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An environmentally friendly microextraction method for the determination of cadmium in water samples

Year 2023, Volume: 16 Issue: 3, 633 - 642, 31.12.2023
https://doi.org/10.18185/erzifbed.1169502

Abstract

An environmentally friendly switchable solvent based microextraction method was developed for cadmium ions prior to determination by FAAS. N, N-dimethyl-n-octylamin and 1-(2-Pyridylazo)-2-naphthol were used as switchable solvent and ligands, respectively. Important method parameters such as pH, amount of extraction solvent and ligand, volume of sample and NaOH and foreign ions effects have been optimized. Limits of detection and quantification, preconcentration factor were determined as 0.063 mg L-1, 0.21 mg L-1 and 60, respectively. The validation study of the developed method was carried out by spiking a fixed amount of cadmium to the water samples and determining the recovery. The method was used to determine the cadmium ions content of various environmental water samples.

References

  • [1] Öktüren Asri, F., Sönmez, S., Çıtak, S., (2007) Kadmiyumun çevre ve insan sağlığı üzerine etkileri, Derim. 24 -32-39. http://www.derim.com.tr/en/pub/issue/4562/62587
  • [2] Örün, E., Yalçın, S. S., (2011) Kurşun, Civa, Kadmiyum: Çocuk Sağlığına Etkileri ve Temasın Belirlenmesinde Saç Örneklerinin Kullanımı, Ankara Üniversitesi Çevrebilimleri Dergisi. 3 73-81. https://dergipark.org.tr/tr/pub/aucevrebilim/issue/40109/477091
  • [3] Aydın Urucu, O., Aracier, E. D., (2021) Switchable Solvent-Based Liquid Phase Microextraction Method for the Detection of Cadmium in Water Samples with Flame Atomic Absorption Spectrometry, Journal AOAC International. 104-645-649. https://doi.org/10.1093/jaoacint/qsaa169
  • [4] Gaubeur, I., Aguirre, M.A., Kovachev, N., Hidalgo, M., Canal, A. S., (2015) Dispersive liquid–liquid microextraction combined with laser-induced breakdown spectrometry and inductively coupled plasma optical emission spectrometry to elemental analysis, Microchemical Journal. 121-219-226.
  • [5] Mostafa, K., Farahnaz, S., Mansour, G.M., Mousa, B., (2016) Flotation-Assisted Homogenous Liquid–Liquid Microextraction for Determination of Cadmium in Vegetables, International Journal of Vegetable Science. 22:3-266-273. DOI:10.1080/19315260.2015.1039744
  • [6] Khan, S., Soylak, M., Gul Kazi, T., (2013) Room Temperature Ionic Liquid-Based Dispersive Liquid Phase Microextraction for the Separation/Preconcentration of Trace Cd2+ as 1-(2-pyridylazo)-2-naphthol (PAN) Complex from Environmental and Biological Samples and Determined by FAAS, Biol Trace Elem Res. 156- 49–55. DOI 10.1007/s12011-013-9853-y
  • [7] Naeemullah, Tuzen, M., Gul Kazi, T., (2016) Simple and green switchable dispersive liquid–liquid microextraction of cadmium in water and food samples, RSC Adv. 6- 28767-28773.
  • [8] Chang, Q., Zhang, J., Du, X., Ma, J., Li, J., (2010) Ultrasound-assisted emulsification solidified floating organic drop microextraction for the determination of trace amounts of copper in water samples. Front. Environ. Sci. Eng. China. 4-187–195. https://doi.org/10.1007/s11783-010-0030-7
  • [9] Yurtman Gündüz, Z., Aydın Urucu, O,, Kök Yetimoğlu, E., Filik, H., (2013) Cloud point extraction for the determination of trace copper(II) in environmental samples using a new synthesized reagent and flame atomic absorption spectrometry. Macedonian Journal Chemical Engineering. (32)-69-78. https://mjcce.org.mk/index.php/MJCCE/article/view/98.
  • [10] Ayman, A. G., Wael A. Z., (2018) Solid-phase extraction method for preconcentration of cadmium and lead in environmental samples using multiwalled carbon nanotubes Turk J Chem. 42- 1018 – 1031.
  • [11] Koçoğlu, E. S., Kublay, İ. Z., Gösterişli, T. U., Bakırdere, S., (2022) Determination of trace cadmium in seawater using combination of polystyrene coated magnetic nanoparticles based DSPE and triethylamine assisted Mg(OH)2 method. Microchemical Journal. 79 -107662.
  • [12] Usama Alshana a, Malek Hassan a, b, Mais Al-Nidawi a, Erkan Yilmaz, Mustafa SoylakSwitchable-hydrophilicity solvent liquid-liquid microextraction, Trends in Analytical Chemistry. 131 -116025.
  • [13] Kasa, N.A., Bakirdere, E.G., Bakirdere, S. A., (2020) Simple and Green Vortex-Assisted Switchable Solvent-Based Microextraction Method by Using Schiff Base Ligand Complexation for Iron Determination in Mineral Spring Water Samples Prior to Slotted Quartz Tube Flame Atomic Absorption Spectrophotometry. Water Air Soil Pollut. 231 -417. https://doi.org/10.1007/s11270-020-04754-0
  • [14] Musarurwa, H., Nikita, T. T., (2021) Switchable solvent-based micro-extraction of pesticides in food and environmental samples, Talanta. 224 -121807.
  • [15] Zhang, S., Chen, B., He, M., Hu, B., (2018) Switchable solvent based liquid phase microextraction of trace lead and cadmium from environmental and biological samples prior to graphite furnace atomic absorption spectrometry detection, Microchemical Journal. 139- 380-385.
  • [16] Soylak, M., Khan, M., Yılmaz, E., (2016) Switchable solvent based liquid phase microextraction of uranium in environmental samples: a green approach. Anal. Methods. 8 -979-986.
  • [17] Li, W., Chen, N., Huang, Z., Zeng, X., Zhu, Y., (2019) Switchable Hydrophilicity Dispersive Solvent-Based Liquid-Liquid Microextraction Coupling to High-Performance Liquid Chromatography for the Determination of Amphenicols in Food Products. Food Anal. Methods. 12 -517–525. https://doi.org/10.1007/s12161-018-1382-z
  • [18] Memon, Z.M., Yılmaz, E., Soylak, M., (2017) Switchable solvent based green liquid phase microextraction method for cobalt in tobacco and food samples prior to flame atomic absorption spectrometric determination, Journal of Molecular Liquids. 229- 459-464.

An environmentally friendly microextraction method for the determination of cadmium in water samples

Year 2023, Volume: 16 Issue: 3, 633 - 642, 31.12.2023
https://doi.org/10.18185/erzifbed.1169502

Abstract

References

  • [1] Öktüren Asri, F., Sönmez, S., Çıtak, S., (2007) Kadmiyumun çevre ve insan sağlığı üzerine etkileri, Derim. 24 -32-39. http://www.derim.com.tr/en/pub/issue/4562/62587
  • [2] Örün, E., Yalçın, S. S., (2011) Kurşun, Civa, Kadmiyum: Çocuk Sağlığına Etkileri ve Temasın Belirlenmesinde Saç Örneklerinin Kullanımı, Ankara Üniversitesi Çevrebilimleri Dergisi. 3 73-81. https://dergipark.org.tr/tr/pub/aucevrebilim/issue/40109/477091
  • [3] Aydın Urucu, O., Aracier, E. D., (2021) Switchable Solvent-Based Liquid Phase Microextraction Method for the Detection of Cadmium in Water Samples with Flame Atomic Absorption Spectrometry, Journal AOAC International. 104-645-649. https://doi.org/10.1093/jaoacint/qsaa169
  • [4] Gaubeur, I., Aguirre, M.A., Kovachev, N., Hidalgo, M., Canal, A. S., (2015) Dispersive liquid–liquid microextraction combined with laser-induced breakdown spectrometry and inductively coupled plasma optical emission spectrometry to elemental analysis, Microchemical Journal. 121-219-226.
  • [5] Mostafa, K., Farahnaz, S., Mansour, G.M., Mousa, B., (2016) Flotation-Assisted Homogenous Liquid–Liquid Microextraction for Determination of Cadmium in Vegetables, International Journal of Vegetable Science. 22:3-266-273. DOI:10.1080/19315260.2015.1039744
  • [6] Khan, S., Soylak, M., Gul Kazi, T., (2013) Room Temperature Ionic Liquid-Based Dispersive Liquid Phase Microextraction for the Separation/Preconcentration of Trace Cd2+ as 1-(2-pyridylazo)-2-naphthol (PAN) Complex from Environmental and Biological Samples and Determined by FAAS, Biol Trace Elem Res. 156- 49–55. DOI 10.1007/s12011-013-9853-y
  • [7] Naeemullah, Tuzen, M., Gul Kazi, T., (2016) Simple and green switchable dispersive liquid–liquid microextraction of cadmium in water and food samples, RSC Adv. 6- 28767-28773.
  • [8] Chang, Q., Zhang, J., Du, X., Ma, J., Li, J., (2010) Ultrasound-assisted emulsification solidified floating organic drop microextraction for the determination of trace amounts of copper in water samples. Front. Environ. Sci. Eng. China. 4-187–195. https://doi.org/10.1007/s11783-010-0030-7
  • [9] Yurtman Gündüz, Z., Aydın Urucu, O,, Kök Yetimoğlu, E., Filik, H., (2013) Cloud point extraction for the determination of trace copper(II) in environmental samples using a new synthesized reagent and flame atomic absorption spectrometry. Macedonian Journal Chemical Engineering. (32)-69-78. https://mjcce.org.mk/index.php/MJCCE/article/view/98.
  • [10] Ayman, A. G., Wael A. Z., (2018) Solid-phase extraction method for preconcentration of cadmium and lead in environmental samples using multiwalled carbon nanotubes Turk J Chem. 42- 1018 – 1031.
  • [11] Koçoğlu, E. S., Kublay, İ. Z., Gösterişli, T. U., Bakırdere, S., (2022) Determination of trace cadmium in seawater using combination of polystyrene coated magnetic nanoparticles based DSPE and triethylamine assisted Mg(OH)2 method. Microchemical Journal. 79 -107662.
  • [12] Usama Alshana a, Malek Hassan a, b, Mais Al-Nidawi a, Erkan Yilmaz, Mustafa SoylakSwitchable-hydrophilicity solvent liquid-liquid microextraction, Trends in Analytical Chemistry. 131 -116025.
  • [13] Kasa, N.A., Bakirdere, E.G., Bakirdere, S. A., (2020) Simple and Green Vortex-Assisted Switchable Solvent-Based Microextraction Method by Using Schiff Base Ligand Complexation for Iron Determination in Mineral Spring Water Samples Prior to Slotted Quartz Tube Flame Atomic Absorption Spectrophotometry. Water Air Soil Pollut. 231 -417. https://doi.org/10.1007/s11270-020-04754-0
  • [14] Musarurwa, H., Nikita, T. T., (2021) Switchable solvent-based micro-extraction of pesticides in food and environmental samples, Talanta. 224 -121807.
  • [15] Zhang, S., Chen, B., He, M., Hu, B., (2018) Switchable solvent based liquid phase microextraction of trace lead and cadmium from environmental and biological samples prior to graphite furnace atomic absorption spectrometry detection, Microchemical Journal. 139- 380-385.
  • [16] Soylak, M., Khan, M., Yılmaz, E., (2016) Switchable solvent based liquid phase microextraction of uranium in environmental samples: a green approach. Anal. Methods. 8 -979-986.
  • [17] Li, W., Chen, N., Huang, Z., Zeng, X., Zhu, Y., (2019) Switchable Hydrophilicity Dispersive Solvent-Based Liquid-Liquid Microextraction Coupling to High-Performance Liquid Chromatography for the Determination of Amphenicols in Food Products. Food Anal. Methods. 12 -517–525. https://doi.org/10.1007/s12161-018-1382-z
  • [18] Memon, Z.M., Yılmaz, E., Soylak, M., (2017) Switchable solvent based green liquid phase microextraction method for cobalt in tobacco and food samples prior to flame atomic absorption spectrometric determination, Journal of Molecular Liquids. 229- 459-464.
There are 18 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Makaleler
Authors

Oya Aydın Urucu 0000-0002-5055-7427

Early Pub Date December 25, 2023
Publication Date December 31, 2023
Published in Issue Year 2023 Volume: 16 Issue: 3

Cite

APA Aydın Urucu, O. (2023). An environmentally friendly microextraction method for the determination of cadmium in water samples. Erzincan University Journal of Science and Technology, 16(3), 633-642. https://doi.org/10.18185/erzifbed.1169502