Research Article
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Year 2025, Volume: 12 Issue: 2, 492 - 500, 16.04.2025
https://doi.org/10.30910/turkjans.1637779

Abstract

References

  • Anonymous, (2022). Zeolit. https://tr.wikipedia.org/wiki/Zeolit. (Access Date: 30.06.2022).
  • Akçakoca, F., & Gökalp, Z. (2020). Yapay Sulak Alanlarda Dolgu Malzemesi Seçimine Yönelik Kolon Test Çalışması. Türk Tarım ve Doğa Bilimleri Dergisi, 7(2), 402-410.
  • Asadi, F., Shariatmadari, H., Mirghaffari, N., 2008. Modification of rice hull and sawdust sorptive characteristics to remove heavy metals from synthetic solutions and wastewater. Journal of hazardous materials, 154(1-3), 451-458.
  • Bolger, P. F., & Stevens, M. A. (1999). Contamination of Australian groundwater systems with nitrate. Land & Water Resources Research & Development Corporation.
  • Chmielewská, E. (2014). Environmental zeolites and aqueous media: Examples of practical solutions. Bentham Science Publishers.
  • Cooper, P., Smith, M., & Maynard, H. (1997). The design and performance of a nitrifying vertical-flow reed bed treatment system. Water Science and Technology, 35(5), 215–221.
  • Dombush, J., (1989). Natural renovation of leachate-degraded groundwater in excavated ponds at a refuse landfill.‟ In. In: Hammer, D.A. (Ed.), Constructed Wetlands for Wastewater Treatment. Chelsea, Lewis, pp. 743–752.
  • DSİ, 2022. Ministry of Agriculture and Forestry of Türkiye, http://www.dsi.gov.tr/toprak-ve-su-kaynaklari (Access Date: 20.05.2022).
  • Dubowy, P. J., & Reaves, R. P. (1994). Constructed wetlands for animal waste management. Department of Forestry and Natural Resources, Purdue University.
  • EEA, (2006). European Environmental Agency. Priority issues of the Mediterranean environment. Report No 4/2006 Luksemburg ISBN 978-92-9167-370-4
  • EPA, (1993). Constructed wetlands for wastewater treatment and wildlife habitat: 17 Case Studies. EPA 832-R-93-005.
  • Valsami-Jones, E. (Ed.). (2004). Phosphorus in Environmental Technology. IWA publishing.
  • Gokalp, Z., & Taş, I. (2018). Constructed wetland technology for domestic wastewater treatment. Current Trends in Natural Sciences Vol, 7(14), 245-250.
  • IWMI, (2023). International Water Management Institute, https://www.iwmi.cgiar.org/ (Access Date: 12.06.2023)
  • Jiang, C., Jia, L., He, Y., Zhang, B., Kirumba, G., Xie, J., 2013. Adsorptive removal of phosphorus from aqueous solution using sponge iron and zeolite. Journal of colloid and interface science, 402, 246-252.
  • Kalderis, D., Bethanis, S., Paraskeva, P., & Diamadopoulos, E. (2008). Production of activated carbon from bagasse and rice husk by a single-stage chemical activation method at low retention times. Bioresource Technology, 99(15), 6809–6816.
  • Karapınar, N. (2009). Natural zeolite is used for phosphorus and ammonium removal from aqueous solutions. Journal of hazardous materials, 170(2-3), 1186-1191.
  • Kumar, A., (2022). Nitrogen removal performance of zeolite-pumice mixtures from wastewaters. Erciyes University, Graduate School of Natural and Applied Sciences, Master Thesis.
  • Lin, L., Wan, C., Lee, D. J., Lei, Z., & Liu, X. (2014). Ammonium assists orthophosphate removal from high-strength wastewaters by natural zeolite. Separation and purification technology, 133, 351-356.
  • Montalvo, S.J., Guerrero, L.E., Milán, Z., Borja, R., 2011. Nitrogen and phosphorus removal using a novel integrated natural zeolite and lime system. Journal of Environmental Science and Health, Part A, 46(12), 1385-1391.
  • MTA, (2021). General Directorate of Mineral Research and Exploration of Türkiye. https://www.mta.gov.tr/v3.0/bilgi-merkezi/zeolit. (Access Date: 30.06.2021)
  • Özkay, F., Kıran, S., Taş, İ., & Kuşvuran, Ş. (2014). Effects of copper, zinc, lead, and cadmium applied with irrigation water on some eggplant plant growth parameters and soil properties. Türk Tarım ve Doğa Bilimleri Dergisi, 1(3), 377-383.
  • Ping, N.I.N.G., Hans-Jörg, B.A.R.T., Bing, L.I., Xiwu, L.U., Zhang, Y., 2008. Phosphate removal from wastewater by model-La (III) zeolite adsorbents. Journal of Environmental Sciences, 20(6), 670-674.
  • Rezai, B., & Allahkarami, E. (2021). Wastewater treatment processes—techniques, technologies, challenges faced, and alternative solutions. In Soft computing techniques in solid waste and wastewater management (pp. 35-53). Elsevier.
  • Rivera, F., Warren, A., Curds, C. R., Robles, E., Gutierrez, A., Gallegos, E., & Calderón, A. (1997). Applying the root zone method to treat and reuse high-strength abattoir waste in Mexico. Water Science and Technology, 35(5), 271-278.
  • Schreijer, M., Kampf, R., Toet, S., & Verhoeven, J. (1997). Constructed wetlands are used to upgrade treated sewage effluents before discharge to natural surface water in Texel Island, The Netherlands—Pilot study. Water Science and Technology, 35(5), 231-237.
  • Shi, W., Fu, Y., Jiang, W., Ye, Y., Kang, J., Liu, D., & Xu, Z. (2019). Enhanced phosphate removal by zeolite loaded with Mg-Al–La ternary (hydro) oxides from aqueous solutions: performance and mechanism. Chemical Engineering Journal, 357, 33-44.
  • SKKY, (2004). Ministry of Environment, Urbanization and Climate Change of Türkiye, https://www.mevzuat.gov.tr/mevzuat?MevzuatNo=7221&MevzuatTur= 7&MevzuatTertip=5, (Access Date: 27.10.2021).
  • Spalding, R. F., & Exner, M. E. (1993). Occurrence of nitrate in groundwater—a review. Journal of Environmental Quality, 22(3), 392-402.
  • Trautmann, N. M., Martin, J. H., Porter, K. S., & Hawk, K. C. (2020). Artificial wetlands are used to treat municipal solid waste landfill leachate. In Constructed wetlands for wastewater treatment (pp. 245-251). CRC Press. TUIK, (2022). Turkish Statistical Institue, https://data.tuik.gov.tr/Kategori/Get Kategori?p=tarim-111&dil=1 (Access Date: 07.08.2022)
  • USEPA. (1988). Design Manual: Constructed Wetlands and Aquatic Plant Systems for Municipal Wastewater Treatment. Ohio, USA.
  • Uzun, O., Gokalp, Z., Irik, H. A., Varol, I. S., & Kanarya, F. O. (2021). Zeolite and pumice-amended mixtures to improve phosphorus removal efficiency of substrate materials from wastewater. Journal of Cleaner Production, 317, 128444.
  • Vera, I., Araya, F., Andrés, E., Sáez, K., & Vidal, G. (2014). Enhanced phosphorus removal from sewage in mesocosm-scale constructed wetland using zeolite as medium and artificial aeration. Environmental Technology, 35(13), 1639-1649.
  • Vo, P. T., Ngo, H. H., Guo, W., Zhou, J. L., Nguyen, P. D., Listowski, A., & Wang, X. C. (2014). A mini-review on the impacts of climate change on wastewater reclamation and reuse. Science of the Total Environment, 494, 9–17.
  • Yeoman, S., Stephenson, T., Lester, J. N., & Perry, R. (1988). The removal of phosphorus during wastewater treatment: a review. Environmental Pollution, 49(3), 183–233.

Phosphorus And Nitrogen Removal Performance Of Zeolite And Rice Husk From Wastewaters

Year 2025, Volume: 12 Issue: 2, 492 - 500, 16.04.2025
https://doi.org/10.30910/turkjans.1637779

Abstract

Nitrogen and phosphorus-rich wastewater effluents result in the eutrophication of water resources and threaten aquatic life. Therefore, aquatic life can be supported by wastewater treatment. In this study, filter column tests assessed the phosphorus and nitrogen removal performance of both zeolites, abundantly available in Türkiye, and rice husk, abundantly available waste material, from synthetic wastewaters. Materials were used alone and in mixtures (25:75, 50:50, and 75:25). Phosphorus and nitrogen solutions at different concentrations (0, 10, 25, and 50 mg L-1) pass through filter media at a flow rate of 5.0 mL/min. Effluent samples taken at the end of the 3rd, 6th, 12th, 24th, and 48th hours were subjected to pH, electrical conductivity (EC), total phosphorus (TP), and total nitrogen (TN) analyses. The highest nitrogen removal efficiency (75.1%) was achieved with 75:25 zeolite: rice husk mixture at the end of the 3rd hour from 10 mg L-1 influent concentration and the lowest with the same mixture at the end of the 48th hour from 50 mg L-1 influent concentration. The highest phosphorus removal efficiency (19.4%) was achieved with pure zeolite at the end of the 3rd hour from 10 mg L-1 influent concentration and the lowest (0.14%) with 25:75 zeolite: rice husk mixture at the end of the 48th hour from 50 mg L-1 influent concentration. Based on the present findings, it was concluded that rice husk further improved the nitrogen removal efficiency of zeolite.

References

  • Anonymous, (2022). Zeolit. https://tr.wikipedia.org/wiki/Zeolit. (Access Date: 30.06.2022).
  • Akçakoca, F., & Gökalp, Z. (2020). Yapay Sulak Alanlarda Dolgu Malzemesi Seçimine Yönelik Kolon Test Çalışması. Türk Tarım ve Doğa Bilimleri Dergisi, 7(2), 402-410.
  • Asadi, F., Shariatmadari, H., Mirghaffari, N., 2008. Modification of rice hull and sawdust sorptive characteristics to remove heavy metals from synthetic solutions and wastewater. Journal of hazardous materials, 154(1-3), 451-458.
  • Bolger, P. F., & Stevens, M. A. (1999). Contamination of Australian groundwater systems with nitrate. Land & Water Resources Research & Development Corporation.
  • Chmielewská, E. (2014). Environmental zeolites and aqueous media: Examples of practical solutions. Bentham Science Publishers.
  • Cooper, P., Smith, M., & Maynard, H. (1997). The design and performance of a nitrifying vertical-flow reed bed treatment system. Water Science and Technology, 35(5), 215–221.
  • Dombush, J., (1989). Natural renovation of leachate-degraded groundwater in excavated ponds at a refuse landfill.‟ In. In: Hammer, D.A. (Ed.), Constructed Wetlands for Wastewater Treatment. Chelsea, Lewis, pp. 743–752.
  • DSİ, 2022. Ministry of Agriculture and Forestry of Türkiye, http://www.dsi.gov.tr/toprak-ve-su-kaynaklari (Access Date: 20.05.2022).
  • Dubowy, P. J., & Reaves, R. P. (1994). Constructed wetlands for animal waste management. Department of Forestry and Natural Resources, Purdue University.
  • EEA, (2006). European Environmental Agency. Priority issues of the Mediterranean environment. Report No 4/2006 Luksemburg ISBN 978-92-9167-370-4
  • EPA, (1993). Constructed wetlands for wastewater treatment and wildlife habitat: 17 Case Studies. EPA 832-R-93-005.
  • Valsami-Jones, E. (Ed.). (2004). Phosphorus in Environmental Technology. IWA publishing.
  • Gokalp, Z., & Taş, I. (2018). Constructed wetland technology for domestic wastewater treatment. Current Trends in Natural Sciences Vol, 7(14), 245-250.
  • IWMI, (2023). International Water Management Institute, https://www.iwmi.cgiar.org/ (Access Date: 12.06.2023)
  • Jiang, C., Jia, L., He, Y., Zhang, B., Kirumba, G., Xie, J., 2013. Adsorptive removal of phosphorus from aqueous solution using sponge iron and zeolite. Journal of colloid and interface science, 402, 246-252.
  • Kalderis, D., Bethanis, S., Paraskeva, P., & Diamadopoulos, E. (2008). Production of activated carbon from bagasse and rice husk by a single-stage chemical activation method at low retention times. Bioresource Technology, 99(15), 6809–6816.
  • Karapınar, N. (2009). Natural zeolite is used for phosphorus and ammonium removal from aqueous solutions. Journal of hazardous materials, 170(2-3), 1186-1191.
  • Kumar, A., (2022). Nitrogen removal performance of zeolite-pumice mixtures from wastewaters. Erciyes University, Graduate School of Natural and Applied Sciences, Master Thesis.
  • Lin, L., Wan, C., Lee, D. J., Lei, Z., & Liu, X. (2014). Ammonium assists orthophosphate removal from high-strength wastewaters by natural zeolite. Separation and purification technology, 133, 351-356.
  • Montalvo, S.J., Guerrero, L.E., Milán, Z., Borja, R., 2011. Nitrogen and phosphorus removal using a novel integrated natural zeolite and lime system. Journal of Environmental Science and Health, Part A, 46(12), 1385-1391.
  • MTA, (2021). General Directorate of Mineral Research and Exploration of Türkiye. https://www.mta.gov.tr/v3.0/bilgi-merkezi/zeolit. (Access Date: 30.06.2021)
  • Özkay, F., Kıran, S., Taş, İ., & Kuşvuran, Ş. (2014). Effects of copper, zinc, lead, and cadmium applied with irrigation water on some eggplant plant growth parameters and soil properties. Türk Tarım ve Doğa Bilimleri Dergisi, 1(3), 377-383.
  • Ping, N.I.N.G., Hans-Jörg, B.A.R.T., Bing, L.I., Xiwu, L.U., Zhang, Y., 2008. Phosphate removal from wastewater by model-La (III) zeolite adsorbents. Journal of Environmental Sciences, 20(6), 670-674.
  • Rezai, B., & Allahkarami, E. (2021). Wastewater treatment processes—techniques, technologies, challenges faced, and alternative solutions. In Soft computing techniques in solid waste and wastewater management (pp. 35-53). Elsevier.
  • Rivera, F., Warren, A., Curds, C. R., Robles, E., Gutierrez, A., Gallegos, E., & Calderón, A. (1997). Applying the root zone method to treat and reuse high-strength abattoir waste in Mexico. Water Science and Technology, 35(5), 271-278.
  • Schreijer, M., Kampf, R., Toet, S., & Verhoeven, J. (1997). Constructed wetlands are used to upgrade treated sewage effluents before discharge to natural surface water in Texel Island, The Netherlands—Pilot study. Water Science and Technology, 35(5), 231-237.
  • Shi, W., Fu, Y., Jiang, W., Ye, Y., Kang, J., Liu, D., & Xu, Z. (2019). Enhanced phosphate removal by zeolite loaded with Mg-Al–La ternary (hydro) oxides from aqueous solutions: performance and mechanism. Chemical Engineering Journal, 357, 33-44.
  • SKKY, (2004). Ministry of Environment, Urbanization and Climate Change of Türkiye, https://www.mevzuat.gov.tr/mevzuat?MevzuatNo=7221&MevzuatTur= 7&MevzuatTertip=5, (Access Date: 27.10.2021).
  • Spalding, R. F., & Exner, M. E. (1993). Occurrence of nitrate in groundwater—a review. Journal of Environmental Quality, 22(3), 392-402.
  • Trautmann, N. M., Martin, J. H., Porter, K. S., & Hawk, K. C. (2020). Artificial wetlands are used to treat municipal solid waste landfill leachate. In Constructed wetlands for wastewater treatment (pp. 245-251). CRC Press. TUIK, (2022). Turkish Statistical Institue, https://data.tuik.gov.tr/Kategori/Get Kategori?p=tarim-111&dil=1 (Access Date: 07.08.2022)
  • USEPA. (1988). Design Manual: Constructed Wetlands and Aquatic Plant Systems for Municipal Wastewater Treatment. Ohio, USA.
  • Uzun, O., Gokalp, Z., Irik, H. A., Varol, I. S., & Kanarya, F. O. (2021). Zeolite and pumice-amended mixtures to improve phosphorus removal efficiency of substrate materials from wastewater. Journal of Cleaner Production, 317, 128444.
  • Vera, I., Araya, F., Andrés, E., Sáez, K., & Vidal, G. (2014). Enhanced phosphorus removal from sewage in mesocosm-scale constructed wetland using zeolite as medium and artificial aeration. Environmental Technology, 35(13), 1639-1649.
  • Vo, P. T., Ngo, H. H., Guo, W., Zhou, J. L., Nguyen, P. D., Listowski, A., & Wang, X. C. (2014). A mini-review on the impacts of climate change on wastewater reclamation and reuse. Science of the Total Environment, 494, 9–17.
  • Yeoman, S., Stephenson, T., Lester, J. N., & Perry, R. (1988). The removal of phosphorus during wastewater treatment: a review. Environmental Pollution, 49(3), 183–233.
There are 35 citations in total.

Details

Primary Language English
Subjects Irrigation Water Quality
Journal Section Research Article
Authors

Yusuf Can Aşık 0009-0008-9892-1444

Hasan Ali Irık 0000-0002-3141-0948

Publication Date April 16, 2025
Submission Date February 11, 2025
Acceptance Date March 27, 2025
Published in Issue Year 2025 Volume: 12 Issue: 2

Cite

APA Aşık, Y. C., & Irık, H. A. (2025). Phosphorus And Nitrogen Removal Performance Of Zeolite And Rice Husk From Wastewaters. Turkish Journal of Agricultural and Natural Sciences, 12(2), 492-500. https://doi.org/10.30910/turkjans.1637779