Research Article

The Effects of Hydroxyapatite on the Corrosion Behaviour of AZ Series Mg Alloys

Volume: 18 Number: 1 March 29, 2023
EN

The Effects of Hydroxyapatite on the Corrosion Behaviour of AZ Series Mg Alloys

Abstract

Metallic biomaterials are widely used in the orthopedic and dental applications owing to their advanced biocompatibility and sophisticated mechanical properties. Many studies are carried out to develop new alloys with high specific strength, high corrosion resistance and high biocompatibility as an alternative to present metallic biomaterials. Mg alloys are potential alloys as a biomaterial, especially because they have low density and high biocompatibility. However, especially the corrosion properties of Mg alloys need to be improved. In this study, the surfaces of AZ31, AZ61 and AZ91 alloys, which are promising as biomaterials, were coated with hydroxyapatite with high biocompatibility, and the effects of the bioceramics coatings on corrosion resistance were comprehensively investigated. Crack-free and porous surface morphologies were obtained in all bioceramic coatings and the presence of the coatings on the surfaces was supported by EDS analysis. As a result of the corrosion tests performed in SBF, it was determined that the AZ91 alloy had the highest corrosion resistance among the uncoated samples. The hydroxyapatite bioceramic coatings also improved the corrosion properties of all samples. However, among all samples, the highest corrosion resistance was obtained in the hydroxyapatite coated AZ91 alloy.

Keywords

References

  1. Hornberger H, Virtanen S, Boccaccini AR. Biomedical coatings on magnesium alloys–a review. Acta Biomater 2012; 8(7): 2442-2455.
  2. Manivasagam G, Dhinasekaran D, Rajamanickam A. Biomedical implants: corrosion and its prevention-a review. Recent Patents on Corrosion Science 2010; 2(1): 40-54.
  3. Jamesh MI, Wu G, Zhao Y, McKenzie DR, Bilek MM, Chu PK. Electrochemical corrosion behavior of biodegradable Mg–Y–RE and Mg–Zn–Zr alloys in Ringer’s solution and simulated body fluid. J Corros Sci Eng 2015; 91: 160-184.
  4. Razavi M., Fathi M. H., Meratian M. Microstructure, mechanical properties and bio-corrosion evaluation of biodegradable AZ91-FA nanocomposites for biomedical applications. Mater Sci Eng A 2010; 527(26): 6938-6944.
  5. Hiromoto S, Tomozawa M, Maruyama N. Fatigue property of a bioabsorbable magnesium alloy with a hydroxyapatite coating formed by a chemical solution deposition. J Mech Behav Biomed Mater 2013; 25; 1-10.
  6. Rončević IŠ, Grubač Z, Metikoš-Huković M. Electrodeposition of hydroxyapatite coating on AZ91D alloy for biodegradable implant application. Int J Electrochem Sci 2014; 9: 5907-5923.
  7. Hu J, Wang C, Ren WC, Zhang S, Liu F. Microstructure evolution and corrosion mechanism of dicalcium phosphate dihydrate coating on magnesium alloy in simulated body fluid. Mater Chem Phys 2010; 119(1-2): 294-298.
  8. Wang H, Guan S, Wang Y, Liu H, Wang H, Wang L, Reb C, Zhu S, Chen K. In vivo degradation behavior of Ca-deficient hydroxyapatite coated Mg–Zn–Ca alloy for bone implant application. Colloids Surf B 2011; 88(1): 254-259.

Details

Primary Language

English

Subjects

Engineering

Journal Section

Research Article

Publication Date

March 29, 2023

Submission Date

September 3, 2022

Acceptance Date

October 29, 2022

Published in Issue

Year 2023 Volume: 18 Number: 1

APA
Say, Y. (2023). The Effects of Hydroxyapatite on the Corrosion Behaviour of AZ Series Mg Alloys. Turkish Journal of Science and Technology, 18(1), 45-57. https://doi.org/10.55525/tjst.1170464
AMA
1.Say Y. The Effects of Hydroxyapatite on the Corrosion Behaviour of AZ Series Mg Alloys. TJST. 2023;18(1):45-57. doi:10.55525/tjst.1170464
Chicago
Say, Yakup. 2023. “The Effects of Hydroxyapatite on the Corrosion Behaviour of AZ Series Mg Alloys”. Turkish Journal of Science and Technology 18 (1): 45-57. https://doi.org/10.55525/tjst.1170464.
EndNote
Say Y (March 1, 2023) The Effects of Hydroxyapatite on the Corrosion Behaviour of AZ Series Mg Alloys. Turkish Journal of Science and Technology 18 1 45–57.
IEEE
[1]Y. Say, “The Effects of Hydroxyapatite on the Corrosion Behaviour of AZ Series Mg Alloys”, TJST, vol. 18, no. 1, pp. 45–57, Mar. 2023, doi: 10.55525/tjst.1170464.
ISNAD
Say, Yakup. “The Effects of Hydroxyapatite on the Corrosion Behaviour of AZ Series Mg Alloys”. Turkish Journal of Science and Technology 18/1 (March 1, 2023): 45-57. https://doi.org/10.55525/tjst.1170464.
JAMA
1.Say Y. The Effects of Hydroxyapatite on the Corrosion Behaviour of AZ Series Mg Alloys. TJST. 2023;18:45–57.
MLA
Say, Yakup. “The Effects of Hydroxyapatite on the Corrosion Behaviour of AZ Series Mg Alloys”. Turkish Journal of Science and Technology, vol. 18, no. 1, Mar. 2023, pp. 45-57, doi:10.55525/tjst.1170464.
Vancouver
1.Yakup Say. The Effects of Hydroxyapatite on the Corrosion Behaviour of AZ Series Mg Alloys. TJST. 2023 Mar. 1;18(1):45-57. doi:10.55525/tjst.1170464

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