TENCELTM KUMAŞLARIN SU VE YAĞ İTİCİLİK ÖZELLİKLERİNİN İYİLEŞTİRİLMESİNDE SİKLODEKSTRİN VE ÇAPRAZ BAĞLAYICI ETKİSİNİN İNCELENMESİ

Öz

Bu çalışmada, normalde hidrofil olan TencelTM liflerinin kullanım olanaklarını genişletmek için su ve yağ iticilik özelliklerinin iyileştirilmesi amaçlanmıştır. Bu amaçla, TencelTM kumaşlara floroalkiloligosiloksan (Dynasylan F 8815), siklodekstrin, çapraz bağlayıcı ve katalizör kullanılarak işlem yapılmıştır. Yedi farklı işlem reçetesi hazırlanarak tek aşamalı veya iki aşamalı olarak kumaşlara uygulanmıştır. Daha sonra numunelerin su ve yağ iticilik değerleri, yıkama sonrası işlemlerin kalıcılığı, patlama mukavemetleri, tutum sertleşmesi ve sararma gibi özellikleri belirlenmiş ve kıyaslanmıştır. Ayrıca numunelerin mikroskobik görünümleri incelenmiş ve kumaş yüzeylerinin kimyasal yapısı karakterize edilmiştir. En başarılı sonuç, floroalkiloligosiloksan, siklodekstrin, çapraz bağlayıcı ve katalizörün TencelTM kumaş yüzeylerine birlikte uygulandığı iki aşamalı işlemle elde edilmiştir.

Anahtar Kelimeler

• Tencel
• Siklodekstrin
• Çapraz bağlayıcı
• Su iticilik
• Yağ iticilik
• Yıkama dayanımı

Investigation of the Effect of Cyclodextrin and Crosslinking Agent on Enhancement of Water and Oil Repellency Properties of TencelTM Fabrics

Öz

In this study, it was intended to enhance the water and oil repellency properties of TencelTM fibres that are in naturally hydrophilic character to expand their usage possibilities. For this aim, TencelTM fabrics were treated by floroalkyloligosiloxan (Dynasylan F 8815), cyclodextrin, crosslinking agent and catalyst. By preparing seven different treatment recipes, fabric application processes were carried out in one or in two stages. Then, the properties of the samples like water and oil repellency values, durability of the treatments after washing, bursting strength, stiffness and yellowness were determined and compared. Moreover, the microscopic images of the samples were evaluated and chemical structure of the fabric surfaces were characterized. The most withstanding outcome was obtained by the two stages application of floroalkyloligosiloxan, cyclodextrin, crosslinking agent and catalyst altogether to TencelTM fabric surfaces.

Anahtar Kelimeler

• Tencel
• Cyclodextrin
• Crosslinking agent
• Water repellency
• Oil repellency
• Washing durability

Kaynakça

1. Abdel-Halim, E.S., Abdel-Mohdy, F.A., Fouda, M.M.G., El-Sawy, S.M., Hamdy, I.A. ve AlDeyab, S.S. (2011) Antimicrobial activity of monochlorotriazinyl-β- cyclodextrin/chlorohexidin diacetate finished cotton fabrics, Carbohydrate Polymers, 86(3), 1389–1394. https://doi.org/10.1016/j.carbpol.2011.06.039
2. Akbulut, M., Doba Kadem, F. ve Oğulata, R.T. (2023) Tencel kumaşa uygulanan farklı boyama yöntemlerinin seçilmiş kumaş performans özelliklerine etkisinin değerlendirilmesi, Çukurova Üniversitesi Mühendislik Fakültesi Dergisi, 38(4), 1107-1115. https://doi.org/10.21605/cukurovaumfd.1410772
3. Aksoy, S.A. ve Genç, E. (2015) Functionalization of cotton fabrics by esterification crosslinking with 1, 2, 3, 4-butanetetracarboxylic acid (BTCA), Cellulose Chemistry and Technology, 49(5-6), 405-413.
4. Andrade, P.F., de Faria, A.F., da Silva, D.S., Bonacin, J.A. ve Gonçalves, M.D.C. (2014) Structural and morphological investigations of β-cyclodextrin-coated silver nanoparticles, Colloids and Surfaces B: Biointerfaces, 118(1), 289–297. https://doi.org/10.1016/j.colsurfb.2014.03.032
5. Azizi, N., Ben Abdelkader, M., Chevalier, Y. ve Majdoub, M. (2019) New β-cyclodextrinbased microcapsules for textiles uses, Fibers and Polymers, 20(4), 683-689. doi: 10.1007/s12221-019-7289-5
6. Basit, A., Latif, W., Baig, S.A., Rehman, A., Hashim, M. ve Rehman, M.Z.U. (2018) The mechanical and comfort properties of viscose with cotton and regenerated fibers blended woven fabrics, Materials Science, 24(2), 230-235. https://doi.org/10.5755/j01.ms.24.2.18260
7. Basit, A., Latif, W., Ashraf, M., Rehman, A., Iqbal, K., Maqsood, H.S., Jabbar, A. ve Baig, S.A. (2019) Comparison of mechanical and thermal comfort properties of Tencel blended with regenerated fibers and cotton woven fabrics, Autex Research Journal, 19(1), 80-85. https://doi.org/10.1515/aut-2018-0035
8. Bezerra, F.M., Carmona, Ó.G., Carmona, C.G., Plath, A.M.S. ve Lis, M. (2019) Biofunctional wool using β-cyclodextrins as vehiculizer of citronella oil, Process Biochemistry, 77(1), 151- 158. https://doi.org/10.1016/j.procbio.2018.11.018

9. Bezerra, F.M., Lis, M.J., Firmino, H.B., Dias da Silva, J.G., Curto Valle, R.D.C.S., Borges Valle, J.A., Scacchetti, F.A.P. ve Tessaro, A.L. (2020) The role of β-cyclodextrin in the textile industry, Molecules, 25(3624), 1-28. https://doi.org/10.3390/molecules25163624
10. Bilir, T.B. ve Şardağ, S. (2017) Tencel ve pamuk karışımlı ipliklerin performans özelliklerinin incelenmesi, Uludağ Üniversitesi Mühendislik Fakültesi Dergisi, 22(1), 13-28. https://doi.org/10.17482/uumfd.305178
11. Bilir, T.B. ve Şardağ, S. (2019) Investigation of mechanical properties of fabrics woven with lyocell/cotton blend yarns, Tekstil ve Konfeksiyon, 29(2), 162-170. https://doi.org/10.32710/tekstilvekonfeksiyon.503392
12. Ciriminna, R., Albo, Y. ve Pagliaro, M. (2020) Sol‐gel nanocoatings to functionalize fibers and textiles: a critical perspective, ChemistrySelect, 5(31), 9776-9780. https://doi.org/10.1002/slct.202001897
13. Çay, A. (2017) Modelling of the drying behaviour of regenerated cellulosic fabrics, Tekstil ve Konfeksiyon, 27(4), 373-381.
14. Çoban, S. (1999) Genel Tekstil Terbiyesi ve Bitim İşlemleri, Ege Üniversitesi Tekstil ve Konfeksiyon Araştırma-Uygulama Merkezi Yayını, İzmir.
15. El-Sayed, E., Othman, H.A. ve Hassabo, A.G. (2021) Cyclodextrin usage in textile industry, Journal of Textiles, Coloration and Polymer Science, 18(2), 111-119. doi: 10.21608/jtcps.2021.76238.1059
16. Farha, F.I., Farhana Iqbal, S.M. ve Mahmud, A. (2019) Compositional and structural influence on some weft-knitted fabrics comprised of cotton and lyocell yarn, Journal of the Institution of Engineers (India): Series E, 100(1), 11-19. https://doi.org/10.1007/s40034-019- 00135-3
17. Guo, S., Li, X., Zhao, R. ve Gong, Y. (2021) Comparison of life cycle assessment between lyocell fiber and viscose fiber in China, The International Journal of Life Cycle Assessment, 26(8), 1545-1555. https://doi.org/10.1007/s11367-021-01916-y
18. Jiang, X., Bai, Y., Chen, X. ve Liu, W. (2020) A review on raw materials, commercial production and properties of lyocell fiber, Journal of Bioresources and Bioproducts, 5(1), 16- 25. https://doi.org/10.1016/j.jobab.2020.03.002
19. Kadam, V., Kyratzis, I.L., Truong, Y.B., Wang, L. ve Padhye, R. (2020) Air filter media functionalized with β‐cyclodextrin for efficient adsorption of volatile organic compounds, Journal of Applied Polymer Science, 137(49228), 1-9. https://doi.org/10.1002/app.49228
20. Khanna, S. ve Chakraborty, J.N. (2018) Mosquito repellent activity of cotton functionalized with inclusion complexes of β-cyclodextrin citrate and essential oils, Fashion and Textiles, 5(9), 1-18. https://doi.org/10.1186/s40691-017-0125-x
21. Lis, M.J., García Carmona, Ó., García Carmona, C. ve Maestá Bezerra, F. (2018) Inclusion complexes of citronella oil with β-cyclodextrin for controlled release in biofunctional textiles, Polymers, 10(1324), 1-14. https://doi.org/10.3390/polym10121324
22. Novikov, M., Thong, K.L., Zazali, N.I.M. ve Hamid, S.B.A. (2018) Treatment of cotton by β-cyclodextrin/triclosan inclusion complex and factors affecting antimicrobial properties, Fibers and Polymers, 19(3), 548-560. https://doi.org/10.1007/s12221-018-7028-3
23. Özen, Ö. ve İşmal, Ö.E. (2023) Doğadan ilham alan çevre dostu tasarımlar için bir potansiyel olarak lyocell lifleri ve doğal boyalar, Sanat&Tasarım Dergisi, 13(1), 201-213. https://doi.org/10.20488/sanattasarim.1313959
24. Periyasamy, A.P., Venkataraman, M., Kremenakova, D., Militky, J. ve Zhou, Y. (2020) Progress in sol-gel technology for the coatings of fabrics, Materials, 13(1838), 1-34. https://doi.org/10.3390/ma13081838
25. Radu, C.D., Parteni, O. ve Ochiuz, L. (2016) Applications of cyclodextrins in medical textiles-review, Journal of Controlled Release, 224(1), 146-157. https://doi.org/10.1016/j.jconrel.2015.12.046
26. Rehman, F., Sanbhal, N., Naveed, T., Farooq, A., Wang, Y. ve Wei, W. (2018) Antibacterial performance of Tencel fabric dyed with pomegranate peel extracted via ultrasonic method, Cellulose, 25(7), 4251-4260. https://doi.org/10.1007/s10570-018-1864-6
27. Sayyed, A.J., Deshmukh, N.A. ve Pinjari, D.V. (2019) A critical review of manufacturing processes used in regenerated cellulosic fibres: viscose, cellulose acetate, cuprammonium, LiCl/DMAc, ionic liquids, and NMMO based lyocell, Cellulose, 26(5), 2913-2940. https://doi.org/10.1007/s10570-019-02318-y
28. Schramm, C. ve Rinderer, B. (2015) Non-formaldehyde, crease-resistant modification of cellulosic material by means of an organotrialkoxysilane and metal alkoxides, Cellulose, 22(4), 2811-2824. https://doi.org/10.1007/s10570-015-0664-5
29. Schramm, C. (2020) High temperature ATR-FTIR characterization of the interaction of polycarboxylic acids and organotrialkoxysilanes with cellulosic material, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 243(118815), 1-12. https://doi.org/10.1016/j.saa.2020.118815
30. Wright, T., Mahmud-Ali, A. ve Bechtold, T. (2020) Surface coated cellulose fibres as a biobased alternative to functional synthetic fibres, Journal of Cleaner Production, 275(123857), 1-10. https://doi.org/10.1016/j.jclepro.2020.123857
31. Wu, X., Yang, C.Q. ve He, Q. (2010) Flame retardant finishing of cotton fleece: part VII. Polycarboxylic acids with different numbers of functional group, Cellulose, 17, 859-870. https://doi.org/10.1007/s10570-010-9416-8
32. Zhang, S., Chen, C., Duan, C., Hu, H., Li, H., Li, J., Liu, Y., Ma, X., Stavik, J. ve Ni, Y. (2018) Regenerated cellulose by the lyocell process, a brief review of the process and properties, BioResources, 13(2), 4577-4592. doi: 10.15376/biores.13.2.Zhang