VARIATION OF MAGNETIC PROPERTIES IN STRONTIUM MAGNET POWDERS WITH Sr/Fe RATIO
Yıl 2023,
Cilt: 6 Sayı: 1, 12 - 15, 30.06.2023
Sümran Bilgin
,
Sultan Öztürk
,
Kürşat İcin
Öz
In this our current research, the effect of Sr/Fe on the phase formation and magnetic properties of strontium hexaferrite powders synthesized by mechanochemical synthesis and heat-treated at 950°C for 1 hour under an open atmosphere was investigated. XRD patterns revealed that the primary phase in all powders was identified as the SrFe12O19 phase. The SEM image showed that the particles had a round morphology with partial agglomeration due to the reduction in particle size. The magnetic properties were found to be affected by Sr/Fe ratio. The (BH)max values increased from 0.35 MGOe to 3.11 MGOe as the Sr/Fe increased from 1:11.0 to 1:12.0. The presence of secondary phases such as α-Fe2O3 and SrO weakened the magnetic properties. The weight fraction of the SrO phase increased with a decrease in stoichiometry from 1:12 to 1:11, which correlated with the weakening of the magnetic properties. The study concludes that the Sr/Fe ratio between Sr/Fe is a critical parameter in determining the magnetic properties of strontium hexaferrite powders.
Destekleyen Kurum
TÜBİTAK
Teşekkür
The authors gratefully acknowledge the financial support provided by the Scientific and Technological Research Council of Turkey (TUBITAK) under Grant Nos. 119M111 and 2210455, as well as the Department of Scientific Research Project of Karadeniz Technical University under Grant Nos. FDK-2018-7685, FYL-2018-7227, and FBA-2019-8162.
Kaynakça
- Zhivulin, V.E., et al., Effect of configurational entropy on phase formation, structure, and magnetic properties of deeply substituted strontium hexaferrites, Ceramics International, 2023, 49(1):1069-1084
- Için, K., et al., Investigation of nano-crystaline strontium hexaferrite magnet powder from mill scale waste by the mechanochemical synthesis: Effect of the annealing temperature, Materials Chemistry and Physics, 2022. 290: 126513
- Darwish, M.A., et al., Heterovalent substituted BaFe12-xSnxO19 (0.1≤ x ≤1.2) M-type hexaferrite: Chemical composition, phase separation, magnetic properties and electrodynamics features. Journal of Alloys and Compounds, 2022, 896:163117
- Akhter, T., et al., Optimization of structural, electrical, and magnetic properties of ytterbium substituted W-type hexaferrite for multi-layer chip inductors, Ceramics International, 2022, 48(22):33177-33184
- Liu, R., et al., Magnetocrystalline anisotropy study of Co-substituted M-type strontium hexaferrite single crystals, Ceramics International, 2023, 49(2):1888-1895
- Garehbaghi, S., and Kianvash, A., Effect of various parameters on the microstructure and magnetic properties of sintered Sr-hexaferrite, Results in Physics, 2019, 12: 1559-1568
- Trusov, L.A., et al. Glass-Ceramic Synthesis of Cr-Substituted Strontium Hexaferrite Nanoparticles with Enhanced Coercivity, Nanomaterials, 2021, 11
- Marjeghal, M.A., Sedghi, A., and Baghshahi, S., Synergic effect of additives on the structure and properties of nano strontium hexaferrite synthesized via the gel combustion method, Materials Science and Engineering: B, 2022, 278: 115631
- Stingaciu, M., et al., High magnetic coercive field in Ca‐Al‐Cr substituted strontium hexaferrite. Journal of Alloys and Compounds, 2021, 883: 160768
- Kumar, A., et al., Lattice strain mediated structural and magnetic properties enhancement of strontium hexaferrite nanomaterials through controlled annealing. Physica B: Condensed Matter, 2021, 600: 412592
- Shoubak, W.M., et al., Controlling the physical properties of polyacrylonitrile by strontium hexaferrite nanoparticles, Polymer Bulletin, 2023
- Kim, C.S., and Yoon, S., Magnetic characterization of La3+ and Li1+ co-substituted M-type strontium hexaferrite, Aip Advances, 2023, 13(2)
- Elanthamilan, E., et al., Strontium hexaferrite microspheres: Synthesis, characterization and visible-light-driven photocatalytic activity towards the degradation of methylene blue dye, Optical Materials, 2023, 137
- Thakur, S., Raina, B., and Bamzai, K.K., Investigations on structural, spectroscopic and magnetic properties of yttrium barium orthoferrite and nickel doped strontium hexaferrite composites, Applied Physics a-Materials Science & Processing, 2022, 128(4)
- Shaterian, M., Mohammadi-Ganjgah, A., and Balaei, M., Synthesis of potential nanostructures based on strontium hexaferrite for electrochemical hydrogen storage, International Journal of Hydrogen Energy, 2022, 47(8): 5372-5379
- Mohammed, I., Mohammed, J., and Srivastava, A.K., Study of structural, morphological, optical bandgap and Urbach's tail of Ni2+ substituted Co2Y-type strontium hexaferrite. Materials Today-Proceedings, 2022, 62: 6634-6640
- Garcia-Martin, E., et al., Dense strontium hexaferrite-based permanent magnet composites assisted by cold sintering process. Journal of Alloys and Compounds, 2022, 917
- Tiwary, R., Narayan, S., and Pandey, O., Preparation of strontium hexaferrite magnets from celestite and blue dust by mechanochemical route. J Journal of Mining Metallurgy, Section B: Metallurgy, 2008, 44(1): 91-100
- Mordina, B., et al., Impact of graphene oxide on the magnetorheological behaviour of BaFe12O19 nanoparticles filled polyacrylamide hydrogel, 2016, 97: 258-272
- Palomino, R.L., et al., Sonochemical assisted synthesis of SrFe12O19 nanoparticles, Ultrason Sonochem, 2016, 29: 470-5
- Luo, J., Preparation of strontium ferrite powders by mechanochemical process, in Applied Mechanics and Materials. 2012, 1736-1740
Yıl 2023,
Cilt: 6 Sayı: 1, 12 - 15, 30.06.2023
Sümran Bilgin
,
Sultan Öztürk
,
Kürşat İcin
Kaynakça
- Zhivulin, V.E., et al., Effect of configurational entropy on phase formation, structure, and magnetic properties of deeply substituted strontium hexaferrites, Ceramics International, 2023, 49(1):1069-1084
- Için, K., et al., Investigation of nano-crystaline strontium hexaferrite magnet powder from mill scale waste by the mechanochemical synthesis: Effect of the annealing temperature, Materials Chemistry and Physics, 2022. 290: 126513
- Darwish, M.A., et al., Heterovalent substituted BaFe12-xSnxO19 (0.1≤ x ≤1.2) M-type hexaferrite: Chemical composition, phase separation, magnetic properties and electrodynamics features. Journal of Alloys and Compounds, 2022, 896:163117
- Akhter, T., et al., Optimization of structural, electrical, and magnetic properties of ytterbium substituted W-type hexaferrite for multi-layer chip inductors, Ceramics International, 2022, 48(22):33177-33184
- Liu, R., et al., Magnetocrystalline anisotropy study of Co-substituted M-type strontium hexaferrite single crystals, Ceramics International, 2023, 49(2):1888-1895
- Garehbaghi, S., and Kianvash, A., Effect of various parameters on the microstructure and magnetic properties of sintered Sr-hexaferrite, Results in Physics, 2019, 12: 1559-1568
- Trusov, L.A., et al. Glass-Ceramic Synthesis of Cr-Substituted Strontium Hexaferrite Nanoparticles with Enhanced Coercivity, Nanomaterials, 2021, 11
- Marjeghal, M.A., Sedghi, A., and Baghshahi, S., Synergic effect of additives on the structure and properties of nano strontium hexaferrite synthesized via the gel combustion method, Materials Science and Engineering: B, 2022, 278: 115631
- Stingaciu, M., et al., High magnetic coercive field in Ca‐Al‐Cr substituted strontium hexaferrite. Journal of Alloys and Compounds, 2021, 883: 160768
- Kumar, A., et al., Lattice strain mediated structural and magnetic properties enhancement of strontium hexaferrite nanomaterials through controlled annealing. Physica B: Condensed Matter, 2021, 600: 412592
- Shoubak, W.M., et al., Controlling the physical properties of polyacrylonitrile by strontium hexaferrite nanoparticles, Polymer Bulletin, 2023
- Kim, C.S., and Yoon, S., Magnetic characterization of La3+ and Li1+ co-substituted M-type strontium hexaferrite, Aip Advances, 2023, 13(2)
- Elanthamilan, E., et al., Strontium hexaferrite microspheres: Synthesis, characterization and visible-light-driven photocatalytic activity towards the degradation of methylene blue dye, Optical Materials, 2023, 137
- Thakur, S., Raina, B., and Bamzai, K.K., Investigations on structural, spectroscopic and magnetic properties of yttrium barium orthoferrite and nickel doped strontium hexaferrite composites, Applied Physics a-Materials Science & Processing, 2022, 128(4)
- Shaterian, M., Mohammadi-Ganjgah, A., and Balaei, M., Synthesis of potential nanostructures based on strontium hexaferrite for electrochemical hydrogen storage, International Journal of Hydrogen Energy, 2022, 47(8): 5372-5379
- Mohammed, I., Mohammed, J., and Srivastava, A.K., Study of structural, morphological, optical bandgap and Urbach's tail of Ni2+ substituted Co2Y-type strontium hexaferrite. Materials Today-Proceedings, 2022, 62: 6634-6640
- Garcia-Martin, E., et al., Dense strontium hexaferrite-based permanent magnet composites assisted by cold sintering process. Journal of Alloys and Compounds, 2022, 917
- Tiwary, R., Narayan, S., and Pandey, O., Preparation of strontium hexaferrite magnets from celestite and blue dust by mechanochemical route. J Journal of Mining Metallurgy, Section B: Metallurgy, 2008, 44(1): 91-100
- Mordina, B., et al., Impact of graphene oxide on the magnetorheological behaviour of BaFe12O19 nanoparticles filled polyacrylamide hydrogel, 2016, 97: 258-272
- Palomino, R.L., et al., Sonochemical assisted synthesis of SrFe12O19 nanoparticles, Ultrason Sonochem, 2016, 29: 470-5
- Luo, J., Preparation of strontium ferrite powders by mechanochemical process, in Applied Mechanics and Materials. 2012, 1736-1740