Technical University Press, Istanbul, Turkey, Vol. 1, Special Issue 2, No. 7, pp. 655-658, February, 2015.

IMPACTS OF NANOSCALE INCLUSIONS ON FIRE RETARDANCY, THERMAL STABILITY, AND MECHANICAL PROPERTIES OF POLYMERIC PVC NANOCOMPOSITES

Year 2017, , 1308 - 1318, 21.07.2017
https://doi.org/10.18186/journal-of-thermal-engineering.330150

Abstract

A number of different
nanoscale inclusions including nanoclay, nanotalc, and graphene were
incorporated with polyvinyl chloride (PVC), dispersed in N,N-Dimethylacetmide
(DMAC) and cast in rectangular aluminum (Al) molds prior to the testing. The
fire retardancy, thermal stability, and mechanical properties of the PVC
nanocomposites were determined using the ASTM UL 94 standard, thermogravimetric
analysis (TGA), differential scanning calorimetry (DSC), and microtensile test
units. Surface morphology studies of the resultant materials were also carried
out using scanning electron microscopy (SEM). Test results showed that the fire
retardancy, thermal stability, and mechanical properties of the PVC
nanocomposites were significantly enhanced in the presence of nanoscale
inclusions. Among the inclusions, graphene had the major impact on improving
the physical properties, which may be because of its higher thermal
conductivity, mechanical strength, size, and shape. Polymers have a wide range of
applications in daily life, but they are highly flammable and mechanically not
stable for different applications. This study has shown that the weakness of
the PVC could be significantly enhanced by incorporating nanoscale inclusions
for various industrial purposes.

References

  • [1] R. Horrocks and D. Price, Fire Retardant Materials, Woodhead Publishing Limited, England, 2001.
  • [2] F. Laoutid, L. Bonnaud, M. Alexandre, J.-M. Lopez-Cuesta, and P. Dubois, “New Prospects in Flame Retardant Polymer Materials: From Fundamentals to Nanocomposites,” Materials Science and Engineering: R: Reports, 2009, Vol. 63(3), pp. 100–125.
  • [3] T. Hull, A. A. Stec, and S. Nazare, “Fire Retardant Effects of Polymer Nanocomposites,” Journal of Nanoscience and Nanotechnology, 2009, Vol. 9(7), pp. 4478–4486.
  • [4] Ghazinezami, A. Jabbarnia, S. Soltani, N. Nuraje, and R. Asmatulu, “Improving the Fire Retardancy of Polymeric Structures via Additions of Nanoclay and Graphene Nanoflakes,” The V International Workshop on Technology and New Materials for Industry, Environment and Health Protection, Issyk-Kul, Kyrgyzstan, September 16–18, 2013, 9 pages.
  • [5] M. Alexandre and P. Dubois, “Polymer-Layered Silicate Nanocomposites: Preparation, Properties and Uses of a New Class of Materials,” Materials Science and Engineering: R: Reports, 2000, Vol. 28(1), pp. 1–63.
  • [6] B.H. Cipiriano, T. Kashiwagi, S. R. Raghavan, Y. Yang, E. A. Grulke, K. Yamamoto, J. R. Sheilds, and J. F. Douglas, “Effects of Aspect Ratio of MWNT on the Flammability Properties of Polymer Nanocomposites,” Polymer, 2007, 48(20), pp. 6086–6096.
  • [7] A.Ghazinezami, “Fire Retardancy, Thermal Stability and Mechanical Properties of Polymeric Based Nanocomposites,” M.S. Thesis, Wichita State University, December, 2013.
  • [8] P. H. Nam, P. Maiti, M. Okamoto, T. Kotaka, N. Hasegawa, and A. Usuki, “A Hierarchical Structure and Properties of Intercalated Polypropylene/Clay Nanocomposites,” Polymer, 2001, Vol. 42(23), pp. 9633–9640.
  • [9] R. Verdejo, M. M. Bernal, L. J. Romasanta, and M. A. Lopez-Manchado, “Graphene Filled Polymer Nanocomposites,” Journal of Materials Chemistry, 2011, Vol. 21(10), pp. 3301–3310.
  • [10] Szentes, C. S. Varga, G. Horvath, Z. Konya, J. Szel, and A. Kukovecz, “Electrical Resistivity and Thermal Properties of Compatibilized Multi-Walled Carbon Nanotube/Polypropylene Composites,” eXPRESS Polymer Letters, 2012, Vol. 6(6), pp. 494–502.
  • [11] L. Wang, L. Zhang, and M. Tian, “Improved Polyvinylpyrrolidone (PVP)/Graphite Nanocomposites by Solution Compounding and Spray Drying,” Polymers for Advanced Technologies, 2012, Vol. 23(3), pp. 652–659.
  • [12] P. Estelle, S. Halelfadl, and T. Mare, “Thermal Conductivity of CNT Water based Nanofluids: Experminetal Trends and Models Overview,” Journal of Thermal Engineering, 2015, Vol. 1, pp. 381-390.
  • [13]W. S. Khan., R. Asmatulu., and M. Eltabey, “Electrical and Thermal Characterization of Electrospun PVP Nanocomposite Fibers,” Journal of Nanomaterials, 2013, Volume 2013, 9 pages.
  • [14] R. F. Zinati, M. R. Razfar, and H. Nazockdast, “Numerical and experimental investigation of FSP of PA 6/MWCNT composite,” Journal of Materials Processing Technology, 2014, Vol. 214, pp. 2300-2315. [15] S. Ramesh, G. B. Teh, R. Louh, Y. K. Hou, P. Y. Sin, and L. J. Yi, “Preparation and Characterization of Plasticized High Molecular Weight PVC-Based Polymer Electrolytes,” Indian Academy of Science, 2010, Vol. 35(1), pp. 87–95.
  • [16] M. Stephan, S. G Kumar, N. G. Renganathan, and M. A Kulandainathan, “Characterization of Poly(Vinylidene Fluoride–hexafluoropropylene) (PVdF–HFP) Electrolytes Complexed with Different Lithium Salts,” European Polymer Journal, 2005, Vol. 41, pp. 15–21.
  • [17] Hitachi High-Tech Dcience Corporation, Thermal Analysis of Polyvinyl Chloride, TA No. 65, 1995.
  • [18] M. Abu-Abdeen, “Static and Dynamic Mechanical Properties of Poly(Vinyl Chloride) Loaded with Aluminum Oxide Nanopowder,” Materials and Design, 2012, Vol. 33, pp. 523–528.
  • [19] W. B. Xu, Z. F. Zhou, M. L. Ge, and W. P. Pan, “Polyvinyl Chloride/Montmorillonite Nanocomposites: Glass Transition Temperature and Mechanical Properties,” Journal of Thermal Analysis and Calorimetry, 2004, Vol 78 (1), pp. 1–9.
  • [20] M. Polaskova, T. Sedlacek , A. Kharlamov, R. Pivokonsky, and P. Saha, “Polyvinylchloride Filled with Bismuth Oxychloride Powder,” Polymer Processing Society Conference,” Larnaca, Cyprus, 2009, p. 97–105.
  • [21] Chen, J.H., Gunes, F., Kim, B.H., and Lee, J.M. “Graphene and 2D Materials: From Synthesis to Applications,” Journal of Nanomaterials, 2016 (in press).
  • [22] B. Yin and M. Hakkarainen, “Flexible and Strong Ternary Blends of Poly(Vinyl Chloride), Poly(Butylene Adipate) and Nanoparticle-Plasticizers,” Material Chemistry and Physics, 2013, Vol.139(2-3) , pp.734–740.
  • [23] Liu, Y. F. Luo, Z. X. Jia, B. C. Zhong, S. Q. Li, B. C. Guo1, and D. M. Jia, “Enhancement of Mechanical Properties of Poly(Vinyl Chloride) with Polymethyl Methacrylate-grafted Halloysite Nanotube,” eXPRESS Polymer Letters, 2011, Vol.5(7), pp. 591–603.
  • [24] Ghazinezami, A. Jabbarnia, and R. Asmatulu, “Fire Retardancy of Polymeric Materials Incorporated with Nanoscale Inclusions,” ASME International Mechanical Engineering Congress and Exposition, San Diego, CA, November 15–21, 2013, 6 pages.
  • [25] M. Zhang, P. Ding, B. Qu, and A. Guan, “A new method to prepare flame retardant polymer composites,” Journal of Materials Processing Technology, 2012, Vol. 208, pp. 342-347. [26] A. Liu and L. A. Berglund, “Fire-Retardant and Ductile Clay Nanopaper Biocomposites Based on Montmorrilonite in Matrix of Cellulose Nanofibers and Carboxymethyl Cellulose,” European Polymer Journal, 2013, Vol. 49, pp. 940–949 . [27] W.S. Khan, R. Asmatulu, I. Ahmed, and T.S. Ravigururajan “Thermal Conductivities of Electrospun PAN and PVP Nanocomposite Fibers Incorporated with MWCNTs and NiZn Ferrite Nanoparticles,” International Journal of Thermal Sciences, 2013, Vol. 71, pp. 74-79.
  • [28] Y. Arao, Flame Retardancy of Polymer Nanocomposite, Springer, Switzerland, 2015.
  • [29] G. Beyer. “ Flame Retardancy of Nanocomposites – from Research to Technical Products,”Journal of Fire Science, Vol.5, 2005, pp.75-87.
  • [30] P. Estelle, S. Halelfadl, T. Mare, “Thermal Conductivity of CNT Water Based Nanofluids: Experimental Trends and Models Overview”, Journal of Thermal Engineering, Yildiz Technical University Press, Istanbul, Turkey, Vol. 1, Issue No. 2, pp. 381-390, April 2015.
  • [31] B. Decker, Y. Gan, S. Calderon, “Thermoelectric Properties of Bismuth Telluride Filled Silicone”, Journal of Thermal Engineering, Yildiz Technical University Press, Istanbul, Turkey, Vol. 1, Special Issue 3, No. 6, pp. 402-407, May, 2015.
  • [32] Uysal, “Relation Between Drill Bit Temperature And Chip Forms In Drilling Of Carbon Black Reinforced Polyamide”, Journal of Thermal Engineering, Yildiz Technical University Press, Istanbul, Turkey, Vol. 1, Special Issue 2, No. 7, pp. 655-658, February, 2015.
There are 29 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Articles
Authors

Ramazan Asmatulu

Publication Date July 21, 2017
Submission Date May 10, 2016
Published in Issue Year 2017

Cite

APA Asmatulu, R. (2017). IMPACTS OF NANOSCALE INCLUSIONS ON FIRE RETARDANCY, THERMAL STABILITY, AND MECHANICAL PROPERTIES OF POLYMERIC PVC NANOCOMPOSITES. Journal of Thermal Engineering, 3(4), 1308-1318. https://doi.org/10.18186/journal-of-thermal-engineering.330150
AMA Asmatulu R. IMPACTS OF NANOSCALE INCLUSIONS ON FIRE RETARDANCY, THERMAL STABILITY, AND MECHANICAL PROPERTIES OF POLYMERIC PVC NANOCOMPOSITES. Journal of Thermal Engineering. July 2017;3(4):1308-1318. doi:10.18186/journal-of-thermal-engineering.330150
Chicago Asmatulu, Ramazan. “IMPACTS OF NANOSCALE INCLUSIONS ON FIRE RETARDANCY, THERMAL STABILITY, AND MECHANICAL PROPERTIES OF POLYMERIC PVC NANOCOMPOSITES”. Journal of Thermal Engineering 3, no. 4 (July 2017): 1308-18. https://doi.org/10.18186/journal-of-thermal-engineering.330150.
EndNote Asmatulu R (July 1, 2017) IMPACTS OF NANOSCALE INCLUSIONS ON FIRE RETARDANCY, THERMAL STABILITY, AND MECHANICAL PROPERTIES OF POLYMERIC PVC NANOCOMPOSITES. Journal of Thermal Engineering 3 4 1308–1318.
IEEE R. Asmatulu, “IMPACTS OF NANOSCALE INCLUSIONS ON FIRE RETARDANCY, THERMAL STABILITY, AND MECHANICAL PROPERTIES OF POLYMERIC PVC NANOCOMPOSITES”, Journal of Thermal Engineering, vol. 3, no. 4, pp. 1308–1318, 2017, doi: 10.18186/journal-of-thermal-engineering.330150.
ISNAD Asmatulu, Ramazan. “IMPACTS OF NANOSCALE INCLUSIONS ON FIRE RETARDANCY, THERMAL STABILITY, AND MECHANICAL PROPERTIES OF POLYMERIC PVC NANOCOMPOSITES”. Journal of Thermal Engineering 3/4 (July 2017), 1308-1318. https://doi.org/10.18186/journal-of-thermal-engineering.330150.
JAMA Asmatulu R. IMPACTS OF NANOSCALE INCLUSIONS ON FIRE RETARDANCY, THERMAL STABILITY, AND MECHANICAL PROPERTIES OF POLYMERIC PVC NANOCOMPOSITES. Journal of Thermal Engineering. 2017;3:1308–1318.
MLA Asmatulu, Ramazan. “IMPACTS OF NANOSCALE INCLUSIONS ON FIRE RETARDANCY, THERMAL STABILITY, AND MECHANICAL PROPERTIES OF POLYMERIC PVC NANOCOMPOSITES”. Journal of Thermal Engineering, vol. 3, no. 4, 2017, pp. 1308-1, doi:10.18186/journal-of-thermal-engineering.330150.
Vancouver Asmatulu R. IMPACTS OF NANOSCALE INCLUSIONS ON FIRE RETARDANCY, THERMAL STABILITY, AND MECHANICAL PROPERTIES OF POLYMERIC PVC NANOCOMPOSITES. Journal of Thermal Engineering. 2017;3(4):1308-1.

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