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The Effect of The Reaction Conditions on The Synthesis and Characterization of Potassium Borate from Potassium Chloride

Yıl 2018, Cilt: 6 Sayı: 3, 92 - 96, 30.09.2018
https://doi.org/10.21541/apjes.382382

Öz

In this study, the synthesis and characterization of
potassium borate were studied using KCl, NaOH and H3BO3 asthe starting materials. The effects of the boron precursor, reaction
temperature and time on the structure of the synthesized potassium borate were
investigated. X-ray diffraction (XRD) showed the synthesized sample was
santite, which has the chemical formula KB5O8
4H2O (Powder diffraction file number:
01-1072-1688). The XRD scores increased upon decreasing the reaction
temperature and time. The characteristic band values observed for boron and
oxygen were investigated using Fourier transform infrared (FT-IR) and Raman
spectroscopy. The morphology of the synthesized samples was characterized using
scanning electron microscopy (SEM). The samples were found to be on the
micro-scale with particle sizes <2.54 µm. The reaction yields were in the
range of 75.01–95.03% for Set-1 and 72.04–92.22% for Set-2.

Kaynakça

  • [1] R. Beatty, The Elements: Boron; Marshall Cavendish, New York, 2006.
  • [2] A. Adair, Understanding the elements of Periodic Table: Boron; The Rosen Publishing Group, United States, 2007.
  • [3] D.M. Schubert, Encyclopedia of Inorganic and Bioinorganic Chemistry, Wiley, 2015.
  • [4] S.B. Carpanter, R.B. Kistler, Industrial Mineral and Rocks: boron and Borates, Society, Mining, Metallurgy, USA, 2006.
  • [5] G.M. Wang, Y.Q. Sun, S.T. Zheng, and G.Y. Yang, “Synthesis and Crystal Structure of a Novel Potassium Borate with an Unprecedented [B12O16(OH)8]4- Anion”, Z. Anorg. Allg. Chem., vol 632, pp 1586-1590, 2006.
  • [6] Z.H. Liu, P.Li, L.Q. Li, and Q.X. Jia, “Synthesis, characterization and thermochemistry of K2B5O8(OH)2H2O”, Thermochim. Acta, vol 454, pp 23–25, 2007.
  • [7] Q. Wu, “Potassium pentaborate”, Acta Cryst. , vol E67, pp sup-1 - sup-7, 2011.
  • [8] H.X. Zhang, J. Zhang, S.T. Zheng, and G.Y. Yang, “Two New Potassium Borates, K4B10O15(OH)4 with Stepped Chain and KB5O7(OH)2.H2O with Double Helical Chain”, Cryst. Growth Des., vol 5, pp 157-161, 2004.
  • [9] S. Svanson, and E. Forslind, “Nuclear magnetic resonance study of boron coordination in potassium borate glasses”, Notes, vol 1, pp 174-175, 1961.
  • [10] A. Alicilar, F.Okenek, B. Kayran, and M. Tufak, “Flame retardation, smoke suppression and antibacterial efficiencies of boron additives in styrene acrylic paints”, Journal of the Faculty of Engineering and Architecture of Gazi University, vol 30, pp 701-709, 2015.
  • [11] I. Dovgaliuk, H. Hagemann, T. Leyssens, M. Devillers, and Y. Filinhuk, “CO2-promoted hydrolysis of KBH4 for efficient hydrogen co-generation”, Int. J. Hydrogen Energy, vol 39, pp 19603-19608, 2014.
  • [12] R.E. Youngman, and J.W. Zwanziger, “Network Modification in Potassium Borate Glasses: Structural Studies with NMR and Raman Spectroscopies”, The Journal of Physical Chemistry, vol 100, pp 16720-16728, 1996.
  • [13] E. Moroydor Derun, A.S. Kipcak, F.T. Senberber, M. Sari Yilmaz, “Characterization and thermal dehydration kinetics of admontite mineral hydrothermally synthesized from magnesium oxide and boric acid precursor”, Res. Chem. Intermed., Volume 41, Issue 2, pp 853–866, 2015.
  • [14] L. Jun, X. Shuping, and G. Shiyang, “FT-IR and Raman spectroscopic study of hydrated borates”, Spectrochim. Acta Mol. Biomol. Spectrosc, vol 51, issue A, pp 519-532, 1995.
  • [15] J. Yongzhong, G. Shiyang, X. Shuping and L. Lun, “FT-IR spectroscopy of supersaturated aqueous solutions of magnesium borate”, Spectrochim. Acta Mol. Biomol. Spectrosc, vol 56, pp 1291−1297, 2000.

The Effect of The Reaction Conditions on The Synthesis and Characterization of Potassium Borate from Potassium Chloride

Yıl 2018, Cilt: 6 Sayı: 3, 92 - 96, 30.09.2018
https://doi.org/10.21541/apjes.382382

Öz

In this study, the synthesis and characterization of potassium borate were studied using KCl, NaOH and H3BOasthe starting materials. The effects of the boron precursor, reaction temperature and time on the structure of the synthesized potassium borate were investigated. X-ray diffraction (XRD) showed the synthesized sample was santite, which has the chemical formula KB5O84H2O (Powder diffraction file number: 01-1072-1688). The XRD scores increased upon decreasing the reaction temperature and time. The characteristic band values observed for boron and oxygen were investigated using Fourier transform infrared (FT-IR) and Raman spectroscopy. The morphology of the synthesized samples was characterized using scanning electron microscopy (SEM). The samples were found to be on the micro-scale with particle sizes <2.54 µm. The reaction yields were in the range of 75.01–95.03% for Set-1 and 72.04–92.22% for Set-2.

Kaynakça

  • [1] R. Beatty, The Elements: Boron; Marshall Cavendish, New York, 2006.
  • [2] A. Adair, Understanding the elements of Periodic Table: Boron; The Rosen Publishing Group, United States, 2007.
  • [3] D.M. Schubert, Encyclopedia of Inorganic and Bioinorganic Chemistry, Wiley, 2015.
  • [4] S.B. Carpanter, R.B. Kistler, Industrial Mineral and Rocks: boron and Borates, Society, Mining, Metallurgy, USA, 2006.
  • [5] G.M. Wang, Y.Q. Sun, S.T. Zheng, and G.Y. Yang, “Synthesis and Crystal Structure of a Novel Potassium Borate with an Unprecedented [B12O16(OH)8]4- Anion”, Z. Anorg. Allg. Chem., vol 632, pp 1586-1590, 2006.
  • [6] Z.H. Liu, P.Li, L.Q. Li, and Q.X. Jia, “Synthesis, characterization and thermochemistry of K2B5O8(OH)2H2O”, Thermochim. Acta, vol 454, pp 23–25, 2007.
  • [7] Q. Wu, “Potassium pentaborate”, Acta Cryst. , vol E67, pp sup-1 - sup-7, 2011.
  • [8] H.X. Zhang, J. Zhang, S.T. Zheng, and G.Y. Yang, “Two New Potassium Borates, K4B10O15(OH)4 with Stepped Chain and KB5O7(OH)2.H2O with Double Helical Chain”, Cryst. Growth Des., vol 5, pp 157-161, 2004.
  • [9] S. Svanson, and E. Forslind, “Nuclear magnetic resonance study of boron coordination in potassium borate glasses”, Notes, vol 1, pp 174-175, 1961.
  • [10] A. Alicilar, F.Okenek, B. Kayran, and M. Tufak, “Flame retardation, smoke suppression and antibacterial efficiencies of boron additives in styrene acrylic paints”, Journal of the Faculty of Engineering and Architecture of Gazi University, vol 30, pp 701-709, 2015.
  • [11] I. Dovgaliuk, H. Hagemann, T. Leyssens, M. Devillers, and Y. Filinhuk, “CO2-promoted hydrolysis of KBH4 for efficient hydrogen co-generation”, Int. J. Hydrogen Energy, vol 39, pp 19603-19608, 2014.
  • [12] R.E. Youngman, and J.W. Zwanziger, “Network Modification in Potassium Borate Glasses: Structural Studies with NMR and Raman Spectroscopies”, The Journal of Physical Chemistry, vol 100, pp 16720-16728, 1996.
  • [13] E. Moroydor Derun, A.S. Kipcak, F.T. Senberber, M. Sari Yilmaz, “Characterization and thermal dehydration kinetics of admontite mineral hydrothermally synthesized from magnesium oxide and boric acid precursor”, Res. Chem. Intermed., Volume 41, Issue 2, pp 853–866, 2015.
  • [14] L. Jun, X. Shuping, and G. Shiyang, “FT-IR and Raman spectroscopic study of hydrated borates”, Spectrochim. Acta Mol. Biomol. Spectrosc, vol 51, issue A, pp 519-532, 1995.
  • [15] J. Yongzhong, G. Shiyang, X. Shuping and L. Lun, “FT-IR spectroscopy of supersaturated aqueous solutions of magnesium borate”, Spectrochim. Acta Mol. Biomol. Spectrosc, vol 56, pp 1291−1297, 2000.
Toplam 15 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Makaleler
Yazarlar

Fatma Tuğçe Şenberber 0000-0002-3257-1524

Yayımlanma Tarihi 30 Eylül 2018
Gönderilme Tarihi 22 Ocak 2018
Yayımlandığı Sayı Yıl 2018 Cilt: 6 Sayı: 3

Kaynak Göster

IEEE F. T. Şenberber, “The Effect of The Reaction Conditions on The Synthesis and Characterization of Potassium Borate from Potassium Chloride”, APJES, c. 6, sy. 3, ss. 92–96, 2018, doi: 10.21541/apjes.382382.