BibTex RIS Kaynak Göster

SYNTHESIS AND CHARACTERIZATION OF SOME (3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-HEPTADECAFLUORODECYL) (METHYL) SULFANE SUBSTITUTED TITANIUM PHTHALOCYANINE DERIVATIVES

Yıl 2013, Cilt: 14 Sayı: 2, 135 - 142, 01.11.2013

Öz

Symmetrically substituted phthalocyanine derivatives have been synthesized from the reaction of anhydrous metal salts of titanium with 4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylthio) phthalonitrile (3). 4-phthalonitrile (1) and 4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylthiol) (2) in dry dimethylformamide as solvent and using K2CO3 as base via the common method of nucleophilic substitution of an activated nitro group in an aromatic ring. The compound 3,9,17,23-bis[ethane-1,1-p-phenol-2,2-p-phenokxy]phthalocyaninatocobalt (II) (FlTi2CoPc) (4) was reacted with the compound 4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylthio) phthalocyaninatotinanium (IV) (5), which is similar to those synthesized in the past, to syhthesize a new derivative containing three phthalocyanines 3,9,17,23-bis[ethane-1,1-p-(4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylthio) phthalocyaninatotinanium (IV))-2,2-p-phenokxy]phthalocyaninatocobalt (II) (FlTi2CoPc)  (6). The synthesized molecules have been characterized by 19F NMR, HETCOR, MALDI-TOFF, UV-Vis and IR spectroscopies.

Kaynakça

  • Arslanoglu, Y., Sevim, A.M., Hamuryudan, E., Gul, A., (2006). Near-IR Absorbing Phthalocyanines, Dyes and Pigments, 68, 129-132.
  • Bıyıkoğlu, Z., (2013). Water-soluble Axially Disubstituted Non-aggregated Silicon Phthalocyanines and Their Electrochemical Properties. Dyes and Pigments, 99, 59–66.
  • Wilfred L.F. Armarego and Christina Li Lin
  • Ceyhan, T., Altındal, A., Erbil, M. K., Bekaroğlu, Ö., (2006). Synthesis, Characterization, Conduction and Gas Sensing Properties of Novel Multinuclear Metallo Phthalocyanines (Zn, Co) With Alkylthio Substituents. Polyhedron, 25, ,737–746.
  • Yılmaz, Ö., (2006), Yeni Tip Okso- Titanyum
  • Gullotti, M., Pasini, A., (1975). Schiff Base Complexes of Oxocatiohs. Part III*. Oxotitanium(IV) Complexes with Tetradentate Optically Active Schiff Bases. Inorganica Chimica Acta, 15, 129- 136.
  • Jin, L., Chen, D., (2012). Enhancement in Photovoltaic Performance of Phthalocyanine-sensitized Solar cells by Attapulgite Nanoparticles. Electrochimica Acta, 72, 40–45.
  • Kobayashi, S., (2002). Dimers, Trimers and Oligomers of Phthalocyanines and Related Compounds, Coordination Chemistry Reviews, 227, 129-152.
  • Lokesh,K. S., Adriaens, A., (2013). Synthesis and Characterization of Tetra-Substituted Palladium Phthalocyanine Complexes. Dyes and Pigments, 96, 1, 269-277.
  • Moussaron, A., Arnoux, P., Vanderesse, R., Sibille, E., (2013). Lipophilic Phthalocyanines for Their Potential Interest in Photodynamic Therapy: Synthesis and photo-physical properties. Tetrahedron, 69, 47, 10116–10122.
  • Shumov,Y. S., Heyrovský, M., (1975). The Relation Between Catalytic and Photoelectro-chemical Properties of Phthalocyanine Films. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 65, 1, 469– 471.
  • Simon, J.; Andre, J.J. (1985). Molecular semiconductors; Chapter 3, 73-149, Springer; Berlin. Chai, (2009), Purification of Laboratory Chemicals (Sixth Edition), ISBN: 978-1- 85617-567-8, Elsevier Inc., Oxford OX2 8DP, UK). (IV) Ftalosiyaninlerin Sentezi ve Karakterizasyonu, Yüksek Lisans Tezi, T.C. Gebze Yüksek Teknoloji Enstitüsü Mühendislik ve Fen Bilimleri Enstitüsü.
  • Zakharov, A.V., Girichev, G. V., (2008). Theoretical Study of The Structure, Vibrational Spectra, and Electronic Spectra of Oxotitanium Porphyrin, Octamethylporphyrin, Porphyrazine, and Phthalocyanine Complexes. Journal of Molecular Structure: THEOCHEM, Volume 851, 1–3,183-196.
  • Zugle, R., Nyokong, T., (2013). Zinc(II) 2,9,16,23-Tetrakis[4-(N-Methylpyridyloxy)]- Phthalocyanine Anchored on An Electrospun Polysulfone Polymer Fiber: Application for Photosensitized Conversion of Methyl Orange. Journal of Molecular Catalysis A: Chemical, 366, 247-253.

(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-HEPTADEKAFLORODESİLL) (METİL) SULFAN SÜBSTİTÜE TİTANYUM FTALOSİYANİN TÜREVLERİNİN SENTEZİ VE KARAKTERİZASYONU

Yıl 2013, Cilt: 14 Sayı: 2, 135 - 142, 01.11.2013

Öz

Kaynakça

  • Arslanoglu, Y., Sevim, A.M., Hamuryudan, E., Gul, A., (2006). Near-IR Absorbing Phthalocyanines, Dyes and Pigments, 68, 129-132.
  • Bıyıkoğlu, Z., (2013). Water-soluble Axially Disubstituted Non-aggregated Silicon Phthalocyanines and Their Electrochemical Properties. Dyes and Pigments, 99, 59–66.
  • Wilfred L.F. Armarego and Christina Li Lin
  • Ceyhan, T., Altındal, A., Erbil, M. K., Bekaroğlu, Ö., (2006). Synthesis, Characterization, Conduction and Gas Sensing Properties of Novel Multinuclear Metallo Phthalocyanines (Zn, Co) With Alkylthio Substituents. Polyhedron, 25, ,737–746.
  • Yılmaz, Ö., (2006), Yeni Tip Okso- Titanyum
  • Gullotti, M., Pasini, A., (1975). Schiff Base Complexes of Oxocatiohs. Part III*. Oxotitanium(IV) Complexes with Tetradentate Optically Active Schiff Bases. Inorganica Chimica Acta, 15, 129- 136.
  • Jin, L., Chen, D., (2012). Enhancement in Photovoltaic Performance of Phthalocyanine-sensitized Solar cells by Attapulgite Nanoparticles. Electrochimica Acta, 72, 40–45.
  • Kobayashi, S., (2002). Dimers, Trimers and Oligomers of Phthalocyanines and Related Compounds, Coordination Chemistry Reviews, 227, 129-152.
  • Lokesh,K. S., Adriaens, A., (2013). Synthesis and Characterization of Tetra-Substituted Palladium Phthalocyanine Complexes. Dyes and Pigments, 96, 1, 269-277.
  • Moussaron, A., Arnoux, P., Vanderesse, R., Sibille, E., (2013). Lipophilic Phthalocyanines for Their Potential Interest in Photodynamic Therapy: Synthesis and photo-physical properties. Tetrahedron, 69, 47, 10116–10122.
  • Shumov,Y. S., Heyrovský, M., (1975). The Relation Between Catalytic and Photoelectro-chemical Properties of Phthalocyanine Films. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 65, 1, 469– 471.
  • Simon, J.; Andre, J.J. (1985). Molecular semiconductors; Chapter 3, 73-149, Springer; Berlin. Chai, (2009), Purification of Laboratory Chemicals (Sixth Edition), ISBN: 978-1- 85617-567-8, Elsevier Inc., Oxford OX2 8DP, UK). (IV) Ftalosiyaninlerin Sentezi ve Karakterizasyonu, Yüksek Lisans Tezi, T.C. Gebze Yüksek Teknoloji Enstitüsü Mühendislik ve Fen Bilimleri Enstitüsü.
  • Zakharov, A.V., Girichev, G. V., (2008). Theoretical Study of The Structure, Vibrational Spectra, and Electronic Spectra of Oxotitanium Porphyrin, Octamethylporphyrin, Porphyrazine, and Phthalocyanine Complexes. Journal of Molecular Structure: THEOCHEM, Volume 851, 1–3,183-196.
  • Zugle, R., Nyokong, T., (2013). Zinc(II) 2,9,16,23-Tetrakis[4-(N-Methylpyridyloxy)]- Phthalocyanine Anchored on An Electrospun Polysulfone Polymer Fiber: Application for Photosensitized Conversion of Methyl Orange. Journal of Molecular Catalysis A: Chemical, 366, 247-253.
Toplam 14 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Bölüm Araştırma Makalesi
Yazarlar

Dilek Elmalı

Gürol Demirel Bu kişi benim

Yayımlanma Tarihi 1 Kasım 2013
Yayımlandığı Sayı Yıl 2013 Cilt: 14 Sayı: 2

Kaynak Göster

APA Elmalı, D., & Demirel, G. (2013). SYNTHESIS AND CHARACTERIZATION OF SOME (3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-HEPTADECAFLUORODECYL) (METHYL) SULFANE SUBSTITUTED TITANIUM PHTHALOCYANINE DERIVATIVES. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, 14(2), 135-142.
AMA Elmalı D, Demirel G. SYNTHESIS AND CHARACTERIZATION OF SOME (3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-HEPTADECAFLUORODECYL) (METHYL) SULFANE SUBSTITUTED TITANIUM PHTHALOCYANINE DERIVATIVES. AUBTD-A. Kasım 2013;14(2):135-142.
Chicago Elmalı, Dilek, ve Gürol Demirel. “SYNTHESIS AND CHARACTERIZATION OF SOME (3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-HEPTADECAFLUORODECYL) (METHYL) SULFANE SUBSTITUTED TITANIUM PHTHALOCYANINE DERIVATIVES”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 14, sy. 2 (Kasım 2013): 135-42.
EndNote Elmalı D, Demirel G (01 Kasım 2013) SYNTHESIS AND CHARACTERIZATION OF SOME (3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-HEPTADECAFLUORODECYL) (METHYL) SULFANE SUBSTITUTED TITANIUM PHTHALOCYANINE DERIVATIVES. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 14 2 135–142.
IEEE D. Elmalı ve G. Demirel, “SYNTHESIS AND CHARACTERIZATION OF SOME (3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-HEPTADECAFLUORODECYL) (METHYL) SULFANE SUBSTITUTED TITANIUM PHTHALOCYANINE DERIVATIVES”, AUBTD-A, c. 14, sy. 2, ss. 135–142, 2013.
ISNAD Elmalı, Dilek - Demirel, Gürol. “SYNTHESIS AND CHARACTERIZATION OF SOME (3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-HEPTADECAFLUORODECYL) (METHYL) SULFANE SUBSTITUTED TITANIUM PHTHALOCYANINE DERIVATIVES”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 14/2 (Kasım 2013), 135-142.
JAMA Elmalı D, Demirel G. SYNTHESIS AND CHARACTERIZATION OF SOME (3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-HEPTADECAFLUORODECYL) (METHYL) SULFANE SUBSTITUTED TITANIUM PHTHALOCYANINE DERIVATIVES. AUBTD-A. 2013;14:135–142.
MLA Elmalı, Dilek ve Gürol Demirel. “SYNTHESIS AND CHARACTERIZATION OF SOME (3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-HEPTADECAFLUORODECYL) (METHYL) SULFANE SUBSTITUTED TITANIUM PHTHALOCYANINE DERIVATIVES”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, c. 14, sy. 2, 2013, ss. 135-42.
Vancouver Elmalı D, Demirel G. SYNTHESIS AND CHARACTERIZATION OF SOME (3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-HEPTADECAFLUORODECYL) (METHYL) SULFANE SUBSTITUTED TITANIUM PHTHALOCYANINE DERIVATIVES. AUBTD-A. 2013;14(2):135-42.