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Vitrinite reflectances and mineralogy of coal clasts in the Late Carboniferous sequences in the two-deep research wells from the Kozlu coalfield (Zonguldak Basin, NW Türkiye)

Year 2024, Volume: 173 Issue: 173, 55 - 83, 26.04.2024
https://doi.org/10.19111/bulletinofmre.1209127

Abstract

Fifty-four coal clast samples in the siliciclastic rocks (e.g., sandstone and conglomerate) were collected from cores of two-deep research wells (K20H and K20K) drilled at the Kozlu coalfield in
Zonguldak Basin, and for the first time, they were evaluated using mineralogy by XRD and SEMEDX and random vitrinite reflectance (%Rr) measurements in order to find out their origin and timing. Petrographic observations on polish surfaces show that the coal clasts are either entirely xylitic/vitrinitic particles or coals including a broader range of macerals. The detected minerals in the samples are mostly derived from the parental coal seams and, to a lesser extent, precipitated from penetrated pore-water in the cleats/fractures of clasts. The %Rr values of coal clasts in Carboniferous sediments are generally relatively higher than those measured in the coal seams due to weak oxidation during transportation. Furthermore, similar mineralogical and maceral compositions between coal clasts and coal seams imply that these clasts were mainly eroded during the peatification and/or early coalification of parental seams and display similar coalification
patterns. The close %Rr value of a coal clast sample in the Early Aptian Zonguldak Formation and Carboniferous coal seams could suggest that this coal clast sample is presumably derived from the
coal seams eroded during Early Aptian.

Ethical Statement

A part of this study is supported by the Turkish Scientific and Technological Research Council of Turkey (TÜBİTAK) under the project YDABCAG-70. The authors would like to thank Prof. Dr. J. HOWER (University of Kentucky) his suggestions during the manuscript preparations.

Supporting Institution

A part of this study is supported by the Turkish Scientific and Technological Research Council of Turkey (TÜBİTAK) under the project YDABCAG-70

Project Number

Turkish Scientific and Technological Research Council of Turkey (TÜBİTAK) under the project YDABCAG-70

Thanks

The authors would like to thank Prof. Dr. J. HOWER (University of Kentucky) his suggestions during the manuscript preparations.

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Year 2024, Volume: 173 Issue: 173, 55 - 83, 26.04.2024
https://doi.org/10.19111/bulletinofmre.1209127

Abstract

Project Number

Turkish Scientific and Technological Research Council of Turkey (TÜBİTAK) under the project YDABCAG-70

References

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  • Cleal, C. J., Van Waveren, I. M. 2012. A reappraisal of the Carboniferous macrofloras of the Zonguldak- Amasra. Coal Basin, north-western Turkey. Geologia Croatica 65, 283-297.
  • Cleal, C. J., Stolle, E., Van Waveren, I. M., King, S., Didari,V. 2017. Carboniferous plant fossils from northern Turkey in the Jongmans Collection, Naturalis, Leiden. Paleontological Journal 51, 770-777.
  • Cleal, C. J., Stolle, E., Van Waveren, I. M., King, S., Didari, V. 2018. Macrofloral biostratigraphy of the upper Bashkirian Kozlu Formation, Zonguldak coalfield, north Turkey. Nurgaloev, D., Barclay, M., Nikolaeva, S., Silantiev, V., Zharinova, V., Vasilyeva O. (Ed.). Advances in Devonian, Carboniferous and Permian Research: Stratigraphy, Environments, Climate and Resources. Filodiritto, Bologna, 82-90.
  • Dai, S., Bechtel, A, Eble, C. F., Flores, R. M., French, D., Graham, I. T., Hood, M. M., Hower, J. C., Korasidis, V. A., Moore, T. A., Püttmann, W., Wei, Q. 2020a. Recognition of peat depositional environments in coal: A review. International Journal of Coal Geology 219, 103383.
  • Daněk, V., Pešek, J., Valterová, P. 2002. Coal clasts in the Bolsovian (Westphalian C) sequence of the Kladno-Rakovník continental basin (Czech Republic): implication of the timing of maturation. Polish Geological Institute Special Paper 7, 63-78.
  • Daniels, S. M., Agnew, C. T., Allott, T. E. H., Evans, M.G. 2008. Water table variability and runoff generation in an eroded peatland, South Pennines, UK. Journal of Hydrology 361, 214-226.
  • Dawson, G. K. W., Golding, S. D., Esterle, J. S., Massarotto, P. 2012. Occurrence of minerals within fractures and matrix of selected Bowen and Ruhr Basin coals. International Journal of Coal Geology 94, 150-166.
  • Dill, H. G., Kus, J., Kaufhold, S., Rammlmair, D., Techmer, A. 2017. Oligo-Miocene coal in a microtidal environment reworked under Quaternary periglacial conditions (Western Falkland Islands/ Isla Gran Malvina) coal formation and natural sand processing. International Journal of Coal Geology 174, 8-22.
  • Dill, H. G., Kus, J., Andrei, B., Sorin-Ionut, B., Stephan, K., Borrego, A. G. 2021. Organic debris and allochthonous coal in Quaternary landforms within a periglacial setting (Longyearbyen Mining District, Norway) - A multi-disciplinary study (coal geology-geomorphology-sedimentology). International Journal of Coal Geology 233, 103625.
  • Gayer, R. A., Pešek, J., Sýkorová, I., Valterová, P. 1996. Coal clasts in the upper Westphalian sequence of the South Wales coal basin: Implications for the timing of maturation and fracture permeability. Geological Society Special Publication 109, 103-120.
  • Geršlová, E., Goldbach, M., Geršl, M., Skupien, P. 2016. Heat flow evolution, subsidence and erosion in Upper Silesian Coal Basin, Czech Republic. International Journal of Coal Geology 154-155, 30-42. Gürdal, G., Yalçın, M. N. 2000. Gas adsorption capacity of Carboniferous coals in the Zonguldak Basin (NW Turkey) and its controlling factors. Fuel 79, 1913- 1924.
  • Gürdal, G., Yalçın, M. N. 2001. Pore volume and surface area of the carboniferous coal from the Zonguldak Basin (NW Turkey) and their variations with rank and maceral composition. International Journal of Coal Geology 48, 133-144.
  • Gürdal, G., Mann, U., Yalçın, M. N. 2004. Comparison of adsorption related properties of Zonguldak Basin coals (NW Turkey) obtained at two different adsorption temperatures of carbon dioxide. Energy Source 26, 1301-1312.
  • Hower, J. C., Davis, A. 1981. Vitrinite reflectance anisotropy as a tectonic fabric element. Geology 9, 165-168.
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There are 69 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Articles
Authors

Ali İhsan Karayiğit This is me 0000-0001-9743-4611

Rıza Görkem Oskay 0000-0003-0748-8363

Project Number Turkish Scientific and Technological Research Council of Turkey (TÜBİTAK) under the project YDABCAG-70
Early Pub Date April 28, 2023
Publication Date April 26, 2024
Published in Issue Year 2024 Volume: 173 Issue: 173

Cite

APA Karayiğit, A. İ., & Oskay, R. G. (2024). Vitrinite reflectances and mineralogy of coal clasts in the Late Carboniferous sequences in the two-deep research wells from the Kozlu coalfield (Zonguldak Basin, NW Türkiye). Bulletin of the Mineral Research and Exploration, 173(173), 55-83. https://doi.org/10.19111/bulletinofmre.1209127
AMA Karayiğit Aİ, Oskay RG. Vitrinite reflectances and mineralogy of coal clasts in the Late Carboniferous sequences in the two-deep research wells from the Kozlu coalfield (Zonguldak Basin, NW Türkiye). Bull.Min.Res.Exp. April 2024;173(173):55-83. doi:10.19111/bulletinofmre.1209127
Chicago Karayiğit, Ali İhsan, and Rıza Görkem Oskay. “Vitrinite Reflectances and Mineralogy of Coal Clasts in the Late Carboniferous Sequences in the Two-Deep Research Wells from the Kozlu Coalfield (Zonguldak Basin, NW Türkiye)”. Bulletin of the Mineral Research and Exploration 173, no. 173 (April 2024): 55-83. https://doi.org/10.19111/bulletinofmre.1209127.
EndNote Karayiğit Aİ, Oskay RG (April 1, 2024) Vitrinite reflectances and mineralogy of coal clasts in the Late Carboniferous sequences in the two-deep research wells from the Kozlu coalfield (Zonguldak Basin, NW Türkiye). Bulletin of the Mineral Research and Exploration 173 173 55–83.
IEEE A. İ. Karayiğit and R. G. Oskay, “Vitrinite reflectances and mineralogy of coal clasts in the Late Carboniferous sequences in the two-deep research wells from the Kozlu coalfield (Zonguldak Basin, NW Türkiye)”, Bull.Min.Res.Exp., vol. 173, no. 173, pp. 55–83, 2024, doi: 10.19111/bulletinofmre.1209127.
ISNAD Karayiğit, Ali İhsan - Oskay, Rıza Görkem. “Vitrinite Reflectances and Mineralogy of Coal Clasts in the Late Carboniferous Sequences in the Two-Deep Research Wells from the Kozlu Coalfield (Zonguldak Basin, NW Türkiye)”. Bulletin of the Mineral Research and Exploration 173/173 (April 2024), 55-83. https://doi.org/10.19111/bulletinofmre.1209127.
JAMA Karayiğit Aİ, Oskay RG. Vitrinite reflectances and mineralogy of coal clasts in the Late Carboniferous sequences in the two-deep research wells from the Kozlu coalfield (Zonguldak Basin, NW Türkiye). Bull.Min.Res.Exp. 2024;173:55–83.
MLA Karayiğit, Ali İhsan and Rıza Görkem Oskay. “Vitrinite Reflectances and Mineralogy of Coal Clasts in the Late Carboniferous Sequences in the Two-Deep Research Wells from the Kozlu Coalfield (Zonguldak Basin, NW Türkiye)”. Bulletin of the Mineral Research and Exploration, vol. 173, no. 173, 2024, pp. 55-83, doi:10.19111/bulletinofmre.1209127.
Vancouver Karayiğit Aİ, Oskay RG. Vitrinite reflectances and mineralogy of coal clasts in the Late Carboniferous sequences in the two-deep research wells from the Kozlu coalfield (Zonguldak Basin, NW Türkiye). Bull.Min.Res.Exp. 2024;173(173):55-83.

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