REMOVAL of DYE POLLUTION by MODIFIED HALLOYSITE as ECO-FRIENDLY ADSORBENT

Yıl 2020, Cilt: 3 Sayı: 1, 47 - 56, 30.06.2020

Davut Laçin , Ayse Aroguz

Öz

In this study, the adsorption capacity of modified halloysite was systematically investigated with respect to temperature in a batch process. The halloysite mineral used in this work was alumina silicate mineral containing similarly structural layers. Halloysite mineral was obtained from Biga Peninsula, Western Anatolia. The characteristic properties of the modified halloysite were analyzed using X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR). The modification process of the halloysite was achieved using a Cetyltrimethylammonium bromide (CTAB) aqueous solution. Methyl orange was used as a model dye to find out the adsorptive percentage capacity of the modified halloysite. It was found that the adsorptive capacity of clay was increased by increasing the contact time and decreasing with temperature. The thermodynamic parameters as Gibbs Free Energy (ΔGo), Enthalpy (ΔHo), Entropy (ΔSo) changes were calculated and the results showed that adsorption is exothermic and spontaneous. The unmodified-clay was used to compare the adsorptive property of the modified-clay for the methyl orange adsorption. The modified halloysite showed a better adsorptive capacity than the untreated halloysite for the adsorption of methyl orange.

Anahtar Kelimeler

Adsorption, Halloysite, Methyl orange

Destekleyen Kurum

Istanbul University-Cerrahpasa

Proje Numarası

Project code: BAP-49753 (Project ID:2071).

Teşekkür

This work was supported by the Scientific Research Fund of the Istanbul University-Cerrahpaşa. Project code: BAP-49753 (Project ID:2071)

Kaynakça

• 1. Zhai, L., Bai, Z., Zhu, Y., Wang, B. and Luo, W., Fabrication of chitosan microspheres for efficient adsorption of methyl orange, Chinese J. Chem Eng, 2018, 26(3), pp.657-666.
• 2. Zhou, Y., Lu, J., Zhou, Y. and Liu, Y., Recent advances for dyes removal using novel adsorbents: A review, Environ Pollut, 2019, 252, pp.352-365.
• 3. Reck, I.M., Paixão, R.M., Bergamasco, R., Vieira, M.F. and Vieira, A.M.S., Removal of tartrazine from aqueous solutions using adsorbents based on activated carbon and Moringa oleifera seeds, J. Cleaner Production, 2018, 171, pp.85-97.
• 4. Sciascia, L., Casella,S., Cavallaro, G., Lazzara, G., Milioto, S., Princivalle, F. and Parisi, F., Olive mill wastewaters decontamination based on organo-nano-clay composites, Ceramics International, 2018, 45 (2), pp. 2751-2759.
• 5. Meenambal, T., Devi, D. and Begum, M., Colour removal from textile waste water using bioculture in continous mode, J.Environ Sci Eng, 2006, 48(4), pp.247-252.
• 6. Sharma, A., Syed, Z., Brighu, U., Bhushan Gupta A. and Ram, C., Adsorption of textile wastewater on alkali-activated sand, J Clean Prod, 2019, 220, pp.23-32.
• 7. Chaari, I., Fakhfakh, E., Medhioub M., Jamoussi, F., Comparative study on adsorption of cationic and anionic dyes by smectite rich natural clays, J Mol Struct, 2019, 1179, pp.672-677.
• 8. Miura A, Kubota T, Hamada K. and Hitomi T., Adsorption efficiency of natural materials for low-concentration cesium in solution, Water Sci Technol, 2016, 73(10), pp.2453-60.
• 9. Tariqul Islam, Md., Saenz-Arana, R., Hernandez, C., Guinto, T., Ahsan, A. Md., Bragg, D.T., Wang, H., Alvarado-Tenorio, B. and Noveron, J. C., Conversion of waste tire rubber into a high-capacity adsorbent for the removal of methylene blue, methyl orange, and tetracycline from water, J. Environ Chem Eng, 2018, 6 (2), pp.3070-3082. 10. Kyzas, G.Z., Christodoulou., E. and N. Bikiaris, D., Basic Dye Removal with Sorption onto Low-Cost Natural Textile Fibers, Process, 2018, 6, pp.1-18.
• 11. Sciascia, L., Casella, S., Cavallaro, G., Lazzara, G., Milioto, S., Princivalle, F. and Parisi, F., Olive mill wastewaters decontamination based on organo-nano-clay composites, Ceram Int, 2019, 45 (2), pp.2751-2759.
• 12. Labastida, E.S., Diaz-Nava, M. C., Illescas, J and Muro, C, Comparison of the Removal of an Anionic Dye from Aqueous Solutions by Adsorption with Organically Modified Clays and their Composites Water Aır Soıl Poll, 2019, 230:88.
• 13. Kausar, A., Iqbal, M., Javed, A., Aftab, K., Nazli, Z.H., Bhatti, H.N. and Nouren, S., Dyes adsorption using clay and modified clay: A review, J Mol Liq, 2018, pp.395-407.
• 14. Mukhopadhyaya, R., Bhadurib, D., Sarkar, B., Rusmin, R., Houe, D., Khanam, R., Sarkar, S., Biswas, J.K. Vithanage, M., Bhatnagar, A. and Ok, Y.S., Clay–polymer nanocomposites: Progress and challenges for use in sustainable water treatment, J Hazard Mater, 2020, 383, 121125.
• 15. Chen, Yu., Peng, J., Xiao, H., Peng, H., Bu, L., Pan, Z., He, Y., Chen, F., Wang, X. and Li, S., Adsorption behavior of hydrotalcite-like modified bentonite for Pb2+, Cu2+and methyl orange removal from water. Appl Surf Sci, 2017, (420), pp.773-781.
• 16. Kang, S., Quin, L., Zhao, Y., Wang, W., Zhang, T., Yang, L., Rao, F and Song, S., Enhanced removal of methyl orange on exfoliated montmorillonite/chitosan gel in presence of methylene blue. Chemosphere, 2020, 238, 124693, pp.1-7.
• 17. Saadat, S., Pandey, G., Tharmavaram, M., Braganza, V. and Rawtani, D., Nano-interfacial decoration of Halloysite Nanotubes for the development of antimicrobial nanocomposites, Adv Colloid Interfac, 2020, 275, 102063, pp.1-14.
• 18. Zhang, Yi., Tang, A., Yang, H. and Ouyang, J., Applications and interfaces of halloysite nanocomposites, Appl Clay Sci, 2016, 119, pp. 8-17.
• 19. Anastopoulos, I., Mittal, A., Usman, M., Mittal, J., Yu, G., Núñez-Delgado, A. and Kornaros, M., A review on halloysite-based adsorbents to remove pollutants in water and wastewater J Mol Liq, 2018, 2691, pp.855-868.
• 20. Zahidah, K.A. Kakooei, S., Ismail, M.C. and Raja, P.B., Halloysite nanotubes as nanocontainer for smart coating application: A review. Prog Org Coat, 2017, 111, pp.175-185.
• 21. Mahrez, N., Bendenia, S., Marouf-Khelifa, K., Batonneau-Gener, I. and Khelifa, A., Improving of the adsorption capacity of halloysite nanotubes intercalated with dimethyl sulfoxide. Compos Interface, 2015, 22 (6), pp.403–417.
• 22. Frost, R.L. and Vassalo, M.A., The Dehydroxylation of the Kaolinite Clay Minerals Using Infrared Emission Spectroscopy, Clay. Clay. Miner, 1996, 44(5), pp. 635-651.
• 23.Özcan, A., Öncü, E.M. and Özcan, A.S., Kinetics, isotherm and thermodynamic studies of adsorption of Acid Blue 193 from aqueous solutions onto natural sepiolite. Colloids and Surfaces A: Physicochem. Eng. Aspects, 2006 (277), pp.90-97.
• 24- Tehrani-Bagha, A.R., Nikkar, H., Mahmoodi, N.M., Markazi, M. and Menger, F.M., The sorption of cationic dyes onto kaolin: Kinetic, isotherm and thermodynamic studies. Desalination, 2011, 266 (1-3), pp. 274–280.
• 25- Gamoudi, S. and Srasra, E., Adsorption of organic dyes by HDPyş-modified clay: Effect of molecular structure on the adsorption. J Mol Struct, 2019,1193, pp.522-531.