Mature petroleum hydrocarbons contamination in surface and subsurface waters of Kızılırmak Graben (Central Anatolia, Turkey): Geochemical evidence for a working petroleum system associated with a possible salt diapir

Year 2022, Volume: 6 Issue: 1, 1 - 15, 30.01.2022

Adil Özdemir , Yildiray Palabıyık , Atilla Karataş , Alperen Şahinoğlu

https://doi.org/10.31127/tuje.747379

Cited By: 5

Abstract

Salt formations exist in Kızılırmak Graben (Central Anatolia, Turkey), which consists of volcano-sedimentary units, and it was stated in previous studies that these formations have a diapiric structure. The adjacent basin, Ayhan Basin, contains bituminous shale and operated coal deposits. For this reason, in this study, it is aimed to investigate the oil and gas potential of the Kızılırmak Graben by conducting TPH (Total Petroleum Hydrocarbons) analysis on the samples taken from natural cold-water resources by making use of the thought that hydrocarbon generation may come into existence from those units in the Ayhan basin. As a consequence of the analyses performed, hydrocarbons have been brought into the open in all the water samples. The organic geochemical methods have been used to find out the source of hydrocarbons determined in the water resources. The disclosed n-alkane hydrocarbons are the mature petroleum hydrocarbons derived from peat/coal type organic matter (Type III kerogen, gas-prone). These mature hydrocarbon-rich waters can be regarded as evidence for the availability of a working hydrocarbon system associated with possible salt diapir identified by using gravity and magnetic data obtained from the investigation area.

Keywords

Kızılırmak Graben, Reservoir-targeted petroleum exploration, TPH in water analysis, Hydrocarbon-rich water, Salt dome

References

• ASTM D7678 - 11. Standard Test Method for Total Petroleum Hydrocarbons (TPH) in Water and Wastewater with Solvent Extraction using Mid-IR Laser Spectroscopy
• Aydın, A. (1997). Gravite verilerinin normalize edilmiş tamgradyan, varyasyon ve istatistik yöntemleri ile hidrokarbon açısından değerlendirilmesi, model çalışmalar ve Hasankale-Horasan (Erzurum) Havzasına uygulanması, PhD Thesis, Karadeniz Technical University, Trabzon, Turkey
• Aydın A (2005). Gravite anomalilerinın doğrudan yorum yöntemleri ile değerlendirilmesi: Hasankale - Horasan bölgesinden bir uygulama. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, 11(1), 95-102
• Akgün F, Olgun E, Kuşçu İ, Toprak V & Göncüoğlu M C (1995). Orta Anadolu Kristalen Kompleksinin “Oligo-Miyosen” örtüsünün stratigrafisi, çökelme ortamı ve gerçek yaşına ilişkin yeni bulgular. TPJD bülteni, 6(1), 51-68
• Banga T, Capuano R M & Bissada K K (2011). Petroleum generation in the southeast Texas basin: Implications for hydrocarbon occurrence at the South Liberty salt dome. AAPG Bulletin, 95(7), 1257-1291
• Barutoğlu Ö H (1961). Turkey salt deposits. Scientific Mining Journal, 1(2), 68-78
• Becker H (1956). Geology and Lignite Deposits of the Region Between Gülşehir and Hacıbektaş (West of Kayseri). Mineral Research and Exploration (MTA), Report No. 2578
• Beyer J, Jonsson G, Porte C, Krahn M M & Ariese F (2010). Analytical methods for determining metabolites of polycyclic aromatic hydrocarbon (PAH) pollutants in fish bile: A review. Environmental Toxicology and Pharmacology, 30(3), 224-244
• Bilginer Ö (1982). Geoelectric Survey of Tuzköy Rock Salt Mine (Nevşehir). Mineral Research and Exploration (MTA), Report No. 7270
• Blood M F (2001). Exploration for a frontier salt basin in Southwest Oman. The Leading Edge, 20(11), 1252-1259
• Bourbonniere R A & Meyers P A (1996). Sedimentary geolipid records of historical changes in the watersheds and productivities of lakes Ontario and Erie. Limnology and Oceanography, 41(2), 352-359
• Bray E E & Evans E D (1961). Distribution of n-paraffins as a clue to the recognition of source rocks. Geochimica et Cosmochimica Acta, 22(1), 2-15
• Bray E E & Evans E D (1965). Hydrocarbons in non-reservoir-rock source beds: Part 1. AAPG Bulletin, 49(3), 248-257
• Burkay İ & Önder İ (1986). Resistivity Survey of Tuzköy Rock Salt Mine (Nevşehir). Mineral Research and Exploration (MTA), Report No. 7875
• Constantino R R, Molina E C, de Souza I A & Vincentelli M G C (2019). Salt structures from inversion of residual gravity anomalies: application in Santos Basin, Brazil. Brazilian Journal of Geology, 49(1), DOI: 10.1590/2317-4889201920180087
• Cranwell P A, Eglinton G & Robinson N (1987). Lipids of aquatic organisms as potential contributors to lacustrine sediments-2. Organic Geochemistry, 11(6), 513-527
• Demircioğlu, R. (2014). Gülşehir-Özkonak (Nevşehir) çevresinde Kırşehir masifi ve örtü birimlerinin jeolojisi ve yapısal özellikleri. PhD Thesis, Selçuk University, Konya, Turkey
• Devi E A, Rachman F, Satyana A H, Fahrudin & Setyawan R (2018). Geochemistry of Mudi and Sukowati oils, East Java basin and their correlative source rocks: Biomarkers and isotopic characterisation. Proceedings, Indonesian Petroleum Association, Forty-Second Annual Convention & Exhibition, May 2018
• Didyk B M, Simoneit B R T, Brassel S C & Englington G (1978). Organic geochemical indicators of paleoenvironmental conditions of sedimentation. Nature, 272, 216-222
• Eke P O & Okeke F N (2016). Identification of hydrocarbon regions in Southern Niger Delta Basin of Nigeria from potential field data. International Journal of Scientific and Technology Research, 5(11), 96-99
• EPA Method 1664. Revision A: N-Hexane Extractable Material (HEM; Oil and Grease) and Silica Gel Treated N-Hexane Extractable Material (SGTHEM; Non-polar Material) by Extraction and Gravimetry.
• Erguvanlı K (1954). Geological Survey of the East of Kırşehir. Mineral Research and Exploration (MTA), Report No. 2373
• Eymold W K, Swana K, Moore M T, Whyte C J, Harkness J S, Talma S, Murray R, Moortgat J B, Miller J, Vengosh A & Darrah T H (2018). Hydrocarbon-rich groundwater above shale-gas formations: A Karoo basin case study. Groundwater, 56(2), 204-224
• Forster A, Sturt H & Meyers P A (2004). Molecular biogeochemistry of Cretaceous black shales from the Demerara Rise: Preliminary shipboard results from sites 1257 and 1258, Leg 207. in Erbacher, J., Mosher, D.C., Malone, M.J., et al., Proceedings of the Ocean Drilling Program, Initial Reports: 207, 1-22.
• Gadirov V G, Eppelbaum L V, Kuderavets R S, Menshov O I & Gadirov K V (2018). Indicative features of local magnetic anomalies from hydrocarbon deposits: examples from Azerbaijan and Ukraine. Acta Geophysica, 66(6), 1463-1483. DOI: 10.1007/s11600-018-0224-0
• Gadirov V G & Eppelbaum L V (2012). Detailed gravity, magnetics successful in exploring Azerbaijan onshore areas. Oil and Gas Journal, 110(11), 60-73
• Gadirov V G (1994). The physical-geological principles of application of gravity and magnetic prospecting in searching oil and gas deposits. Proceed. of 10th Petroleum Congress and Exhibition of Turkey, Ankara, 197-203
• Geist E L, Childs J R & Scholl D W (1987). “Evolution and petroleum geology of Amlia and Amukta intra-arc summit basins, Aleutian Ridge”. Marine and Petroleum Geology, 4(4), 334-352
• Goossens H, Duren C, De Leeuw J W & Schenck P A (1989). Lipids and their mode of occurrence in bacteria and sediments-2. Lipids in the sediment of a stratified, freshwater lake. Organic Geochemistry, 14(1), 27-41
• Griffin W R (1949). Residual gravity in theory and practice. Geophysics, 14(1), 39-58
• Gürbüz A, Saraç G & Yavuz N (2019). Paleoenvironments of the Cappadocia region during the Neogene and Quaternary, central Turkey. Mediterranean Geoscience Reviews, 1(2), 271-296.
• Hakimi M H, Al-Matary A M & Ahmed A (2018). Bulk geochemical characteristics and carbon isotope composition of oils from the Sayhut sub-basin in the Gulf of Aden with emphasis on organic matter input, age and maturity. Egyptian Journal of Petroleum, 27(3), 361-370
• Hartkopf-Fröder C, Kloppisch M, Mann U, Neumann-Mahlkau P, Schaefer R G & Wilkes H (2007). The end-Frasnian mass extinction in the Eifel Mountains, Germany: new insights from organic matter composition and preservation. Geological Society, London, Special Publications, 278(1), 173-196. DOI: 10.1144/SP278.8
• Hunt J M (1995). Petroleum Geochemistry and Geology. W.H. Freeman and Company, New York
• Inoue E (1967). Geology and Coal Reserves of Dadağı-Arafa Coal Field. Mineral Research and Exploration (MTA), Report No. 3948
• ISO 5667-3. Water Quality - Sampling - Part 3: Preservation and Handling of Water Samples.
• ISO 9377-2. Water Quality - Determination of Hydrocarbon Oil Index - Part 2: Method Using Solvent Extraction and Gas Chromatography.
• Ivakhnenko O P, Abirov R & Logvinenko A (2015). New method for characterisation of petroleum reservoir fluid-mineral deposits using magnetic analysis. Energy Procedia, 76, 454-462
• Jallouli C, Chikhaoui M, Braham A, Turki M M, Mickus K & Benassi R (2005). Evidence for Triassic salt domes in the Tunisian Atlas from gravity and geological data. Tectonophysics, 396, 209-225
• Karatas A, Ozdemir A & Sahinoglu A (2019). Investigation of Oil and Gas Potential of Karaburun Peninsula and Seferihisar Uplift (Western Anatolia) by Iodine Hydrogeochemistry and Total Petroleum Hydrocarbon (TPH) in Water Analysis. Marmara University, Project No (9505): SOS-A-100719-0267
• Kayakıran S (1979). Research and Exploration of Gülşehir Rock Salt Mine (Studies in 1977 and 1978). Mineral Research and Exploration (MTA), Report No. 6606
• Kayhan M (1976). Turkey Salt Inventory. Mineral Research and Exploration (MTA), Publication No: 164, 78
• Koçyiğit A & Doğan U (2016). Strike-slip neotectonic regime and related structures in the Cappadocia region: a case study in the Salanda basin, Central Anatolia, Turkey. Turkish Journal of Earth Sciences, 25(5), 393-417
• Kosaroglu S, Buyuksarac A & Aydemir A (2016). Modeling of shallow structures in the Cappadocia region using gravity and aeromagnetic anomalies. Journal of Asian Earth Sciences, 124, 214-226
• Kreuzer R L, Darrah T H, Grove B S, Moore M T, Warner N R, Eymold W K & Poreda R J (2018). Structural and hydrogeological controls on hydrocarbon and brine migration into drinking water aquifers in Southern New York. Groundwater, 56(2), 225-244
• Kroon J (2011). Biomarkers in the Lower Huron Shale (Upper Devonian) As Indicators of Organic Matter Source, Depositional Environment, and Thermal Maturity. MSc. Thesis, Clemson University, US.
• Larasati D, Suprayogi K & Akbar A (2016). Crude oil characterization of Tarakan basin: Application of biomarkers. The 9th International Conference on Petroleum Geochemistry in the Africa - Asia Region, Bandung, Indonesia, 15 -17 November 2016
• Lebküchner R F (1957). Geology of Kayseri and Avanos-Ürgüp-Boğazlıyan. Mineral Research and Exploration (MTA), Report No. 2656
• Liu S, Qi S, Luo Z, Liu F, Ding Y, Huang H, Chen Z & Cheng S (2018). The origin of high hydrocarbon groundwater in shallow Triassic aquifer in Northwest Guizhou, China. Environmental Geochemistry and Health, 40(1), 415-433
• Lyatsky H V, Thurston J B, Brown R J & Lyatsky V B (1992). Hydrocarbon exploration applications of potential field horizontal gradient vector maps. Canadian Society of Exploration Geophysicists Recorder, 17(9), 10-15
• Meyers P A & Ishiwatari R (1993). Lacustrine organic geochemistry-an overview of indicators of organic matter sources and diagenesis in lake sediments. Organic Geochemistry, 20(7), 867-900
• Mille G, Asia L, Guiliano M, Malleret L & Doumenq P (2007). Hydrocarbons in coastal sediments from the Mediterranean Sea (Gulf of Fos area, France). Marine Pollution Bulletin, 54(5), 566-575
• Ministry of Agriculture and Forestry of Turkey, 2004a. Surface Water Quality Regulation of Turkey, http://www.resmigazete.gov.tr/eskiler/2016/08/20160810-9.htm (Accessed 02 June 2020)
• Ministry of Agriculture and Forestry of Turkey, 2004b. Water Pollution Control Regulation of Turkey (in Turkish),http://www.mevzuat.gov.tr/Metin.Aspx? MevzuatKod=7.5.7221&MevzuatIliski=0&sourceXmlSearch= (Accessed 02 June 2020)
• MTA (General Directorate of Mineral Research and Exploration) (2002) Geological Map of Turkey: General Directorate of Mineral Research and Exploration Publication, scale 1/500,000, 18 sheets
• Nava-Flores M, Ortiz-Aleman C, Orozco-del-Castillo M G Urrutia-Fucugauchi J, Rodriguez-Castellanos A, Couder-Castañeda C & Trujillo-Alcantara A (2016). 3D gravity modeling of complex salt features in the Southern Gulf of Mexico. International Journal of Geophysics, 1702164, 12
• Nettleton L L (1976). Gravity and Magnetics in Oil Prospecting. McGraw-Hill
• Ogden DE, Sleep NH, (2011) Explosive eruption of coal and basalt and the end-Permian mass extinction. Earth, Atmospheric, and Planetary Sciences, 109(1): 59-62.
• Onojake M C, Osuji L C & Oforka N C (2013). Preliminary hydrocarbon analysis of crude oils from Umutu/Bomu fields, southwest Niger Delta, Nigeria. Egyptian Journal of Petroleum, 22(2), 217-224
• Ozdemir A (2018). Usage of the Total Petroleum Hydrocarbons (TPH) in water analysis for oil and gas exploration: First important results from Turkey. Journal of Engineering Sciences and Design, 6(4), 615-636
• Ozdemir A (2019a). Organic hydrogeochemical evidence of Hasanoğlan (Ankara) petroleum system. Pamukkale University Journal of Engineering Sciences, 25(6), 748-763
• Ozdemir A (2019b). Mature hydrocarbons-rich waters as geochemical evidence of working petroleum system of Mamak (Ankara) and potential trap area in the region. European Journal of Science and Technology, 17, 244-260
• Ozdemir A (2019c). Organic hydrogeochemical evidence of pre-Neogene petroleum system of the Buyuk Menderes graben and potential traps (Western Turkey). European Journal of Science and Technology, 16, 325-354
• Ozdemir A & Palabiyik Y (2019a). A review of Paleozoic - Miocene petroleum source rocks of Turkey by paleogeographic and paleotectonic data: New interpretations and major outcomes. 7th International Symposium on Academic Studies in Science, Engineering and Architecture Sciences, November 15-17, Ankara, Turkey, 689-725
• Ozdemir A & Palabiyik Y (2019b). A new approach to petroleum source rock occurrence: The relationships between petroleum source rock, ophiolites, mantle plume and mass extinction. IV. International Congress of Scientific and Professional Studies - Engineering (BILMES EN), November 07 - 10, Ankara, Turkey, 28-39
• Ozdemir A, Karataş A, Palabiyik Y, Yaşar E & Sahinoglu A (2020). Oil and gas exploration in Seferihisar Uplift (Western Turkey) containing an operable-size gold deposit: Geochemical evidence for the presence of a working petroleum system. Geomechanics and Geophysics for Geo-Energy and Geo-Resources, 6(1), DOI: 10.1007/s40948-020-00152-2
• Palabiyik Y, Ozdemir A & Sahinoglu A (2019). Investigation of Oil and Gas Potential of Uludag Massif (Northwestern Anatolia) by Iodine Hydrogeochemistry and Total Petroleum Hydrocarbon (TPH) in Water Analysis, Istanbul Technical University, Scientific Research Project, Project No: MAB-2019-42217, 76 p.
• Palabiyik Y & Ozdemir A (2020). Use of TPH (Total Petroleum Hydrocarbons) in water analysis for oil and gas exploration in Turkey: The case studies from Western, Northwestern and Central Anatolia regions and major outcomes. Turkey IV. Scientific and Technical Petroleum Congress, October 26-28, Ankara, Turkey (in press)
• Palabiyik Y, Ozdemir A, Karataş A & Özyağcı M (2020). Identification of Oil and Gas Potential of Kastamonu and Sinop and their Surroundings (Central Pontides) by Using Total Petroleum Hydrocarbons (TPH) in Water Analysis, Istanbul Technical University, Scientific Research Project, Project No: MGA-2020-42587 (continue)
• Pašteka R (2000). 2D semi-automated interpretation methods in gravimetry and magnetometry. Acta Geologica Universitatis Comeniana, 55, 5-50
• Peters K E, Walters C C & Moldowan J M (2005). The Biomarker Guide: Biomarkers and Isotopes in Petroleum Exploration and Earth History, Second Ed, Vol 2. Cambridge University Press
• Peters K E, Fraser T H, Amris W, Rustanto B & Hermanto E (1999). Geochemistry of crude oils from eastern Indonesia. AAPG Bulletin, 83, 1927-1942
• Peters K E & Moldowan J M (1993). The Biomarker Guide, Interpreting Molecular Fossils in Petroleum and Ancient Sediments. Englewood Cliffs, Jersey, Prentice Hall
• Pinto V, Casas A, Rivero L & Torne M (2005). 3D gravity modeling of the Triassic salt diapirs of the Cubeta Alavesa (northern Spain). Tectonophysics, 405, 65-75
• Piskarev A L & Tchernyshev M Y (1997). Magnetic and gravity anomaly patterns related to hydrocarbon fields in northern West Siberia. Geophysics, 62(3), 831-841
• Pourreza S & Hajizadeh F (2019). Simulation of a salt dome using 2D linear and nonlinear inverse modeling of residual gravity field data. Bulletin of the Mineral Research and Exploration, 160, 231-244
• Reul K (1954). Lignite occurrences around Kayseri. Mineral Research and Exploration (MTA), Report No. 2240
• Satyana A H (2015). Subvolcanic hydrocarbon prospectivity of Java: Opportunities and challenges. Proceedings, Indonesian Petroleum Association. Thirty-Ninth Annual Convention & Exhibition, May 2015. IPA15-G-105
• Sharma P V (1986). Geophysical Methods in Geology (2nd Edition). Elsevier
• Stadtler C, Fichler C, Hokstad K, Myrlund E A, Wienecke S & Fotland B (2014). Improved salt imaging in a basin context by high resolution potential field data: Nordkapp Basin, Barents Sea. Geophysical Prospecting, 2014, 62, 615-630
• Stephen O I & Iduma U (2018). Hydrocarbon potential of Nigeria’s Inland Basin: Case study of Afikpo basin. Journal of Applied Geology and Geophysics, 6(4), 1-24
• Svancara J (1983). Approximate method for direct interpretation of gravity anomalies caused by surface three‐dimensional geologic structures. Geophysics, 48(3), 361-366 https://doi.org/10.1190/1.1441474
• Svensen H, Fristad KE, Polozov AG, Planke S. (2015) Volatile generation and release from continental large igneous provinces. In: Schmidt, A., Fristad, K.E., and Elkins-Tanton, L.T., (Eds.), Volcanism and Global Environmental Change, Cambridge University Press, UK, https://doi.org/10.1017/CBO9781107415683.015
• Syaifudin M, Eddy A, Subroto E A, Noeradi D & Kesumajana A H P (2015). Characterızation and correlatıon study of source rocks and oils in Kuang area, South Sumatra basin: The potential of Lemat formation as hydrocarbon source rocks. Proceedings of Indonesian Petroleum Association, Thirty-Ninth Annual Convention & Exhibition, May 2015, IPA15-G-034
• Taka M, Dümenci S, Kalkan İ & Şener M (2004). Sedimentology and Coal Potential of Tertiary Cover of the Central Anatolian Crystalline Complex. Mineral Research and Exploration (MTA), Report No. 10722
• Tissot B P & Welte D H (1984). Petroleum Formation and Occurrence. Springer-Verlag
• Töpfer K D (1977). Improved technique for rapid interpretation of gravity anomalies caused by two-dimensional sedimentary basins. Journal of Geophysics, 43, 645-654
• Tran K L & Philippe B (1993). Oil and rock extract analysis. Applied Petroleum Geochemistry (M.L., Bordenave, ed.), p. 373-394
• Ünüçok C (1985). Geological Survey and Reserve Report of Tuzköy Rock Salt Mine (Nevşehir-Gülşehir), Mineral Research and Exploration (MTA), Report No. 7897
• Volkman J K & Maxwell J R (1986). Acyclic isoprenoids as biological markers. Biological Markers in the Sedimentary Record (R.B. Johns, eds.), Elsevier, New York; 1-42
• Waples D W (1985). Geochemistry in Petroleum Exploration. International Human Resources Development Corp., US.
• Wedding H (1967). A Coal Prospection in Dadağı (Nevşehir-Gülşehir). Mineral Research and Exploration (MTA), Report No. 3927
• Zemo D A & Foote G R (2003). The technical case eliminating the use of the TPH analysis in assessing and regulating dissolved petroleum hydrocarbons in groundwater. Ground Water Monitoring & Remediation, 23(3), 95-104
• Zheng Y Zhou W Meyers PA & Xie S. (2007) Lipid biomarkers in the Zoigê- Hongyuan peat deposit: Indicators of Holocene climate changes in West China. Organic Geochemistry, 38: 1927-1940.