Schiff Bazlarının Dioksouranyum (VI) Komplekslerinin Sentezi ve Karakterizasyonu (Karışık Ligandlar Bölüm 1)

Yıl 2014, Cilt: 3 Sayı: 1, 74 - 80, 01.06.2014

Erdal Canpolat

https://doi.org/10.17798/beufen.41970

Öz

Schiff Bazları ve piridin, dimetilformamid, 2,2’-bipridin, 1,10-fenantrolin yada trietilamin ile dioksouranyum
(VI)’un yeni seri karışık-ligand kompleksleri sentezlenmiştir. Komplekslerin sentezinde elementel analiz,
İnfrared, proton NMR, karbon-13 NMR, elektronik spektrum, manyetik süssebtibilite ve termogravimetrik analiz
kullanılmıştır. Komplekslerin genel formulü [(L1)(UO2)(OAc)(H2O)].2H2O (1), [(L2)(UO2)(OAc)(py)].H2O (2),
[(L3)(UO2)(OAc)(DMF)].2H2O (3), [(L4)(UO2)(OAc)(bipy)].H2O (4), [(L5)(UO2)(OAc)(phen)].H2O (5) and
[(L6)(UO2)(OAc)(Et3N)].3H2O (6). şeklindedir.

Anahtar Kelimeler

Schiff Bazları, Schiff Bazlarının UO2(VI) Kompleksleri

Kaynakça

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