Symmetrically substituted phthalocyanine derivatives have been synthesized from the reaction of anhydrous metal salts of titanium with 4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylthio) phthalonitrile (3). 4-phthalonitrile (1) and 4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylthiol) (2) in dry dimethylformamide as solvent and using K2CO3 as base via the common method of nucleophilic substitution of an activated nitro group in an aromatic ring. The compound 3,9,17,23-bis[ethane-1,1-p-phenol-2,2-p-phenokxy]phthalocyaninatocobalt (II) (FlTi2CoPc) (4) was reacted with the compound 4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylthio) phthalocyaninatotinanium (IV) (5), which is similar to those synthesized in the past, to syhthesize a new derivative containing three phthalocyanines 3,9,17,23-bis[ethane-1,1-p-(4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylthio) phthalocyaninatotinanium (IV))-2,2-p-phenokxy]phthalocyaninatocobalt (II) (FlTi2CoPc) (6). The synthesized molecules have been characterized by 19F NMR, HETCOR, MALDI-TOFF, UV-Vis and IR spectroscopies.
Birincil Dil | İngilizce |
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Bölüm | Araştırma Makalesi |
Yazarlar | |
Yayımlanma Tarihi | 1 Kasım 2013 |
Yayımlandığı Sayı | Yıl 2013 Cilt: 14 Sayı: 2 |