Green Synthesis of ZSM-5-Like Material from Rice Husk: Structural and Morphological Characterization

Abstract

This study proposes the derivation of SiO2 from rice husk ash and reports the properties of in-house made zeolite ZSM-5, correlated with the commercial one. The rice husk ash is treated with an alkaline solution followed by hydrothermal treatment (850oC). The synthesized samples were characterized by XRF, XRD, FESEM and FTIR. The XRF analysis on the synthesized rice husk ash confirms the presence of 92% silica, while the XRD analysis shows the formation of amorphous structure and crystalline form it was observed the presence of crystalline silica in the form of cristobalite. in addition, the field-emission scanning electron microscope (FE-SEM), shows the presence of micro scale shapeless morphology and varying SiO2/Al2O3 molar ratios from 20 to 40, the cubic crystals appears zeolite-like material. Fourier transform infrared (FT-IR) appears to be a technique of the outcome of double-ring tetrahedral vibration and in-house zeolite prepared from the rice husk ash possesses the asymmetric stretching of the Si tetrahedral within the zeolite framework. It is inferred that the extraction of silica from raw rice husk is an economical and environmentally beneficial substitute. In addition, this novel approach proposes the development of green chemical techniques for ZSM-5 production from agricultural byproducts

Keywords

• Amorphous
• silica
• crystallization
• temperature
• hydrothermal treatment.

References

1. Sheldon, R. A. (2005). Green solvents for sustainable organic synthesis: state of the art. Green Chemistry, 7(5), 267-278.
2. Kumar, A., Sengupta, B., Dasgupta, D., Mandal, T., &Datta, S. (2016). Recovery of value added products from rice husk ash to explore an economic way for recycle and reuse of agricultural waste. Reviews in Environmental Science and Bio/Technology, 15, 47-65.
3. Li, Y., Li, L., & Yu, J. (2017). Applications of zeolites in sustainable chemistry. Chem, 3(6), 928-949.
4. Vasconcelos, A. A., Len, T., de Oliveira, A. D. N., Costa, A. A. F. D., Souza, A. R. D. S., Costa, C. E. F. D., ... &Nascimento, L. A. S. D. (2023). Zeolites: a theoretical and Practical Approach with uses in (Bio) Chemical processes. Applied Sciences, 13(3), 1897.
5. Ciriminna, R., &Pagliaro, M. (2022). Open challenges in sol–gel science and technology. Journal of Sol-Gel Science and Technology, 101(1), 29-36.
6. Li, R., Chong, S., Altaf, N., Gao, Y., Louis, B., & Wang, Q. (2019). Synthesis of ZSM-5/siliceous zeolite composites for improvement of hydrophobic adsorption of volatile organic compounds. Frontiers in chemistry, 7, 505.
7. Zhang, C., Li, S., & Bao, S. (2018). A facile and green method for the synthesis of hierarchical ZSM-5 zeolite aggregates from rice husk ash. Research on Chemical Intermediates, 44, 3581-3595.
8. Y Wu, Z., & M Wang, Y. (2014). Catalytic application of mesoporous ZSM-5 zeolite. Current Organic Chemistry, 18(10), 1305-1322.

9. Nguyen, D. K., Dinh, V. P., Nguyen, H. Q., & Hung, N. T. (2023). Zeolite ZSM‐5 synthesized from natural silica sources and its applications: a critical review. Journal of Chemical Technology & Biotechnology, 98(6), 1339-1355.
10. Malpani, S. K., &Goyal, D. (2023). Synthesis, analysis, and multi-faceted applications of solid wastes-derived silica nanoparticles: a comprehensive review (2010-2022). Enviromental science and pollution research, 30(11),28321-28343.
11. Yogesh, P., Chandramohan, D., Rajeswari, N., & Palani, S. (2023). Effect of Exhaust Gas Recirculation on a CRDI Engine fuelled with Biodiesel, Ethanol and Butanol. International Journal of Vehicle Structures & Systems (IJVSS), 15(3).
12. Al-Jubouri, S. M., Al-Jendeel, H. A., Rashid, S. A., & Al-Batty, S. (2022). Antibiotics adsorption from contaminated water by composites of ZSM-5 zeolite nanocrystals coated carbon. Journal of Water Process Engineering, 47, 102745.
13. Sheldon, R. A. (2005). Green solvents for sustainable organic synthesis: state of the art. Green Chemistry, 7(5), 267-278.
14. Sivalingam, S., & Sen, S. (2020). Rice husk ash derived nanocrystalline ZSM-5 for highly efficient removal of a toxic textile dye. Journal of Materials Research and Technology, 9(6), 14853-14864.
15. Madani, M., Hosny, S., Alshangiti, D. M., Nady, N., Alkhursani, S. A., Alkhaldi, H., &Gaber, G. A. (2022). Green synthesis of nanoparticles for varied applications: Green renewable resources and energy-efficient synthetic routes. Nanotechnology Reviews, 11(1), 731-759.
16. Sabarish, R., &Unnikrishnan, G. (2019). Synthesis, characterization and evaluations of micro/mesoporous ZSM-5 zeolite using starch as bio template. SN applied sciences, 1, 1-13.
17. Bangwar, D. K., Saand, A., Keerio, M. A., Soomro, M. A., & Bhatti, N. U. K. (2017). Development of an amorphous silica from rice husk waste. Engineering, Technology & Applied Science Research, 7(6), 2184-2188.
18. Yalcin, B. K., &Ipek, B. (2021). Fluoride-free synthesis of mesoporous [Al]-[B]-ZSM-5 using cetyltrimethylammonium bromide and methanol-to-olefin activity with high propene selectivity. Applied Catalysis A: General, 610, 117915.
19. Güler, Ö., Başgöz, Ö., & Yavuz, Ç. (2021). Production of new type insulation material: Expanded Perlite-Silica aerogel composite. Turkish Journal of Engineering, 5(3), 95-99.
20. Kadja, G. T., Azhari, N. J., Mukti, R. R., & Khalil, M. (2020). A mechanistic investigation of sustainable solvent-free, seed-directed synthesis of ZSM-5 zeolites in the absence of an organic structure-directing agent. ACS omega, 6(1), 925-933.
21. Kandula, M., Gutta, N., Aytam, H. P., Perupogu, V., Manda, K., &Akula, V. (2022). Rice Husk Ash Derived SiO2 for Template Free Synthesis of H-ZSM-5 Support for Ni Catalyst: Investigation on Non-Oxidative CH4 Cracking for Clean H2 Production. Catalysis Surveys from Asia, 26(4), 336-345.
22. Wang, Y. (2021). Synthesis of template-free ZSM-5 from rice husk ash at low temperatures and its CO2 adsorption performance. ACS omega, 6(5), 3961-3972.Jia, H., Du, T., Fang, X., Gong, H., Qiu, Z., Li, Y., &
23. Susana, I. G. B., & Alit, I. B. (2021). Rice husk as sustainable waste energy for small farmers-A review. World Journal of Advanced Engineering Technology and Sciences, 3(2), 001-006.
24. Selvanayagam, B. F., Palani, S., Gopi, P., Parthiban, G., Siranjeevi, R., & Jeyahar, P. S. (2023). Experimental Investigation in Performance Evaluation of Nano Additives Diesel Blend using Diesel Engine. International Journal of Vehicle Structures & Systems (IJVSS), 15(1).
25. Pandiangan, K. D., Simanjuntak, W., Hadi, S., Ilim, I., & Amrulloh, H. (2021). Physical characteristics and utilization of ZSM-5 prepared from rice husk silica and aluminum hydroxide as catalyst for transesterification of Ricinuscommunis oil. Materials Research Express, 8(6), 065506.
26. Ong, H. R., Iskandar, W. M. E., & Khan, M. M. R. (2019). Rice Husk Nanosilica Preparation and Its Potential Application as Nanofluids. In Engineered Nanomaterials-Health and Safety. IntechOpen.
27. Öztürk, O., & Türköz, M. (2022). Effect of silica fume on the undrained strength parameters of dispersive. Turkish Journal of Engineering, 6(4), 293-299.
28. YalÇin, B. K., & Ipek, B. (2020). One-step synthesis of hierarchical [B]-ZSM-5 using cetyltrimethylammonium bromide as mesoporogen. Turkish Journal of Chemistry, 44(3), 841-858.
29. Zhang, C., Li, S., & Bao, S. (2019). Sustainable synthesis of ZSM-5 zeolite from rice husk ash without addition of solvents. Waste and Biomass Valorization, 10, 2825-2835.
30. Khoshbin, R., & Karimzadeh, R. (2017). Synthesis of mesoporous ZSM-5 from rice husk ash with ultrasound assisted alkali-treatment method used in catalytic cracking of light naphtha. Advanced Powder Technology, 28(8), 1888-1897
31. Garba, J., Abd Wahid, S., Ahmad Hamdanı, M. S., Faruq Sadiq, T. (2024). Adsorption-desorption of glyphosate in tropical sandy soil exposed to burning or applied with agricultural waste. Turkish Journal of Engineering, 8(3), 469-482. https://doi.org/10.31127/tuje.1428763
32. Ali, I. O., Hassan, A. M., Shaaban, S. M., & Soliman, K. S. (2011). Synthesis and characterization of ZSM-5 zeolite from rice husk ash and their adsorption of Pb2+ onto unmodified and surfactant-modified zeolite. Separation and Purification Technology, 83, 38-44.