The Use of Acrylamide-Crotonic Acid Nested Network Structured Hydrogels for Adsorption of the Methylene Blue

Year 2017, Volume: 9 Issue: 2, 119 - 130, 15.06.2017

Murat İnal , Beste Çağdaş Tunalı Mustafa Yiğitoğlu

https://doi.org/10.29137/umagd.352513

Abstract

In this study acrylamide-crotonic acid hydrogels are used as adsorbent
for removal of methylene blue. The effects of pH, crotonic acid percentage,
initial dye concentration and reusage number on the adsorption of the dye are
investigated. When the pH increased adsorption also slightly increased with the
hydrogels made up of only acrylamide. With the acrylamide crotonic acid
hydrogels adsorption rates are similar in pH 7,9 and 10 but there is a significant
decrease in pH 8. Adsorption increases with the increasing crotonic acid
percentage in hydrogels. In addition, the adsorption-desorption results showed
that the adsorption capacity of the hydrogel was not changed even after 20
times repeated use. Results show that acrylamide-crotonic acid hydrogels can be
used as adsorbent for dye removal in industrial textile waste water.

Keywords

acrylamide, crotonic acid, hydrogel, methylene blue, adsorption, textile

Akrilamid-Krotonik Asit İç İçe Geçmiş Ağ Yapılı Hidrojellerinin Metilen Mavisinin Adsorpsiyonunda Kullanımı

Abstract

Bu çalışmada akrilamid-krotonik asit hidrojelleri metilen mavisi
boyasının gideriminde adsorban olarak kullanılmıştır. Boyanın adsorpsiyonuna
pH’nın, krotonik asit yüzdesinin, başlangıç boya derişiminin ve tekrar kullanım
sayısının etkisi araştırılmıştır. Yalnızca akrilamidle hazırlanan hidrojellerde
pH’nın artması ile adsorpsiyonda bir miktar artış görülmüştür.
Akrilamid-krotonik asit hidrojellerinde pH 7, 9 ve 10’da adsorpsiyon hemen
hemen yakın bulunmuş, buna karşılık pH 8’de belirgin bir azalma gözlenmiştir.
Hidrojellerde bulunan krotonik asit yüzdesinin artması ile adsorpsiyon belirgin
bir şekilde artmıştır. Ayrıca adsorbsiyon-desorpsiyon çalışmaları sonucu
göstermektedir ki, 20 kere tekrar kullanımdan sonra bile hidrojellerin
adsorpsiyon kapasitesi hemen hemen hiç azalmamıştır. Sonuçlar
akrilamid-krotonik asit hidrojellerin endüstriyel ölçekte tekstil atık
sularından boyaların gideriminde adsorban olarak kullanılabileceğini
göstermektedir.

Keywords

akrilamid, krotonik asit, hidrojel, metilen mavisi, adsorpsiyon, tekstil

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