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KLASİK ÇÖZÜCÜLERE BİR ALTERNATİF; İYONİK SIVILAR

Yıl 2010, Cilt: 11 Sayı: 2, 90 - 100, 05.08.2016

Öz

Organik reaksiyonlar genelde çözücü ortamında yapılır. Son yıllarda yeni bir çözücü sınıfı bulundu ve bunlar iyonik sıvı olarak adlandırılır. Bu çözücüler çoğunlukla oda sıcaklığında sıvıdırlar ve iyonik türlerden oluşurlar. Düşük buhar basınçları, mükemmel kimyasal ve termal kararlılıkları, potansiyel geri kazanımları ve tekrar kullanımları gibi dikkat çekici özelliklere sahiptirler. İyonik sıvılar geniş olarak araştırılmaktadır ve organik sentez, enzimatik kataliz, ayırma işlemleri vb. gibi uygulamalarda kullanılmaktadır. Bu derleme iyonik sıvılar hakkında genel bir bilgi vermektedir

Kaynakça

  •  ARMSTRONG DW, HE L, LIU YS. Examination of ionic liquids and their ınteraction with molecules, when used as stationary phases in gas chromatography. Anal. Chem. 71: 3873-3876, 1999.
  •  BERTHOD A, RUIZ-ANGEL MJ, CARDA-BROCH S. Ionic liquids in separation techniques, Journal of Chromatography A. 1184: 6–18, 2008.
  •  CHEN LQ. Fujishima A. An alternative ionic liquid based electrolyte for dye-sensitized solar cells. Photochem. Photobiol. Sci.3: 918–919, 2004
  •  CHUM HL, KOCH VR, MILLER LL, OSTERYOUNG RA. An electrochemical scrutiny of organometallic ıron complexes and hexamethylbenzene in a room temperature molten salt. J.Am.Chem.Soc. 97: 3264-3267, 1975.
  •  CHUNMING C, JINGWEN R, QIUNAN Y. Preparation of mesoporous titania particles using ionic liquid dissolving starch as templates. Rare Metals. 28(5): 434-438, 2009.
  •  DI NOTO V, NEGRO E, SANCHEZ JH, IOJOIU C. Structure-relaxation interplay of a new nanostructured membrane based on tetraethylammonium trifluoromethanesulfonate ionic liquid and neutralized nafion 117
  • for high- temperature fuel cells. J.Am.Chem.Soc. 132(7): 2183-2195, 2010.
  •  EARLE MJ, SEDDON KR. Ionic liquids. Green solvents for the future. Pure Appl. Chem. 72(7): 1391– 1398, 2000.
  •  FEHER E, MAJOR B, BELAFI-BAKO K, GUBICZA L. Semi-continuous enzymatic production and membrane assisted separation of isoamyl acetate in alcohol ionic liquid biphasic system. Desalination. 241: 8-13, 2009.
  •  GARCIA J, TORRECILLA JS, FERNANDEZ A, OLIET M, RODRIGUEZ F. (Liquid + liquid) equilibria in the binary systems (aliphatic, or aromatic hydrocarbons + 1-ethyl-3-methylimidazolium ethylsulfate, or 1-butyl-3-methylimidazolium methylsulfate ionic liquids). J. Chem. Thermodynamics. 42: 144–150, 2010.
  •  GONZALEZ EJ, CALVAR N, GOMEZ E, DOMINGUEZ A. Separation of benzene from alkanes using 1- ethyl-3-methylpyridinium ethylsulfate ionic liquid at several temperatures and atmospheric pressure: Effect of the size of the aliphatic hydrocarbons. J. Chem. Thermodynamics. 42: 104–109, 2010.
  •  GORDON CM, HOLBREY JD, KENNEDY AR, SEDDON KR. Ionic liquid crystals: Hexafluorophosphate salts. J. Mater. Chem. 8: 2627–2636, 1998.
  •  GUERFI A, DONTIGNY M, CHAREST P, PETITCLERC M, LAGACÉ M, VIJH A, ZAGHIB K. Improved electrolytes for Li-ion batteries: Mixtures of ionic liquid and organic electrolyte with enhanced safety and electrochemical performance. J.Power Sources. 195: 845–852, 2010.
  •  JAIN N, KUMAR A, CHAUHAN S, CHAUHAN SMS. Chemical and biochemical transformations in ionic liquids. Tetrahedron. 61: 1015–1060, 2005.
  •  JIMENEZ AE, BERMUDEZ MD. Ionic liquids as lubricants of titanium-steel contact. Part 2: Friction, wear and surface interactions at high temperature. Tribology Let. 37(2): 431-443, 2010.
  •  KESKİN S. Cleaning of contaminated soils using ionic liquids and supercritical carbon dioxide. Yüksek Lisans tezi, Boğaziçi University, 2006.
  •  MARSH KN, DEEV A, WU AC-T, TRAN E, KLAMT A. Room temperature ionic liquids as replacements for conventional solvents. Korean J. Chem. Eng. 19(3): 357-362, 2002.
  •  QINA W, LI SFY. Determination of ammonium and metal ions by capillary electrophoresis–potential gradient detection using ionic liquid as background electrolyte and covalent coating reagent. J. Chromatogr. A. 1048: 253–256, 2004.
  •  RESTOLHO J, MATA JL, SARAMAGO B. On the interfacial behavior of ionic liquids: Surface tensions and contact angles. J. Colloid Interface Sci. 340: 82–86, 2009.
  •  SEDDON, KR. Ionic Liquids for Clean Technology. J. Chem. T ech. Biotechnol. 68: 351-356, 1997.
  •  SMCIK M, KOGELNIG D, STOJANOVIC A, KORNER W, KRACHLER R, WALLNER G. Uranium extraction from aqueous solutions by ionic liquids. Applied Radiation and Isotopes. 67: 2146–2149, 2009.
  •  WALDEN P. Bull.Acad.Imper.Sci.(St.Peterburg). 1800, 1914.  WELTON T. Room-temperature ionic liquids. Solvents for synthesis and catalysis. Chem. Rev. 99: 2071- 2083, 1999.
  •  WILKES JS, LEVISKY JA, WILSON RA, HUSSEY CL. Inorg.Chem. 21: 1236-1264, 1982.
  •  WILKES, J.S. A short history of ionic liquids—from molten salts to neoteric solvents, Green Chemistry. 4: 73–80, 2002.
  •  XIAOHUA X, LIANG Z, XIA L, SHENGXIANG J. Ionic liquids as additives in high performance liquid chromatography analysis of amines and the interaction mechanism of ionic liquids. Anal. Chim. Acta. 519: 207–211, 2004.
  •  XUE BF, WANG HX, HU YS, LI H, WANG ZX, MENG QB, HUANG XJ, SATO O, CHEN LQ.
  • FUJİSHİMA A. An alternative ionic liquid based electrolyte for dye-sensitized solar cells. Photochem. Photobiol. Sci.3: 918–919, 2004.
  •  ZHAO D, LIAO Y, ZHANG Z. Toxicity of Ionic Liquids. Clean. 35(1): 42–48, 2007.
  •  ZHAO H. Innovative applications of ionic liquids as ‘‘Green’’ engineering liquids. Chem. Eng. Comm. 193: 1660–1677, 2006.

A Alternative to Conventional Solvents; Ionic Liquids

Yıl 2010, Cilt: 11 Sayı: 2, 90 - 100, 05.08.2016

Öz

Organic reactions have usually been carried out in solvent medium. Recently, a new class of solvent has emerged and they are called ionic liquids. These solvents are often liquid at room temperature and consist of ionic species. They possess attractive properties such as negligible vapor pressure, excellent chemical and thermal stability, potential recoverability and recyclability. Ionic liquids are being intensively investigated and applications such as organic synthesis, enzymatic catalysis, separation processes, etc. were found. This review gives an overview about the ionic liquids

Kaynakça

  •  ARMSTRONG DW, HE L, LIU YS. Examination of ionic liquids and their ınteraction with molecules, when used as stationary phases in gas chromatography. Anal. Chem. 71: 3873-3876, 1999.
  •  BERTHOD A, RUIZ-ANGEL MJ, CARDA-BROCH S. Ionic liquids in separation techniques, Journal of Chromatography A. 1184: 6–18, 2008.
  •  CHEN LQ. Fujishima A. An alternative ionic liquid based electrolyte for dye-sensitized solar cells. Photochem. Photobiol. Sci.3: 918–919, 2004
  •  CHUM HL, KOCH VR, MILLER LL, OSTERYOUNG RA. An electrochemical scrutiny of organometallic ıron complexes and hexamethylbenzene in a room temperature molten salt. J.Am.Chem.Soc. 97: 3264-3267, 1975.
  •  CHUNMING C, JINGWEN R, QIUNAN Y. Preparation of mesoporous titania particles using ionic liquid dissolving starch as templates. Rare Metals. 28(5): 434-438, 2009.
  •  DI NOTO V, NEGRO E, SANCHEZ JH, IOJOIU C. Structure-relaxation interplay of a new nanostructured membrane based on tetraethylammonium trifluoromethanesulfonate ionic liquid and neutralized nafion 117
  • for high- temperature fuel cells. J.Am.Chem.Soc. 132(7): 2183-2195, 2010.
  •  EARLE MJ, SEDDON KR. Ionic liquids. Green solvents for the future. Pure Appl. Chem. 72(7): 1391– 1398, 2000.
  •  FEHER E, MAJOR B, BELAFI-BAKO K, GUBICZA L. Semi-continuous enzymatic production and membrane assisted separation of isoamyl acetate in alcohol ionic liquid biphasic system. Desalination. 241: 8-13, 2009.
  •  GARCIA J, TORRECILLA JS, FERNANDEZ A, OLIET M, RODRIGUEZ F. (Liquid + liquid) equilibria in the binary systems (aliphatic, or aromatic hydrocarbons + 1-ethyl-3-methylimidazolium ethylsulfate, or 1-butyl-3-methylimidazolium methylsulfate ionic liquids). J. Chem. Thermodynamics. 42: 144–150, 2010.
  •  GONZALEZ EJ, CALVAR N, GOMEZ E, DOMINGUEZ A. Separation of benzene from alkanes using 1- ethyl-3-methylpyridinium ethylsulfate ionic liquid at several temperatures and atmospheric pressure: Effect of the size of the aliphatic hydrocarbons. J. Chem. Thermodynamics. 42: 104–109, 2010.
  •  GORDON CM, HOLBREY JD, KENNEDY AR, SEDDON KR. Ionic liquid crystals: Hexafluorophosphate salts. J. Mater. Chem. 8: 2627–2636, 1998.
  •  GUERFI A, DONTIGNY M, CHAREST P, PETITCLERC M, LAGACÉ M, VIJH A, ZAGHIB K. Improved electrolytes for Li-ion batteries: Mixtures of ionic liquid and organic electrolyte with enhanced safety and electrochemical performance. J.Power Sources. 195: 845–852, 2010.
  •  JAIN N, KUMAR A, CHAUHAN S, CHAUHAN SMS. Chemical and biochemical transformations in ionic liquids. Tetrahedron. 61: 1015–1060, 2005.
  •  JIMENEZ AE, BERMUDEZ MD. Ionic liquids as lubricants of titanium-steel contact. Part 2: Friction, wear and surface interactions at high temperature. Tribology Let. 37(2): 431-443, 2010.
  •  KESKİN S. Cleaning of contaminated soils using ionic liquids and supercritical carbon dioxide. Yüksek Lisans tezi, Boğaziçi University, 2006.
  •  MARSH KN, DEEV A, WU AC-T, TRAN E, KLAMT A. Room temperature ionic liquids as replacements for conventional solvents. Korean J. Chem. Eng. 19(3): 357-362, 2002.
  •  QINA W, LI SFY. Determination of ammonium and metal ions by capillary electrophoresis–potential gradient detection using ionic liquid as background electrolyte and covalent coating reagent. J. Chromatogr. A. 1048: 253–256, 2004.
  •  RESTOLHO J, MATA JL, SARAMAGO B. On the interfacial behavior of ionic liquids: Surface tensions and contact angles. J. Colloid Interface Sci. 340: 82–86, 2009.
  •  SEDDON, KR. Ionic Liquids for Clean Technology. J. Chem. T ech. Biotechnol. 68: 351-356, 1997.
  •  SMCIK M, KOGELNIG D, STOJANOVIC A, KORNER W, KRACHLER R, WALLNER G. Uranium extraction from aqueous solutions by ionic liquids. Applied Radiation and Isotopes. 67: 2146–2149, 2009.
  •  WALDEN P. Bull.Acad.Imper.Sci.(St.Peterburg). 1800, 1914.  WELTON T. Room-temperature ionic liquids. Solvents for synthesis and catalysis. Chem. Rev. 99: 2071- 2083, 1999.
  •  WILKES JS, LEVISKY JA, WILSON RA, HUSSEY CL. Inorg.Chem. 21: 1236-1264, 1982.
  •  WILKES, J.S. A short history of ionic liquids—from molten salts to neoteric solvents, Green Chemistry. 4: 73–80, 2002.
  •  XIAOHUA X, LIANG Z, XIA L, SHENGXIANG J. Ionic liquids as additives in high performance liquid chromatography analysis of amines and the interaction mechanism of ionic liquids. Anal. Chim. Acta. 519: 207–211, 2004.
  •  XUE BF, WANG HX, HU YS, LI H, WANG ZX, MENG QB, HUANG XJ, SATO O, CHEN LQ.
  • FUJİSHİMA A. An alternative ionic liquid based electrolyte for dye-sensitized solar cells. Photochem. Photobiol. Sci.3: 918–919, 2004.
  •  ZHAO D, LIAO Y, ZHANG Z. Toxicity of Ionic Liquids. Clean. 35(1): 42–48, 2007.
  •  ZHAO H. Innovative applications of ionic liquids as ‘‘Green’’ engineering liquids. Chem. Eng. Comm. 193: 1660–1677, 2006.
Toplam 29 adet kaynakça vardır.

Ayrıntılar

Diğer ID JA56AD67AS
Bölüm Makaleler
Yazarlar

Hakan Kolancılar Bu kişi benim

Yayımlanma Tarihi 5 Ağustos 2016
Yayımlandığı Sayı Yıl 2010 Cilt: 11 Sayı: 2

Kaynak Göster

APA Kolancılar, H. (2016). KLASİK ÇÖZÜCÜLERE BİR ALTERNATİF; İYONİK SIVILAR. Trakya Üniversitesi Fen Bilimleri Dergisi, 11(2), 90-100.
AMA Kolancılar H. KLASİK ÇÖZÜCÜLERE BİR ALTERNATİF; İYONİK SIVILAR. Trakya Univ J Sci. Ağustos 2016;11(2):90-100.
Chicago Kolancılar, Hakan. “KLASİK ÇÖZÜCÜLERE BİR ALTERNATİF; İYONİK SIVILAR”. Trakya Üniversitesi Fen Bilimleri Dergisi 11, sy. 2 (Ağustos 2016): 90-100.
EndNote Kolancılar H (01 Ağustos 2016) KLASİK ÇÖZÜCÜLERE BİR ALTERNATİF; İYONİK SIVILAR. Trakya Üniversitesi Fen Bilimleri Dergisi 11 2 90–100.
IEEE H. Kolancılar, “KLASİK ÇÖZÜCÜLERE BİR ALTERNATİF; İYONİK SIVILAR”, Trakya Univ J Sci, c. 11, sy. 2, ss. 90–100, 2016.
ISNAD Kolancılar, Hakan. “KLASİK ÇÖZÜCÜLERE BİR ALTERNATİF; İYONİK SIVILAR”. Trakya Üniversitesi Fen Bilimleri Dergisi 11/2 (Ağustos 2016), 90-100.
JAMA Kolancılar H. KLASİK ÇÖZÜCÜLERE BİR ALTERNATİF; İYONİK SIVILAR. Trakya Univ J Sci. 2016;11:90–100.
MLA Kolancılar, Hakan. “KLASİK ÇÖZÜCÜLERE BİR ALTERNATİF; İYONİK SIVILAR”. Trakya Üniversitesi Fen Bilimleri Dergisi, c. 11, sy. 2, 2016, ss. 90-100.
Vancouver Kolancılar H. KLASİK ÇÖZÜCÜLERE BİR ALTERNATİF; İYONİK SIVILAR. Trakya Univ J Sci. 2016;11(2):90-100.