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Termoplastik ve CFRP Yapıların Birleştirilmesinde Yapıştırıcı Cinsi ve Yüzey Hazırlığının Malzemenin Mekanik Dayanımı Üzerindeki Etkileri

Year 2025, Volume: 13 Issue: 2, 538 - 552, 30.06.2025
https://doi.org/10.29109/gujsc.1625639

Abstract

Kompozit malzemeler, hafiflik, dayanıklılık ve esneklikleriyle birçok endüstride tercih edilmektedir. Havacılık, otomotiv ve uzay endüstrilerinde yaygın olan karbon fiber takviyeli kompozitler, yüksek dayanım ve düşük ağırlıklarıyla dikkat çekmektedir. Yüksek basınçlı hidrojen depolama tanklarının üretiminde de sıklıkla kullanılan bu malzemeler, termoplastik ve termoset yapıların birleşim bölgelerindeki dayanımlarıyla önem kazanmaktadır. Bu çalışmada, karbon fiber epoksi kompozitlerin HDPE malzemelerle birleştirilmesinde yapıştırıcı türü ve yüzey hazırlığının mekanik dayanım üzerindeki etkileri araştırılmıştır. ASTM D5868 standardına uygun çekme testleri yapılmış, SEM analizleriyle hasar mekanizmaları incelenmiştir. Sonuçlar, DP190 yapıştırıcısının 120’lik zımpara ile, DP460’ın 180’lik zımpara ile optimum performans gösterdiğini, epoksinin ise yüksek dayanım gerektiren uygulamalarda öne çıktığını göstermiştir. Bu bulgular, Tip-IV hidrojen tanklarının güvenliğini artırmak ve endüstriyel uygulamalarda daha etkin birleştirme yöntemleri geliştirmek adına önemli bir katkı sunmaktadır.

Ethical Statement

Gerekli değil

Supporting Institution

Düzce Üniversitesi Bilimsel Araştırma Projeleri Koordinatörlüğü

Project Number

2024.06.05.1466

Thanks

Düzce Üniversitesi Bilimsel Araştırma Projeleri Koordinatörlüğü

References

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  • [35] Liu M, Lin K, Zhou M, Wallwork A, Bissett MA, Young RJ, et al. Mechanism of gas barrier improvement of graphene/polypropylene nanocomposites for new-generation light-weight hydrogen storage. Compos Sci Technol [Internet]. 2024;110483.Availablefrom:https://linkinghub.elsevier.com/retrieve/pii/S0266353824000538
  • [36] Su Y, Lv H, Feng C, Zhang C. Hydrogen permeability of polyamide 6 as the liner material of Type Ⅳ hydrogen storage tanks: A molecular dynamics investigation. Int J Hydrogen Energy. 2024;50:1598–606.
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Effects of Adhesive Type and Surface Preparation on the Mechanical Strength of Thermoplastic and CFRP Structures

Year 2025, Volume: 13 Issue: 2, 538 - 552, 30.06.2025
https://doi.org/10.29109/gujsc.1625639

Abstract

Composite materials are widely used in industries for their lightweight, durability, and flexibility. Carbon fiber-reinforced composites are particularly demanded and used in aerospace, automotive, and space industries due to their high strength and low weight. They are also critical in manufacturing high-pressure hydrogen storage tanks, where the interfacial strength between thermoplastic and thermoset materials is crucial. This study investigates the effects of adhesive type and surface preparation on the mechanical strength of carbon fiber-reinforced composites bonded with HDPE. Tensile tests were performed according to ASTM D5868, and SEM analyses were conducted to evaluate damage mechanisms. The results show that DP190 adhesive achieves optimal performance with 120-grit sanding, DP460 performs best with 180-grit sanding, and epoxy is ideal for high-strength applications. These findings contribute to enhancing the safety of Type-IV hydrogen tanks and developing more reliable bonding methods for industrial applications.

Ethical Statement

Unnecessary

Supporting Institution

Düzce University Scientific Research Projects Coordination Office

Project Number

2024.06.05.1466

Thanks

Düzce University Scientific Research Projects Coordination Office

References

  • [1]Fava RA. Polymers (1980). Part C, Physical Properties Methods of Experimental Physics ; V. 16. 1,554
  • [2] Nielsen LE. Models for the Permeability of Filled Polymer Systems. Journal of Macromolecular Science: Part A - Chemistry. 1967; 1(5):929–42.
  • [3] Cussler EL, Hughes SE, Ward WJ, Aris R. Barrier membranes. J Memb Sci. 1988; 38(2):161–74.
  • [4] Kim HM, Lee JK, Lee HS. Transparent and high gas barrier films based on poly(vinyl alcohol)/graphene oxide composites. Thin Solid Films. 2011; 519(22):7766–71.
  • [5] Sun L, Boo WJ, Clearfield A, Sue HJ, Pham HQ. Barrier properties of model epoxy nanocomposites. J Memb Sci. 2008; 318(1–2):129–36.
  • [6] Drozdov AD, Christiansen J de C. Micromechanical modeling of barrier properties of polymer nanocomposites. Compos Sci Technol. 2020; 189.
  • [7] Huang HD, Ren PG, Xu JZ, Xu L, Zhong GJ, Hsiao BS, et al. Improved barrier properties of poly(lactic acid) with randomly dispersed graphene oxide nanosheets. J Memb Sci. 2014; 464:110–8.
  • [8] Minelli M, Baschetti MG, Doghieri F. Analysis of modeling results for barrier properties in ordered nanocomposite systems. J Memb Sci. 2009; 327(1–2):208–15.
  • [9] Huang HD, Ren PG, Chen J, Zhang WQ, Ji X, Li ZM. High barrier graphene oxide nanosheet/poly(vinyl alcohol) nanocomposite films. J Memb Sci. 2012; 409–410:156–63.
  • [10] Govindaraj P, Sokolova A, Salim N, Juodkazis S, Fuss FK, Fox B, et al. Distribution states of graphene in polymer nanocomposites: A review. 2021: Vol. 226, Composites Part B: Engineering.
  • [11] Carrera MC, Erdmann E, Destéfanis HA. Barrier properties and structural study of nanocomposite of HDPE/montmorillonite modified with polyvinylalcohol. Journal of Chemistry.Vol. 2013; 1-7.
  • [12] Rueda F, Marquez A, Otegui JL, Frontini PM. Buckling collapse of HDPE liners: Experimental set-up and FEM simulations. Thin-Walled Structures. 2016; 109:103–12.
  • [13] Li X, Tabil LG, Oguocha IN, Panigrahi S. Thermal diffusivity, thermal conductivity, and specific heat of flax fiber-HDPE biocomposites at processing temperatures. Compos Sci Technol. 2008; 68(7–8):1753–8.
  • [14] Luo S, Fu J, Zhou Y, Yi C. The production of hydrogen-rich gas by catalytic pyrolysis of biomass using waste heat from blast-furnace slag. Renew Energy. 2017;101:1030–6.
  • [15] Warner M, Jeng T, Ayar S, Sekhar S, Marin D, Engler A, et al. Reduced graphene oxide catalytically enhances the rate of cyanate ester curing under variable frequency microwave heating. J Appl Polym Sci. 2023;140(21).
  • [16] Warner M, Jeng T, Ayar S, Sekhar S, Marin D, Engler A, et al. Reduced graphene oxide catalytically enhances the rate of cyanate ester curing under variable frequency microwave heating. J Appl Polym Sci. 2023;140(21).
  • [17] Ma Q, Rejab MRM, Azeem M, Hassan SA, Yang B, Kumar AP. Opportunities and challenges on composite pressure vessels (CPVs) from advanced filament winding machinery: A short communication. Int J Hydrogen Energy. 2024; 57:1364–72.
  • [18] Hu Z, Chen M, Pan B. Simulation and burst validation of 70 MPa type IV hydrogen storage vessel with dome reinforcement. Int J Hydrogen Energy. 2021;46(46):23779–94.
  • [19] Air A, Oromiehie E, Prusty BG. Design and manufacture of a Type V composite pressure vessel using automated fibre placement. Compos B Eng. 2023;266.
  • [20] Wang X, Tian M, Chen X, Xie P, Yang J, Chen J, et al. Advances on materials design and manufacture technology of plastic liner of type Ⅳ hydrogen storage vessel. Vol. 47, International Journal of Hydrogen Energy. Elsevier Ltd; 2022. p. 8382–408.
  • [21] Sharma P, Burolia AK, Adak NC, Daiya J, Sardar HH, Neogi S. Effect of tension on liner buckling and performance of a type-4 cylinder for storage of compressed gases with experimental validation. Thin-Walled Structures. 2023;189.
  • [22] Fang Q, Ji D. Molecular simulation of hydrogen permeation behavior in liner polymer materials of Type Ⅳ hydrogen storage vessels. Mater Today Commun. 2023;35.
  • [23] Condé-Wolter J, Ruf MG, Liebsch A, Lebelt T, Koch I, Drechsler K, et al. Hydrogen permeability of thermoplastic composites and liner systems for future mobility applications. Compos Part A Appl Sci Manuf. 2023;167.
  • [24] Condé-Wolter J, Ruf MG, Liebsch A, Lebelt T, Koch I, Drechsler K, et al. Hydrogen permeability of thermoplastic composites and liner systems for future mobility applications. Compos Part A Appl Sci Manuf. 2023;167.
  • [25] Hu Z, Chen M, Pan B. Simulation and burst validation of 70 MPa type IV hydrogen storage vessel with dome reinforcement. Int J Hydrogen Energy. 2021;46(46):23779–94.
  • [26] Sun Y, Lv H, Zhou W, Zhang C. Research on hydrogen permeability of polyamide 6 as the liner material for type Ⅳ hydrogen storage tank. Int J Hydrogen Energy. 2020;45(46):24980–90.
  • [27] Barthélémy H. Hydrogen storage - Industrial prospectives. Int J Hydrogen Energy. 2012;37(22):17364–72.
  • [28] Rueda F, Torres JP, Machado M, Frontini PM, Otegui JL. External pressure induced buckling collapse of high density polyethylene (HDPE) liners: FEM modeling and predictions. Thin-Walled Structures. 2015;96:56–63.
  • [29] Rueda F, Otegui JL, Frontini P. Numerical tool to model collapse of polymeric liners in pipelines. Eng Fail Anal. 2012;20:25–34.
  • [30] Bo K, Feng H, Jiang Y, Deng G, Wang D, Zhang Y. Study of blister phenomena on polymer liner of type IV hydrogen storage cylinders. Int J Hydrogen Energy. 2024;54:922–36.
  • [31] Huang HD, Ren PG, Xu JZ, Xu L, Zhong GJ, Hsiao BS, et al. Improved barrier properties of poly(lactic acid) with randomly dispersed graphene oxide nanosheets. J Memb Sci. 2014;464:110–8.
  • [32] Bo K, Feng H, Jiang Y, Deng G, Wang D, Zhang Y. Study of blister phenomena on polymer liner of type IV hydrogen storage cylinders. Int J Hydrogen Energy. 2024;54:922–36.
  • [33] Blanc-Vannet P, Papin P, Weber M, Renault P, Pepin J, Lainé E, et al. Sample scale testing method to prevent collapse of plastic liners in composite pressure vessels. Int J Hydrogen Energy. 2019;8682–91.
  • [34] Mariscal G, Depcik C, Chao H, Wu G, Li X. Technical and economic feasibility of applying fuel cells as the power source of unmanned aerial vehicles. Energy Convers Manag. 2024;301.
  • [35] Liu M, Lin K, Zhou M, Wallwork A, Bissett MA, Young RJ, et al. Mechanism of gas barrier improvement of graphene/polypropylene nanocomposites for new-generation light-weight hydrogen storage. Compos Sci Technol [Internet]. 2024;110483.Availablefrom:https://linkinghub.elsevier.com/retrieve/pii/S0266353824000538
  • [36] Su Y, Lv H, Feng C, Zhang C. Hydrogen permeability of polyamide 6 as the liner material of Type Ⅳ hydrogen storage tanks: A molecular dynamics investigation. Int J Hydrogen Energy. 2024;50:1598–606.
  • [37] Sapre S, Pareek K, Vyas M. Investigation of structural stability of type IV compressed hydrogen storage tank during refueling of fuel cell vehicle. Energy Storage. 2020;2(4).
  • [38] Liu G, Zhang X, Yang Z, Wang L, Yang F, Wang R. Effects of interfaces and ordered microstructures on thermal properties of graphene flakes/polyethylene composites. Polym Compos. 2023;44(2):1371–80.
  • [39] Blanco-Aguilera R, Martinez-Agirre M, Berasategi J, Penalba M, Bou-Ali MM, Shevtsova V. Effect of liner thermal properties and liner pre-cooling on the thermal management of fast-filling of hydrogen tanks. Int J Hydrogen Energy. 2024;52:1159–72.
  • [40] Drozdov AD, Christiansen J de C. Micromechanical modeling of barrier properties of polymer nanocomposites. Compos Sci Technol. 2020;189.
  • [41] Balasooriya W, Clute C, Schrittesser B, Pinter G. A Review on Applicability, Limitations, and Improvements of Polymeric Materials in High-Pressure Hydrogen Gas Atmospheres. Vol. 62, Polymer Reviews. Taylor and Francis Ltd.; 2022. p. 175–209.
  • [42] K. Nemani et al., “Surface Modification: Surface Modification of Polymers: Methods and Applications (Adv. Mater. Interfaces 24/2018),” Adv. Mater. Interfaces, vol.5,2018, doi: 10.1002/admi.201870121.
  • [43] E. M. Liston, M. L., and M. R. and Wertheimer, “Plasma surface modification of polymers for improved adhesion: a critical review,” J. Adhes. Sci. Technol., vol. 7, no. 10, pp. 1091–1127, 1993, doi: 10.1163/156856193X00600.
  • [44] Pizzi, A., & Mittal, K.L. (Eds.). (2003). Handbook of Adhesive Technology, Revised and Expanded (2nd ed.). CRC Press. https://doi.org/10.1201/9780203912225
  • [45] E. M. Petrie, Epoxy Adhesive Formulations. in McGraw Hill professional. McGraw Hill LLC, 2005; [Online]. Available: https://books.google.com.tr/books?id=738MPfO5FEkC
  • [46] A. J. Kinloch, Adhesion and adhesives: science and technology. Springer Science & Business Media, 1987;
  • [47] Yudhanto, Arief & Alfano, Marco & Lubineau, Gilles. Surface preparation strategies in secondary bonded thermoset-based composite materials: A review. Composites Part A Applied Science and Manufacturing. 2021; 147. 106443. 10.1016/j.compositesa.2021.106443.
  • [48] Nasiry Khanlar L, Revilla-León M, Barmak AB, Ikeda M, Alsandi Q, Tagami J, Zandinejad A. Surface roughness and shear bond strength to composite resin of additively manufactured interim restorative material with different printing orientations. J Prosthet Dent. 2023 May;129(5):788-795. doi: 10.1016/j.prosdent.2021.08.010. Epub 2021 Oct 1. PMID: 34602276.
  • [49] Budhe, S., Ghumatkar, A., Birajdar, N. et al. Effect of surface roughness using different adherend materials on the adhesive bond strength. Appl Adhes Sci 3, 20 2015; https://doi.org/10.1186/s40563-015-0050-4.
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There are 59 citations in total.

Details

Primary Language English
Subjects Composite and Hybrid Materials
Journal Section Tasarım ve Teknoloji
Authors

Emin Öztürk 0009-0000-4070-9661

Mert Kılınçel 0000-0001-7057-4390

Gülden Kabakçı 0000-0002-7181-4998

Ahmet Kömürcü 0009-0009-1039-094X

Project Number 2024.06.05.1466
Early Pub Date May 26, 2025
Publication Date June 30, 2025
Submission Date January 23, 2025
Acceptance Date April 6, 2025
Published in Issue Year 2025 Volume: 13 Issue: 2

Cite

APA Öztürk, E., Kılınçel, M., Kabakçı, G., Kömürcü, A. (2025). Effects of Adhesive Type and Surface Preparation on the Mechanical Strength of Thermoplastic and CFRP Structures. Gazi Üniversitesi Fen Bilimleri Dergisi Part C: Tasarım Ve Teknoloji, 13(2), 538-552. https://doi.org/10.29109/gujsc.1625639

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